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The post-Variscan uplift of the western Anti-Atlas Precambrian core is studied by zircon fission track (ZFT) analysis of ten samples of granites and schists from the Kerdous and Ifni inliers. All samples yield Carboniferous ZFT ages ranging from 358 +/- 31 Ma to 319 +/- 32 Ma, with nine dates younger than 338 +/- 35 Ma. The weighted mean age calculated for these nine samples is 328 +/- 30 Ma. These results compare with the available K-Ar datings of white mica and biotite from the same rocks or from the overlying Ediacaran-Cambrian low-grade metasediments. The fact that different systems with distinct closure temperatures yield similar ages suggests the occurrence of a short Carboniferous thermal event followed by rapid cooling. Consistent with the regional geological framework, the thermal event is assigned to the Variscan folding, being followed by rapid exhumation and cooling related to the post-folding erosion. To cite this article: S. Sebti et aL, C. R. Geoscience 341 (2009).
A reconstruction of Milankovitch to millennial-scale variability of sea surface temperature (SST) and sea surface productivity in the Pleistocene midlatitude North Atlantic Ocean (marine isotope stage (MIS) 16-9) and its relationship to ice sheet instability was carried out on sediments from Integrated Ocean Drilling Program (IODP) Site U1313. This reconstruction is based on alkenone and n-alkane concentrations, U-37(K)' index, total organic carbon (TOC) and carbonate contents, X-ray diffraction data, magnetic susceptibility, and accumulation rates. Increased input of ice-rafted debris occurred during MIS 16, 12, and 10, characterized by high concentrations of dolomite, quartz, and feldspars and elevated accumulation rates of terrigenous matter. Minimum input values of terrigenous matter, on the other hand, were determined for MIS 13 and 11. Peak values of dolomite, coinciding with quartz, plagioclase, and kalifeldspar peaks and maxima in long-chain n-alkanes indicative for land plants, are interpreted as Heinrich-like events related to sudden instability of the Laurentide Ice Sheet during early and late (deglacial) phases of the glacials. The coincidence of increased TOC values with elevated absolute concentrations of alkenones suggests increased glacial productivity, probably due to a more southern position of the Polar Front. Alkenone-based SST reached absolute maxima of about 19 degrees C during MIS 11.3 and absolute minima of <10 degrees C during MIS 12 and 10. Within MIS 11, prominent cooling events (MIS 11.22 and 11.24) occurred. The absolute SST minima recorded directly before and after the glacial maxima MIS 10.2 and 12.2 are related to Heinrich-like event meltwater pulses, as supported by the coincidence of SST minima and maxima in C-37:4 alkenones and dolomite. These sudden meltwater pulses, especially during terminations IV and V, probably caused a collapse of phytoplankton productivity as indicated by the distinct drop in alkenone concentrations. Ice sheet disintegration and subsequent surges and outbursts of icebergs and meltwater discharge may have been triggered by increased insolation in the northern high latitudes.
This study presents an unsupervised feature selection and learning approach for the discovery and intuitive imaging of significant temporal patterns in seismic single-station or network recordings. For this purpose, the data are parametrized by real-valued feature vectors for short time windows using standard analysis tools for seismic data, such as frequency-wavenumber, polarization, and spectral analysis. We use Self-Organizing Maps (SOMs) for a data-driven feature selection, visualization and clustering procedure, which is in particular suitable for high-dimensional data sets. Our feature selection method is based on significance testing using the Wald-Wolfowitz runs test for-individual features and on correlation hunting with SOMs in feature subsets. Using synthetics composed of Rayleigh and Love waves and real-world data, we show the robustness and the improved discriminative power of that approach compared to feature subsets manually selected from individual wavefield parametrization methods. Furthermore, the capability of the clustering and visualization techniques to investigate the discrimination of wave phases is shown by means of synthetic waveforms and regional earthquake recordings.
