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- Riemannian manifold (2)
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- Risiko (2)
- Rohstoffe (2)
- RubisCO (2)
- Rumpf (2)
- Russisch (2)
- Räuber-Beute (2)
- Röntgenstrahlung (2)
- Rückenschmerzen (2)
- SAR (2)
- SCFA (2)
- SDS PAGE (2)
- SDS-PAGE (2)
- SHG (2)
- SIEM (2)
- STG decomposition (2)
- STG-Dekomposition (2)
- STM (2)
- Sakkadendetektion (2)
- Salz (2)
- Salzschmelze-Templating (2)
- Sanierung (2)
- Satellitenbilder (2)
- Satzverständnis (2)
- Sauerstoff (2)
- Savanna (2)
- Savanne (2)
- Scalability (2)
- Schaum (2)
- Schema-Entdeckung (2)
- Schnee (2)
- Schriftspracherwerb (2)
- Schwarmbeben (2)
- Schwarzes Loch (2)
- Schwarzes Meer (2)
- Sedimentation (2)
- Sedimentology (2)
- Sedimenttransport (2)
- Seesediment (2)
- Seitenverschiebung (2)
- Selbstassemblierung (2)
- Selektion (2)
- Selektivität (2)
- Selen (2)
- Sensitivitätsanalyse (2)
- Sensor (2)
- Sentinel-1 (2)
- Sequence alignment (2)
- Sequenzierung der nächsten Generation (2)
- Service-Oriented Architecture (2)
- Service-Orientierte Architekturen (2)
- Silene vulgaris (2)
- Silizium (2)
- Simulated patients (2)
- Situations (2)
- Skalierbarkeit (2)
- Skalierung (2)
- Slumming (2)
- Software (2)
- Softwarevisualisierung (2)
- Sol-Gel (2)
- Solanaceae (2)
- Solanum tuberosum (2)
- Solar corona (2)
- Solidago canadensis (2)
- Solidago gigantea (2)
- Sonne (2)
- Sorption (2)
- South America (2)
- South Korea (2)
- Spin Geometry (2)
- Sport (2)
- Sprachkontakt (2)
- Sprachwissenschaft (2)
- Staatsbürgerschaft (2)
- Standardized patients (2)
- State Machine (2)
- Statistik (2)
- Sternatmosphären (2)
- Sternphysik (2)
- Stochastic Differential Equation (2)
- Stochastik (2)
- Stochastische Resonanz (2)
- Stochastischer Prozess (2)
- Stratigraphy (2)
- Streuung (2)
- Strukturbildung (2)
- Stärke (2)
- Störungen (2)
- Sun: activity (2)
- Sun: coronal mass ejections (CMEs) (2)
- Supernovaüberrest (2)
- Supraleiter (2)
- Surrogate Data (2)
- Survey (2)
- Survival (2)
- Sustainability (2)
- Svalbard (2)
- Swedish (2)
- Switzerland (2)
- Synchronisierung (2)
- Synchrotronstrahlung (2)
- Synthesis (2)
- SysML (2)
- Systematic review (2)
- Systemsoftware (2)
- Säuglinge (2)
- Südamerika (2)
- Südkorea (2)
- Südostasien (2)
- TAVI (2)
- TRMM (2)
- Tagalog acquisition (2)
- Taiwan (2)
- Team sports (2)
- Technologiebewertung (2)
- Tectonics (2)
- Temporallogik (2)
- Tense Semantics (2)
- Tensid (2)
- Testen (2)
- Theorembeweisen (2)
- Theoretische Ökologie (2)
- Thermal effects (2)
- Thermokarst (2)
- Thiouracil (2)
- Tibet Plateau (2)
- Tiefer See (2)
- Tien Shan (2)
- Tomographie (2)
- Topik (2)
- Topographie (2)
- Totes Meer Störungssystem (2)
- Transkriptom (2)
- Transmembranprotein (2)
- Transparenz (2)
- Transport (2)
- Tree (2)
- Trends (2)
- Tunneleffekt (2)
- Turkish-German bilingualism (2)
- Typ-2-Diabetes (2)
- UAV (2)
- UV radiation (2)
- Ultrazentrifuge (2)
- Uncertainties (2)
- Unifikation (2)
- Universität Potsdam (2)
- VIIRS DNB (2)
- Validation (2)
- Vergewaltigungsmythen (2)
- Verhalten (2)
- Verification (2)
- Versionsverwaltung (2)
- Verwaltungsreform (2)
- Verwerfungen (2)
- Virtual Reality (2)
- Visual World (2)
- Visualization (2)
- Vitamin A (2)
- Vogtland/West Bohemia (2)
- Vogtland/Westböhmen (2)
- Vollkorn (2)
- Vorlandbecken (2)
- Vulkan (2)
- WKB method (2)
- Wahrnehmung (2)
- Wahrscheinlichkeitstheorie (2)
- Wald (2)
- Waldbewirtschaftung (2)
- Walking (2)
- Warven (2)
- Wasserqualität (2)
- Wellengleichung (2)
- Werkzeuge (2)
- West Germany (2)
- Westdeutschland (2)
- Wetterextreme (2)
- Wetterlagen (2)
- Wiederkehrdiagramme (2)
- Wiener measure (2)
- Winderosion (2)
- Wirbelsäule (2)
- Wirtschaft (2)
- Wissenschaftsgeschichte (2)
- Wissensgraph (2)
- Work-related Training (2)
- World Bank (2)
- Worterkennung (2)
- Wärmefluss (2)
- Wärmeleitfähigkeit (2)
- X-rays: binaries (2)
- Younger Dryas (2)
- Youth (2)
- Zaremba problem (2)
- Zellmotilität (2)
- Zellproliferation (2)
- Zink (2)
- Zooplankton (2)
- Zugriffskontrolle (2)
- Zuweisung thematischer Rollen (2)
- Zwei-Prozess Modelle (2)
- Zwitterionen (2)
- absorption (2)
- academic failure (2)
- academic leadership (2)
- accretion (2)
- acculturation (2)
- accumulation rates (2)
- accuracy (2)
- achilles tendinopathy (2)
- acid ceramidase (2)
- actin cytoskeleton (2)
- action language (2)
- active galactic nuclei (2)
- active labor market policies (2)
- activity (2)
- acute coronary syndrome (2)
- acute kidney injury (2)
- ad hoc learning (2)
- ad hoc messaging network (2)
- adaptive Systeme (2)
- adaptive force (2)
- adaptive systems (2)
- additive particle (2)
- additive particles (2)
- adipogenesis (2)
- adipose tissue (2)
- administrative reforms (2)
- adoption (2)
- aerosols (2)
- aesthetics (2)
- affective priming (2)
- age differences (2)
- age of acquisition (2)
- aggregation (2)
- aid effectiveness (2)
- air-water interface (2)
- alcohol consumption (2)
- alexithymia (2)
- allgemeine Relativitätstheorie (2)
- alumni work (2)
- amoeboid motion (2)
- amygdala (2)
- amöboide Bewegung (2)
- analytic continuation (2)
- anaphora (2)
- anaphors (2)
- ancient (2)
- ancient sedimentary DNA (2)
- angiogenesis (2)
- animacy (2)
- anisotropy (2)
- annotation (2)
- annotation projection (2)
