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The Karaburun Peninsula, which is considered part of the Anatolide-Tauride Block of Turkey, contains clastic and carbonate sequences deposited on the northern margin of Gondwana. The Palaeozoic clastic sequence, which is intruded by the Early Triassic granitoid and tectonically overlies a Mesozoic melange sequence, can be divided into three subunits: a lower clastic subunit consisting of a sandstone-shale alternation, an upper clastic subunit consisting of black chert-bearing shales, sandstone and conglomerate, and a Permo-Carboniferous carbonate subunit. The lower Triassic Karaburun I-type granitoid has a high initial Sr-87/Sr-86 ratio (0.709021-0.709168), and low Nd-143/Nd-144 ratio (0.512004-0.512023) and epsilon Nd (-5.34 to -5.70) isotopic values. Geochronological data indicate a crystallization (intrusion) age of 247.1 +/- 2.0 Ma (Scythian). Geochemically, the acidic magmatism reflects a subduction-related continental-arc basin tectonic setting, which can be linked to the opening of the northern branch of Neo-Tethys as a continental back-arc rifting basin on the northern margin of Gondwana. This can be related to the closure through southward subduction of the Palaeotethys Ocean beneath Gondwana.
Afyon Zone, which was derived from the Anatolide-Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic basement and unconformably overlying Triassic-Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated from the underlying Silurian-Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (similar to 250 Ma) ages, which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys.
Successful delivery of the United Nations sustainable development goals and implementation of the Paris Agreement requires technologies that utilize a wide range of minerals in vast quantities. Metal recycling and technological change will contribute to sustaining supply, but mining must continue and grow for the foreseeable future to ensure that such minerals remain available to industry. New links are needed between existing institutional frameworks to oversee responsible sourcing of minerals, trajectories for mineral exploration, environmental practices, and consumer awareness of the effects of consumption. Here we present, through analysis of a comprehensive set of data and demand forecasts, an interdisciplinary perspective on how best to ensure ecologically viable continuity of global mineral supply over the coming decades.
The Garzn Complex of the Garzn Massif in SW Colombia is composed of the Vergel Granulite Unit (VG) and the Las Margaritas Migmatite Unit (LMM). Previous studies reveal peak temperature conditions for the VG of about 740 A degrees C. The present study considers the remarkable exsolution phenomena in feldspars and pyroxenes and titanium-in-quartz thermometry. Recalculated ternary feldspar compositions indicate temperatures around 900-1,000 A degrees C just at or above the ultra-high temperature-metamorphism (UHTM) boundary of granulites. The calculated temperatures range of exsolved ortho- and clinopyroxenes also supports the existence of an UHTM event. In addition, titanium-in-quartz thermometry points towards ultra-high temperatures. It is the first known UHTM crustal segment in the northern part of South America. Although a mean geothermal gradient of ca 38 A degrees C km(-1) could imply additional heat supply in the lower crust controlling this extreme of peak metamorphism, an alternative model is suggested. The formation of the Vergel Granulite Unit is supposed to be formed in a continental back-arc environment with a thinned and weakened crust behind a magmatic arc (Guapotn-Mancagua Gneiss) followed by collision. In contrast, rocks of the adjacent Las Margaritas Migmatite Unit display "normal" granulite facies temperatures and are formed in a colder lower crust outside the arc, preserved by the Guapotn-Mancagu Gneiss. Back-arc formation was followed by inversion and thickening of the basin. The three units that form the modern-day Garzn Massif, were juxtaposed upon each other during collision (at ca. 1,000 Ma) and exhumation. The collision leading to the deformation of the studied area is part of the Grenville orogeny leading to the amalgamation of Rodinia.
