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Yet another Theta-System
(2002)
We report on the effect of vibrational resonance in a spatially extended system of coupled noisy oscillators under the action of two periodic forces, a low-frequency one (signal) and a high-frequency one (carrier). Vibrational resonance manifests itself in the fact that for optimally selected values of high-frequency force amplitude, the response of the system to a low-frequency signal is optimal. This phenomenon is a synthesis of two effects, a noise- induced phase transition leading to bistability, and a conventional vibrational resonance, resulting in the optimization of signal processing. Numerical simulations, which demonstrate this effect for an extended system, can be understood by means of a zero-dimensional "effective" model. The behavior of this "effective" model is also confirmed by an experimental realization of an electronic circuit.
Two Hybrid cDNA Cloning
(2002)
Towards a better understanding of laser beam melt ablation using methods of statistical analysis
(2002)
Laser beam melt ablation, as a contact free machining process, offers several advantages compared to conventional processing mechanisms. Although the idea behind it is rather simple, the process has a major limitation: with increasing ablation rate surface quality of the workpiece processed declines rapidly. The structures observed show a clear dependence of the line energy. In dependence of this parameter several regimes of the process have been separated. These are clearly distinguishable as well in the surfaces obtained as in the signals gained by the measurement of the process emissions which is the observed quantity chosen.
Tomography of AM Herculis
(2002)
From the root bark of Erythrina burttii three new isoflav-3-enes, 7,4'-dihydroxy-2'-methoxy-6- (1'',1''-dimethylallyl)isoflav-3-ene (trivial name, burttinol-A), 4'-hydroxy-2'- methoxy-(2'',2''-dimethylpyrano[5'',6'':8,7]isoflav-3-ene (trivial name, burttinol-B), 7,4'-dihydroxy-2'-methoxy-8-(3'',3''-dimethylallyl)isoflav-3-ene (trivial name, burttinol-C), and a new 2-arylbenzofuran, 6,4'-dihydroxy-2'-methoxy-5- (1'',1''-dimethylallyl)-2-arylbenzofuran (trivial name, burttinol-D) were isolated. In addition, the known compounds, abyssinone V-4'-methyl ether, bidwillol A, calopocarpin, erybraedin A, erythrabyssin II, isobavachalcone, phaseollidin and phaseollin were identified. The structures were determined on the basis of spectroscopic evidence.
Highly relativistic jets are most probably driven by strong magnetic fields and launched from the accretion disk surrounding a central black hole. Applying the jet flow parameters (velocity, density, temperature) calculated from the magnetohydrodynamic (MHD) equations, we derive the thermal X-ray luminosity along the inner jet flow in the energy range 0.2-10.1 keV. Here, we concentrate on the case of Galactic microquasars emitting highly relativistic jets. For a 5 Msun central object and a jet mass flow rate of dot {M}j = 10-8 Msun yr-1 we obtain a jet X-ray luminosity LX ~ 1033 erg s-1. Emission lines of Fe XXV and Fe XXVI are clearly visible. Relativistic effects such as Doppler shift and boosting were considered for different inclinations of the jet axis. Due to the chosen geometry of the MHD jet the inner X-ray emitting part is not yet collimated. Therefore, depending on the viewing angle, the Doppler boosting does not play a major role in the total spectra.
The continued linguistic contact in the islands of Britain and Ireland over the past two millenia has led to linguistic convergence processes between the Insular Celtic and West Germanic languages involved. While the Latin, Old Norse and Norman French contact scenarios were recognised and have been well studied since the 19c, the Celtic component received much less scholarly attention until the 1990s because of the continued linguistic bias, once fostered by 19c Anglo-Saxonisms and the idea of racial purity of the Egnlish population. It is only in the very recent past that the many different contact areas between English and the Insular Celtic languages have received recognition after New Labour's post-1997 introduction of "devolution" politics. The closest and longest interaction took of course place between English and Welsh. The present article looks at three major types of interaction which led to convergence in a number of important linguistic features: (1) mutual retention of shared archaic features, (2) mutual shared innovations, and (3) transfer from one language to another, either by unilateral or by bilateral transfer. The exemplary contact features discussed in this article relate to the retention of interdental fricatives, the shared innovation of analycity and multi-word verb formation, and clefting as feature transfer. Transfer is likely to have taken place under the following conditions: (a) earlier written documentation in the donor language, (b) higher frequency of occurrence in the donor language, (c) conformity with other structures in the donor language, and (d) grammaticalisation in the donor language. The conclusion endorses Salikoko Mufwene's claim that the making of English in the island of Britain was subject to the same contact processes which created the English based creoles from indigenised Englishes during the colonial period.
