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- engagement (6)
- ensemble Kalman filter (6)
- enzymes (6)
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- exposure (6)
- first passage (6)
- flexibility (6)
- food web (6)
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- function (6)
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- grain size (6)
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- history (6)
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- impact (6)
- inclusive education (6)
- index (6)
- information structure (6)
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- inversion (6)
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- quantification (6)
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- vitamin A (6)
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- Cue-based retrieval (5)
- Cultural diversity (5)
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- 4 (4)
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- academic self-concept (4)
- acceleration (4)
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- accretion, accretion disks (4)
- acid ceramidase (4)
- actin (4)
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- auxin (4)
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- conjugated polymers (4)
- construction (4)
- contrast (4)
- conversation analysis (4)
- coping (4)
- core (4)
- correlations (4)
- corruption (4)
- creep (4)
- crop production (4)
- cue-based retrieval (4)
- cyber aggression (4)
- data (4)
- data integration (4)
- database (4)
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- deposition (4)
- depressive symptoms (4)
- developmental dyscalculia (4)
- diagnostics (4)
- dialogue (4)
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- early warning (4)
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- electrostatics (4)
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- employment (4)
- energy efficiency (4)
- entropy (4)
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- precuneus (3)
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- pubertal timing (3)
- publication bias (3)
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- relatedness (3)
- relationships (3)
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- shape-memory polymer (3)
- shoot apical meristem (3)
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- similarity measures (3)
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- singularity (3)
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- standards (3)
- starch granule surface (3)
- stars: (3)
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- stars: individual (WR 6) (3)
- stars: mass loss (3)
- stars: pre-main sequence (3)
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- state (3)
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- storage (3)
- streamflow (3)
- stress memory (3)
- stress recovery (3)
- stress tolerance (3)
- stress-gradient hypothesis (3)
- striking combat sports (3)
- subdiffusion (3)
- subject-verb agreement (3)
- subjective well-being (3)
- substance use (3)
- sucrose (3)
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- sulfate reduction (3)
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- tunneling (3)
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- variance (3)
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- water dikinase (3)
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- weak ergodicity breaking (3)
- weathering (3)
- weight (3)
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- wh-movement (3)
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- wind speed (3)
- window of opportunity (3)
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- yedoma (3)
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- Öffentlichkeit (3)
- Ökonomische Bildung (3)
- (Anti)aromaticity (2)
- ) (2)
- 19. Jahrhundert (2)
- 2-deoxy-D-ribose-5-phoshphate aldolase (2)
- 2D perovskites (2)
- 2P cross section (2)
- 3D Point Clouds (2)
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- IBM (2)
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- ICT (2)
- IL-8 transcription (2)
- IMF (2)
- INOPEX (2)
- ISM (2)
- ISM: individual objects: G338.3-0.0 (2)
- Iambic (2)
- Iceland (2)
- Imageability (2)
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- Masked priming (2)
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- Mellin symbols with values in the edge calculus (2)
- Mellin transform (2)
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- Networked foresight (2)
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- Preterm birth (2)
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- Seismotectonic segmentation (2)
- Seismotectonics (2)
- Selbstwirksamkeit (2)
- Selection (2)
- Selection vs. age-class forests (2)
- Self (2)
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- differentiation (2)
- diffraction (2)
- diffusing diffusivity (2)
- digital education (2)
- digital elevation model (2)
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- digital identity (2)
- digital teaching (2)
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- digitization (2)
- dimerization (2)
- disability-adjusted life years (2)
- discharge (2)
- discourse production (2)
- disease severity (2)
- dispersion (2)
- disposition (2)
- distance scale (2)
- distributed systems (2)
- divergence (2)
- diversification (2)
- diversity climate (2)
- division of labor (2)
- division of labour (2)
- donor-acceptor systems (2)
- downstep (2)
- drainage of the catchment area (2)
- driving force (2)
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- dual GLP-1/glucagon receptor agonist (2)
- dual task (2)
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- duration (2)
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- dyes (2)
- dyes/pigments (2)
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- dynamo (2)
- dysfunction (2)
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- eHealth (2)
- eNOS (2)
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- early stopping (2)
- earthquake hazards (2)
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- earthquake modeling (2)
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- eccentric training (2)
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- ecological momentary assessment (2)
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- edge-driven convection (2)
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- effectors (2)
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- electroactive polymer (2)
- electrodes (2)
- electroencephalography (2)
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- electron-transfer (2)
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- elemental composition (2)
- elementary school (2)
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- engineering (2)
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- flowering (2)
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- interleukin-8 (2)
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- kognitive Aktivierung (2)
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- mean squared displacement (2)
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- oncology (2)
- one-carbon metabolism (2)
- online (2)
- online course (2)
- online disinhibition (2)
- ontogenesis (2)
- ontogeny (2)
- ontology (2)
- opacity (2)
- open (2)
- open clusters and associations: general (2)
- open data (2)
- open education (2)
- open innovation (2)
- open-field (2)
- operator-valued symbols (2)
- oppositions (2)
- optical imaging (2)
- optical manipulation (2)
- optical remote sensing (2)
- optical sensors (2)
- optionality (2)
- orbifolds (2)
- orchard management (2)
- orchestration (2)
- order (2)
- organ growth (2)
- organic carbon (2)
- organic chemistry (2)
- organic electronics (2)
- organization theory (2)
- organizational change (2)
- organizational reform (2)
- origins (2)
- oroclinal bending (2)
- orogenic peridotite (2)
- orogenic processes (2)
- orogeny (2)
- orographic rainfall (2)
- orthogroup (2)
- orthopedic (2)
- osmotic-pressure (2)
- osteoblast (2)
- other-race effect (2)
- outbreak (2)
- outcome measures (2)
- output analysis (2)
- overland flow (2)
- overreaching (2)
- overtraining (2)
- overuse injuries (2)
- oxidation state (2)
- oxygen heterocycles (2)
- oxygen plasma (2)
- oxygenation (2)
- p-Aminophenol (2)
- pH-responsive (2)
- pQCT (2)
- palaeoenvironmental proxies (2)
- palaeoenvironmental reconstruction (2)
- paleo-sediment (2)
- paleoceanography (2)
- paleoecology (2)
- paleovegetation (2)
- palmitoylation (2)
- panic (2)
- parafoveal preview benefit (2)
- parafoveal vision (2)
- parameter (2)
- parameterization (2)
- parameters (2)
- parasitoid (2)
- parchment (2)
- parental leave (2)
- parenting (2)
- partial least squares (2)
- particle filter (2)
- particles (2)
- particulate matter (2)
- partnership trajectories (2)
- party competition (2)
- pasture (2)
- pathway (2)
- pathways (2)
- patient education (2)
- pea (2)
- peace (2)
- peacebuilding (2)
- peacekeeping (2)
- peak height velocity (2)
- peak torque (2)
- pediatrics (2)
- peer influences (2)
- peers (2)
- pension insurance (2)
- peptide (2)
- perceived predation risk (2)
- perceived stress (2)
- perception of robots (2)
- perceptual reorganization (2)
- performance assessment (2)
- performance budget (2)
- performance information (2)
- performance measurement (2)
- periphyton (2)
- permittivity enhancement (2)
- permutation entropy (2)
- perovskite solar cell (2)
- person (2)
- personality change (2)
- personality traits (2)
- personhood (2)
- perspective taking (2)
- persulfide (2)
- pesticides (2)
- phagocytosis (2)
- pharmacokinetics (2)
- phase behavior (2)
- phase dynamics (2)
- phase morphology (2)
- phase transfer (2)
- phenolic compounds (2)
- phenology (2)
- phenomics (2)
- phenprocoumon (2)
- phosphatidylserine (2)
- phosphoglucan (2)
- phosphoproteomics (2)
- phosphorylase (2)
- photo-isomerization (2)
- photocatalysts (2)
- photochromism (2)
- photodehydro-Diels-Alder reaction (2)
- photoelectron (2)
- photogrammetry (2)
- photoisomerization (2)
- photoluminescence quenching (2)
- photon density wave spectroscopy (2)
- photonic crystals (2)
- photosensitive surfactants (2)
- photoswitches (2)
- photosynthetic rate (2)
- phreeqc (2)
- phylogenomics (2)
- physical conditioning human (2)
- physical inactivity (2)
- physical performance (2)
- physics education (2)
- physiological consequences (2)
- phytoplankton communities (2)
- pigment composition (2)
- pitch angle (2)
- planetary boundaries (2)
- planetary rings (2)
- planetary systems (2)
- planets and satellites: composition (2)
- planets and satellites: fundamental parameters (2)
- planets and satellites: gaseous planets (2)
- planets and satellites: general (2)
- plant architecture (2)
- plant invasions (2)
- plant species richness (2)
- plant traits (2)
- plant volatiles (2)
- plant-soil (belowground) interactions (2)
- plants (2)
- plasma density (2)
- plasma instabilities (2)
- plasmasphere (2)
- plasmaspheric hiss (2)
- plastid transformation (2)
- plateau (2)
- platform innovation (2)
- platinum (2)
- plausibility (2)
- playa (2)
- pluvial floods (2)
- plyometric exercise (2)
- plyometrics (2)
- polarity (2)
- policy analysis (2)
- policy reform (2)
- policy-making (2)
- political philosophy (2)
- politische Ideologie (2)
- pollinator shift (2)
- poly(epsilon-caprolactone) (2)
- polyadenylation (2)
- polyampholytes (2)
- polycystic ovary syndrome (2)
- polyelectrolytes (2)
- polyester (2)
- polyesterurethanes (2)
- polymersomes (2)
- polysemy (2)
- polystyrene-block-poly(4-vinylpyridine) (2)
- population cycles (2)
- population genetics (2)
- population growth rate (2)
- population pharmacokinetics (2)
- population size (2)
- population structure (2)
- pore pressure (2)
- porous silicon (2)
- positioning (2)
- positive solutions (2)