- anomaly detection (2)
- antecedent complexity (2)
- anthropometry (2)
- anti-doping (2)
- anti-fouling materials (2)
- antibody (2)
- antidepressants (2)
- antifouling (2)
- apoptosis (2)
- aptamers (2)
- aquatic ecosystems (2)
- aquatic fungi (2)
- arable land (2)
- arbuscular mycorrhizal symbiosis (2)
- architecture (2)
- area (2)
- argument mining (2)
- argumentation (2)
- argumentation structure (2)
- arktische Tundra (2)
- arsenolipids present (2)
- aspect (2)
- assemblies (2)
- associations (2)
- astrocytes (2)
- astronomy (2)
- astrophotonics (2)
- asymptotic expansion (2)
- athmospheric circulation (2)
- atom chip (2)
- attenuation tomography (2)
- attitudes (2)
- attribution (2)
- august 2002 (2)
- authenticity (2)
- autocorrelation (2)
- automation (2)
- autophagy (2)
- auxotrophy (2)
- avoidance (2)
- azobenzene surfactant (2)
- batch processing (2)
- behaviour (2)
- benchmarking (2)
- bicameralism (2)
- big data services (2)
- binary black holes (2)
- biochemistry (2)
- biodegradable polymers (2)
- bioelectrocatalysis (2)
- biofilms (2)
- biogenic amine (2)
- biomaterial (2)
- biosensors (2)
- bird migration (2)
- birds (2)
- birth-death-mutation-competition point process (2)
- black hole (2)
- blind source separation (2)
- body image (2)
- bone remodeling (2)
- book history (2)
- boronic acid (2)
- boundary element method (2)
- bounded model checking (2)
- brain (2)
- branched chain amino acids (2)
- branching (2)
- brushes (2)
- brushite (2)
- bullying (2)
- business model (2)
- calcite (2)
- calcium (2)
- calcium carbonate (2)
- canalization (2)
- cancer detection (2)
- capacity (2)
- carbon dots (2)
- carbon materials (2)
- carbon monoxide (2)
- carbon pricing (2)
- carbon-cycle (2)
- carbon-dioxide (2)
- carbon-dioxide capture (2)
- carbon-dioxide emissions (2)
- cardiorespiratory fitness (2)
- cardiovascular diseases (2)
- cardiovascular-disease (2)
- catalysts (2)
- cavity quantum electrodynamics (2)
- cell motility (2)
- cell polarity (2)
- cell wall (2)
- cell-based assay (2)
- cellular bioenergetics (2)
- cellular signalling (2)
- censoring (2)
- centrosome (2)
- charge storage (2)
- charge transport (2)
- charge-transfer (2)
- child (2)
- chimera states (2)
- chitosan (2)
- chlamydomonas (2)
- chromatin (2)
- chronic kidney disease (2)
- chronic pain (2)
- chronisch-entzündliche Darmerkrankungen (2)
- circular dichroism (2)
- circulation patterns (2)
- citation analysis (2)
- citizen participation (2)
- citizenship (2)
- cleft constructions (2)
- climate dynamics (2)
- climate extremes (2)
- climate impacts (2)
- climate networks (2)
- climate varibility (2)
- clinical sample (2)
- cluster analysis (2)
- clusters (2)
- co-limitation (2)
- co-occurrence analysis (2)
- coast (2)
- coastal flood damage (2)
- cobalt (2)
- cod-liver (2)
- coefficient (2)
- coffee (2)
- coffee processing (2)
- cognitive control (2)
- cognitive enhancement (2)
- cognitive psychology (2)
- cognitive skills (2)
- coiled coil (2)
- collaborative work (2)
- colloid (2)
- combat sports (2)
- community ecology (2)
- community structure (2)
- comorbidity (2)
- complex (2)
- complex network (2)
- compression (2)
- computational biology (2)
- computational design (2)
- computed tomography (2)
- computer games (2)
- computer graphics (2)
- computer science education (2)
- computer security (2)
- computer-based training (2)
- concepts (2)
- concurrent training (2)
- conditional reasoning (2)
- conduct problems (2)
- confinement (2)
- conflict management (2)
- conflict resolution (2)
- conformational-changes (2)
- congeneric species (2)
- conjunction (2)
- constitutive activity (2)
- construct validity (2)
- consumer behavior (2)
- content-addressable memory (2)
- continental lithosphere (2)
- continuous integration (2)
- contrast (2)
- contrastive topic (2)
- control (2)
- controlled polymerization (2)
- conversation analysis (2)
- convolutional neural network (2)
- cooperative phenomena (2)
- coping strategies (2)
- coronary artery disease (2)
- coronary heart disease (2)
- corruption (2)
- cortisol (2)
- cosmological simulations (2)
- counting (2)
- coupling (2)
- crisis (2)
- cryptography (2)
- cues (2)
- cultural identity (2)
- culture (2)
- cyber-physische Systeme (2)
- cyberbullying victimization (2)
- cyclic AMP (2)
- cycling (2)
- cytochrome c (2)
- cytosolic tRNA thiolation (2)
- damage estimation (2)
- dark matter (2)
- data (2)
- data fusion (2)
- data privacy (2)
- data processing (2)
- data quality (2)
- data science (2)
- database systems (2)
- decentralisation (2)
- deception (2)
- decision trees (2)
- decline (2)
- deduplication (2)
- deep convection (2)
- deep reinforcement learning (2)
- deep-sea (2)
- deficiency (2)
- definite pseudoclefts (2)
- definiteness (2)
- democratization (2)
- denitrification (2)
- density (2)
- dependency resolution (2)
- depressive disorder (2)
- depressive symptoms (2)
- desert (2)
- design (2)
- design parameters (2)
- detailed balance equation (2)
- detector development (2)
- deutsche Geschichte (2)
- developmental dyscalculia (2)
- dialogue (2)
- diatoms (2)
- dictator game (2)
- dietary patterns (2)
- differential gene expression (2)
- differentiation (2)
- digital health (2)
- digital learning (2)
- digital rock physics (2)
- digital sovereignty (2)