From the peak of a gravitational microlensing high-magnification event in the A component of QSO 2237+0305, which was accurately monitored by the Gravitational Lenses International Time Project collaboration, we derived new information on the nature and size of the optical V-band and R-band sources in the distant quasar. If the microlensing peak is caused by a microcaustic crossing, we first obtain that the standard accretion disk is a scenario more reliable/ feasible than other typical axially symmetric models. Moreover, the standard scenario fits both the V-band and R-band observations with reduced ?2 values very close to 1. Taking into account all these results, a standard accretion disk around a supermassive black hole is a good candidate for the optical continuum main source in QSO 2237+0305. Second, using the standard source model and a robust upper limit on the transverse galactic velocity, we infer that 90% of the V- band and R-band luminosities are emitted from a region with a radial size less than 1.2×10-2 pc (=3.7×1016 cm, at a 2 ? confidence level).
We present models for the complete life and death of a 60 Msolar star evolving in a close binary system, from the main-sequence phase to the formation of a compact remnant and fallback of supernova debris. After core hydrogen exhaustion, the star expands, loses most of its envelope by Roche lobe overflow, and becomes a Wolf-Rayet star. We study its post-mass transfer evolution as a function of the Wolf-Rayet wind mass-loss rate (which is currently not well constrained and will probably vary with the initial metallicity of the star). Varying this mass-loss rate by a factor of 6 leads to stellar masses at collapse that range from 3.1 up to 10.7 Msolar. Because of different carbon abundances left by core helium burning and nonmonotonic effects of the late shell-burning stages as function of the stellar mass, we find that, although the iron core masses at collapse are generally larger for stars with larger final masses, they do not depend monotonically on the final stellar mass or even the C/O core mass. We then compute the evolution of all models through collapse and bounce. The results range from strong supernova explosions (Ekin>1051ergs) for the lower final masses to the direct collapse of the star into a black hole for the largest final mass. Correspondingly, the final remnant masses, which were computed by following the supernova evolution and fallback of material for a timescale of about one year, are between 1.2 and 10 Msolar. We discuss the remaining uncertainties of this result and outline the consequences of our results for the understanding of the progenitor evolution of X-ray binaries and gamma-ray burst models.
The influence of the charge density of polyelectrolytes on the growth of polyelectrolyte multilayers via layer- by-layer self-assembly from pure aqueous solutions was studied. Multilayers were built from strong polyanions, namely poly(styrenesulfonate) and an exfoliated synthetic hectorite, and cationic copolymers of diallyldimethylammonium chloride (DADMAC) with N-methyl-N-vinylformamide (NMVF) for which the composition and thus the charge density was varied systematically. The analysis of the system {cationic copolymer/poly(styrenesulfonate)} reveals that a critical linear charge density Ïc of 0.036 elementary charge/Å of contour length is necessary to obtain stable multilayer growth in pure water. Above Ïc, the increment of thickness/deposition cycle varies with the linear charge density of the cationic copolymers, in good agreement with current theories of polyelectrolyte solutions. As linear charge density increases, the system passes successively through a charge-dependent ?Debye-Hu ckel? regime and then through a chargeindependent ?strong-screening? regime where counterion condensation dominates the behavior. Analogous results were obtained for the variation of the basal spacing of internally structured hybrid multilayers {cationic copolymer/hectorite}. However, by contrast with the first system, no critical linear charge density was found for the hybrid system. This is explained by additional, nonelectrostatic interactions between the clay platelets and the formamide fragment.
Electrostatically self-assembled (ESA) polyelectrolyte films show in general no internal structure. The use of special polycations, however, namely of lyotropic ionenes, may give rise to highly ordered coatings. In this article, the influence of the charge density of the polyanion, as well as the distribution of the charged groups within this polymer, is examined, using a series of anionic cellulose derivatives. Various techniques were used to study the films? growth and internal structure. Both showed to be affected in particular by the charge density but also by the substitution pattern.