- possessives (2)
- post-natal (2)
- posttraumatic stress disorder (2)
- postural sway (2)
- potassium channel (2)
- power spectral analysis (2)
- pp-wave solutions (2)
- practice (2)
- pragmaticalisation (2)
- pre-activity (2)
- pre-natal (2)
- pre-school (2)
- pre-service teachers (2)
- precaution (2)
- predation (2)
- predation risk (2)
- predator (2)
- predictability (2)
- prediction error (2)
- predictive coding (2)
- predictive models (2)
- predictive systems ecology (2)
- predictors (2)
- preference (2)
- preference assessment (2)
- preference for agency (2)
- preferential flow (2)
- prefixes (2)
- prefrontal cortex (2)
- preprocessing (2)
- presidentialism (2)
- pressures (2)
- prestige (2)
- presupposition (2)
- prevalence information (2)
- printing (2)
- prior knowledge (2)
- privatization (2)
- proactive personality (2)
- proactive work behavior (2)
- probability (2)
- probability density function (2)
- problem (2)
- problem-solving (2)
- problems (2)
- process (2)
- process analytical technology (2)
- process mining (2)
- process modeling (2)
- process modelling (2)
- process simulation (2)
- process tracing (2)
- process-based model (2)
- process-based modeling (2)
- processes (2)
- product generation engineering (2)
- production planning (2)
- professional (2)
- professional knowledge (2)
- professionalization (2)
- prognosis (2)
- proliferation (2)
- prolonged grief disorder (2)
- proper motions (2)
- property rights (2)
- prosocial (2)
- prosodic cues (2)
- prosody processing (2)
- prospective (2)
- prostaglandins (2)
- protease inhibitors (2)
- protected area (2)
- protection motivation theory (2)
- protective factors (2)
- protein carbonyls (2)
- protein engineering (2)
- protein modification (2)
- protein restriction (2)
- protein search (2)
- protein translocation (2)
- protein-protein (2)
- proteomic analysis (2)
- protest (2)
- protonation (2)
- prototype-willingness-model (2)
- psychische Störungen (2)
- psycho-oncology (2)
- psychological detachment (2)
- psychological distress (2)
- psychological problems (2)
- psychological well-being (2)
- psychologinguistics (2)
- psychopathy (2)
- psychophysics (2)
- psychopower (2)
- psychosocial moderators (2)
- psychotherapeutic competencies (2)
- puberty (2)
- public (2)
- public engagement (2)
- public good (2)
- public management (2)
- public policy (2)
- public sector reform (2)
- pulling isometric muscle action (PIMA) (2)
- pulsars: individual: PSR B0833-45 (2)
- purification (2)
- qualitative content analysis (2)
- quantum (2)
- quantum field theory (2)
- quartz crystal microbalance (2)
- quasi-Fermi level splitting (2)
- quenched energy landscape (2)
- questioning solutions (2)
- radhard design (2)
- radial flow (2)
- radiation mechanisms: nonthermal (2)
- radiation therapy (2)
- radiative forcing (2)
- radiocarbon dating (2)
- radiogenic isotopes (2)
- radiography (2)
- radiosensitizers (2)
- rainfall (2)
- rainfall gradient (2)
- random diffusivity (2)
- random matrix theory (2)
- random number generation (2)
- random-walks (2)
- randomized controlled trial (2)
- range dynamics (2)
- range of motion (2)
- range size (2)
- rank (2)
- rapid test kit (2)
- rare events (2)
- rate of perceived exertion (2)
- rate of torque development (2)
- ray tracing (2)
- reactance (2)
- reaction kinetics theory (2)
- reaction monitoring (2)
- reactive transport modeling (2)
- real-time (2)
- receiver function (2)
- reciprocal class (2)
- reciprocal teaching (2)
- recollection (2)
- recollimation shocks (2)
- recombinant inbred line (2)
- recombination order (2)
- record (2)
- record linkage (2)
- recreational sport (2)
- recurrence analysis (2)
- recurrence quantification analysis (2)
- redemption (2)
- redox homeostasis (2)
- redox polymers (2)
- redox processes (2)
- redox state (2)
- reduction (2)
- reed (2)
- referential coding (2)
- reflexives (2)
- reforms (2)
- refugee youth (2)
- regional development (2)
- regional flood frequency analysis (2)
- regionalisation (2)
- register (2)
- regularity (2)
- regulations (2)
- regulatory T cells (2)
- regulatory physiology (2)
- reinforcement (2)
- relations (2)
- relationship (2)
- relationship constellations (2)
- relative pollen productivity (2)
- relaxation (2)
- relaxor-ferroelectric polymer (2)
- remission (2)
- remote teaching (2)
- renormalization Hopf algebra (2)
- replacement (2)
- repository far-field (2)
- reproducing kernel Hilbert space (2)
- reproductive strategies (2)
- reproductive success (2)
- resampling (2)
- research challenges (2)
- research framework (2)
- research priorities (2)
- research transparency (2)
- reservoir (2)
- reservoir characterization (2)
- resetting (2)
- resolution infrared-spectroscopy (2)
- resonance energy transfer (2)
- resonances (2)
- resource allocation (2)
- resource selection (2)
- restricted range (2)
- resurrection plants (2)
- retentivity (2)
- retrogressive thaw slumps (2)
- retrospective (2)
- revegetation (2)
- reversible measure (2)
- reward anticipation (2)
- rewards (2)
- rhizosphere (2)
- rhythm (2)
- ribosome assembly (2)
- rifting (2)
- ring current (2)
- ring current electrons (2)
- risk aversion (2)
- risk communication (2)
- risk governance (2)
- risk management cycle (2)
- risk perceptions (2)
- risk-factors (2)
- risks (2)
- river erosion (2)
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- river networks (2)
- rock (2)
- rock glacier (2)
- role-play (2)
- rolling averages (2)
- root morphology (2)
- root water uptake (2)
- rotational diffusion (2)
- rotifer (2)
- rules (2)
- runners (2)
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- rupture (2)
- rupturing of metal film (2)
- réchauffement planétaire (2)
- sACC (2)
- sadness (2)
- salamanders (2)
- salience (2)
- saliency (2)
- salinity (2)
- salinization (2)
- salivary alpha-amylase (2)
- salivary gland (2)
- salt (2)
- salt pan (2)
- salt structures (2)
- sample preparation (2)
- satellite data (2)
- satisfaction (2)
- savanna ecology (2)
- scaffolding (2)
- scalability (2)
- scale-dependence (2)
- scanning tunneling microscopy (2)
- scene perception (2)
- school learning (2)
- school mathematics (2)
- school quality (2)
- science (2)
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- scientific image (2)
- scoping review (2)
- scrambling (2)
- sea level (2)
- sea level rise (2)
- second chambers (2)
- second language processing (2)
- secondary prevention (2)
- secular changes (2)
- secular variation (2)
- sedentary (2)
- sediment core (2)
- sediment routing (2)
- sediment storage (2)
- sediment supply (2)
- sediment transport (2)
- sediment yield (2)
- sediments (2)
- seed (2)
- seed dispersal syndrome (2)
- seed provisioning (2)
- seismic monitoring (2)
- seismology (2)
- selective autophagy (2)
- selective laser melting (2)
- selective laser melting (SLM) (2)
- selenoprotein P (2)
- self threat (2)
- self-assembled monolayers (2)
- self-control (2)
- self-determination theory (2)
- self-disclosure (2)
- self-enhancement (2)
- self-evaluation (2)
- self-harm (2)
- self-incompatibility (2)
- self-isolation (2)
- self-objectification (2)
- self-organisation (2)
- self-perceived ability (2)
- self-regulated learning (2)
- self-report (2)
- self-similarity (2)
- self-sovereign identity (2)
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- semi-arid hydrology (2)
- semiconducting polymers (2)
- semiconductor lasers (2)
- sensor (2)
- sensor alignment (2)
- sensor data (2)
- sensor fusion (2)
- sensors and actuators (2)
- sentence parsing (2)
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- separation of powers (2)
- sequential data assimilation (2)
- serious game (2)
- serum (2)
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- sexual behavior (2)
- sexual coercion (2)
- sexual dimorphism (2)
- sexual reproduction (2)
- sexual self-esteem (2)
- sexual victimisation (2)
- shadow education (2)
- shallow structure hypothesis (2)
- shieldings (TSNMRS) (2)
- shoe (2)
- short latency response (2)
- short-read mapping (2)
- shortening (2)
- shotgun sequencing (2)
- shoulder (2)
- shrub-encroachment (2)
- sibilant (2)
- sign language (2)
- signal propagation (2)
- signalling (2)
- silica (2)
- silver (2)
- silviculture (2)
- simplicity (2)
- simulation model (2)
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- simultaneous bilingualism (2)
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- single-cell analysis (2)
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- situational strength (2)
- size (2)
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- skeletal muscle (2)
- skill (2)
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- social epistemology (2)
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- social modulation (2)
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- social network (2)
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- sodium hydroxide etching (2)
- soft errors (2)
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- soil fatigue (2)
- soil landscape (2)
- soils (2)
- solar powered light-emitting diode (2)
- solubility (2)
- solvent vapor annealing (2)
- somatic variables (2)
- source parameters (2)
- source-sink dynamics (2)
- soy protein (2)
- space use (2)
- space-charge stability (2)
- spacing (2)
- spatial autocorrelation (2)
- spatial heterogeneity (2)
- spatial scales (2)
- spatial vision (2)
- spatially explicit model (2)
- speakers (2)
- special education (2)
- species assembly (2)
- species diversity (2)
- species interactions (2)
- species recognition (2)
- specific developmental disorder (2)
- specific language impairment (2)
- specificity (2)
- specifier proteins (2)
- spectral analysis (2)
- spectroscopic ellipsometry (2)
- speech motor control (2)
- speech segmentation (2)
- speed-accuracy trade-off (2)
- speleothems (2)
- sphingomyelin (2)
- sphingosine kinase (2)
- spider silk (2)
- spin transition (2)
- spin-orbit coupling (2)
- spin-orbit interaction (2)
- split Hopkinson pressure bar (2)
- splitting (2)
- sport (2)
- sportliche Leistung (2)
- sports medicine (2)
- sprint (2)
- sprints (2)
- stable carbon isotopes (2)
- stable matching (2)
- stakeholder engagement (2)
- standard (2)
- starch granule initiation (2)
- starch granule morphology (2)
- starch granules (2)
- starch morphology (2)
- starch synthase (2)
- stars: flare (2)
- stars: individual ([HD 36486]delta Ori A) (2)
- stars: individual (gamma Cassiopeiae) (2)
- stars: individual: WR 102c (2)
- stars: individual: WR 102ka (2)
- stars: jets (2)
- stars: solar-type (2)
- stars: variables: Cepheids (2)
- starvation (2)
- statistical methods (2)
- statistical tools (2)
- stem cell adhesion (2)
- step selection (2)
- stereoselectivity (2)
- stereotypes (2)
- sterol (2)
- stimulus-response compatibility (2)
- stokes shift (2)
- storage capacity (2)
- storm surge (2)
- strain localization (2)
- strategic growth adjustment (2)
- strategy (2)
- stratification (2)
- streptavidin (2)
- stressors (2)
- strong semilattice of semigroups (2)
- structural change (2)
- structural health monitoring (2)
- structural thermodynamics (2)
- structures (2)
- students (2)
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- study designs (2)
- stumbling (2)
- style transfer (2)
- subcellular localization (2)
- subcutaneous adipose tissue (2)
- subduction initiation (2)
- subject-oriented learning (2)
- submarine (2)
- submillimetre: ISM (2)
- subsea permafrost (2)
- substituent effects (2)
- substitution effects (2)
- subsurface life (2)
- succession (2)
- sufficiency (2)
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- sulfite oxidase (2)
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- sustainability science (2)
- swallowing (2)
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- symptom checker apps (2)
- synchronization transition (2)
- synchrotron X-ray refraction radiography (2)
- synovial fluid (2)
- syrphids (2)
- systems theory (2)
- tablet (2)
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- task (2)
