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We present a nonparametric way to retrieve an additive system of differential equations in embedding space from a single time series. These equations can be treated with dynamical systems theory and allow for long-term predictions. We apply our method to a modified chaotic Chua oscillator in order to demonstrate its potential
The internet offers citizens new possibilities to participate in political communication by setting topics on the agenda of public discussion that are neglected by the conventional media. The article examines if and how the topics of the new emerging political public on the web differ from the topics generated by traditional media. The empirical analysis reveals that the topics are mostly the same. However, the analysis also shows that a clear separate public sphere exists that deals with topics outside the political mainstream.
An expansion for a class of functions is called stable if the partial sums are bounded uniformly in the class. Stable expansions are of key importance in numerical analysis where functions are given up to certain error. We show that expansions in homogeneous functions are always stable on a small ball around the origin, and evaluate the radius of the largest ball with this property.
A new synthesis of 9 alpha-hydroxy-alpha-agarofuran (6 alpha) is described, using a microbiological hydroxylation alpha-agarofuran (5) as the key reaction. The stereochemistry of the biohydroxylation was determined on the basis of a NOESY-experiment and GIAO calculations at the B3LYP/cc-pVDZ level. A strong gamma-effect was observed at C15 of the agarofuran ring which was correctly predicted by the GIAO-B3LYP calculations
In order to investigate the temporal characteristics of cognitive processing, we apply multivariate phase synchronization analysis to event-related potentials. The experimental design combines a semantic incongruity in a sentence context with a physical mismatch (color change). In the ERP average, these result in an N400 component and a P300-like positivity, respectively. Synchronization analysis shows an effect of global desynchronization in the theta band around 288 ms after stimulus presentation for the semantic incongruity, while the physical mismatch elicits an increase of global synchronization in the alpha band around 204 ms. Both of these effects clearly precede those in the ERP aver-age. Moreover, the delay between synchronization effect and ERP component correlates with the complexity Of the cognitive processes. (C) 2005 Lippincott Williams Wilkins
In order to investigate the temporal characteristics of cognitive processing, we apply multivariate phase synchronization analysis to event-related potentials. The experimental design combines a semantic incongruity in a sentence context with a physical mismatch (color change). In the ERP average, these result in an N400 component and a P300-like positivity, respectively. The synchronization analysis shows an effect of global desynchronization in the theta band around 288ms after stimulus presentation for the semantic incongruity, while the physical mismatch elicits an increase of global synchronization in the alpha band around 204ms. Both of these effects clearly precede those in the ERP average. Moreover, the delay between synchronization effect and ERP component correlates with the complexity of the cognitive processes.
Adsorption layers of soluble surfactants enable and govern a variety of phenomena in surface and colloidal sciences, such as foams. The ability of a surfactant solution to form wet foam lamellae is governed by the surface dilatational rheology. Only systems having a non-vanishing imaginary part in their surface dilatational modulus, E, are able to form wet foams. The aim of this thesis is to illuminate the dissipative processes that give rise to the imaginary part of the modulus. There are two controversial models discussed in the literature. The reorientation model assumes that the surfactants adsorb in two distinct states, differing in their orientation. This model is able to describe the frequency dependence of the modulus E. However, it assumes reorientation dynamics in the millisecond time regime. In order to assess this model, we designed a SHG pump-probe experiment that addresses the orientation dynamics. Results obtained reveal that the orientation dynamics occur in the picosecond time regime, being in strong contradiction with the two states model. The second model regards the interface as an interphase. The adsorption layer consists of a topmost monolayer and an adjacent sublayer. The dissipative process is due to the molecular exchange between both layers. The assessment of this model required the design of an experiment that discriminates between the surface compositional term and the sublayer contribution. Such an experiment has been successfully designed and results on elastic and viscoelastic surfactant provided evidence for the correctness of the model. Because of its inherent surface specificity, surface SHG is a powerful analytical tool that can be used to gain information on molecular dynamics and reorganization of soluble surfactants. They are central elements of both experiments. However, they impose several structural elements of the model system. During the course of this thesis, a proper model system has been identified and characterized. The combination of several linear and nonlinear optical techniques, allowed for a detailed picture of the interfacial architecture of these surfactants.