We present a new determination of the time delay of the gravitational lens system HE 1104-1805 (``Double Hamburger'') based on a previously unpublished dataset. We argue that the previously published value of Delta tA-B=0.73 years was affected by a bias of the employed method. We determine a new value of Delta tA-B=0.85+/-0.05 years (2sigma confidence level), using six different techniques based on non interpolation methods in the time domain. The result demonstrates that even in the case of poorly sampled lightcurves, useful information can be obtained with regard to the time delay. The error estimates were calculated through Monte Carlo simulations. With two already existing models for the lens and using its recently determined redshift, we infer a range of values of the Hubble parameter: H0=48+/-4 km s-1 Mpc-1 (2sigma ) for a singular isothermal ellipsoid (SIE) and H0=62+/-4 km s-1 Mpc-1 (2sigma ) for a constant mass-to-light ratio plus shear model (M/L+gamma ). The possibly much larger errors due to systematic uncertainties in modeling the lens potential are not included in this error estimate.
Temperature and polymer induced structural changes in SDS/decanol based multilamellar vesicles
(2002)
We consider an ensemble of coupled nonlinear noisy oscillators demonstrating in the thermodynamic limit an Ising-type transition. In the ordered phase and for finite ensembles stochastic flips of the mean field are observed with the rate depending on the ensemble size. When a small periodic force acts on the ensemble, the linear response of the system has a maximum at a certain system size, similar to the stochastic resonance phenomenon. We demonstrate this effect of system size resonance for different types of noisy oscillators and for different ensemblesùlattices with nearest neighbors coupling and globally coupled populations. The Ising model is also shown to demonstrate the system size resonance.
Citrate-capped gold nanoparticles as well as planar gold surfaces can be efficiently grafted with a covalently attached polymer monolayer a few nanometers thick, by simple contact of the metal surface with dilute aqueous solutions of hydrophilic polymers that are end-capped with disulfide moieties, as shown by UV/vis absorption, dynamic light scattering, and surface plasmon resonance studies. The hydrophilic polymer-coated gold colloids can be freeze-dried and stored as powders that can be subsequently dissolved to yield stable aqueous dispersions, even at very large concentrations. They allow for applying filtrations, gel permeation chromatography, or centrifugation. They do not suffer from undesirable nonspecific adsorption of proteins while allowing the diffusion of small species within the hydrogel surface coating. In addition, specific properties of the original hydrophilic polymers are retained such as a lower critical solution temperature. The latter feature could be useful to enhance optical responses of functionalized gold surfaces toward interaction with various substrates.
In this article, the synthesis of analogs of N,N',N''-triacetylchitotriose in which the central sugar residue was replaced by a succinic acid is presented. Mol. modeling calcns. revealed that the pseudotrisaccharides exist in low energy extended conformations which show similar space filling as N,N',N''-triacetylchitotriose. Of the N,N',N''-triacetylchitotriose pseudosugar analogs tested as chitinase inhibitors, none showed any appreciable competition (numerical data not presented). The conformational anal. along with further synthetic efforts will hopefully lead to more efficient pseudosaccharides as chitinase inhibitors.
We analyse time series from a study on bimanual rhythmic movements in which the speed of performance (the external control parameter) was experimentally manipulated. Using symbolic transformations as a visualization technique we observe qualitative changes in the dynamics of the timing patterns. Such phase transitions are quantitatively described by measures of complexity. Using these results we develop an advanced symbolic coding which enables us to detect important dynamical structures. Furthermore, our analysis raises new questions concerning the modelling of the underlying human cognitive-motor system.
Observational data of natural systems, as measured in medical measurements are typically quite different from those obtained in laboratories. Due to the peculiarities of these data, wellknown characteristics, such as power spectra or fractal dimension, often do not provide a suitable description. To study such data, we present here some measures of complexity, which are basing on symbolic dynamics. Firstly, a motivation for using symbolic dynamics and measures of complexity in data analysis based on the logistic map is given and next, two applications to medical data are shown. We demonstrate that symbolic dynamics is a useful tool for the risk assessment of patients after myocardial infarction as well as for the evaluation of th e architecture of human cancellous bone.