The Subandean fold and thrust belt of Bolivia constitutes the easternmost part of the Andean orogen that reflects thin-skinned shortening and eastward propagation of the Andean deformation front. The exact interplay of tectonics, climate, and erosion in the deposition of up to 7.5 km of late Cenozoic strata exposed in the Subandes remains unclear. To better constrain these relationships, we use four W-E industry seismic reflection profiles, eight new zircon U-Pb ages from Mio-Pliocene sedimentary strata, and cross-section balancing to evaluate the rates of thrust propagation, shortening, and deposition pinch-out migration. Eastward thrusting arrived in the Subandean belt at similar to 12.4 +/- 0.5 Ma and propagated rapidly toward the foreland unit approximately 6 Ma. This was followed by out-of- sequence deformation from ca. 4 to 2.1 Ma and by renewed eastward propagation thereafter. Our results show that the thrust-front propagation- and deposition pinch-out migration rates mimic the sediment accumulation rate. The rates of deposition pinchout migration and thrust propagation increased three- and two fold, respectively (8 mm/a; 3.3 mm/a) at 86 Ma. The three-fold increase in deposition pinch-out migration rate at this time is an indication of enhanced erosional efficiency in the hinterland, probably coupled with flexural rebound of the basin. Following the pulse of pinch-out migration, the Subandean belt witnessed rapid similar to 80 km eastward propagation of thrusting to the La Vertiente structure at 6 Ma. As there is no evidence for this event of thrust front migration being linked to an increase in shortening rate, the enhanced frontal accretion suggests a shift to supercritical wedge taper conditions. We propose that the supercritical state was due to a drop in basal strength, caused by sediment loading and pore fluid overpressure. This scenario implies that climate-controlled variation in erosional efficiency was the driver of late Miocene mass redistribution, which induced flexural rebound of the Subandean thrust belt, spreading of a large clastic wedge across the basin, and subsequent thrust-front propagation.
We analyzed published records of terrigenous dust flux from marine sediments off subtropical West Africa, the eastern Mediterranean Sea, and the Arabian Sea, and lake records from East Africa using statistical methods to detect trends, rhythms and events in Plio-Pleistocene African climate. The critical reassessment of the environmental significance of dust flux and lake records removes the apparent inconsistencies between marine vs. terrestrial records of African climate variability. Based on these results, major steps in mammalian and hominin evolution occurred during episodes of a wetter, but highly variable climate largely controlled by orbitally induced insolation changes in the low latitudes.
Geothermobarometric, radiogenic isotopic and thermochronologic data are used to track the influence of an ancient continental margin (Western Province) on development of an adjacent Carboniferous-Cretaceous magmatic arc (Outboard Median Batholith) in Fiordland, New Zealand. The data show a record of complicated Mesozoic Gondwana margin growth. Paragneiss within the Outboard Median Batholith is of Carboniferous to Jurassic age and records burial to middle crustal depths in Late Jurassic-Early Cretaceous during subduction-related plutonism and arc thickening. In contrast, Western Province metasedimentary rocks in the area of study immediately west of the Outboard Median Batholith are Late Cambrian-Early Ordovician in age, recrystallized at the amphibolite facies in the Late Devonian-Early Carboniferous and exhibit no evidence for Mesozoic textural or isotopic reequilibration. A phase of deformation, between 128 and 116 Ma deformed, exhumed, and cooled the Outboard Median Batholith to greenschist facies temperatures, while large parts of the Western Province underwent >= 9 kbar metamorphic conditions. Zircon grains from Mesozoic inboard plutons are isotopically more evolved (epsilon Hf(t) = +2.3 to +4.0) than those in the Outboard Median Batholith (epsilon Hf(t) = +9.4 to +11.1). The contrasting zircon Hf isotope ratios, absence of S-type plutons or Proterozoic-Early Paleozoic inherited zircon, and the apparent absence of Early Paleozoic metasedimentary rocks indicates that the Outboard Median Batholith is unlikely to be underlain by the Western Province continental lithosphere. The new data are consistent with the Outboard Median Batholith representing an allochthonous (although not necessarily exotic) arc that was juxtaposed onto the Gondwana continental margin along the intervening Grebe Mylonite Zone.