- digital technologies (2)
- digital transformation (2)
- digital whiteboard (2)
- digitale Souveränität (2)
- digitalisation (2)
- diode laser spectroscopy (2)
- direct electron transfer (2)
- direct manipulation (2)
- disaster risk reduction (2)
- discourse production (2)
- discourse structure (2)
- discrepancy principle (2)
- discrimination networks (2)
- displacement (2)
- dissolution (2)
- divergent thinking (2)
- diversification (2)
- dopamine (2)
- dormancy (2)
- dropout (2)
- droughts (2)
- drug delivery (2)
- drug release (2)
- drugs (2)
- drylands (2)
- dual-process (2)
- duality formula (2)
- dunkle Materie (2)
- dyadic coping (2)
- dye (2)
- dye removal (2)
- dynamic reconfiguration (2)
- dünne Filme (2)
- e-government (2)
- e-learning platform (2)
- early warning (2)
- earthquake catalog (2)
- earthquake interaction (2)
- earthquake modeling (2)
- earthquake swarm (2)
- earthquake swarm 2008/09 (2)
- earthquake swarms (2)
- earthquakes (2)
- eastern south–central Andes (2)
- eco-hydrological modelling (2)
- eco-hydrology (2)
- ecohydrology (2)
- economic impacts (2)
- ecosystem functioning (2)
- eddy covariance (2)
- edge singularities (2)
- edge-degenerate operators (2)
- effectiveness (2)
- ego depletion (2)
- eindeutige Spaltenkombination (2)
- eingebettete Systeme (2)
- elasticity (2)
- electret (2)
- electrical muscle stimulation (2)
- electrocatalysis (2)
- electrolytes (2)
- electron acceleration (2)
- electron dynamics (2)
- electron-transfer (2)
- electronic structure (2)
- electronic tool integration (2)
- electronic-structure (2)
- electrospinning (2)
- elektronische Struktur (2)
- ellipsis processing (2)
- elliptic boundary value problems (2)
- elliptic families (2)
- elliptic family (2)
- elliptic system (2)
- elliptic systems (2)
- embedded systems (2)
- embodiment (2)
- emotional valence (2)
- emulsion (2)
- endophytes (2)
- energy efficiency (2)
- energy expenditure (2)
- energy prices (2)
- energy-metabolism (2)
- ensemble Kalman filter (2)
- environmental DNA (2)
- environmental change (2)
- environmental filtering (2)
- environmental policy (2)
- ephrin (2)
- epizoochory (2)
- equatorial electrojet (2)
- ereigniskorrelierte Potentiale (2)
- erythropoiesis (2)
- escherichia-coli (2)
- eta-invariant (2)
- ethnic differences (2)
- europium (2)
- eutrophication (2)
- evaluative study (2)
- evaporation (2)
- event synchronization (2)
- event-related potentials (ERP) (2)
- evolution equation (2)
- evolutionary biology (2)
- evolutionary economics (2)
- exact simulation (2)
- exekutive Funktionen (2)
- exercise intensity (2)
- expansion microscopy (2)
- expectation (2)
- experience (2)
- experimental linguistics (2)
- experimental studies (2)
- experimentelle Studien (2)
- exploratory-behavior (2)
- extrasolar planets (2)
- extremes (2)
- eye movement (2)
- eye-movements (2)
- fMRT (2)
- fNIRS (2)
- fabrication (2)
- face morphing (2)
- facial feedback (2)
- facilitation (2)
- failure (2)
- faking (2)
- fatty acid (2)
- fatty acids (2)
- fatty-acids (2)
- fault reactivation (2)
- faults (2)
- feature selection (2)
- federalism (2)
- fence ecology (2)
- ferroelectret (2)
- ferroelectrets (2)
- ferroelectricity (2)
- ferroelectrics (2)
- fiction (2)
- fieldwork (2)
- finance (2)
- finite differences (2)
- fire (2)
- firm performance (2)
- first language acquisition (2)
- first passage time (2)
- first-passage time (2)
- fiscal federalism (2)
- fitness (2)
- fixation durations (2)
- fixational eye movements (2)
- flash floods (2)
- flood hazard (2)
- flooding (2)
- floodplains (2)
- fluid flow (2)
- fluorescence (2)
- fluorescence correlation spectroscopy (2)
- fluorescent dyes (2)
- fluorescent proteins (2)
- foam (2)
- focus ambiguity (2)
- focus asymmetries (2)
- focus constructions (2)
- focus intonation (2)
- focus marker (2)
- focus movement (2)
- focus particle (2)
- focus sensitive expressions (2)
- focus types (2)
- food prices (2)
- force production (2)
- forecasting (2)
- foregrounding (2)
- foreign policy (2)
- forest management (2)
- forest structure (2)
- forestry (2)
- formale Semantik (2)
- formalism (2)
- fracture (2)
- frailty (2)
- fruit (2)
- functional capacity (2)
- functional dependencies (2)
- functional dependency (2)
- functionalization (2)
- fungi (2)
- funktionale Abhängigkeit (2)
- funktionale Abhängigkeiten (2)
- funktionelle Diversität (2)
- gadolinium (2)
- galactic astronomy (2)
- galaktisches Zentrum (2)
- galaxy formation (2)
- gamma rays (2)
- gamma-rays (2)
- gammalib/ctools (2)
- gas adsorption (2)
- gas-production (2)
- geladene Systeme (2)
- gelatin (2)
- gender differences (2)
- gender wage gap (2)
- gene regulation (2)
- gene regulatory networks (2)
- genealogy (2)
- generalization (2)
- genetic screen (2)
- genetischer Screen (2)
- genome scan (2)
- genotype (2)
- geodesics (2)
- geomagnetic field (2)
- geometry (2)
- geostatistics (2)
- geothermal energy (2)
- giving-up density (2)
- glacier (2)
- glaciers (2)
- global monsoon (2)
- global positioning system (2)
- global vegetation model (2)
- globular clusters (2)
- glomerular filtration rate (2)
- glucagon (2)
- glucose (2)
- glutathione (2)
- glycogen (2)
- glycoprotein (2)
- goblet cells (2)
- gold (2)
- gold nanoparticles (2)
- government (2)
- grammar (2)
- graph transformations (2)
