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Monolayers of rod-shaped and disc-shaped liquid crystalline compounds at the air-water interface
(1986)
Calamitic (rod-shaped) and discotic (disc-shaped) thermotropic liquid crystalline (LC) compounds were spread at the air-water interface, and their ability to form monolayers was studied. The calamitic LCs investigated were found to form monolayers which behave analogously to conventional amphiphiles such as fatty acids. The spreading of the discotic LCs produced monolayers as well, but with a behaviour different from classical amphiphiles. The areas occupied per molecule are too small to allow the contact of all hydrophilic groups with the water surface and the packing of all hydrophobic chains. Various molecular arrangements of the discotics at the water surface to fit the spreading data are discussed.
In order to investigate the temporal characteristics of cognitive processing, we apply multivariate phase synchronization analysis to event-related potentials. The experimental design combines a semantic incongruity in a sentence context with a physical mismatch (color change). In the ERP average, these result in an N400 component and a P300-like positivity, respectively. The synchronization analysis shows an effect of global desynchronization in the theta band around 288ms after stimulus presentation for the semantic incongruity, while the physical mismatch elicits an increase of global synchronization in the alpha band around 204ms. Both of these effects clearly precede those in the ERP average. Moreover, the delay between synchronization effect and ERP component correlates with the complexity of the cognitive processes.
The boundary paradigm (Rayner, 1975) with a novel preview manipulation was used to examine the extent of parafoveal processing of words to the right of fixation. Words n+1 and n+2 had either correct or incorrect previews prior to fixation (prior to crossing the boundary location). In addition, the manipulation utilized either a high or low frequency word in word n+1 location on the assumption that it would be more likely that n+2 preview effects could be obtained when word n+1 was high frequency. The primary findings were that there was no evidence for a preview benefit for word n+2 and no evidence for parafoveal-on-foveal effects when word n+1 is at least four letters long. We discuss implications for models of eye-movement control in reading.
The end of the cold war division of the Baltic Sea in 1989, and the three Baltic states’ return to independence in 1991 created new opportunities for the decision-makers of the area, as well as new possibilities for fashioning security in the region. This article will examine the security debate affecting the Baltic Sea region in the post-cold war period, and in particular, the relevance of the European Union to that debate. The following section will examine various concepts of security relevant to the Baltic region; the third section looks at the EU and the Baltic area; and the last part deals with the implications that EU membership by the Baltic Sea states may have for the security of the Baltic Sea zone.
Wie beständig ist der Mythos „Barack Obama“? Klar ist: Der neue Präsident tritt ein schweres Erbe an. Herausforderungen wie die Wirtschaftskrise, schwierige außen- und sicherheitspolitische Gegebenheiten und die Beziehungen zu Russland warten auf ihn. Der Autor, ein exzellenter Kenner der USA und ehemaliger Diplomat, beleuchtet die Situation der Vereinigten Staaten nach der Wahl.
Many methods have been proposed for the simulation of constrained mechanical systems. The most obvious of these have mild instabilities and drift problems. Consequently, stabilization techniques have been proposed A popular stabilization method is Baumgarte's technique, but the choice of parameters to make it robust has been unclear in practice. Some of the simulation methods that have been proposed and used in computations are reviewed here, from a stability point of view. This involves concepts of differential-algebraic equation (DAE) and ordinary differential equation (ODE) invariants. An explanation of the difficulties that may be encountered using Baumgarte's method is given, and a discussion of why a further quest for better parameter values for this method will always remain frustrating is presented. It is then shown how Baumgarte's method can be improved. An efficient stabilization technique is proposed, which may employ explicit ODE solvers in case of nonstiff or highly oscillatory problems and which relates to coordinate projection methods. Examples of a two-link planar robotic arm and a squeezing mechanism illustrate the effectiveness of this new stabilization method.
Many methods have been proposed for the stabilization of higher index differential-algebraic equations (DAEs). Such methods often involve constraint differentiation and problem stabilization, thus obtaining a stabilized index reduction. A popular method is Baumgarte stabilization, but the choice of parameters to make it robust is unclear in practice. Here we explain why the Baumgarte method may run into trouble. We then show how to improve it. We further develop a unifying theory for stabilization methods which includes many of the various techniques proposed in the literature. Our approach is to (i) consider stabilization of ODEs with invariants, (ii) discretize the stabilizing term in a simple way, generally different from the ODE discretization, and (iii) use orthogonal projections whenever possible. The best methods thus obtained are related to methods of coordinate projection. We discuss them and make concrete algorithmic suggestions.