Accretionary orogens are considered major sites of formation of juvenile continental crust. In the central and southern Andes this is contradicted by two observations: siliciclastic fills of Paleozoic basins in the central Andean segment of the accretionary Terra Australis Orogen consist almost exclusively of shales and mature sandstones; and magmatic rocks connected to the Famatinian (Ordovician) and Late Paleozoic magmatic arcs are predominantly felsic and characterized by significant crustal contamination and strongly unradiogenic Nd isotope compositions. Evidence of juvenile crustal additions is scarce. We present laser ablation (LA)-ICPMS U-Pb ages and LA-MC-ICPMS Hf isotope data of detrital zircons from seven Devonian to Permian turbidite sandstones incorporated into a Late Paleozoic accretionary wedge at the western margin of Gondwana in northern Chile. The combination with Nd whole-rock isotope data permits us to trace the evolution of the South American continental crust through several Proterozoic and Paleozoic orogenic cycles. The analyzed detrital zircon spectra reflect all Proterozoic orogenic cycles representing the step-wise evolution of the accretionary SW Amazonia Orogenic System between 2.0 and 0.9 Ga, followed by the Terra Australis Orogen between 0.9 and 0.25 Ga. The zircon populations are characterized by two prominent maxima reflecting input from Sunsas (Grenville) age magmatic rocks (1.2-0.9 Ga) and from the Ordovician to Silurian Famatinian magmatic arc (0.52-0.42 Ga). Grains of Devonian age are scarce or absent from the analyzed zircon populations. The Hf isotopic compositions of selected dated zircons at the time of their crystallization (epsilon Hf-(T); T = 3.3-0.25 Ga) vary between -18 and +11. All sandstones have a significant juvenile component; between 20 and 50% of the zircons from each sedimentary rock have positive epsilon Hf-(T) and can be considered juvenile. The majority of the juvenile grains have Hf-depleted mantle model ages (Hf T-DM) between 1.55 and 0.8 Ga. the time of the Rondonia-San Ignacio and Sunsas orogenic events on the Amazonia craton. The corresponding whole-rock epsilon Nd-(T) values fot these same rocks are between -8 and -3 indicating a mixture of older evolved and juvenile sources. Nd-depleted mantle model ages (Nd T-DM*) are between 1.5 and 1.2 Ga and coincide broadly with the zircon Hf model ages. Our data indicate that the Paleo- and Mesoproterozoic SW Amazonia Orogenic System, and the subsequent Neoproterozoic and Paleozoic Terra Australis Orogen in the region of the central and southern Andes, developed following two markedly different patterns of accretionary orogenic crustal evolution. The SW Amazonia Orogenic System developed by southwestward growth over approximately 1.1 Ga through a combination of accretion of juvenile material and crustal recycling typical of the extensional or retreating mode of accretionary orogens. In contrast, the central Andean segment of the Terra Australis Orogen evolved from 0.9 to 0.25 Ga in the compressional or advancing mode in a relatively fixed position without the accretion of oceanic crustal units or large scale input of juvenile material to the orogenic crust. Here, recycling mainly of Mesoproterozoic continental crust has been the dominant process of crustal evolution. (C) 2009 Elsevier B.V. All rights reserved.
The seismicity of the Dead Sea fault zone (DSFZ) during the last two millennia is characterized by a number of damaging and partly devastating earthquakes. These events pose a considerable seismic hazard and seismic risk to Syria, Lebanon, Palestine, Jordan, and Israel. The occurrence rates for large earthquakes along the DSFZ show indications to temporal changes in the long-term view. The aim of this thesis is to find out, if the occurrence rates of large earthquakes (Mw ≥ 6) in different parts of the DSFZ are time-dependent and how. The results are applied to probabilistic seismic hazard assessments (PSHA) in the DSFZ and neighboring areas. Therefore, four time-dependent statistical models (distributions), including Weibull, Gamma, Lognormal and Brownian Passage Time (BPT), are applied beside the exponential distribution (Poisson process) as the classical time-independent model. In order to make sure, if the earthquake occurrence rate follows a unimodal or a multimodal form, a nonparametric bootstrap test of multimodality has been done. A modified method of weighted Maximum Likelihood Estimation (MLE) is