- graphite (2)
- grassland (2)
- green growth (2)
- gross primary production (2)
- groundwater (2)
- groundwater recharge (2)
- grüne Chemie (2)
- grüne Investitionen (2)
- guilt (2)
- gut microbiota (2)
- gyrochronology (2)
- habit formation (2)
- habitat (2)
- hard core potential (2)
- health behavior (2)
- health care (2)
- heart (2)
- heart failure (2)
- heart rate variability (2)
- heat equation (2)
- heat stress memory (2)
- heat transport (2)
- hemoglobin amount (2)
- heteroatom-doped carbons (2)
- heteroatoms (2)
- heterosis (2)
- heterotrophic bacteria (2)
- hierarchical porosity (2)
- hierarchische Porosität (2)
- high pressure (2)
- high resolution (2)
- high-intensity interval training (2)
- high-resolution record (2)
- higher education management (2)
- hip (2)
- history and philosophy of astronomy (2)
- hohe Auflösung (2)
- holding capacity (2)
- holding isometric muscle action (HIMA) (2)
- holomorphic solution (2)
- homeostasis (2)
- homotopy classification (2)
- human capital (2)
- human computer interaction (2)
- hybrid (2)
- hybridization capture (2)
- hydraulic fracturing (2)
- hydrodynamic modelling (2)
- hydrodynamische Modellierung (2)
- hydrogenation (2)
- hydrological modeling (2)
- hydrological models (2)
- hydrologische Prozesse (2)
- hydroxyapatite (2)
- hypertension (2)
- hypothesis (2)
- ice (2)
- ice core (2)
- ice sheet (2)
- identity management (2)
- ill-posed problem (2)
- immobilization (2)
- immune system (2)
- immunology (2)
- impact assessment (2)
- implementation (2)
- implicit association test (IAT) (2)
- implicit attitude (2)
- implizit (2)
- in vitro (2)
- in-situ stress (2)
- in-situ testing (2)
- in-vivo (2)
- inbreeding depression (2)
- inclusion dependencies (2)
- inclusion dependency (2)
- index formulas (2)
- index selection (2)
- indirect tests (2)
- individual anaerobic threshold (2)
- individual based modeling (2)
- individuals (2)
- inductive invariant checking (2)
- inertial measurement unit (2)
- infancy (2)
- infection (2)
- inferences (2)
- infinite divisibility (2)
- infinitely divisible point processes (2)
- inflected nouns (2)
- informatics education (2)
- information (2)
- inheritance (2)
- inhibition (2)
- initial data (2)
- injection (2)
- innovation management (2)
- inorganic perovskites (2)
- insula (2)
- insulin signaling (2)
- integral formulas (2)
- integrated optics (2)
- intelligence (2)
- interactional linguistics (2)
- interactive media (2)
- interest (2)
- interface engineering (2)
- interfacial recombination (2)
- international comparison (2)
- international cooperation (2)
- international law (2)
- interoceptive awareness (2)
- interspecific interactions (2)
- intimate partner violence (2)
- intracellular-transport (2)
- intraclass correlation (2)
- intraspecific trait variation (2)
- inundation (2)
- inventory (2)
- inverse ill-posed problem (2)
- inverse theory (2)
- ion mobility spectrometry (2)
- ionic conductivity (2)
- ionic strength (2)
- ionische Flüssigkeiten (2)
- ionosphere (2)
- ions (2)
- isomerization (2)
- isotopes (2)
- job satisfaction (2)
- job search (2)
- jumping (2)
- justice sensitivity (2)
- k-Induktion (2)
- k-induction (2)
- k-inductive invariant checking (2)
- kernel methods (2)
- kidney transplantation (2)
- knowledge (2)
- knowledge graphs (2)
- kognitive Fähigkeiten (2)
- kontinuierliche Integration (2)
- kontrollierte Polymerisation (2)
- kontrollierte radikalische Polymerisationen (2)
- kooperative Phänomene (2)
- labor market policy (2)
- lacustrine sediment (2)
- lake-level change (2)
- landing positions (2)
- langevin equation (2)
- language comprehension (2)
- language processing (2)
- large-scale (2)
- large-scale assessment (2)
- laser powder bed fusion (2)
- laser pulses (2)
- last glacial period (2)
- lead (2)
- leaf (2)
- leaking (2)
- learners (2)
- learning and memory (2)
- learning styles (2)
- lexical tones (2)
- lexicon size (2)
- lichens (2)
- life satisfaction (2)
- lifestyle (2)
- linear mixed model (2)
- linke Peripherie (2)
- linking coefficients (2)
- lipid biomarkers (2)
- lipid metabolism (2)
- liquid-phase catalysis (2)
- live programming (2)
- liver (2)
- load (2)
- local government (2)
- locus coeruleus (2)
- locus of control (2)
- logic (2)
- logic programming (2)
- long-distance dispersal (2)
- long-term effects (2)
- long-time behaviour (2)
- low-back-pain (2)
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Additive manufacturing (AM) processes enable the production of metal structures with exceptional design freedom, of which laser powder bed fusion (PBF-LB) is one of the most common. In this process, a laser melts a bed of loose feedstock powder particles layer-by-layer to build a structure with the desired geometry. During fabrication, the repeated melting and rapid, directional solidification create large temperature gradients that generate large thermal stress. This thermal stress can itself lead to cracking or delamination during fabrication. More often, large residual stresses remain in the final part as a footprint of the thermal stress. This residual stress can cause premature distortion or even failure of the part in service. Hence, knowledge of the residual stress field is critical for both process optimization and structural integrity.