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- teen dating violence (2)
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- temperature dependence (2)
- temperature increase (2)
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- temporal dynamics (2)
- term (2)
- termination (2)
- terminology (2)
- terpenoids (2)
- tetrabromidocuprate(II) (2)
- tetrahedral boron (2)
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- tissue (2)
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- trace (2)
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- tree rings (2)
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- trunk cross-sectional area (2)
- tunnel vision (2)
- type specimens (2)
- type-III effector (2)
- tyramine (2)
- uPA (2)
- ubiquitin (2)
- ubiquitination (2)
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- ultrasonography (2)
- ultraviolet: stars (2)
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- upper limb (2)
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- urine (2)
- urokinase (2)
- use (2)
- user-generated content (2)
- vagueness (2)
- value chain analysis (2)
- value change (2)
- variable geometry truss (2)
- vegetation dynamics (2)
- vegetation reconstruction (2)
- vesicle (2)
- vesicles (2)
- veterinary cordon fence (2)
- video analysis (2)
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- viscoelasticity (2)
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- visual search (2)
- visual word recognition (2)
- visual world eye-tracking (2)
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- visual-world paradigm (2)
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- winter wheat (2)
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- word embeddings (2)
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- "Little Ice Age' (LIA) (1)
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- "click" chemistry (1)
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Institute
- Institut für Biochemie und Biologie (4839)
- Institut für Physik und Astronomie (4797)
- Institut für Geowissenschaften (3216)
- Institut für Chemie (2947)
- Wirtschaftswissenschaften (2063)
- Department Psychologie (2062)
- Historisches Institut (2004)
- Sozialwissenschaften (1653)
- Institut für Mathematik (1645)
- Institut für Romanistik (1599)
Mobbing an Schulen
(2016)
Das Buch beginnt mit einem ausführlichen Einblick in die Mobbing-Forschung, u. a. zu Merkmalen und Erscheinungsformen von Mobbing. Darüber hinaus werden Ursachen und Folgen von Mobbing, aber auch neue Formen wie das Cyber-Mobbing thematisiert. Im weiteren Verlauf stehen dann das Eingreifen bei und Vorbeugen von Mobbing im Mittelpunkt. Dabei werden etablierte Interventions- und Präventionsprogramme verständlich präsentiert, konkrete Empfehlungen gegeben, wie man in Mobbing-Situationen handeln kann, und Gelingensbedingungen beschrieben, wie es gar nicht erst zu Mobbing kommt. Gespickt mit vielen Fallbeispielen und einer ausführlichen Materialsammlung zum Download wird die Darstellung anschaulich und der praktische Transfer des präsentierten Wissens erleichtert.
The microstructure of permafrost ground contains clues to its formation and hence its preconditioning to future change.
We applied X-ray computed microtomography (CT) to obtain high-resolution data (Delta x = 50 mu m) of the composition of a 164 cm long permafrost core drilled in a Yedoma upland in north-eastern Siberia.
The CT analysis allowed the microstructures to be directly mapped and volumetric contents of excess ice, gas inclusions, and two distinct sediment types to be quantified. Using laboratory measurements of coarsely resolved core samples, we statistically estimated the composition of the sediment types and used it to indirectly quantify volumetric contents of pore ice, organic matter, and mineral material along the core.
We conclude that CT is a promising method for obtaining physical properties of permafrost cores which opens novel research potentials.
In contrast to molecular-dipole polymers, such as PVDF, ferroelectrets are a new class of flexible spatially heterogeneous piezoelectric polymers with dosed or open voids that act as deformable macro-dipoles after charging.
With a spectrum of manufacturing processes being developed to engineer the heterogeneous structures, ferroelectrets are made with attractive piezoelectric properties well-suited for applications, such as pressure sensors, acoustic transducers, etc.
However, the sources of the macro-dipole charges have usually been the same, microscopic dielectric barrier discharges within the voids, induced when the ferroelectrets are poled under a large electric field typically via a so-called corona poling, resulting in the separation and trapping of opposite charges into the interior walls of the voids.
Such a process is inherently self-limiting, as the reverse internal field from the macro-dipoles eventually extinguishes the microdischarges, resulting in limited density of ions and not too high overall piezoelectric performance. Here, a new method to form ferroelectrets with gigantic electroactivity is proposed and demonstrated with the aid of an external ion booster.
A laminate consisting of expanded polytetrafluoroethylene (ePTFE) and fluorinated-ethylene-propylene (FEP) was prefilled with bipolar ions produced externally by an ionizer and sequentially poled to force the separation of positive and negative ions into the open fibrous structure, rendering an impressive piezoelectric d(33)( )coefficient of 1600 pC/N-an improvement by a factor of 4 in comparison with the d(33) of a similar sandwich poled with nonenhanced corona poling.
The (pre)filling dearly increases the ion density in the open voids significantly. The charges stored in the open-cell structure stays at a high level for at least 4 months. In addition, an all-organic nanogenerator was made from an ePTFE-based ferroelectret, with conducting poly(3,4-ethylene dioxythiophene): poly(styrenesulfonate) (PEDOT: PSS) coated fabric electrodes.
When poled with this ion-boosting process, it yielded an output power twice that of a similar sample poled in a conventional corona-only process. The doubling in output power is mainly brought about by the significantly higher charge density achieved with the aid of external booster.
Furthermore, aside from the bipolar ions, extra monopolar ions can during the corona poling be blown into the open pores by using for instance a negative ionic hair dryer to produce a unipolar ePTFE-based ferroelectret with its d(33) coefficient enhanced by a factor of 3. Ion-boosting poling thus unleashes a new route to produce bipolar or unipolar open-cell ferroelectrets with highly enhanced piezoelectric response.
Hepatocytes secrete retinol-binding pro-tein 4 (RBP4) into circulation, thereby mobilizing vitamin A from the liver to provide retinol for extrahepatic tissues. Obesity and insulin resistance are associated with elevated RBP4 levels in the blood.
However, in a previous study, we observed that chronically increased RBP4 by forced Rbp4 expres-sion in the liver does not impair glucose homeostasis in mice.
Here, we investigated the effects of an acute mobilization of hepatic vitamin A stores by hepatic overexpression of RBP4 in mice.
We show that he-patic retinol mobilization decreases body fat content and enhances fat turnover. Mechanistically, we found that acute retinol mobilization increases hepatic expression and serum levels of fibroblast growth factor 21 (FGF21), which is regulated by retinol mobilization and retinoic acid in primary hepato-cytes.
Moreover, we provide evidence that the insulin-sensitizing effect of FGF21 is associated with organ-specific adaptations in retinoid homeostasis.
Taken together, our findings identify a novel cross-talk between retinoid homeostasis and FGF21 in mice with acute RBP4-mediated retinol mobilization from the liver.
For an effectively one-dimensional, semi-infinite disordered system connected to a reservoir of tracer particles kept at constant concentration, we provide the dynamics of the concentration profile.
Technically, we start with the Montroll-Weiss equation of a continuous time random walk with a scale-free waiting time density.
From this we pass to a formulation in terms of the fractional diffusion equation for the concentration profile C(x, t) in a semi-infinite space for the boundary condition C(0, t) = C-0, using a subordination approach.
From this we deduce the tracer flux and the so-called breakthrough curve (BTC) at a given distance from the tracer source.
In particular, BTCs are routinely measured in geophysical contexts but are also of interest in single-particle tracking experiments.
For the "residual' BTCs, given by 1- P(x, t), we demonstrate a long-time power-law behaviour that can be compared conveniently to experimental measurements.
For completeness we also derive expressions for the moments in this constant-concentration boundary condition.
Climate change, driven by increasing atmospheric levels of carbon dioxide (CO2), presents a significant societal challenge for the 21st century. Biotechnological approaches for microbial production of commodity chemicals and fuels offer possible solutions to re-fix CO2 from the atmosphere, thereby mitigating carbon emissions and contributing to a sustainable carbon-economy in the future. Biological CO2 fixation is also at the heart of agricultural productivity, where photosynthesis and the Calvin-Benson-Bassham cycle present promising biotechnological targets for crop improvement.
Synthetic biology allows testing metabolic solutions not known to exist in nature, which may exceed their natural counterparts in terms of efficiency. In this thesis, I explore the design of such new-to-nature metabolic pathways for biological CO2 utilization and their implementation in living cells (in vivo).
In the first chapter, I describe the development of a metabolic pathway that enables intracellular conversion of CO2 to formate, giving access to highly efficient carbon fixation routes. In nature, CO2-reduction remains restricted to anaerobic organisms and low redox potentials. Here, we introduce the “CORE cycle”, a synthetic metabolic pathway that converts CO2 to formate under fully aerobic conditions and ambient CO2 levels, using only NADPH as a reductant. We leverage this synthetic, ATP-energized pathway to overcome the thermodynamic and kinetic barriers associated with CO2-reduction. Applying rational metabolic engineering and adaptive evolution, this work demonstrates that Escherichia coli can utilize ambient CO2 as the sole source of one-carbon units and serine, achieving a first step towards novel modes of synthetic autotrophy. We further apply computational modeling to showcase the potential of the CORE cycle as a photorespiratory bypass for enhancing photosynthesis.
In the second chapter, I describe the development of the “LCM module”, a novel metabolic route for CO2-incorporating conversion of acetyl-CoA to pyruvate. This route relies on the newly uncovered, promiscuous activity of an adenosylcobalamin (B12)-dependent enzyme, which we significantly optimize through targeted hypermutation and in vivo selection strategies. The LCM module provides a shorter and more efficient pathway for acetyl-CoA assimilation compared to natural routes, offering novel opportunities for synthetic CO2 fixation.
Overall, through theoretical pathway analysis, enzyme bioprospecting, and modular metabolic engineering in E. coli, this thesis expands the solution space for biological CO2 fixation.
Optics is a core field in the curricula of secondary physics education. In this study, we present the development and validation of a test instrument in the field of optics, the ray optics in converging lenses concept inventory (ROC-CI). It was developed for and validated with middle school students, but can also be adapted for the use in higher levels of physics education.