applied to estimate the parameters of the models. For the multimodal cases, an Expectation Maximization (EM) method is used in addition to the MLE method. The selection of the best model is done by two methods; the Bayesian Information Criterion (BIC) as well as a modified Kolmogorov-Smirnov goodness-of-fit test. Finally, the confidence intervals of the estimated parameters corresponding to the candidate models are calculated, using the bootstrap confidence sets. In this thesis, earthquakes with Mw ≥ 6 along the DSFZ, with a width of about 20 km and inside 29.5° ≤ latitude ≤ 37° are considered as the dataset. The completeness of this dataset is calculated since 300 A.D. The DSFZ has been divided into three sub zones; the southern, the central and the northern sub zone respectively. The central and the northern sub zones have been investigated but not the southern sub zone, because of the lack of sufficient data. The results of the thesis for the central part of the DSFZ show that the earthquake occurrence rate does not significantly pursue a multimodal form. There is also no considerable difference between the time-dependent and time-independent models. Since the time-independent model is easier to interpret, the earthquake occurrence rate in this sub zone has been estimated under the exponential distribution assumption (Poisson process) and will be considered as time-independent with the amount of 9.72 * 10-3 events/year. The northern part of the DSFZ is a special case, where the last earthquake has occurred in 1872 (about 137 years ago). However, the mean recurrence time of Mw ≥ 6 events in this area is about 51 years. Moreover, about 96 percent of the observed earthquake inter-event times (the time between two successive earthquakes) in the dataset regarding to this sub zone are smaller than 137 years. Therefore, it is a zone with an overdue earthquake. The results for this sub zone verify that the earthquake occurrence rate is strongly time-dependent, especially shortly after an earthquake occurrence. A bimodal Weibull-Weibull model has been selected as the best fit for this sub zone. The earthquake occurrence rate, corresponding to the selected model, is a smooth function of time and reveals two clusters within the time after an earthquake occurrence. The first cluster begins right after an earthquake occurrence, lasts about 80 years, and is explicitly time-dependent. The occurrence rate, regarding to this cluster, is considerably lower right after an earthquake occurrence, increases strongly during the following ten years and reaches its maximum about 0.024 events/year, then decreases over the next 70 years to its minimum about 0.0145 events/year. The second cluster begins 80 years after an earthquake occurrence and lasts until the next earthquake occurs. The earthquake occurrence rate, corresponding to this cluster, increases extremely slowly, such as it can be considered as an almost constant rate about 0.015 events/year. The results are applied to calculate the time-dependent PSHA in the northern part of the DSFZ and neighbouring areas.
Stable isotope altimetry is a useful tool for estimating paleoelevation in sedimentary records. Yet questions remain regarding how source moisture, climate, and local topography can influence these estimates. Here we present stable isotope altimetry results on late Quaternary pedogenic carbonates of known elevation on both flanks of the Andean orogen at 33 degrees S. We measured delta O-18 values of pedogenic carbonates and river water samples from small drainages at regular elevation increments within the Rio Aconcagua (Chile) and Rio Mendoza (Argentina) catchments. The delta O-18 values of river waters correlate well with elevation and show similar isotopic gradients between the Chilean (-3.7 parts per thousand/km) and Argentine (-4.8 parts per thousand/km) sides of the range. Uncertainties associated with scatter in the river water data and assumptions about the temperature of carbonate formation indicate that elevation estimates have 1 sigma errors of 350-450 m. We estimate the isotopic composition of soil water from pedogenic carbonates on both sides of the range by assuming mean annual temperatures based the modern temperature lapse rate from meteorological station data. Combined, our data show that stable isotope altimetry produces reasonable estimates of modern elevation, with the majority of our samples (60%) within the 1 sigma uncertainties and 77% within 2 sigma.