Diffraction-based techniques allow the non-destructive characterization of the residual stress fields. However, such methods require a good knowledge of the material of interest, as certain assumptions must be made to accurately determine residual stress. First, the measured lattice plane spacings must be converted to lattice strains with the knowledge of a strain-free material state. Second, the measured lattice strains must be related to the macroscopic stress using Hooke's law, which requires knowledge of the stiffness of the material. Since most crystal structures exhibit anisotropic material behavior, the elastic behavior is specific to each lattice plane of the single crystal. Thus, the use of individual lattice planes in monochromatic diffraction residual stress analysis requires knowledge of the lattice plane-specific elastic properties. In addition, knowledge of the microstructure of the material is required for a reliable assessment of residual stress.
This work presents a toolbox for reliable diffraction-based residual stress analysis. This is presented for a nickel-based superalloy produced by PBF-LB. First, this work reviews the existing literature in the field of residual stress analysis of laser-based AM using diffraction-based techniques. Second, the elastic and plastic anisotropy of the nickel-based superalloy Inconel 718 produced by PBF-LB is studied using in situ energy dispersive synchrotron X-ray and neutron diffraction techniques. These experiments are complemented by ex situ material characterization techniques. These methods establish the relationship between the microstructure and texture of the material and its elastic and plastic anisotropy. Finally, surface, sub-surface, and bulk residual stress are determined using a texture-based approach. Uncertainties of different methods for obtaining stress-free reference values are discussed.
The tensile behavior in the as-built condition is shown to be controlled by texture and cellular sub-grain structure, while in the heat-treated condition the precipitation of strengthening phases and grain morphology dictate the behavior. In fact, the results of this thesis show that the diffraction elastic constants depend on the underlying microstructure, including texture and grain morphology. For columnar microstructures in both as-built and heat-treated conditions, the diffraction elastic constants are best described by the Reuss iso-stress model. Furthermore, the low accumulation of intergranular strains during deformation demonstrates the robustness of using the 311 reflection for the diffraction-based residual stress analysis with columnar textured microstructures. The differences between texture-based and quasi-isotropic approaches for the residual stress analysis are shown to be insignificant in the observed case. However, the analysis of the sub-surface residual stress distributions show, that different scanning strategies result in a change in the orientation of the residual stress tensor. Furthermore, the location of the critical sub-surface tensile residual stress is related to the surface roughness and the microstructure. Finally, recommendations are given for the diffraction-based determination and evaluation of residual stress in textured additively manufactured alloys.
The European Water Framework Directive (WFD) has identified river morphological alteration and diffuse pollution as the two main pressures affecting water bodies in Europe at the catchment scale. Consequently, river restoration has become a priority to achieve the WFD's objective of good ecological status. However, little is known about the effects of stream morphological changes, such as re-meandering, on in-stream nitrate retention at the river network scale. Therefore, catchment nitrate modeling is necessary to guide the implementation of spatially targeted and cost-effective mitigation measures. Meanwhile, Germany, like many other regions in central Europe, has experienced consecutive summer droughts from 2015-2018, resulting in significant changes in river nitrate concentrations in various catchments. However, the mechanistic exploration of catchment nitrate responses to changing weather conditions is still lacking.
Firstly, a fully distributed, process-based catchment Nitrate model (mHM-Nitrate) was used, which was properly calibrated and comprehensively evaluated at numerous spatially distributed nitrate sampling locations. Three calibration schemes were designed, taking into account land use, stream order, and mean nitrate concentrations, and they varied in spatial coverage but used data from the same period (2011–2019). The model performance for discharge was similar among the three schemes, with Nash-Sutcliffe Efficiency (NSE) scores ranging from 0.88 to 0.92. However, for nitrate concentrations, scheme 2 outperformed schemes 1 and 3 when compared to observed data from eight gauging stations. This was likely because scheme 2 incorporated a diverse range of data, including low discharge values and nitrate concentrations, and thus provided a better representation of within-catchment heterogenous. Therefore, the study suggests that strategically selecting gauging stations that reflect the full range of within-catchment heterogeneity is more important for calibration than simply increasing the number of stations.
Secondly, the mHM-Nitrate model was used to reveal the causal relations between sequential droughts and nitrate concentration in the Bode catchment (3200 km2) in central Germany, where stream nitrate concentrations exhibited contrasting trends from upstream to downstream reaches. The model was evaluated using data from six gauging stations, reflecting different levels of runoff components and their associated nitrate-mixing from upstream to downstream. Results indicated that the mHM-Nitrate model reproduced dynamics of daily discharge and nitrate concentration well, with Nash-Sutcliffe Efficiency ≥ 0.73 for discharge and Kling-Gupta Efficiency ≥ 0.50 for nitrate concentration at most stations. Particularly, the spatially contrasting trends of nitrate concentration were successfully captured by the model. The decrease of nitrate concentration in the lowland area in drought years (2015-2018) was presumably due to (1) limited terrestrial export loading (ca. 40% lower than that of normal years 2004-2014), and (2) increased in-stream retention efficiency (20% higher in summer within the whole river network). From a mechanistic modelling perspective, this study provided insights into spatially heterogeneous flow and nitrate dynamics and effects of sequential droughts, which shed light on water-quality responses to future climate change, as droughts are projected to be more frequent.
Thirdly, this study investigated the effects of stream restoration via re-meandering on in-stream nitrate retention at network-scale in the well-monitored Bode catchment. The mHM-Nitrate model showed good performance in reproducing daily discharge and nitrate concentrations, with median Kling-Gupta values of 0.78 and 0.74, respectively. The mean and standard deviation of gross nitrate retention efficiency, which accounted for both denitrification and assimilatory uptake, were 5.1 ± 0.61% and 74.7 ± 23.2% in winter and summer, respectively, within the stream network. The study found that in the summer, denitrification rates were about two times higher in lowland sub-catchments dominated by agricultural lands than in mountainous sub-catchments dominated by forested areas, with median ± SD of 204 ± 22.6 and 102 ± 22.1 mg N m-2 d-1, respectively. Similarly, assimilatory uptake rates were approximately five times higher in streams surrounded by lowland agricultural areas than in those in higher-elevation, forested areas, with median ± SD of 200 ± 27.1 and 39.1 ± 8.7 mg N m-2 d-1, respectively. Therefore, restoration strategies targeting lowland agricultural areas may have greater potential for increasing nitrate retention. The study also found that restoring stream sinuosity could increase net nitrate retention efficiency by up to 25.4 ± 5.3%, with greater effects seen in small streams. These results suggest that restoration efforts should consider augmenting stream sinuosity to increase nitrate retention and decrease nitrate concentrations at the catchment scale.