Adaptability of information systems has become a substantial competition factor. Today's insufficient methodical support for the realization of adaptability frequently leads to unused potentials of deployed information technology in enterprises. In this contribution a procedure is presented, which addresses the demand to determine the necessary adaptability of an enterprise related to its surrounding environmental environment.
The concept of adaptability has been widely recognised as research field in recent years. Business information systems play a key part in terms of business performance. Adaptability of information systems therefore is a primary goal of vendors and end-users. However, so far concepts that help to determine the adaptability of Information Systems are missing. Based on research results of the project CHANGE1 this contribution presents an integrated process model addressing the problem and a possible solution.
Für Unternehmen stellt sich immer wieder die Frage nach der Stabilität der Geschäftsprozesse. Wie flexibel bzw. wandlungsfähig müssen Unternehmensarchitekturen ausgelegt werden, damit Veränderungen in der Aufbau- oder Ablauforganisation ITseitig auch in Zukunft gefolgt werden kann? Dazu wird im folgenden Beitrag das Paradigma Wandlungsfähigkeit als Gestaltungsziel von Unternehmensarchitekturen charakterisiert und der Zusammenhang zwischen Veränderungen des Umfeldes eines Unternehmens und erforderlicher Anpassungsfähigkeit der Informationssysteme erläutert.
Wandlungsfähigkeit von Informationssystemen ist zu einem wesentlichen Wettbewerbsfaktor geworden. Die derzeit unzureichende methodische Unterstützung zur Umsetzung von Wandlungsfähigkeit führt in Unternehmen häufig zu ungenutzten Potentialen einer leistungsfähigen Struktur durch die eingesetzte Informationstechnologie. Ziel des Forschungsprojektes CHANGE ist es, Methoden und Vorgehensmodelle zu entwickeln, die eine dauerhafte Wandlungsfähigkeit von Informationssystemen unterstützen. Dazu wird im Rahmen dieses Beitrages ein Verfahren vorgestellt, welches der Forderung zur Ermittlung der notwendigen Wandlungsfähigkeit unter Einbeziehung des Unternehmensumfeldes nachkommt. Als wesentliches Ergebnis wird ein Kennzahlensystem entwickelt, das zum einen die Umweltsituation als Indikator für den Wandlungsdruck eines Unternehmens beschreibt. Im nächsten Schritt werden Kriterien zur Ermittlung des Wandlungspotentials der eingesetzten IT herangezogen. Abschließend werden beide Dimensionen zusammengeführt und in ihrer Bedeutung für die IT Strategie eines Unternehmens interpretiert.
Andrianov, Igor V. ; Klamroth, Tillmann ; Saalfrank, Peter ; Bovensiepen, U. ; Gahl, Cornelius ; Wolf, M. M.
Recent experiments using time- and angle-resolved two-photon photoemission (2PPE) spectroscopy at metal/polar adsorbate interfaces succeeded in time-dependent analysis of the process of electron solvation. A fully quantum mechanical, two-dimensional simulation of this process, which explicitly includes laser excitation, is presented here, confirming the origin of characteristic features, such as the experimental observation of an apparently negative dispersion. The inference of the spatial extent of the localized electron states from the angular dependence of the 2PPE spectra has been found to be non-trivial and system-dependent. (C) 2005 American Institute of Physics
Apitz, Sabine E. ; Bell, Elanor M. ; Damgaard, Lars ; Gilbert, Franck ; Glud, R ; Hall, P. O. J. ; Kershaw, P. J. ; Nickel, L ; Parker, R ; Rabouille, Christophe ; Shimmield, Grahamm ; Solan, Martin ; Soltwedel, Thomas ; Spagnoli, Federico ; Witte, Ursula
The second election of President Bush is the climax of twelve years of successful activity by the Republicans. Rarely before could an American president rely on a majority in both houses of the Congress. Consequently, Bush has ever since his re-election conveyed the impression that he is committed to follow the paths he had taken during his first term at home and in international affairs without any concessions. Therefore, also his new initiatives towards Europe seem to be aimed only to improve the transatlantic atmosphere but not to develop a more cooperative American foreign policy.