The ROC-CI can be used as a formative or a summative assessment of students' conceptual understanding of image formation by converging lenses, assessing the following: (i) the overall understanding of fundamental concepts related to converging lenses, (ii) the understanding of specific concepts, and (iii) students' propensity for difficulties within this topic.
The initial ROC-CI consists of 16 multiple-choice items; however, one item was removed based on various quality checks.
We validated the ROC-CI thoroughly with distractor analyses, classical test theory, item response theory, structural analyses, and analyses of students' total scores at different measurement points as quantitative approaches, as well as student interviews and an expert survey as qualitative approaches. The quantitative analyses are mostly based on a dataset of N 1/4 318 middle school students who took the ROC-CI as a post-test. The student interviews were conducted with seven middle school students after they were taught the concepts of converging lenses.
The expert survey included five experts who evaluated both individual items and the test as a whole.
The analyses showed good to excellent results for the test instrument, corroborating the 15-item ROC-CI's validity and its compliance with the three foci outlined above.
We estimate the source parameters of small-magnitude earthquakes that occurred during 2008-2020 in the Irpinia faults area (southern Italy).
We apply a spectral decomposition approach to isolate the source contribution from propagation and site effects for similar to 3000 earthquakes in the local magnitude range between M-L 0 and 4.2.
We develop our analyses in three steps. First, we fit the Brune (1970) model to the nonparametric source spectra to estimate corner frequency and seismic moment, and we map the spatial distribution of stress drop across the Irpinia area.
We found stress drops in the range 0.4-8.1 MPa, with earthquakes deeper than 7 km characterized by higher average stress drop (i.e., 3.2 MPa).
Second, assuming a simple stress-release model (kanamori and Heaton, 2000), we derive fracture energy and critical slip-weakening distance. The spatial variability of stress drop and fracture energy allows us to image the present stress conditions of fault segments activated during the 23 November 1980 M-s 6.9 earthquake.
The variability of the source parameters shows clear patterns of the fault mechanical properties, suggesting that the Irpinia fault system can be divided into three main sectors, with the northern and southern ones showing different properties from the central one.
Our results agree with previous studies indicating the presence of fluids with different composition in the different sectors of the Irpinia fault system. In the third step, we compare the time evolution of source parameters with a time series of geodetic displacement recorded near the fault system.
Temporal trends in the correlation between geodetic displacement and different source parameters indicate that the poroelastic deformation perturbation generated by the karst aquifer recharge is modulating not only the occurrence rate of micro-seismicity ( D' Agostino et al., 2018) but may lead to rupture asperities with different sizes and characteristics.
Polyzwitterions are generally known for their anti-adhesive properties, including resistance to protein and cell adhesion, and overall high bio-inertness.
Yet there are a few polyzwitterions to which mammalian cells do adhere.
To understand the structural features of this behavior, a panel of polyzwitterions with different functional groups and overall degrees of hydrophobicity is analyzed here, and their physical and biological properties are correlated to these structural differences. Cell adhesion is focused on, which is the basic requirement for cell viability, proliferation, and growth.
With the here presented polyzwitterion panel, three different types of cell-surface interactions are observed: adhesion, slight attachment, and cell repellency. Using immunofluorescence methods, it is found that human keratinocytes (HaCaT) form focal adhesions on the cell-adhesive polyzwitterions, but not on the sample that has only slight cell attachment.
Gene expression analysis indicates that HaCaT cells cultivated in the presence of a non-adhesive polyzwitterion have up-regulated inflammatory and apoptosis-related cell signaling pathways, while the gene expression of HaCaT cells grown on a cell-adhesive polyzwitterion does not differ from the gene expression of the growth control, and thus can be defined as fully cell-compatible.
Electrochemical methods offer great promise in meeting the demand for user-friendly on-site devices for monitoring important parameters. The food industry often runs own lab procedures, for example, for mycotoxin analysis, but it is a major goal to simplify analysis, linking analytical methods with smart technologies. Enzyme-linked immunosorbent assays, with photometric detection of 3,3',5,5'-tetramethylbenzidine (TMB), form a good basis for sensitive detection. To provide a straightforward approach for the miniaturization of the detection step, we have studied the pitfalls of the electrochemical TMB detection. By cyclic voltammetry it was found that the TMB electrochemistry is strongly dependent on the pH and the electrode material. A stable electrode response to TMB could be achieved at pH 1 on gold electrodes. We created a smartphone-based, electrochemical, immunomagnetic assay for the detection of ochratoxin A in real samples, providing a solid basis for sensing of further analytes.
Solar filaments often erupt partially. Although how they split remains elusive, the splitting process has the potential of revealing the filament structure and eruption mechanism. Here we investigate the pre-eruption splitting of an apparently single filament and its subsequent partial eruption on 2012 September 27. The evolution is characterized by three stages with distinct dynamics. During the quasi-static stage, the splitting proceeds gradually for about 1.5 hr, with the upper branch rising at a few kilometers per second and displaying swirling motions about its axis. During the precursor stage that lasts for about 10 minutes, the upper branch rises at tens of kilometers per second, with a pair of conjugated dimming regions starting to develop at its footpoints; with the swirling motions turning chaotic, the axis of the upper branch whips southward, which drives an arc-shaped extreme-ultraviolet front propagating in a similar direction. During the eruption stage, the upper branch erupts with the onset of a C3.7-class two-ribbon flare, while the lower branch remains stable. Judging from the well-separated footpoints of the upper branch from those of the lower one, we suggest that the pre-eruption filament processes a double-decker structure composed of two distinct flux bundles, whose formation is associated with gradual magnetic flux cancellations and converging photospheric flows around the polarity inversion line.
Glaubensfragen
(2021)
Der Artikel gibt einen Überblick über die verschiedenen Phasen von siebzig Jahren christlich-jüdischer Dialog und blickt in die Zukunft. Akzeptieren Christen die Konsequenzen, die aus der Immanenz des Judentums in ihrer Religion folgen? Vor allem in zentralen Handlungsfeldern der systematischen Theologie bleibt viel Raum für Entwicklung, allen voran der Christologie.
Although distally steepened carbonate ramps have been studied by numerous researchers, the processes that control the development of these carbonate systems, including tectonics, differential carbonate production along the ramp profile, or antecedent physiography of the slopes, are an ongoing discussion. We use a stratigraphic forward model to test different hypotheses to unravel controls over distally steepened ramp development, referenced to the well-known Upper Miocene Menorca carbonate ramp (Spain). Sensitivity tests show that distally steepened ramps develop under complex interaction among accommodation, carbonate production and sediment transport parameters. Ramp slope initiation is favoured by still stands and falls of sea-level, in a setting with high-frequency sea-level fluctuations with amplitude between 20 m and 40 m. Low-frequency and higher amplitude sea-level fluctuations of about 115 m tend to form models with no significant slope development. The impact of antecedent slope on the geometry of ramps is determined by the paleoslope inclination, with flat to subhorizontal paleosurfaces resulting in ramps that mirror the antecedent slope. In contrast, steeper paleosurfaces tend to result in ramps with well-defined slopes. Our models, therefore, show that the ramp profile becomes more influenced by the depth constraints on the carbonate sediment producers than by the geometry of the underlying topography as the inclination of the paleosurface increases. The presented models also show that seagrass-dominated shallow carbonate production tends to result in steep slopes due to the low-transport characteristic imposed by seagrass trapping. This steepness can, however, be altered by the introduction of high transport sediment grains from deeper carbonate producers, which fill the slopes and more distal sections of the ramp profile.
Non-local muscle fatigue effects on muscle strength, power, and endurance in healthy individuals
(2021)
Background
The fatigue of a muscle or muscle group can produce global responses to a variety of systems (i.e., cardiovascular, endocrine, and others). There are also reported strength and endurance impairments of non-exercised muscles following the fatigue of another muscle; however, the literature is inconsistent.
Objective
To examine whether non-local muscle fatigue (NLMF) occurs following the performance of a fatiguing bout of exercise of a different muscle(s).
Design
Systematic review and meta-analysis.
Search and Inclusion
A systematic literature search using a Boolean search strategy was conducted with PubMed, SPORTDiscus, Web of Science, and Google Scholar in April 2020, and was supplemented with additional 'snowballing' searches up to September 2020. To be included in our analysis, studies had to include at least one intentional performance measure (i.e., strength, endurance, or power), which if reduced could be considered evidence of muscle fatigue, and also had to include the implementation of a fatiguing protocol to a location (i.e., limb or limbs) that differed to those for which performance was measured. We excluded studies that measured only mechanistic variables such as electromyographic activity, or spinal/supraspinal excitability. After search and screening, 52 studies were eligible for inclusion including 57 groups of participants (median sample = 11) and a total of 303 participants.
Results
The main multilevel meta-analysis model including all effects sizes (278 across 50 clusters [median = 4, range = 1 to 18 effects per cluster) revealed a trivial point estimate with high precision for the interval estimate [- 0.02 (95% CIs = - 0.14 to 0.09)], yet with substantial heterogeneity (Q((277)) = 642.3, p < 0.01), I-2 = 67.4%). Subgroup and meta-regression analyses showed that NLMF effects were not moderated by study design (between vs. within-participant), homologous vs. heterologous effects, upper or lower body effects, participant training status, sex, age, the time of post-fatigue protocol measurement, or the severity of the fatigue protocol. However, there did appear to be an effect of type of outcome measure where both strength [0.11 (95% CIs = 0.01-0.21)] and power outcomes had trivial effects [- 0.01 (95% CIs = - 0.24 to 0.22)], whereas endurance outcomes showed moderate albeit imprecise effects [- 0.54 (95% CIs = - 0.95 to - 0.14)].
Conclusions
Overall, the findings do not support the existence of a general NLMF effect; however, when examining specific types of performance outcomes, there may be an effect specifically upon endurance-based outcomes (i.e., time to task failure). However, there are relatively fewer studies that have examined endurance effects or mechanisms explaining this possible effect, in addition to fewer studies including women or younger and older participants, and considering causal effects of prior training history through the use of longitudinal intervention study designs. Thus, it seems pertinent that future research on NLMF effects should be redirected towards these still relatively unexplored areas.
Involvement in sport and exercise not only provides participants with health benefits but can be an important aspect of living a meaningful life. The COVID-19 pandemic and the temporary cessation of public life in March/April/May 2020 came with restrictions, which probably also made it difficult, if not impossible, to participate in certain types of sport or exercise. Following the philosophical position that different types of sport and exercise offer different ways of "relating to the world," this study explored (dis)continuity in the type of sport and exercise people practiced during the pandemic-related lockdown, and possible effects on mood. Data from a survey of 601 adult exercisers, collected shortly after the COVID-19 outbreak in Finland, were analyzed. Approximately one third (35%) of the participants changed their "worldmaking" and shifted to "I-Nature"-type activities. We observed worse mood during the pandemic in those who shifted from "I-Me," compared to those who had preferred the "I-Nature" relation already before the pandemic and thus experienced continuity. The clouded mood of those experiencing discontinuity may be the result of a temporary loss of "feeling at home" in their new exercise life-world. However, further empirical investigation must follow, because the observed effect sizes were small.