Climate change fundamentally transforms glaciated high-alpine regions, with well-known cryospheric and hydrological implications, such as accelerating glacier retreat, transiently increased runoff, longer snow-free periods and more frequent and intense summer rainstorms. These changes affect the availability and transport of sediments in high alpine areas by altering the interaction and intensity of different erosion processes and catchment properties.
Gaining insight into the future alterations in suspended sediment transport by high alpine streams is crucial, given its wide-ranging implications, e.g. for flood damage potential, flood hazard in downstream river reaches, hydropower production, riverine ecology and water quality. However, the current understanding of how climate change will impact suspended sediment dynamics in these high alpine regions is limited. For one, this is due to the scarcity of measurement time series that are long enough to e.g. infer trends. On the other hand, it is difficult – if not impossible – to develop process-based models, due to the complexity and multitude of processes involved in high alpine sediment dynamics. Therefore, knowledge has so far been confined to conceptual models (which do not facilitate deriving concrete timings or magnitudes for individual catchments) or qualitative estimates (‘higher export in warmer years’) that may not be able to capture decreases in sediment export. Recently, machine-learning approaches have gained in popularity for modeling sediment dynamics, since their black box nature tailors them to the problem at hand, i.e. relatively well-understood input and output data, linked by very complex processes.
Therefore, the overarching aim of this thesis is to estimate sediment export from the high alpine Ötztal valley in Tyrol, Austria, over decadal timescales in the past and future – i.e. timescales relevant to anthropogenic climate change. This is achieved by informing, extending, evaluating and applying a quantile regression forest (QRF) approach, i.e. a nonparametric, multivariate machine-learning technique based on random forest.
The first study included in this thesis aimed to understand present sediment dynamics, i.e. in the period with available measurements (up to 15 years). To inform the modeling setup for the two subsequent studies, this study identified the most important predictors, areas within the catchments and time periods. To that end, water and sediment yields from three nested gauges in the upper Ötztal, Vent, Sölden and Tumpen (98 to almost 800 km² catchment area, 930 to 3772 m a.s.l.) were analyzed for their distribution in space, their seasonality and spatial differences therein, and the relative importance of short-term events. The findings suggest that the areas situated above 2500 m a.s.l., containing glacier tongues and recently deglaciated areas, play a pivotal role in sediment generation across all sub-catchments. In contrast, precipitation events were relatively unimportant (on average, 21 % of annual sediment yield was associated to precipitation events). Thus, the second and third study focused on the Vent catchment and its sub-catchment above gauge Vernagt (11.4 and 98 km², 1891 to 3772 m a.s.l.), due to their higher share of areas above 2500 m. Additionally, they included discharge, precipitation and air temperature (as well as their antecedent conditions) as predictors.
The second study aimed to estimate sediment export since the 1960s/70s at gauges Vent and Vernagt. This was facilitated by the availability of long records of the predictors, discharge, precipitation and air temperature, and shorter records (four and 15 years) of turbidity-derived sediment concentrations at the two gauges. The third study aimed to estimate future sediment export until 2100, by applying the QRF models developed in the second study to pre-existing precipitation and temperature projections (EURO-CORDEX) and discharge projections (physically-based hydroclimatological and snow model AMUNDSEN) for the three representative concentration pathways RCP2.6, RCP4.5 and RCP8.5.
The combined results of the second and third study show overall increasing sediment export in the past and decreasing export in the future. This suggests that peak sediment is underway or has already passed – unless precipitation changes unfold differently than represented in the projections or changes in the catchment erodibility prevail and override these trends. Despite the overall future decrease, very high sediment export is possible in response to precipitation events. This two-fold development has important implications for managing sediment, flood hazard and riverine ecology.
This thesis shows that QRF can be a very useful tool to model sediment export in high-alpine areas. Several validations in the second study showed good performance of QRF and its superiority to traditional sediment rating curves – especially in periods that contained high sediment export events, which points to its ability to deal with threshold effects. A technical limitation of QRF is the inability to extrapolate beyond the range of values represented in the training data. We assessed the number and severity of such out-of-observation-range (OOOR) days in both studies, which showed that there were few OOOR days in the second study and that uncertainties associated with OOOR days were small before 2070 in the third study. As the pre-processed data and model code have been made publically available, future studies can easily test further approaches or apply QRF to further catchments.
Large parts of the Earth’s interior are inaccessible to direct observation, yet global geodynamic processes are governed by the physical material properties under extreme pressure and temperature conditions. It is therefore essential to investigate the deep Earth’s physical properties through in-situ laboratory experiments. With this goal in mind, the optical properties of mantle minerals at high pressure offer a unique way to determine a variety of physical properties, in a straight-forward, reproducible, and time-effective manner, thus providing valuable insights into the physical processes of the deep Earth. This thesis focusses on the system Mg-Fe-O, specifically on the optical properties of periclase (MgO) and its iron-bearing variant ferropericlase ((Mg,Fe)O), forming a major planetary building block. The primary objective is to establish links between physical material properties and optical properties. In particular the spin transition in ferropericlase, the second-most abundant phase of the lower mantle, is known to change the physical material properties. Although the spin transition region likely extends down to the core-mantle boundary, the ef-fects of the mixed-spin state, where both high- and low-spin state are present, remains poorly constrained.
