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A series of new poly-1,3,4-oxadiazoles has been synthesized by polycondensation reaction of hydrazine sulfate with a mixture of a dicarboxylic acid containing unsaturated bonds and a dicarboxylic acid containing silicon, by using methanesulfonic acid/phosphorus pentoxide as a reaction medium. These polymers were highly thermostable but they were only soluble in strong inorganic acids such as sulfuric or methanesulfonic ones. An alternative way was followed by using the corresponding dihydrazides containing unsaturated bonds and the corresponding diacid chloride containing silicon that reacted in N-methylpyrrolidinone (NMP) to give soluble silicon-containing unsaturated polyhydrazides, which were cyclodehydrated either by thermal or chemical treatment to give the corresponding polyoxadiazoles. Very thin coatings of polyhydrazides and polyoxadiazoles were deposited onto silicon wafers and they showed a very smooth surface, free of pinholes, when studied by atomic force microscopy (AFM). Some polyoxadiazole films showed strong blue photoluminescence.
In the roughly 20 years of its existence as an observational science, gravitational lensing has established itself as a valuable tool in many astrophysical fields. In the introduction of this review we briefly present the basics of lensing. Then it is shown that the two propagation effects, lensing and scintillation, have a number of properties in common. In the main part various lensing phenomena are discussed with emphasis on recent observations.
So far, the evolution of post-AGB stars is not fully understood. In particular the formation of hydrogen- deficient and hydrogen-free Central Stars of Planetary Nebulae (CSPN) is unsettled. New evolution models, which allow for the consistent treatment of the physics of late thermal pulses, promise new insights to the formation of these stars. In this paper we summarize the results of non-LTE analyses of CSPN with wind. By comparing these results with the predictions of the new evolution models, open questions concerning the evolution of the stars might be answered. In addition we discuss the driving mechanism of the winds of Wolf-Rayet CSPN. New models, which account for millions of iron lines, support the assumptions that these winds are driven by radiation.
We propose a technique to calculate large-scale dimension densities in both higher-dimensional spatio-temporal systems and low-dimensional systems from only a few data points, where known methods usually have an unsatisfactory scaling behavior. This is mainly due to boundary and finite size effects. With our rather simple method we normalize boundary effects and get a significant correction of the dimension estimate. This straightforward approach is basing on rather general assumptions. So even weak coherent structures obtained from small spatial couplings can be detected with this method, what is impossible by using the Lyapunov-dimension density. We demonstrate the efficiency of our technique for coupled logistic maps, coupled tent maps, the Lorenz-attractor and the Roessler-attractor.
We present a measure of quantum entanglement which is capable of quantifying the degree of entanglement of a multi-partite quantum system. This measure, which is based on a generalization of the Schmidt rank of a pure state, is defined on the full state space and is shown to be an entanglement monotone, that is, it cannot increase under local quantum operations with classical communication and under mixing. For a large class of mixed states this measure of entanglement can be calculated exactly, and it provides a detailed classification of mixed states.
We have recently reported the phenomenon of doubly stochastic resonance [Phys. Rev. Lett. 85, 227 (2000)], a synthesis of noise-induced transition and stochastic resonance. The essential feature of this phenomenon is that multiplicative noise induces a bimodality and additive noise causes stochastic resonance behavior in the induced structure. In the present paper we outline possible applications of this effect and design a simple lattice of electronic circuits for the experimental realization of doubly stochastic resonance.
We have obtained time-resolved observations of line-profile variations of the two Wolf-Rayet stars WR 135 and WR 111. The spectra, taken during two consecutive nights, cover a broad range from 4470 to 6590 Ang. The profile variability of the C iii emission line at 5696 Ang in WR 135 is shown in detail. The principal difficulties to constrain the velocity law from the frequency drift of discrete spectral features is discussed, emphasizing the crucial dependence on the adopted location of the line-emission region, and the possible necessity to distinguish between the motion of structures and the flow of the matter. - Full access to the observational data is provided via anonymous file transfer.