Lower Cretaceous early syn-rift facies along the eastern flank of the Eastern Cordillera of Colombia, their provenance, and structural context, reveal the complex interactions between Cretaceous extension, spatio-temporal trends in associated sedimentation, and subsequent inversion of the Cretaceous Guatiquia paleo-rift. South of 4 degrees 30'N lat, early syn-rift alluvial sequences in former extensional footwall areas were contemporaneous with fan- delta deposits in shallow marine environments in adjacent hanging-wall areas. In general, footwall erosion was more pronounced in the southern part of the paleorift. In contrast, early syn-rift sequences in former footwall areas in the northern rift sectors mainly comprise shallow marine supratidal sabkha to intertidal strata, whereas hanging-wall units display rapid transitions to open-sea shales. In comparison with the southern paleo-rift sector, fan-delta deposits in the north are scarce, and provenance suggests negligible footwall erosion. The southern graben segment had longer, and less numerous normal faults, whereas the northern graben segment was characterized by shorter, rectilinear faults. To the east, the graben system was bounded by major basin-margin faults with protracted activity and greater throw as compared with intrabasinal faults to the west. Intrabasinal structures grew through segment linkage and probably interacted kinematically with basin-margin faults. Basin-margin faults constitute a coherent fault system that was conditioned by pre-existing basement fabrics. Structural mapping, analysis of present-day topography, and balanced cross sections indicate that positive inversion of extensional structures was focused along basin-bounding faults, whereas intrabasinal faults remained unaffected and were passively transported by motion along the basin-bounding faults. Thus, zones of maximum subsidence in extension accommodated maximum elevation in contraction, and former topographic highs remained as elevated areas. This documents the role of basin-bounding faults as multiphased, long-lived features conditioned by basement discontinuities. Inversion of basin-bounding faults was more efficient in the southern than in the northern graben segment, possibly documenting the inheritance and pivotal role of fault-displacement gradients. Our observations highlight similarities between inversion features in orogenic belts and intra-plate basins, emphasizing the importance of the observed phenomena as predictive tools in the spatiotemporal analysis of inversion histories in orogens, as well as in hydrocarbon and mineral deposits exploration.
Upper Thanetian microbialite-coral mounds from the Adriatic Carbonate Platform (SW Slovenia) are described herein for the first time, representing an important case study of extensively microbially-cemented boundstones in the Early Paleogene. The mounds are constructed primarily by microbialites associated to small-sized coral colonies, forming metric bioconstructions in a mid-ramp setting. Detailed macroscopic and microscopic studies show that microbes are the major framework builders, playing a prominent role in the stabilization and growth of the mounds, with corals being the second most important component. Microbial carbonates represent up to 70% of the mounds, forming centimetric-thick crusts alternating with coral colonies. The microbial nature of the crusts is demonstrated by their growth form and internal microfabrics, showing accretionary, binding, and encrusting growth fabrics, often with gravity-defying geometries. Thin sections and polished slabs reveal a broad range of mesofabrics, with dense, structureless micrite (leiolite), laminated crusts (stromatolites), and clotted micritic masses (thrombolites). A first layer of micro- encrusters, including leiolites and thrombolites, occurs in cryptic habitats, whereas discontinuous stromatolites encrust the upper surface of corals. A second encrustation, the major mound construction phase, follows and is dominated by thrombolites, encrusting corals and other micro-encrusters. This sequence represents the basic constructional unit horizontally and vertically interlocked, in an irregular pattern, to form the mounds. The processes, which favored the deposition of these microbial carbonates, were mainly related to in situ precipitation, with minor evidences for grain agglutination and trapping processes. Scleractinian corals comprise moderately diversified community of small (centimetric) colonial, massive, platy encrusting, and branching forms. Coral colonies are distributed uniformly throughout the mounds without developing any ecological zonation. These features indicate that coral development remained at the pioneer stage throughout the mound growth. The spatial relationships between corals and microbialites, as well as the characteristics of microbial crusts and coral colonies, indicate a strong ecological competition between corals and microbes. A model for the evolution of the trophic structures during the mound growth is proposed, with changes in the paleoecology of the main bioconstructors triggered by frequent environmental perturbations. Turbidity and nutrient pressure, interpreted here as related to frequent recurrences of wet phases during the warm, humid climate of the Uppermost Thanetian, might have promoted temporary dominance of microbes over corals, causing rapid environmentally- driven "phase shifts" in the dominant biota.