In the studies presented herein, we show how optical properties are linked to physical properties such as electrical conductivity, radiative thermal conductivity and viscosity. We also show how the optical properties reveal changes in the chemical bonding. Furthermore, we unveil how the chemical bonding, the optical and other physical properties are affected by the iron spin transition. We find opposing trends in the pres-sure dependence of the refractive index of MgO and (Mg,Fe)O. From 1 atm to ~140 GPa, the refractive index of MgO decreases by ~2.4% from 1.737 to 1.696 (±0.017). In contrast, the refractive index of (Mg0.87Fe0.13)O (Fp13) and (Mg0.76Fe0.24)O (Fp24) ferropericlase increases with pressure, likely because Fe Fe interactions between adjacent iron sites hinder a strong decrease of polarizability, as it is observed with increasing density in the case of pure MgO. An analysis of the index dispersion in MgO (decreasing by ~23% from 1 atm to ~103 GPa) reflects a widening of the band gap from ~7.4 eV at 1 atm to ~8.5 (±0.6) eV at ~103 GPa. The index dispersion (between 550 and 870 nm) of Fp13 reveals a decrease by a factor of ~3 over the spin transition range (~44–100 GPa). We show that the electrical band gap of ferropericlase significantly widens up to ~4.7 eV in the mixed spin region, equivalent to an increase by a factor of ~1.7. We propose that this is due to a lower electron mobility between adjacent Fe2+ sites of opposite spin, explaining the previously observed low electrical conductivity in the mixed spin region. From the study of absorbance spectra in Fp13, we show an increasing covalency of the Fe-O bond with pressure for high-spin ferropericlase, whereas in the low-spin state a trend to a more ionic nature of the Fe-O bond is observed, indicating a bond weakening effect of the spin transition. We found that the spin transition is ultimately caused by both an increase of the ligand field-splitting energy and a decreasing spin-pairing energy of high-spin Fe2+.
The reliance on fossil fuels has resulted in an abnormal increase in the concentration of greenhouse gases, contributing to the global climate crisis. In response, a rapid transition to renewable energy sources has begun, particularly lithium-ion batteries, playing a crucial role in the green energy transformation. However, concerns regarding the availability and geopolitical implications of lithium have prompted the exploration of alternative rechargeable battery systems, such as sodium-ion batteries. Sodium is significantly abundant and more homogeneously distributed in the crust and seawater, making it easier and less expensive to extract than lithium. However, because of the mysterious nature of its components, sodium-ion batteries are not yet sufficiently advanced to take the place of lithium-ion batteries. Specifically, sodium exhibits a more metallic character and a larger ionic radius, resulting in a different ion storage mechanism utilized in lithium-ion batteries. Innovations in synthetic methods, post-treatments, and interface engineering clearly demonstrate the significance of developing high-performance carbonaceous anode materials for sodium-ion batteries. The objective of this dissertation is to present a systematic approach for fabricating efficient, high-performance, and sustainable carbonaceous anode materials for sodium-ion batteries. This will involve a comprehensive investigation of different chemical environments and post-modification techniques as well.
This dissertation focuses on three main objectives. Firstly, it explores the significance of post-synthetic methods in designing interfaces. A conformal carbon nitride coating is deposited through chemical vapor deposition on a carbon electrode as an artificial solid-electrolyte interface layer, resulting in improved electrochemical performance. The interaction between the carbon nitride artificial interface and the carbon electrode enhances initial Coulombic efficiency, rate performance, and total capacity. Secondly, a novel process for preparing sulfur-rich carbon as a high-performing anode material for sodium-ion batteries is presented. The method involves using an oligo-3,4-ethylenedioxythiophene precursor for high sulfur content hard carbon anode to investigate the sulfur heteroatom effect on the electrochemical sodium storage mechanism. By optimizing the condensation temperature, a significant transformation in the materials’ nanostructure is achieved, leading to improved electrochemical performance. The use of in-operando small-angle X-ray scattering provides valuable insights into the interaction between micropores and sodium ions during the electrochemical processes. Lastly, the development of high-capacity hard carbon, derived from 5-hydroxymethyl furfural, is examined. This carbon material exhibits exceptional performance at both low and high current densities. Extensive electrochemical and physicochemical characterizations shed light on the sodium storage mechanism concerning the chemical environment, establishing the material’s stability and potential applications in sodium-ion batteries.
The evaluation of process-oriented cognitive theories through time-ordered observations is crucial for the advancement of cognitive science. The findings presented herein integrate insights from research on eye-movement control and sentence comprehension during reading, addressing challenges in modeling time-ordered data, statistical inference, and interindividual variability. Using kernel density estimation and a pseudo-marginal likelihood for fixation durations and locations, a likelihood implementation of the SWIFT model of eye-movement control during reading (Engbert et al., Psychological Review, 112, 2005, pp. 777–813) is proposed. Within the broader framework of data assimilation, Bayesian parameter inference with adaptive Markov Chain Monte Carlo techniques is facilitated for reliable model fitting. Across the different studies, this framework has shown to enable reliable parameter recovery from simulated data and prediction of experimental summary statistics. Despite its complexity, SWIFT can be fitted within a principled Bayesian workflow, capturing interindividual differences and modeling experimental effects on reading across different geometrical alterations of text. Based on these advancements, the integrated dynamical model SEAM is proposed, which combines eye-movement control, a traditionally psychological research area, and post-lexical language processing in the form of cue-based memory retrieval (Lewis & Vasishth, Cognitive Science, 29, 2005, pp. 375–419), typically the purview of psycholinguistics. This proof-of-concept integration marks a significant step forward in natural language comprehension during reading and suggests that the presented methodology can be useful to develop complex cognitive dynamical models that integrate processes at levels of perception, higher cognition, and (oculo-)motor control. These findings collectively advance process-oriented cognitive modeling and highlight the importance of Bayesian inference, individual differences, and interdisciplinary integration for a holistic understanding of reading processes. Implications for theory and methodology, including proposals for model comparison and hierarchical parameter inference, are briefly discussed.
Organic solar cells (OSCs) represent a new generation of solar cells with a range of captivating attributes including low-cost, light-weight, aesthetically pleasing appearance, and flexibility. Different from traditional silicon solar cells, the photon-electron conversion in OSCs is usually accomplished in an active layer formed by blending two kinds of organic molecules (donor and acceptor) with different energy levels together.