Finding millisecond binary pulsars in 47 tucanae by applying the hough transformation to radio data
(2005)
Aulke, Gudrun ; Brandenburg, Silke ; Drechsler-Köhler, Beate ; Giest, Hartmut ; Haas, Wolfgang ; Hinze, Gabriele ; Höffer, Ute ; Koriller, Astrid ; Lüftner, Werner ; Müller, Uta ; Mues, Rainer ; Papstein, Gisela ; Schiepe, Axel
Aulke, Gudrun ; Brandenburg, Silke ; Drechsler-Köhler, Beate ; Giest, Hartmut ; Haas, Wolfgang ; Hinze, Gabriele ; Höffer, Ute ; Koriller, Astrid ; Lüftner, Werner ; Müller, Uta ; Mues, Rainer ; Papstein, Gisela ; Schiepe, Axel
Aulke, Gudrun ; Brandenburg, Silke ; Drechsler-Köhler, Beate ; Giest, Hartmut ; Haas, Wolfgang ; Hinze, Gabriele ; Höffer, Ute ; Koriller, Astrid ; Lüftner, Werner ; Müller, Uta ; Mues, Rainer ; Papstein, Gisela ; Schiepe, Axel
Aulke, Gudrun ; Brandenburg, Silke ; Drechsler-Köhler, Beate ; Giest, Hartmut ; Haas, Wolfgang ; Hinze, Gabriele ; Höffer, Ute ; Koriller, Astrid ; Lüftner, Werner ; Müller, Uta ; Mues, Rainer ; Papstein, Gisela ; Schiepe, Axel
Aulke, Gudrun ; Brandenburg, Silke ; Drechsler-Köhler, Beate ; Giest, Hartmut ; Haas, Wolfgang ; Hinze, Gabriele ; Höffer, Ute ; Koriller, Astrid ; Lüftner, Werner ; Müller, Uta ; Mues, Rainer ; Papstein, Gisela ; Schiepe, Axel
Aulke, Gudrun ; Brandenburg, Silke ; Drechsler-Köhler, Beate ; Giest, Hartmut ; Haas, Wolfgang ; Hinze, Gabriele ; Höffer, Ute ; Koriller, Astrid ; Lüftner, Werner ; Müller, Uta ; Mues, Rainer ; Papstein, Gisela ; Schiepe, Axel
Recent work on mutation-selection models has revealed that, under specific assumptions on the fitness function and the mutation rates, asymptotic estimates for the leading eigenvalue of the mutation-reproduction matrix may be obtained through a low-dimensional maximum principle in the limit N --> infinity (where N, or N-d with d greater than or equal to 1, is proportional to the number of types). In order to extend this variational principle to a larger class of models, we consider here a family of reversible matrices of asymptotic dimension N-d and identify conditions under which the high-dimensional Rayleigh-Ritz variational problem may be reduced to a low-dimensional one that yields the leading eigenvalue up to an error term of order 1/N. For a large class of mutation-selection models, this implies estimates for the mean fitness, as well as a concentration result for the ancestral distribution of types
The luminescence of a ladder-type methyl-poly(para-phenylene) (MeLPPP) doped with platinum-porphyrin dye PtOEP covering the concentration 10(-3)-5% by weight has been measured employing cw and transient techniques. Upon excitation into the range of absorption of the host, strong phosphorescence of the dopant is observed. Possible ways of populating the dopant triplet state are considered. (c) 2004 Elsevier B.V. All rights reserved
Der vorliegende Beitrag gibt eine Einführung in die Analyse und Optimierung wissensintensiver Geschäftsprozesse. Dazu wird die Modellierungsmethodik KMDL® vorgestellt und ein Szenario ihrer Anwendung auf wissensintensive Prozesse im Finanzdienstleistungssektor entworfen. Dies wird exemplarisch am Dienstleistungsentwicklungsprozess sowie am Kundenberatungsprozess demonstriert. Dabei werden für beide Prozesse durch den Einsatz der KMDL® erkennbare Potenzialfelder aufgezeigt und Handlungsempfehlungen entworfen.