The dual isotopes of deep nitrate as a constraint on the cycle and budget of oceanic fixed nitrogen
(2009)
We compare the output of an 18-box geochemical model of the ocean with measurements to investigate the controls on both the mean values and variation of nitrate delta N-15 and delta O-18 in the ocean interior. The delta O-18 of nitrate is our focus because it has been explored less in previous work. Denitrification raises the delta N-15 and delta O-18 of mean ocean nitrate by equal amounts above their input values for N-2 fixation (for delta N-15) and nitrification (for delta O-18), generating parallel gradients in the delta N-15 and delta O-18 of deep ocean nitrate. Partial nitrate assimilation in the photic zone also causes equivalent increases in the delta N-15 and delta O-18 of the residual nitrate that can be transported into the interior. However, the regeneration and nitrification of sinking N can be said to decouple the N and O isotopes of deep ocean nitrate, especially when the sinking N is produced in a low latitude region, where nitrate consumption is effectively complete. The delta N-15 of the regenerated nitrate is equivalent to that originally consumed, whereas the regeneration replaces nitrate previously elevated in delta O-18 due to denitrification or nitrate assimilation with nitrate having the delta O-18 of nitrification. This lowers the delta O-18 of mean ocean nitrate and weakens nitrate delta O-18 gradients in the interior relative to those in delta N-15. This decoupling is characterized and quantified in the box model, and agreement with data shows its clear importance in the real ocean. At the same time, the model appears to generate overly strong gradients in both delta O-18 and delta N-15 within the ocean interior and a mean ocean nitrate delta O-18 that is higher than measured. This may be due to, in the model, too strong an impact of partial nitrate assimilation in the Southern Ocean on the delta N-15 and delta O-18 of preformed nitrate and/or too little cycling of intermediate-depth nitrate through the low latitude photic zone.
"Hastite", the orthorhombic dimorph of CoSe2, formerly considered as a valid mineral species occurring in the Trogtal quarries, Harz Mountains, Germany, is discredited as being identical with ferroselite, orthorhombic FeSe2. The discreditation has been unanimously approved by the IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) (IMA No. 07-E). We also provide observations on the composition, homogeneity, and origin of trogtalite (cubic CoSe2) from its type locality.
P>A vertical array of accelerometers was installed in Atakoy (western Istanbul) with the long-term aim of improving our understanding of in situ soil behaviour, to assess the modelling and parametric uncertainties associated with the employed methodologies for strong-motion site-response analysis, and for shallow geological investigations. Geotechnical and geophysical investigations were carried out to define the subsoil structure at the selected site. Data associated with 10 earthquakes (2.7 < M < 4.3) collected during the first months of operation of the array were used to image the upgoing and downgoing waves by deconvolution of waveforms recorded at different depths. Results have shown that the velocity of propagation of the imaged upgoing and downgoing waves in the borehole is consistent with that of S or P waves, depending on the component of ground acceleration analysed but independent of the chosen signal window. In particular, an excellent agreement was found between the observed upgoing and downgoing wave traveltimes and the ones calculated using a model derived by seismic noise analysis of array data. The presence of a smaller pulse on the waveforms obtained by deconvolution of the horizontal components suggests both internal S-wave reflection and S-to-P mode conversion, as well as a not normal incidence of the wavefield. The presence of a pulse propagating with S-wave velocity in the uppermost 25 m in the waveforms obtained by the deconvolution of the vertical components suggests P-to-S mode conversion. These evidences imply that, even when site amplification is mainly related to 1-D effects, the standard practice in engineering seismology of deconvolving the surface recording down to the bedrock using an approximate S-wave transfer function (generally valid for vertical incidence of SH waves) might lead to errors in the estimation of the input ground motion required in engineering calculations. Finally, downgoing waves with significant amplitudes were found down to 70 m and even to 140 m depth. This result provides a warning about the use of shallow borehole recordings as input for the numerical simulation of ground motion and for the derivation of ground motion prediction relationships.