Mining of metabolite-protein interaction networks facilitates the identification of design principles underlying the regulation of different cellular processes. However, identification and characterization of the regulatory role that metabolites play in interactions with proteins on a genome-scale level remains a pressing task. Based on availability of high-quality metabolite-protein interaction networks and genome-scale metabolic networks, here we propose a supervised machine learning approach, called CIRI that determines whether or not a metabolite is involved in a competitive inhibitory regulatory interaction with an enzyme. First, we show that CIRI outperforms the naive approach based on a structural similarity threshold for a putative competitive inhibitor and the substrates of a metabolic reaction. We also validate the performance of CIRI on several unseen data sets and databases of metabolite-protein interactions not used in the training, and demonstrate that the classifier can be effectively used to predict competitive inhibitory interactions. Finally, we show that CIRI can be employed to refine predictions about metabolite-protein interactions from a recently proposed PROMIS approach that employs metabolomics and proteomics profiles from size exclusion chromatography in E. coli to predict metaboliteprotein interactions. Altogether, CIRI fills a gap in cataloguing metabolite-protein interactions and can be used in directing future machine learning efforts to categorize the regulatory type of these interactions.
We have directly resolved in the present work the interfacial composition during and after the interactions of a saturated atmosphere of oil vapor with soluble surfactant solutions at a planar water/air interface for the first time. Experiments were conducted on interactions of hexane vapor with solutions of alkyltrimethylammonium bromides and sodium dodecyl sulfate to observe the balance between cooperativity and competition of the components at the interface.
In all cases, hexane adsorption was strongly enhanced by the presence of the surfactant, even at bulk surfactant concentrations four orders of magnitude below the critical micelle concentration. Cooperativity of the surfactant adsorption was observed only for sodium dodecyl sulfate at intermediate bulk concentrations, yet for all four systems, competition set in at higher concentrations, as hexane adsorption reduced the surfactant surface excess. The data fully supported the complete removal of hexane from the interface following venting of the system to remove the saturated atmosphere of oil vapor.
These results help to identify future experiments that would elaborate and could explain the cooperativity of surfactant adsorption, such as on cationic surfactants with short alkyl chains and a broader series of anionic surfactants. This work holds relevance for oil recovery applications with foam, where there is a gas phase saturated with oil vapor.
Phonologie, die Lehre von der lautlichen Organisation der Sprache, ist einer der zentralen Bereiche der Sprachwissenschaft. Auch das Schriftsystem, das Gegenstand der Graphematik ist, gewinnt zunehmend an Bedeutung für Forschung und Lehre. Dieser Band informiert über Form und Funktion der wichtigsten Einheiten des gesprochenen und geschriebenen Deutschen, von den Lauten und Buchstaben über Sprech- und Schreibsilben bis hin zu phonologischen und graphematischen Wörtern, phonologischen Äußerungen und graphematischen Sätzen. In zweifarbiger Gestaltung mit Definitionen, Beispielen, Grafiken und Aufgaben. – Die 2. Auflage wurde durchgängig aktualisiert und erweitert.
The human language processing mechanism assigns a structure to the incoming materials as they unfold. There is evidence that the parser prefers some attachment types over others; however, theories of sentence processing are still in dispute over the stage at which each source of information contributes to the parsing system. The present study aims to identify the nature of initial parsing decisions during sentence processing through manipulating attachment type and verbs' argument structure. To this end, we designed a self-paced reading task using globally ambiguous constructions in Dutch. The structures included double locative prepositional phrases (PPs) where the first PP could attach both to the verb (high attachment) and the noun preceding it (low attachment). To disambiguate the structures, we presented a visual context in the form of short animation clips prior to each reading task. Furthermore, we manipulated the argument structure of the sentences using 2- and 3-argument verbs. The results showed that parsing decisions were influenced by contextual cues depending on the argument structure of the verb. That is, the visual context overcame the preference for high attachment only in the case of 2-argument verbs, while this preference persisted in structures including 3-argument verbs as represented by longer reading times for the low attachment interpretations. These findings can be taken as evidence that our language processing system actively integrates information from linguistic and non-linguistic sources from the initial stages of analysis to build up meaning. We discuss our findings in light of serial and parallel models of sentence processing.
Recent studies indicated severe decline of insect diversity and abundance across major parts of Central Europe.
Theoretical studies showed that the drivers behind biodiversity loss vary considerably over time. However, these scenarios so far have been insufficiently approved by long-term and large-scale data.
In this study we analysed the temporal trends of butterflies and Zygaenid moths across the federal state of Salzburg, northern Austria, from 1920 to 2019. Our study area covers a large variety of habitats and altitudes.
Various changes of land use and intensification occurred during and shortly before our studied period, with a first wave of habitat destruction starting in the late 19th century, followed by the deterioration of habitat quality since the mid-20th century. We used 59,870 presence-only data of 168 butterfly and burnet moth species.
Each of these species was classified according to ecological characteristics. Break point analyses for non-linear temporal trends in the community composition returned two major time windows.
These time windows coincide with periods characterized by severe habitat destruction and the deterioration of habitat quality due to agricultural intensification. We found significant reductions of the proportion of species requiring specific habitats since 1920 and until today.
We identified additional break points for species requiring high habitat qualities, endangered butterfly species, and sedentary species, particularly after a main break point in the 1960s.
Our findings underline that, apart from habitat destruction, the deterioration of habitat quality is a main driver of biodiversity loss in general.
Therefore, nature conservation should focus on maintaining the highest possible habitat quality.
Nudix hydrolase NUDT19 regulates mitochondrial function and ATP production in murine hepatocytes
(2022)
Changes in intracellular CoA levels are known to contribute to the development of non-alcoholic fatty liver disease (NAFLD) in type 2 diabetes (T2D) in human and rodents. However, the underlying genetic basis is still poorly understood.
Due to their diverse susceptibility towards metabolic diseases, mouse inbred strains have been proven to serve as powerful tools for the identification of novel genetic factors that underlie the patho-physiology of NAFLD and diabetes. Transcriptome analysis of mouse liver samples revealed the nucleoside diphosphate linked moiety X-type motif Nudt19 as novel candidate gene responsible for NAFLD and T2D development. Knockdown (KD) of Nudt19 increased mitochondrial and glycolytic ATP production rates in Hepa 1-6 cells by 41% and 10%, respectively.
The enforced utilization of glutamine or fatty acids as energy substrate reduced uncoupled respiration by 41% and 47%, respectively, in non-target (NT) siRNA transfected cells.
This reduction was prevented upon Nudt19 KD. Furthermore, incubation with palmitate or oleate respectively increased mitochondrial ATP production by 31% and 20%, and uncoupled respiration by 23% and 30% in Nudt19 KD cells, but not in NT cells.
The enhanced fatty acid oxidation in Nudt19 KD cells was accompanied by a 1.3-fold increased abundance of Pdk4.
This study is the first to describe Nudt19 as regulator of hepatic lipid metabolism and potential mediator of NAFLD and T2D development.
Due to the great potential of surface-enhanced Raman scattering (SERS) as local vibrational probe of lipid-nanostructure interaction in lipid bilayers, it is important to characterize these interactions in detail.
The interpretation of SERS data of lipids in living cells requires an understanding of how the molecules interact with gold nanostructures and how intermolecular interactions influence the proximity and contact between lipids and nanoparticles.
Ceramide, a sphingolipid that acts as important structural component and regulator of biological function, therefore of interest to probing, lacks a phosphocholine head group that is common to many lipids used in liposome models.
SERS spectra of liposomes of a mixture of ceramide, phosphatidic acid, and phosphatidylcholine, as well as of pure ceramide and of the phospholipid mixture are reported.
Distinct groups of SERS spectra represent varied contributions of the choline, sphingosine, and phosphate head groups and the structures of the acyl chains. Spectral bands related to the state of order of the membrane and moreover to the amide function of the sphingosine head groups indicate that the gold nanoparticles interact with molecules involved in different intermolecular relations.
While cryogenic electron microscopy shows the formation of bilayer liposomes in all preparations, pure ceramide was found to also form supramolecular, concentric stacked and densely packed lamellar, nonliposomal structures. That the formation of such supramolecular assemblies supports the intermolecular interactions of ceramide is indicated by the SERS data.
The unique spectral features that are assigned to the ceramide-containing lipid model systems here enable an identification of these molecules in biological systems and allow us to obtain information on their structure and interaction by SERS.
Describing the heterogeneous structure of forests is often challenging.
One possibility is to analyze forest biomass in different plots and to derive plot-based frequency distributions.
However, these frequency distributions depend on the plot size and thus are scale dependent.
This study provides insights about transferring them between scales. Understanding the effects of scale on distributions of biomass is particularly important for comparing information from different sources such as inventories, remote sensing and modeling, all of which can operate at different spatial resolutions. Reliable methods to compare results of vegetation models at a grid scale with field data collected at smaller scales are still missing.
The scaling of biomass and variables, which determine the forest biomass, was investigated for a tropical forest in Panama. Based on field inventory data from Barro Colorado Island, spanning 50 ha over 30 years, the distributions of aboveground biomass, biomass gain and mortality were derived at different spatial resolutions, ranging from 10 to 100 m. Methods for fitting parametric distribution functions were compared.
Further, it was tested under which assumptions about the distributions a simple stochastic simulation forest model could best reproduce observed biomass distributions at all scales. Also, an analytical forest model for calculating biomass distributions at equilibrium and assuming mortality as a white shot noise process was tested.
Scaling exponents of about 0.47 were found for the standard deviations of the biomass and gain distributions, while mortality showed a different scaling relationship with an exponent of 0.3. Lognormal and gamma distribution functions fitted with the moment matching estimation method allowed for consistent parameter transfers between scales. Both forest models (stochastic simulation and analytical solution) were able to reproduce observed biomass distributions across scales, when combined with the derived scaling relationships.
The study demonstrates a way of how to approach the scaling problem in model-data comparisons by providing a transfer relationship. Further research is needed for a better understanding of the mechanisms that shape the frequency distributions at the different scales.