On the occasion of the 30th anniversary of the Warsaw treaty’s signing, Egon Bahr, the intellectual father of the German Ostpolitik, describes his courageous efforts at that time. The aim of this politics was to gain space for strengthening own peace and security in Europe. Irrefutable principles of the policy of that time were non-aggression and the recognition of the borders. Going back to these principles, Egon Bahr redefines Germany’s future foreign policy too. Jahresabo: 40,00 € (ermäßigt: 25,00 €)
Parsing costs as predictors of reading difficulty: An evaluation using the Potsdam Sentence Corpus
(2008)
The surprisal of a word on a probabilistic grammar constitutes a promising complexity metric for human sentence comprehension difficulty. Using two different grammar types, surprisal is shown to have an effect on fixation durations and regression probabilities in a sample of German readers’ eye movements, the Potsdam Sentence Corpus. A linear mixed-effects model was used to quantify the effect of surprisal while taking into account unigram and bigram frequency, word length, and empirically-derived word predictability; the so-called “early” and “late” measures of processing difficulty both showed an effect of surprisal. Surprisal is also shown to have a small but statistically non-significant effect on empirically-derived predictability itself. This work thus demonstrates the importance of including parsing costs as a predictor of comprehension difficulty in models of reading, and suggests that a simple identification of syntactic parsing costs with early measures and late measures with durations of post-syntactic events may be difficult to uphold.
Eye fixation durations during normal reading correlate with processing difficulty but the specific cognitive mechanisms reflected in these measures are not well understood. This study finds support in German readers’ eyefixations for two distinct difficulty metrics: surprisal, which reflects the change in probabilities across syntactic analyses as new words are integrated, and retrieval, which quantifies comprehension difficulty in terms of working memory constraints. We examine the predictions of both metrics using a family of dependency parsers indexed by an upper limit on the number of candidate syntactic analyses they retain at successive words. Surprisal models all fixation measures and regression probability. By contrast, retrieval does not model any measure in serial processing. As more candidate analyses are considered in parallel at each word, retrieval can account for the same measures as surprisal. This pattern suggests an important role for ranked parallelism in theories of sentence comprehension.
This introduction provides an overview of feminist approaches to International Relations. The authors compare the Anglo-American debate with the Germanspeaking discussion in order to reveal similarities and differences. They identify three particular areas of research that characterize the German-speaking feminist debate in International Relations: (1) works evolving out of peace studies; (2) research on globalization and international economic institutions; (3) studies focusing on women’s movements together with most current works centering around international norms. They argue that feminist approaches to norms constitute a particularly promising research area which provides new "tools" to account for international, regional or domestic policy-change. Gender-sensitive research on norms also allows to address ethical questions that are vital for feminist understandings of science. Moreover, this new focus on norms enables bridge-building between feminism and the mainstream.
Am 8. August 2008 richtete sich alle mediale Aufmerksamkeit schlagartig von Beijing und den Olympischen Spielen auf den Kaukasus – genauer: auf Georgien. Unvorbereitet traf die Meldung über den Krieg im Kaukasus aber nur diejenigen, die glaubten, die „eingefrorenen Konflikte“ im Süden des Gebirgszuges seien beigelegt. Seit den Kriegen um die „abtrünnigen Teilrepubliken“ Georgiens, Südossetien und Abchasien, in den frühen 1990er Jahren sind diese jedoch nie zur Ruhe gekommen.
In the rapidly growing literature on globalization, many authors have emphasized the apparent disembedding of social relations from their local-territorial preconditions. Such arguments neglect the relatively fixed and immobile forms of territorial organization upon which the current round of globalization is premised, such as urban-regional agglomerations and territorial states. Drawing on the work of David Harvey and Henri Lefebvre, this article argues that processes of reterritorialization - the reconfiguration of forms of terrritorial organization such as cities and states - must be viewed as an intrinsic moment of the current round of globalization. Globalization is conceived here as a reterritorialization of both socio-economic and political-institutional spaces that unfolds simultaneously upon multiple, superimposed geographical scales. The ongoing restructuring of contemporary urban spaces and state institutional-territorial structures must be viewed at once as presupposition, a medium and an outcome of this highly contested dynamic of global spatial restructuring. New theories and representations of the scaling of spatial practices are needed to grasp the rapidly changing territorial organization of world capitalism in the late 20th century.