Foreland-basin systems are excellent archives to decipher the feedbacks between surface and tectonic processes in orogens. The sedimentary architecture of a foreland-basin system reflects the balance between tectonic subsidence causing long-term accommodation space and sediment influx corresponding to efficiency of erosion and mass-redistribution processes. In order to explore the effects of climatic and tectonic forcing in such a system, I investigated the Oligo-Miocene foreland-basin sediments of the southern Alborz mountains, an intracontinental orogen in northern Iran, related to the Arabia-Eurasia continental collision. This work includes absolute dating methods such as 40Ar/39Ar and zircon (U-Th)/He thermochronology, magnetostratigraphy, sedimentological analysis, sandstone and conglomerate provenance study, carbon and oxygen isotope analysis, and clay mineralogy study. Results show a systematic correlation between coarsening-upward cycles and sediment accumulation rates in the basin on 105 to 106yr time scales. During thrust loading phases, the coarse-grained fraction supplied by the uplifting range is stored in the proximal part of the basin (sedimentary facies retrogradation), while fine-grained sediments are deposited in distal sectors. Variations in sediment provenance during these phases of enhanced tectonic activity give evidence for erosional unroofing phases and/or drainage-reorganization events. In addition, enhanced tectonic activity promoted the growth of topography and associated orographic barrier effects, as demonstrated by sedimentologic indicators and the analysis of stable C and O isotopes from calcareous paleosols and lacustrine/palustrine samples. Extensive progradation of coarse-grained deposits occurs during phases of decreased subsidence, when the coarse-grained fraction supplied by the uplifting range cannot be completely stored in the proximal part of the basin. In this environment, a reduction in basin subsidence is associated with laterally stacked fluvial channel deposits, and is related to intra-foreland uplift, as documented by growth strata, tectonic tilting, and sediment reworking. Increase in sediment accumulation rate associated with progradation of vertically-stacked coarse-grained fluvial channels also occurs. Paleosol O-isotope data shows that this increase is related to wetter climatic phases, suggesting that surface processes are more efficient and exhumation rates increase, giving rise to a positive feedback. Furthermore, isotopic and sedimentologic data show that starting from 10-9 Ma, climate became less arid with an increase in seasonality of precipitation. Because important changes were also recorded in the Mediterranean Sea and Asia at that time, the evidence for climatic variability observed in the Alborz mountains most likely reflects changes in Northern Hemisphere atmospheric circulation patterns. This study has additional implications for the evolution of the Alborz mountains and the Arabia-Eurasia continental collision zone. At the orogenic scale, the locus of deformation did not move steadily southward, but stepped forward and backward since Oligocene time. In particular, from ~ 17.5 to 6.2 Ma the orogen grew by a combination of frontal accretion and wedge-internal deformation on time scales of ca. 0.7 to 2 m.y. Moreover, the provenance data suggest that prior to 10-9 Ma the shortening direction changed from NW-SE to NNE-SSW, in agreement with structural data. On the scale of the entire collision zone, the evolution of the studied basins and adjacent mountain ranges suggests a new geodynamic model for the evolution of the Arabia-Eurasia continental collision zone. Numerous sedimentary basins in the Alborz mountains and in other locations of the Arabia-Eurasia collision zone record a change from a tensional (transtensional) to a compressional (transpressional) tectonic setting by ~ 36 Ma. I interpret this to reflect the onset of subduction of the stretched Arabian continental lithosphere beneath central Iran, leading to moderate plate coupling and lower- and upper-plate deformation (soft continental collision). The increase in deformation rates in the southern Alborz mountains from ~ 17.5 Ma suggests that significant upper-plate deformation must have started by the early Miocene most likely in response to an increase in degree of plate coupling. I suggest that this was related to the subduction of thicker Arabian continental lithosphere and the consequent onset of hard continental collision. This model reconciles the apparent lag time of 15-20 m.y between the late Eocene to early Oligocene age for the initial Arabia-Eurasia continental collision and the onset of widespread deformation across the collision zone to the north in early to late Miocene time.
Tectonic and climatic control on evolution of rift lakes in the Central Kenya Rift, East Africa
(2009)
The long-term histories of the neighboring Nakuru-Elmenteita and Naivasha lake basins in the Central Kenya Rift illustrate the relative importance of tectonic versus climatic effects on rift-lake evolution and the formation of disparate sedimentary environments. Although modem climate conditions in the Central Kenya Rift are very similar for these basins, hydrology and hydrochemistry of present-day lakes Nakuru, Elmenteita and Naivasha contrast dramatically due to tectonically controlled differences in basin geometries, catchment size, and fluvial processes. In this study, we use eighteen C-14 and Ar-40/Ar-39 dated fluvio-lacustrine sedimentary sections to unravel the spatiotemporal evolution of the lake basins in response to tectonic and climatic influences. We reconstruct paleoclimatic and ecological trends recorded in these basins based on fossil diatom assemblages and geologic field mapping. Our study shows a tendency towards increasing alkalinity and shrinkage of water bodies in both lake basins during the last million years. Ongoing volcano-tectonic segmentation of the lake basins, as well as reorganization of upstream drainage networks have led to contrasting hydrologic regimes with adjacent alkaline and freshwater conditions. During extreme wet periods in the past, such as during the early Holocene climate optimum, lake levels were high and all basins evolved toward freshwater systems. During drier periods some of these lakes revert back to alkaline conditions, while others maintain freshwater characteristics. Our results have important implications for the use and interpretation of lake sediment as climate archives in tectonically active regions and emphasize the need to deconvolve lacustrine records with respect to tectonics versus climatic forcing mechanisms.