High-pressure/low-temperature (HP/LT) chloritoid-bearing micaschists crop out widely in the central part of northern Turkey and represent deep-seated subduction-accretionary complexes. Three peak metamorphic assemblages are identified in the area studied: (1) garnet-chloritoid-glaucophane with pseudomorphs after lawsonite; (2) chloritoid with pseudomorphs after glaucophane; and (3) chloritoid with pseudomorphs after jadeite in addition to phengite, paragonite, quartz, chlorite, rutile, and apatite. The latter is interpreted as transformation of a chloritoid + glaucophane assemblage to chloritoid + jadeite with increasing pressure; PT modeling indicates similar to 17 and 22-25 kbars for the two peak parageneses. The diversity of peak metamorphic assemblages and the PT estimates suggest that basal accretion occurred at different depths within the wedge. The depth of the basal accretion is possibly controlled by the slab-mantle decoupling depth. Stretching and thinning of the lithospheric fore arc induced by the slab rollback possibly caused shallowing of the slab-mantle decoupling depth which limited depth of the basal accretion from 70-80km to similar to 55km within the subduction channel. A slab-mantle coupling depth-controlled basal accretion may also explain the scarcity of eclogite and high-grade blueschist facies metamorphic rocks in active intraoceanic subduction zones. Because the overriding plate is young and hot in intraoceanic subductions, the slab and mantle are coupled at a relatively shallow depth before eclogitization of the oceanic crust. This prevents accretion and exhumation of eclogite along the subduction channel.
A tectonic slice of an arc sequence consisting of low-grade metavolcanic rocks and overlying metasedimentary succession is exposed in the Central Pontides north of the Izmir-Ankara-Erzincan suture separating Laurasia from Gondwana-derived terranes. The metavolcanic rocks mainly consist of basaltic andesite/andesite and mafic cognate xenolith-bearing rhyolite with their pyroclastic equivalents, which are interbedded with recrystallized pelagic limestone and chert. The metasedimentary succession comprises recrystallized micritic limestone with rare volcanogenic metaclastic rocks and stratigraphically overlies the metavolcanic rocks. The geochemistry of the metavolcanic rocks indicates an arc setting evidenced by depletion of HFSE (Ti, P and Nb) and enrichment of fluid mobile LILE. Identical trace and rare earth elements compositions of basaltic andesites/andesites and rhyolites suggest that they are cogenetic and derived from a common parental magma. The arc sequence crops out between an Albian-Turonian subduction-accretionary complex representing the Laurasian active margin and an ophiolitic melange. Absence of continent derived detritus in the arc sequence and its tectonic setting in a wide Cretaceous accretionary complex suggest that the Kosdag Arc was intra-oceanic. Zircons from two metarhyolite samples give Late Cretaceous (93.8 +/- 1.9 and 94.4 +/- 1.9 Ma) U/Pb ages. These ages are the same as the age of the supra-subduction ophiolites in western Turkey, which implies that that the Kosdag Arc may represent part of the incipient arc formed during the generation of the supra-subduction ophiolites. The low-grade regional metamorphism in the Kosdag Arc is constrained to 69.9 +/- 0.4 Ma by Ar-40/Ar-39 muscovite dating indicating that the arc sequence became part of a wide Tethyan Cretaceous accretionary complex by the latest Cretaceous. Non-collisional cessation of the arc volcanism is possibly associated with southward migration of the magmatism as in the Izu-Bonin-Mariana arc system. (c) 2015 Elsevier Ltd. All rights reserved.
Albian-Turonian subduction-accretionary complexes are exposed widely in the Central Pontides. A major portion of the accretionary complexes is made up of a metaflysch sequence consisting of slate/phyllite and metasandstone intercalation with blocks of marble, Na-amphibole bearing metabasite, and serpentinite. The metaflysch sequence represents distal parts of a large Lower Cretaceous submarine turbidite fan deposited on the Laurasian active continental margin that was subsequently accreted and metamorphosed during the Albian. Raman spectra of carbonaceous material of the metapelitic rocks revealed that the metaflysch consists of metamorphic packets with distinct peak metamorphic temperatures. The majority of the metapelites are low-temperature (ca. 330 degrees C) slates characterized by lack of differentiation of the graphite (G) and D2 defect bands. They possibly represent offscraped distal turbidites along the toe of the Albian accretionary wedge. Other phyllites are characterized by a slightly pronounced G band with a D2 defect band occurring on its shoulder. Peak metamorphic temperatures of these phyllites are constrained to 370-385 degrees C. The phyllites are associated with a strip of incipient blueschist facies metabasites and are found as a sliver within the offscraped distal turbidites. We interpret the phyllites as underplated continental sediments together with oceanic crustal basalt along the basal decollement. Tectonic emplacement of the underplated rocks into the offscraped distal turbidites was possibly achieved by out-of-sequence thrusting causing tectonic thickening and uplift of the wedge.