Die zunehmend dynamische Umwelt erfordert steigende Adaptivität von Softwareentwicklungsprozessen. Dem kann durch eine Prozessgestaltung nach Methoden des geschäftsprozessorientierten Wissensmanagements und dem damit vollzogenen Paradigmenwechsel zur nachfrageorientierten Wissensverteilung begegnet werden. In diesem Beitrag wird die Analyse einer ausgewählten Instanz eines mit der KMDL-SE beschriebenen Softwareentwicklungsprozesses vorgestellt
This study concerns the Quantitative Phase Analysis (QPA) of historical bricks coming from the complex of the Great Palace of the Byzantine Emperors in Istanbul. The studied samples are characterised by different chemical compositions (low and high calcium content), variable firing temperatures and different amounts of soluble salts as damage products. In the low-Ca samples, the decrease of the phyllosilicate content (from 23.4 to 6.9 wt%) is associated to the increase of the amorphous fraction (from 24 to 48%). This clear negative correlation between the phyllosilicate content and the amorphous fraction indicates that in low-Ca systems vitrification processes are overwhelming with respect to nucleation and recrystallisation processes. By contrast, high-Ca samples present newly formed Ca(Mg) silicates (diopside from 5.7 to 27.2%; anorthite from 1.4 to 8.7%) and aluminium silicates (gehlenite only in two samples, 6.2 and 7.7%) associated to the decrease of quartz (from 27.7 to 11.5%), phyllosilicate (from 6.5% until complete break down) and amorphous (from 30 to 14%) phase fractions. These findings support the role played by the CaO(MgO) content deriving from carbonates decomposition which reacts with Al2O3 and SiO2 oxides from dehydroxylated clay minerals and quartz grains. The above results have been obtained by X-ray powder diffraction data using the combined Rietveld refinement - internal standard method in order to estimate both the crystalline and the amorphous phase fractions. In addition, the coexistence of two distinct plagioclases in high-Ca samples was modelled as follows: a primary albite, which tends to incorporate Ca during the firing process as demonstrated by the increasing of gamma crystallographic angle, and a newly formed anorthite. Finally, by difference between the X-ray fluorescence data and the chemical compositions inferred by QPA, it proved possible to roughly estimate the residual chemical composition attributable to the amorphous fraction. On the basis of our data, we believe that Rietveld refinement combined with the internal standard method represent a powerful tool to better characterise complex polycrystalline and amorphous mixture as in the case of historical bricks
The gastrointestinal glutathione peroxidase (GI-GPx, GPx2) is a selenoprotein that was suggested to act as barrier against hydroperoxide absorption but has also been implicated in the control of inflammation and malignant growth. In CaCo-2 cells, GI-GPx was induced by t-butyl hydroquinone (tBHQ) and sulforaphane (SFN), i.e., "antioxidants" known to activate the "antioxidant response element" (ARE) via electrophilic thiol modification of Keap1 in the Nrf2/ Keap1 system. The functional significance of a putative ARE in the GI-GPx promoter was validated by transcriptional activation of reporter gene constructs upon exposure to electrophiles (tBHQ, SFN, and curcumin) or overexpression of Nrf2 and by reversal of these effects by mutation of the ARE in the promoter and by overexpressed Keap1. Binding of Nrf2 to the ARE sequence in authentic gpx2 was corroborated by chromatin immunoprecipitation. Thus, the presumed natural antioxidants sulforaphane and curcumin may exert their anti-inflammatory and anticarcinogenic effects not only by induction of phase 2 enzymes but also by the up-regulation of the selenoprotein GI-GPx