Suspended sediment transport in a highly erodible catchment : the River Isábena (Southern Pyrenees)
(2009)
Understanding and quantifying sediment load is important in catchments draining highly erodible materials that eventually contribute to siltation of downstream reservoirs. Within this context, the suspended sediment transport and its temporal dynamics have been studied in the River Isabena (445 km(2), south-central Pyrenees, Ebro basin) by means of direct sampling and turbidity recording during a 3-year dry period. The average flood-suspended sediment concentration was 8 g l(-1). with maximum instantaneous values above 350 g l(-1). The high scatter between discharge and suspended sediment concentrations (up to five orders of magnitude) has not permitted the use of rating curve methods to estimate the total load. Interpolation techniques yielded a mean annual sediment load of 184,253 t y(-1) for the study period, with a specific yield of 414 t km(-2) y(-1). This value resembles those reported for small torrents in nearby mountainous environments and is the result of the high connectivity between the badland source areas and stream courses, a fact that maximises sediment conveyance through the catchment. Floods dominated the sediment transport and yield. However, sediment transport was more constant through time than that observed in Mediterranean counterparts; this can be attributed to the role of base flows that entrain fine sediment temporarily stored in the channel and force the river to carry high sediment concentrations (i.e., generally in the order of 0.5 g l(-1)), even under minimum flow conditions.
The low-productivity South Pacific Gyre (SPG) is Earth's largest oceanic province. Its sediment accumulates extraordinarily slowly (0.1-1 m per million years). This sediment contains a living community that is characterized by very low biomass and very low metabolic activity. At every depth in cored SPG sediment, mean cell abundances are 3 to 4 orders of magnitude lower than at the same depths in all previously explored subseafloor communities. The net rate of respiration by the subseafloor sedimentary community at each SPG site is 1 to 3 orders of magnitude lower than the rates at previously explored sites. Because of the low respiration rates and the thinness of the sediment, interstitial waters are oxic throughout the sediment column in most of this region. Consequently, the sedimentary community of the SPG is predominantly aerobic, unlike previously explored subseafloor communities. Generation of H-2 by radiolysis of water is a significant electron-donor source for this community. The per-cell respiration rates of this community are about 2 orders of magnitude higher (in oxidation/reduction equivalents) than in previously explored anaerobic subseafloor communities. Respiration rates and cell concentrations in subseafloor sediment throughout almost half of the world ocean may approach those in SPG sediment.
Measurements of benthic foraminiferal cadmium:calcium (Cd/Ca) have indicated that the glacial-interglacial change in deep North Pacific phosphate (PO4) concentration was minimal which has been taken by some, workers as a sign that the biological pump did not store more carbon in the deep glacial ocean. Here we present sedimentary redox- sensitive trace metal records from Ocean Drilling Program (ODP) Site 882 (NW subarctic Pacific, water depth 3244 m) to make inferences about changes in deep North Pacific oxygenation and thus respired carbon storage - over the past 150,000 yr. These observations are complemented with biogenic barium and opal measurements as indicators for past organic carbon export to separate the influences of deep-water oxygen concentration and sedimentary organic carbon respiration on the redox state of the sediment. Our results suggest that the deep subarctic Pacific water mass was deleted in ox en during glacial maxima, though it was not anoxic. We reconcile our results with the existing benthic foraminiferal Cd/Ca by invoking a decrease in the fraction of the deep ocean nutrient inventory that was preformed, rather than remineralized. This change would have corresponded to an increase in the deep Pacific storage of respired carbon, which Would have lowered atmospheric carbon dioxide (CO2) by sequestering CO2 away from the atmosphere and by increasing ocean alkalinity through a transient dissolution event in the deep sea. The magnitude of change in preformed nutrients suggested by the North Pacific data Would have accounted for a majority of the observed decrease in glacial atmospheric PCO2.