Clusty is a new open source toolbox dedicated to earthquake clustering based on waveforms recorded across a network of seismic stations. Its main application is the study of active faults and the detection and characterization of faults and fault networks. By using a density-based clustering approach, earthquakes pertaining to a common fault can be recognized even over long fault segments, and the first-order geometry and extent of active faults can be inferred. Clusty implements multiple techniques to compute a waveform based network similarity from maximum cross-correlation coefficients at multiple stations. The clustering procedure is designed to be transparent and parameters can be easily tuned. It is supported by a number of analysis visualization tools which help to assess the homogeneity within each cluster and the differences among distinct clusters. The toolbox returns graphical representations of the results. A list of representative events and stacked waveforms facilitate further analyses like moment tensor inversion. Results obtained in various frequency bands can be combined to account for large magnitude ranges. Thanks to the simple configuration, the toolbox is easily adaptable to new data sets and to large magnitude ranges. To show the potential of our new toolbox, we apply Clusty to the aftershock sequence of the M-w 6.9 25 October 2018 Zakynthos (Greece) Earthquake. Thanks to the complex tectonic setting at the western termination of the Hellenic Subduction System where multiple faults and faulting styles operate simultaneously, the Zakynthos data set provides an ideal case-study for our clustering analysis toolbox. Our results support the activation of several faults and provide insight into the geometry of faults or fault segments. We identify two large thrust faulting clusters in the vicinity of the main shock and multiple strike-slip clusters to the east, west and south of these clusters. Despite its location within the largest thrust cluster, the main shock does not show a high waveform similarity to any of the clusters. This is consistent with the results of other studies suggesting a complex failure mechanism for the main shock. We propose the existence of conjugated strike-slip faults in the south of the study area. Our waveform similarity based clustering toolbox is able to reveal distinct event clusters which cannot be discriminated based on locations and/or timing only. Additionally, the clustering results allows distinction between fault and auxiliary planes of focal mechanisms and to associate them to known active faults.
Scanning manufacturing parameters determining the residual stress state in LPBF IN718 small parts
(2021)
The influence of scan strategy on the residual stress (RS) state of an as-built IN718 alloy produced by means of laser powder bed fusion (LPBF) is investigated. Two scan vector rotations (90 degrees-alternation and 67 degrees-rotation), each produced following two different scan vector lengths (long and short), are used to manufacture four rectangular prisms. Neutron diffraction (ND) and laboratory X-ray diffraction (XRD) techniques are used to map the bulk and surface RS state, respectively. The distortion induced upon removal from the baseplate is measured via profilometry. XRD measurements show that the two long scan vector strategies lead to higher RS when compared with the equivalent short scan vector strategies. Also, the 67 degrees-rotation strategies generate lower RS than their 90 degrees-alternation counterparts. Due to the lack of reliable stress-free d0 references, the ND results are analyzed using von Mises stress. In general, ND results show significant RS spatial non-uniformity. A comparison between ND and distortion results indicates that the RS component parallel to the building direction (Z-axis) has a predominant role in the Z-displacement. The use of a stress balance scheme allows to discuss the d0 variability along the length of the specimens, as well as examine the absolute RS state.
Impact of Late Pleistocene climate variability on paleo-erosion rates in the western Himalaya
(2022)
It has been proposed that at short timescales of 10(2)-10(5) yr, climatic variability can explain variations in sediment flux, but in orogens with pronounced climatic gradients rate changes caused by the oscillating efficiency in rainfall, runoff, and/or sediment transport and deposition are still not well-constrained.
To explore landscape responses under variable climatic forcing, we evaluate time windows of prevailing sediment aggradation and related paleo-erosion rates from the southern flanks of the Dhauladhar Range in the western Himalaya.
We compare past and present Be-10-derived erosion rates of well-dated Late Pleistocene fluvial landforms and modern river sediments and reconstruct the sediment aggradation and incision history based on new luminescence data.
Our results document significant variations in erosion rates ranging from 0.1 to 3.4 mm/yr over the Late Pleistocene.
We find that, during times of weak monsoon intensity, the moderately steep areas (hillslope angles of 27 +/- 13 degrees) erode at lower rates of 0.1-0.4 mm/yr compared to steeper (>40 degrees) crestal regions of the Dhauladhar Range that erode at 0.8-1.3 mm/yr.
In contrast, during several millennia of stronger monsoon intensity, both the moderately steep and high slope areas record higher erosion rates (>1-3.4 mm/yr). Lithological clast-count analysis shows that this increase of erosion is focused in the moderately steep areas, where Lesser Himalayan rocks are exposed.
Our data thus highlight the highly non-linear response of climatic forcing on landscape evolution and suggest complex depositional processes and sedimentary signals in downstream areas. (C) 2021 Elsevier B.V. All rights reserved.
Media discourse about Islamist terrorism can be understood as an important source for the construction of meaning and reality. This chapter aims to explore the different meanings of threat constituted by the media discourse about Islamist terrorism. Additionally, it seeks to shed light on the role of anti-Muslim stereotypes and racism in the discursive construction of meaning and knowledge. Therefore, this study examines the discourse on three terrorist events from the years 2015 and 2016 gathered from four major German newspapers. By applying the Sociology of Knowledge Approach to Discourse (SKAD), the findings reveal three interpretive schemes about threats associated with Islamist terrorism and their different references to anti-Muslim stereotypes and racism.
The current study examined the impact of the Good Behavior Game (GBG) on the academic engagement (AE) and disruptive behavior (DB) of at-risk students' in a German inclusive primary school sample using behavioral progress monitoring.
A multiple baseline design across participants was employed to evaluate the effects of the GBG on 35 primary school students in seven classrooms from grade 1 to 3 (M-age = 8.01 years, SDage = 0.81 years).
The implementation of the GBG was randomly staggered by 2 weeks across classrooms. Teacher-completed Direct Behavior Rating (DBR) was applied to measure AE and DB. We used piecewise regression and a multilevel extension to estimate the individual case-specific treatment effects as well as the generalized effects across cases.
Piecewise regressions for each case showed significant immediate treatment effects for the majority of participants (82.86%) for one or both outcome measures.
The multilevel approach revealed that the GBG improved at-risk students' classroom behaviors generally with a significant immediate treatment effect across cases (for AE, B = 0.74, p < 0.001; for DB, B = -1.29, p < 0.001).
The moderation between intervention effectiveness and teacher ratings of students' risks for externalizing psychosocial problems was significant for DB (B = -0.07, p = 0.047) but not for AE.
Findings are consistent with previous studies indicating that the GBG is an appropriate classroom-based intervention for at-risk students and expand the literature regarding differential effects for affected students.
In addition, the study supports the relevance of behavioral progress monitoring and data-based decision-making in inclusive schools in order to evaluate the effectiveness of the GBG and, if necessary, to modify the intervention for individual students or the whole group.
The efficient use of natural resources is considered a necessary condition for their sustainable use. Extending the lifetime of products and using resources circularly are two popular strategies to increase the efficiency of resource use.
Both strategies are usually assumed to contribute to the eco-efficiency of resource use independently.
We argue that a move to a circular economy creates opportunity costs for consumers holding on to their products, due to the resource embedded in the product. Assuming rational consumers, we develop a model that determines optimal replacement times for products subject to minimizing average costs over time.
We find that in a perfectly circular economy, consumers are incentivized to discard their products more quickly than in a perfectly linear economy.
A direct consequence of our finding is that extending product use is in direct conflict with closing resource loops in the circular economy.
We identify the salvage value of discarded products and technical progress as two factors that determine the impact that closing resource loops has on the duration of product use. The article highlights the risk that closing resource loops and moving to a more circular economy incentivizes more unsustainable behavior.
Bastnsite [REE(CO3)F] is the main mineral of REE ore deposits in carbonatites. Synthetic bastnsite-like compounds were precipitated from aqueous solutions by many different methods, but previous attempts to model magmatic crystallization of bastnsite from hydrous calciocarbonatite melts were unsuccessful.
Here we present the first experimental evidence that bastnsite and two other REE carbonates, burbankite, and lukechangite, can crystallize from carbonatite melt in the synthetic system La(CO3)F-CaCO3-Na2CO3 at temperatures between 580 and 850 degrees C and a pressure 100 MPa.
The experiments on starting mixtures of reagent-grade CaCO3, Na2CO3, La-2(CO3)(3), and LaF3 were carried out in cold-seal rapid-quench pressure vessels.
The studied system is an isobaric pseudoternary join of a quinary system where CO2 and fluorides act as independent components. Liquidus phases in the run products are calcite, nyerereite, Na carbonate, bastnsite, burbankite solid solution (Na,Ca)(3)(Ca,La)(3)(CO3)(5), and lukechangite Na3La2(CO3)(4)F. Calcite and bastnite form a eutectic in the boundary join La(CO3)F-CaCO3 at 780 +/- 20 degrees C and 58 wt% La(CO3)F. Phase equilibria in the boundary join La(CO3)F-Na2CO3 are complicated by peritectic reaction between Ca-free end-member of burbankite solid solution petersenite (Pet) and lukechangite (Luk) with liquid (L): Na4La2(CO3)(5) (Pet) + NaF (L) = Na3La2(CO3)(4)F (Luk) + Na2CO3 (Nc).
The right-hand-side assemblage becomes stable below 600 +/- 20 degrees C. In ternary mixtures, bastnsite (Bst), burbankite (Bur), and calcite (Cc) are involved in another peritectic reaction: 2La(CO3)F (Bst) + CaCO3 (Cc) + 2Na(2)CO(3) (L) = Na2CaLa2(CO3)(5) (Bur) + 2NaF (L). Burbankite in equilibrium with calcite replaces bastnsite below 730 +/- 20 degrees C. Stable solidus assemblages in the pseudoternary system are: basnsite-burbankite-fluorite-calcite, basnasite-burbankite-fluorite-lukechangite, bastnsite-burbankite-lukechangite, burbankite-lukechangite-nyerereitecalcite, and burbankite-lukechangite-nyerereite-natrite. Addition of 10 wt% Ca-3(PO4)(2) to one of the ternary mixtures resulted in massive crystallization of La-bearing apatite and monazite and complete disappearance of bastnsite and burbankite.
Our results confirm that REE-bearing phosphates are much more stable than carbonates and fluorocarbonates.
Therefore, primary crystallization of the latter from common carbonatite magmas is unlikely. Possible exceptions are carbonatites at Mountain Pass that are characterized by very low P2O5 concentrations (usually at or below 0.5 wt%) and extremely high REE contents in the order of a few weight percent or more. In other carbonatites, bastnsite and burbankite probably crystallized from highly concentrated alkaline carbonate-chloride brines that were found in melt inclusions and are thought to be responsible for widespread fenitization around carbonatite bodies.