The use of nano zerovalent iron (nZVI) for environmental remediation is a promising new technique for in situ remediation. Due to its high surface area and high reactivity, nZVI is able to dechlorinate organic contaminants and render them harmless. Limited mobility, due to fast aggregation and sedimentation of nZVI, limits the capability for source and plume remediation. Carbo-Iron is a newly developed material consisting of activated carbon particles (d50 = 0,8 µm) that are plated with nZVI particles. These particles combine the mobility of activated carbon and the reactivity of nZVI. This paper presents the first results of the transport experiments.
Mit diesem Heft wird die Diskussion über eine neue deutsche Ostpolitik fortgesetzt und abgeschlossen. Diese hatte im Heft Nr. 49 mit Thesen von Jochen Franzke begonnen, im nächsten Heft wurden erste Beiträge publiziert. Insgesamt haben sich Wissenschaftler und Politiker aus Deutschland, Österreich, Polen, Finnland und Tschechien beteiligt. Die Debatte schließt mit Schlussbemerkungen des Initiators. Ulrich Best, Katrin Böttger, Vladimir Handl, Heinz Timmermann, Christian Wipperfürth, Sabina Wölkner, Gesine Schwan, Dieter Segert, Beata Wilga, Markus Löning und Ole Diehl, Angelica Schwall-Düren, Wolfgang Gehrcke und Jochen Franzke
The article argues that the concept of statehood is not functioning any longer. It exists a crisis for the international legal order which is represented by the failure of state to maintain order within its borders. The problem of violence in international relations are connected to the implosion of a considerable number of the state entities in the contemporary international society. The federalist institutional approach in international law and international theory could not contribute in an appropriate way to the solution of the "problem of violence", because it supposes a willingness on the part of states to do so. Only the concept of "national interest", in a sociological sense, connected to the development of a discource of solidarity and mutual responsibility between the "West" and the "rest of the world" offers the possibility to create a common consciousness which could make it easier to overcome the contemporary crises for the international legal order.
A multitype Dawson-Watanabe process is conditioned, in subcritical and critical cases, on non-extinction in the remote future. On every finite time interval, its distribution is absolutely continuous with respect to the law of the unconditioned process. A martingale problem characterization is also given. Several results on the long time behavior of the conditioned mass process - the conditioned multitype Feller branching diffusion - are then proved. The general case is first considered, where the mutation matrix which models the interaction between the types, is irreducible. Several two-type models with decomposable mutation matrices are analyzed too .
The ten-years presidency of Alberto Fujimori in Peru is a classic example of the sort of hybrid democracy that emerged in various Latin American countries in the 1990s, combining a mixture of democratic and clearly non-democratic elements. Fujimori was one of the more autocratic Latin American leaders of the 1990s, he is being the only regime formally to break with pre-existing constitutional rules. Closely tied to the military and intelligence apparatus, his government involved a concentration of political power that reduced the scope and autonomy of other branches of the state. But, unlike previous Latin American military dictatorships, Fujimori’s government enjoyed a considerable popularity, born out of disaffection for representative institutions. The article argues, however, that these characteristics of apparent strength carried within them the seeds of their own destruction. Far from establishing lasting political stability, the regime was weakly based. Within six weeks of his inauguration for a third term in July 2000, Fujimori was obliged to announce his intention to withdraw from politics. Two months later, he was ousted altogether.
After the democratic euphoria of the early 1990s, today the "third wave of democratization" seems to be less a triumph of political liberalism and much more a success story of a "defective" form of democracy. The authors argue that none of the strategies which can be found in contemporary democratization studies is satisfactory. They offer an alternative two-step-strategy of (1) specifying the root concept of democracy and (2) building subtypes of democracy which are based on this specified root concept. In doing so, the authors conceptualize the model of embedded democracy, from which they generate the concept of "defective democracy" and present a typology of these "defective democracies".