Objective:
Little attention has been given to the relationship between cyber polyvictimization and academic outcomes (e.g., classroom misconduct, school readiness, academic performance, absenteeism, school behavioral problems), and the factors, such as parent social support, that buffer against the negative outcomes associated with experiencing multiple forms of victimization. Addressing gaps in the literature by including a longitudinal design and objective assessments of academic outcomes, the present study examined the moderating effect of parent social support in the association between cyber polyvictimization and academic outcomes over one and a half years later.
Method:
Participants were 371 8th graders (50% female) from middle schools in the United States, who completed questionnaires on offline and cyber polyvictimization and parent social support during the 7th grade. Teachers completed questionnaires on students' classroom misconduct and school readiness during 7th and 8th grade. School records were used to determine absenteeism, academic performance, and school behavioral problems (i.e., referrals, in-school suspension, out-of-school suspension) during 7th and 8th grade.
Results:
Findings revealed that 7th grade cyber polyvictimization was related positively to 8th grade classroom misconduct, absenteeism, and school behavioral problems, while it was negatively associated with 8th grade academic performance and school readiness. Parent social support moderated the associations between cyber polyvictimization and school readiness, academic performance, and absenteeism. Conclusion: The results highlight the importance of intervening in adolescents' experience of cyber polyvictimization to reduce negative academic outcomes.
Fractional Brownian motion, a Gaussian non-Markovian self-similar process with stationary long-correlated increments, has been identified to give rise to the anomalous diffusion behavior in a great variety of physical systems. The correlation and diffusion properties of this random motion are fully characterized by its index of self-similarity or the Hurst exponent.
However, recent single-particle tracking experiments in biological cells revealed highly complicated anomalous diffusion phenomena that cannot be attributed to a class of self-similar random processes.
Inspired by these observations, we here study the process that preserves the properties of the fractional Brownian motion at a single trajectory level; however, the Hurst index randomly changes from trajectory to trajectory.
We provide a general mathematical framework for analytical, numerical, and statistical analysis of the fractional Brownian motion with the random Hurst exponent.
The explicit formulas for probability density function, mean-squared displacement, and autocovariance function of the increments are presented for three generic distributions of the Hurst exponent, namely, two-point, uniform, and beta distributions.
The important features of the process studied here are accelerating diffusion and persistence transition, which we demonstrate analytically and numerically.
The chaotic spatio-temporal electrical activity during life-threatening cardiac arrhythmias like ventricular fibrillation is governed by the dynamics of vortex-like spiral or scroll waves. The organizing centers of these waves are called wave tips (2D) or filaments (3D) and they play a key role in understanding and controlling the complex and chaotic electrical dynamics. Therefore, in many experimental and numerical setups it is required to detect the tips of the observed spiral waves. Most of the currently used methods significantly suffer from the influence of noise and are often adjusted to a specific situation (e.g. a specific numerical cardiac cell model). In this study, we use a specific type of deep neural networks (UNet), for detecting spiral wave tips and show that this approach is robust against the influence of intermediate noise levels. Furthermore, we demonstrate that if the UNet is trained with a pool of numerical cell models, spiral wave tips in unknown cell models can also be detected reliably, suggesting that the UNet can in some sense learn the concept of spiral wave tips in a general way, and thus could also be used in experimental situations in the future (ex-vivo, cell-culture or optogenetic experiments).
Background & aims:
This study aimed to describe the association of healthy eating literacy (HEL) with energy, nutrients, and food consumption in young women who had normal and lean weight at a Japanese university, considering their resident status.
Methods:
Cross-sectional data from the Ochanomizu Health Study were used in this study. Participants answered a self-administered, two-part, anonymous survey in 2018 and 2019.
A total of 203 female undergraduate students with lean and normal body mass index (BMI) were included in the analysis. Single and stepwise multiple linear regression analysis was used to examine the association of HEL and resident status with healthy food consumption, such as vegetables, fish, and shellfish.
The dependent variables were HEL and resident status, and the covariates were age, BMI, and the total metabolic equivalents.
Results:
The median (25th and 75th percentiles) age, BMI, and total HEL score were 20 (19, 21) years, 20.2 (18.9, 21.3) kg/m 2, and 18 (16, 20), respectively.
Resident status and HEL were independently associated with vegetables, fish, and shellfish intake.
Participants who had higher total HEL scores and lived in their family home consumed significantly more vegetables (b = 0.17 and-0.34, p < 0.05) and fish and shellfish (b = 0.24,-0.28, p < 0.001).
Conclusion:
This study provides an insight into the association between HEL and dietary consumption in young women with normal and lean BMI.
Cosmic-ray (CR) diffusion is the result of the interaction of such charged particles against magnetic fluctuations. These fluctuations originate from large-scale turbulence cascading toward smaller spatial scales, decomposed into three different modes, as described by magnetohydrodynamics (MHD) theory.
As a consequence, the description of particle diffusion strongly depends on the model describing the injected turbulence.
Moreover, the amount of energy assigned to each of the three modes is, in general, not equally divided, which implies that diffusion properties might be different from one region to another.
Here, motivated by the detection of different MHD modes inside the Cygnus-X star-forming region, we study the 3D transport of CRs injected by two prominent sources within a two-zone model that represents the distribution of the modes.
Then, by convolving the propagated CR distribution with the neutral gas, we are able to explain the 𝛾-ray diffuse emission in the region, observed by the Fermi-LAT and HAWC Collaborations.
Such a result represents an important step in the long-standing problem of connecting the CR observables with the microphysics of particle transport.
Organic-inorganic composite materials with tailored properties can be designed in the lab through bioinspired approaches.
In this context, we exploited the particle-based crystallisation process of calcium sulfate, a technologically important mineral, to hybridise inorganic and organic matter.
We identified and synthesised an organic polymer showing strong affinity to bind to the surfaces of mineral precursors as well as intrinsic tendency to self-organise. Subsequently, polymer-coated building units were allowed to self-assemble via oriented attachment, aggregation and phase transformation, which produced ordered superstructures where the organic polymer is intercalated between the subunits and surrounds the hybrid core as a shell.
This specific architecture across multiple length scales leads to unique mechanical properties, comparable to those of natural biominerals.
Thus, our results devise a straightforward pathway to prepare organic-inorganic hybrid structures via bottom-up self-assembly processes innate to the crystallisation of the inorganic phase.
This approach can likely be transferred to other inorganic minerals, affording next-generation materials for applications in the construction sector, biomedicine and beyond.
Evolutionary reduction of adult body size (miniaturization) has profound consequences for organismal biology and is an important subject of evolutionary research. Based on two individuals we describe a new, extremely miniaturized chameleon, which may be the world's smallest reptile species. The male holotype of Brookesia nana sp. nov. has a snout-vent length of 13.5 mm (total length 21.6 mm) and has large, apparently fully developed hemipenes, making it apparently the smallest mature male amniote ever recorded. The female paratype measures 19.2 mm snout-vent length (total length 28.9 mm) and a micro-CT scan revealed developing eggs in the body cavity, likewise indicating sexual maturity. The new chameleon is only known from a degraded montane rainforest in northern Madagascar and might be threatened by extinction. Molecular phylogenetic analyses place it as sister to B. karchei, the largest species in the clade of miniaturized Brookesia species, for which we resurrect Evoluticauda Angel, 1942 as subgenus name. The genetic divergence of B. nana sp. nov. is rather strong (9.914.9% to all other Evoluticauda species in the 16S rRNA gene). A comparative study of genital length in Malagasy chameleons revealed a tendency for the smallest chameleons to have the relatively largest hemipenes, which might be a consequence of a reversed sexual size dimorphism with males substantially smaller than females in the smallest species. The miniaturized males may need larger hemipenes to enable a better mechanical fit with female genitals during copulation. Comprehensive studies of female genitalia are needed to test this hypothesis and to better understand the evolution of genitalia in reptiles.
The desiccation of the Aral Sea represents one of the largest human-made environmental regional disasters. The salt- and toxin-enriched dried-out basin provides a natural laboratory for studying ecosystem functioning and rhizosphere assembly under extreme anthropogenic conditions.
Here, we investigated the prokaryotic rhizosphere communities of the native pioneer plant Suaeda acuminata (C.A.Mey.) Moq. in comparison to bulk soil across a gradient of desiccation (5, 10, and 40 years) by metagenome and amplicon sequencing combined with quantitative PCR (qPCR) analyses. The rhizosphere effect was evident due to significantly higher bacterial abundances but less diversity in the rhizosphere compared to bulk soil. Interestingly, in the highest salinity (5 years of desiccation), rhizosphere functions were mainly provided by archaeal communities.
Along the desiccation gradient, we observed a significant change in the rhizosphere microbiota, which was reflected by (i) a decreasing archaeon-bacterium ratio, (ii) replacement of halophilic archaea by specific plant-associated bacteria, i.e., Alphaproteobacteria and Actinobacteria, and (iii) an adaptation of specific, potentially plant-beneficial biosynthetic pathways.
In general, both bacteria and archaea were found to be involved in carbon cycling and fixation, as well as methane and nitrogen metabolism.
Analysis of metagenome-assembled genomes (MAGs) showed specific signatures for production of osmoprotectants, assimilatory nitrate reduction, and transport system induction.
Our results provide evidence that rhizosphere assembly by cofiltering specific taxa with distinct traits is a mechanism which allows plants to thrive under extreme conditions. Overall, our findings highlight a function-based rhizosphere assembly, the importance of plant-microbe interactions in salinated soils, and their exploitation potential for ecosystem restoration approaches.IMPORTANCE
The desertification of the Aral Sea basin in Uzbekistan and Kazakhstan represents one of the most serious anthropogenic environmental disasters of the last century. Since the 1960s, the world's fourth-largest inland body of water has been constantly shrinking, which has resulted in an extreme increase of salinity accompanied by accumulation of many hazardous and carcinogenic substances, as well as heavy metals, in the dried-out basin.
Here, we investigated bacterial and archaeal communities in the rhizosphere of pioneer plants by combining classic molecular methods with amplicon sequencing as well as metagenomics for functional insights.
By implementing a desiccation gradient, we observed (i) remarkable differences in the archaeon-bacterium ratio of plant rhizosphere samples, (ii) replacement of archaeal indicator taxa during succession, and (iii) the presence of specific, potentially plant-beneficial biosynthetic pathways in archaea present during the early stages.
In addition, our results provide hitherto-undescribed insights into the functional redundancy between plant-associated archaea and bacteria.
The desertification of the Aral Sea basin in Uzbekistan and Kazakhstan represents one of the most serious anthropogenic environmental disasters of the last century.
Since the 1960s, the world's fourth-largest inland body of water has been constantly shrinking, which has resulted in an extreme increase of salinity accompanied by accumulation of many hazardous and carcinogenic substances, as well as heavy metals, in the dried-out basin.
From June to August 2021, we deployed a dense seismic nodal network across the Hengill geothermal area in southwest Iceland to image and characterize faults and high-temperature zones at high resolution.
The nodal network comprised 498 geophone nodes spread across the northern Nesjavellir and southern Hverahlio geothermal fields and was complemented by an existing permanent and temporary backbone seismic network of a total of 44 short-period and broadband stations.
In addition, we recorded distributed acoustic sensing data along two fiber optic telecommunication cables near the Nesjavellir geothermal power plant with commercial interrogators.
During the time of deployment, a vibroseis survey took place around the Nesjavellir power plant.
Here, we describe the network and the recorded datasets.
Furthermore, we showsome initial results that indicate a high data quality and highlight the potential of the seismic records for various follow up studies, such as high-resolution event location to delineate faults and body- and surface-wave tomographies to image the subsurface velocity structure in great detail.
Lakes act as important sinks for inorganic and organic sediment components. However, investigations of sedimentary carbon budgets within glacial lakes are currently absent from Arctic Siberia. The aim of this paper is to provide the first reconstruction of accumulation rates, sediment and carbon budgets from a lacustrine sediment core from Lake Rauchuagytgyn, Chukotka (Arctic Siberia). We combined multiple sediment biogeochemical and sedimentological parameters from a radiocarbon-dated 6.5m sediment core with lake basin hydroacoustic data to derive sediment stratigraphy, sediment volumes and infill budgets. Our results distinguished three principal sediment and carbon accumulation regimes that could be identified across all measured environmental proxies including early Marine Isotope Stage 2 (MIS2) (ca. 29-23.4 ka cal BP), mid-MIS2-early MIS1 (ca. 23.4-11.69 ka cal BP) and the Holocene (ca. 11.69-present). Estimated organic carbon accumulation rates (OCARs) were higher within Holocene sediments (average 3.53 gOCm(-2) a(-1)) than Pleistocene sediments (average 1.08 gOCm(-2) a(-1)) and are similar to those calculated for boreal lakes from Quebec and Finland and Lake Baikal but significantly lower than Siberian thermokarst lakes and Alberta glacial lakes. Using a bootstrapping approach, we estimated the total organic carbon pool to be 0.26 +/- 0.02 Mt and a total sediment pool of 25.7 +/- 1.71 Mt within a hydroacoustically derived sediment volume of ca. 32 990 557m(3). The total organic carbon pool is substantially smaller than Alaskan yedoma, thermokarst lake sediments and Alberta glacial lakes but shares similarities with Finnish boreal lakes. Temporal variability in sediment and carbon accumulation dynamics at Lake Rauchuagytgyn is controlled predominantly by palaeoclimate variation that regulates lake ice-cover dynamics and catchment glacial, fluvial and permafrost processes through time. These processes, in turn, affect catchment and within-lake primary productivity as well as catchment soil development. Spatial differences compared to other lake systems at a trans-regional scale likely relate to the high-latitude, mountainous location of Lake Rauchuagytgyn.
Martian atmospheric spectral end-members retrieval from ExoMars Thermal Infrared (TIRVIM) data
(2022)
Key knowledge about planetary composition can be recovered from the study of thermal infrared spectral range datasets.
This range has a huge diagnostic potential because it contains diagnostic absorptions from a planetary surface and atmosphere. The main goal of this study is to process and interpret the dataset from the Thermal Infrared channel (TIRVIM) which is part of the Atmospheric Chemistry Suite of the ExoMars2016 Trace Gas Orbiter mission to find and characterize dust and water ice clouds in the atmosphere.
The method employed here is based on the application of principal component analysis and target transformation techniques to extract the independent variable components present in the analyzed dataset. Spectral shapes of both atmospheric dust and water ice aerosols have been recovered from the analysis of TIRVIM data.
The comparison between our results with those previously obtained on Thermal Emission Spectrometer (TES) data and with previous analysis on TIRVIM data, validates the methodology here applied, showing that it allows to correctly recover the atmospheric spectral endmembers present in the TIRVIM data.
Moreover, comparison with atmospheric retrievals on PFS, TES and IRIS data, allowed us to assess the temporal stability and homogeneity of dust and water ice components in the Martian atmosphere over a time period of almost 50 years.
Heat shock factor HSFA2 fine-tunes resetting of thermomemory via plastidic metalloprotease FtsH6
(2022)
The transcription factor HSFA2 fine-tunes a balance between prolongation and resetting of thermomemory in Arabidopsis via the regulation of both memory-supporting and memory-resetting genes.
Plants 'memorize' stressful events and protect themselves from future, often more severe, stresses. To maximize growth after stress, plants 'reset' or 'forget' memories of stressful situations, which requires an intricate balance between stress memory formation and the degree of forgetfulness.
HEAT SHOCK PROTEIN 21 (HSP21) encodes a small heat shock protein in plastids of Arabidopsis thaliana. HSP21 functions as a key component of thermomemory, which requires a sustained elevated level of HSP21 during recovery from heat stress. A heat-induced metalloprotease, filamentation temperature-sensitive H6 (FtsH6), degrades HSP21 to its pre-stress abundance, thereby resetting memory during the recovery phase. The transcription factor heat shock factor A2 (HSFA2) activates downstream genes essential for mounting thermomemory, acting as a positive regulator in the process.
Here, using a yeast one-hybrid screen, we identify HSFA2 as an upstream transactivator of the resetting element FtsH6. Constitutive and inducible overexpression of HSFA2 increases expression of FtsH6, whereas it is drastically reduced in the hsfa2 knockout mutant. Chromatin immunoprecipitation reveals in planta binding of HSFA2 to the FtsH6 promoter. Importantly, overexpression of HSFA2 improves thermomemory more profoundly in ftsh6 than wild-type plants.
Thus, by activating both memory-supporting and memory-resetting genes, HSFA2 acts as a cellular homeostasis factor during thermomemory.
As cultural diversity is increasing around the globe, a more nuanced understanding of the cultural diversity climate in classroom settings is needed, including how its different aspects relate to student outcomes. We developed the Classroom Cultural Diversity Climate Scale (CCDCS), integrating theory and research from social psychology and multicultural education and including novel facets like polyculturalism, which has not been studied in the school context before. We then studied associations with intergroup relations, socio-emotional adjustment, and school achievement among students of immigrant and non-immigrant background at the individual and classroom levels. The scale includes six subscales in the two broad dimensions of equality and inclusion: contact and cooperation, (un)equal treatment, and color-evasion, and cultural pluralism: heritage and intercultural learning, critical consciousness, and polyculturalism. Using data from 1,335 secondary school students in Germany (Mage = 14.7; 51% male; 51% immigrant background), the scale demonstrated measurement invariance by immigrant background, gender, and school track, and reliability at individual and classroom levels. A more positive diversity climate, with better intercultural relations (equality and inclusion) and more opportunities to learn about cultural diversity (cultural pluralism), was associated with more positive student outcomes. Interestingly, polyculturalism was not associated with negative effects observed for other facets of cultural pluralism. Relations for different climate aspects also varied by outcome and students' immigrant background. This underscores the importance of a nuanced perspective when evaluating different approaches to cultural diversity in context.
Aim: Study aim was to investigate the effects of therapeutic phlebotomy on ambulatory blood pressure in patients with grade 1 hypertension.
Methods: In this randomized-controlled intervention study, patients with unmedicated hypertension grade 1 were randomized into an intervention group (phlebotomy group; 500 mL bloodletting at baseline and after 6 weeks) and a control group (waiting list) and followed up for 8 weeks. Primary endpoint was the 24-h ambulatory mean arterial pressure between the intervention and control groups after 8 weeks. Secondary outcome parameters included ambulatory/resting systolic/diastolic blood pressure, heart rate, and selected laboratory parameters (e.g., hemoglobin, hematocrit, erythrocytes, and ferritin). Resting systolic/diastolic blood pressure/heart rate and blood count were also assessed at 6 weeks before the second phlebotomy to ensure safety. A per-protocol analysis was performed.
Results: Fifty-three hypertension participants (56.7 +/- 10.5 years) were included in the analysis (n = 25 intervention group, n = 28 control group). The ambulatory measured mean arterial pressure decreased by -1.12 +/- 5.16mmHg in the intervention group and increased by 0.43 +/- 3.82mmHg in the control group (between-group difference: -1.55 +/- 4.46, p = 0.22). Hemoglobin, hematocrit, erythrocytes, and ferritin showed more pronounced reductions in the intervention group in comparison with the control group, with significant between-group differences. Subgroup analysis showed trends regarding the effects on different groups classified by serum ferritin concentration, body mass index, age, and sex. Two adverse events (AEs) (anemia and dizziness) occurred in association with the phlebotomy, but no serious AEs.
Conclusions: Study results showed that therapeutic phlebotomy resulted in only minimal reductions of 24-h ambulatory blood pressure measurement values in patients with unmedicated grade 1 hypertension. Further high-quality clinical studies are warranted, as this finding contradicts the results of other studies.
The early exhumation history of the Tauern Window in the European Eastern Alps and its surface expression is poorly dated and quantified, partly because thermochronological and provenance information are sparse from the Upper Austrian Northern Alpine Foreland Basin. For the first time, we combine a single-grain double-dating approach (Apatite Fission Track and U-Pb dating) with trace-element geochemistry analysis on the same apatites to reconstruct the provenance and exhumation history of the late Oligocene/early Miocene Eastern Alps. The results from 22 samples from the Chattian to Burdigalian sedimentary infill of the Upper Austrian Northern Alpine Foreland Basin were integrated with a 3D seismic-reflection data set and published stratigraphic reports. Our highly discriminative data set indicates an increasing proportion of apatites (from 6% to 23%) with Sr/Y values <0.1 up-section and an increasing amount of apatites (from 24% to 38%) containing >1,000 ppm light rare-earth elements from Chattian to Burdigalian time. The number of U-Pb ages with acceptable uncertainties increases from 40% to 59% up-section, with mostly late Variscan/Permian ages, while an increasing number of grains (10%-27%) have Eocene or younger apatite fission track cooling ages. The changes in the apatite trace-element geochemistry and U-Pb data mirror increased sediment input from an >= upper amphibolite-facies metamorphic source of late Variscan/Permian age - probably the otztal-Bundschuh nappe system - accompanied by increasing exhumation rates indicated by decreasing apatite fission track lag times. We attribute these changes to the surface response to upright folding and doming in the Penninic units of the future Tauern Window starting at 29-27 Ma. This early period of exhumation (0.3-0.6 mm/a) is triggered by early Adriatic indentation along the Giudicarie Fault System.
Jüdische Musik
(2021)