The first part of this thesis focuses on a better understanding of the role of the energetic offset and each recombination channel on the performance of these low-offset OSCs. By combining advanced experimental techniques with optical and electrical simulation, the energetic offsets between CT and excitons, several important insights were achieved: 1. The short circuit current density and fill-factor of low-offset systems are largely determined by field-dependent charge generation in such low-offset OSCs. Interestingly, it is strongly evident that such field-dependent charge generation originates from a field-dependent exciton dissociation yield. 2. The reduced energetic offset was found to be accompanied by strongly enhanced bimolecular recombination coefficient, which cannot be explained solely by exciton repopulation from CT states. This implies the existence of another dark decay channel apart from CT.
The second focus of the thesis was on the technical perspective. In this thesis, the influence of optical artifacts in differential absorption spectroscopy upon the change of sample configuration and active layer thickness was studied. It is exemplified and discussed thoroughly and systematically in terms of optical simulations and experiments, how optical artifacts originated from non-uniform carrier profile and interference can manipulate not only the measured spectra, but also the decay dynamics in various measurement conditions. In the end of this study, a generalized methodology based on an inverse optical transfer matrix formalism was provided to correct the spectra and decay dynamics manipulated by optical artifacts.
Overall, this thesis paves the way for a deeper understanding of the keys toward higher PCEs in low-offset OSC devices, from the perspectives of both device physics and characterization techniques.
Open edX is an incredible platform to deliver MOOCs and SPOCs, designed to be robust and support hundreds of thousands of students at the same time. Nevertheless, it lacks a lot of the fine-grained functionality needed to handle students individually in an on-campus course. This short session will present the ongoing project undertaken by the 6 public universities of the Region of Madrid plus the Universitat Politècnica de València, in the framework of a national initiative called UniDigital, funded by the Ministry of Universities of Spain within the Plan de Recuperación, Transformación y Resiliencia of the European Union. This project, led by three of these Spanish universities (UC3M, UPV, UAM), is investing more than half a million euros with the purpose of bringing the Open edX platform closer to the functionalities required for an LMS to support on-campus teaching. The aim of the project is to coordinate what is going to be developed with the Open edX development community, so these developments are incorporated into the core of the Open edX platform in its next releases. Features like a complete redesign of platform analytics to make them real-time, the creation of dashboards based on these analytics, the integration of a system for customized automatic feedback, improvement of exams and tasks and the extension of grading capabilities, improvements in the graphical interfaces for both students and teachers, the extension of the emailing capabilities, redesign of the file management system, integration of H5P content, the integration of a tool to create mind maps, the creation of a system to detect students at risk, or the integration of an advanced voice assistant and a gamification mobile app, among others, are part of the functionalities to be developed. The idea is to transform a first-class MOOC platform into the next on-campus LMS.
It is a well-attested finding in head-initial languages that individuals with aphasia (IWA) have greater difficulties in comprehending object-extracted relative clauses (ORCs) as compared to subject-extracted relative clauses (SRCs). Adopting the linguistically based approach of Relativized Minimality (RM; Rizzi, 1990, 2004), the subject-object asymmetry is attributed to the occurrence of a Minimality effect in ORCs due to reduced processing capacities in IWA (Garraffa & Grillo, 2008; Grillo, 2008, 2009). For ORCs, it is claimed that the embedded subject intervenes in the syntactic dependency between the moved object and its trace, resulting in greater processing demands. In contrast, no such intervener is present in SRCs. Based on the theoretical framework of RM and findings from language acquisition (Belletti et al., 2012; Friedmann et al., 2009), it is assumed that Minimality effects are alleviated when the moved object and the intervening subject differ in terms of relevant syntactic features. For German, the language under investigation, the RM approach predicts that number (i.e., singular vs. plural) and the lexical restriction [+NP] feature (i.e., lexically restricted determiner phrases vs. lexically unrestricted pronouns) are considered relevant in the computation of Minimality. Greater degrees of featural distinctiveness are predicted to result in more facilitated processing of ORCs, because IWA can more easily distinguish between the moved object and the intervener.
This cumulative dissertation aims to provide empirical evidence on the validity of the RM approach in accounting for comprehension patterns during relative clause (RC) processing in German-speaking IWA. For that purpose, I conducted two studies including visual-world eye-tracking experiments embedded within an auditory referent-identification task to study the offline and online processing of German RCs. More specifically, target sentences were created to evaluate (a) whether IWA demonstrate a subject-object asymmetry, (b) whether dissimilarity in the number and/or the [+NP] features facilitates ORC processing, and (c) whether sentence processing in IWA benefits from greater degrees of featural distinctiveness. Furthermore, by comparing RCs disambiguated through case marking (at the relative pronoun or the following noun phrase) and number marking (inflection of the sentence-final verb), it was possible to consider the role of the relative position of the disambiguation point. The RM approach predicts that dissimilarity in case should not affect the occurrence of Minimality effects. However, the case cue to sentence interpretation appears earlier within RCs than the number cue, which may result in lower processing costs in case-disambiguated RCs compared to number-disambiguated RCs.
In study I, target sentences varied with respect to word order (SRC vs. ORC) and dissimilarity in the [+NP] feature (lexically restricted determiner phrase vs. pronouns as embedded element). Moreover, by comparing the impact of these manipulations in case- and number-disambiguated RCs, the effect of dissimilarity in the number feature was explored. IWA demonstrated a subject-object asymmetry, indicating the occurrence of a Minimality effect in ORCs. However, dissimilarity neither in the number feature nor in the [+NP] feature alone facilitated ORC processing. Instead, only ORCs involving distinct specifications of both the number and the [+NP] features were well comprehended by IWA. In study II, only temporarily ambiguous ORCs disambiguated through case or number marking were investigated, while controlling for varying points of disambiguation. There was a slight processing advantage of case marking as cue to sentence interpretation as compared to number marking.
Taken together, these findings suggest that the RM approach can only partially capture empirical data from German IWA. In processing complex syntactic structures, IWA are susceptible to the occurrence of the intervening subject in ORCs. The new findings reported in the thesis show that structural dissimilarity can modulate sentence comprehension in aphasia. Interestingly, IWA can override Minimality effects in ORCs and derive correct sentence meaning if the featural specifications of the constituents are maximally different, because they can more easily distinguish the moved object and the intervening subject given their reduced processing capacities. This dissertation presents new scientific knowledge that highlights how the syntactic theory of RM helps to uncover selective effects of morpho-syntactic features on sentence comprehension in aphasia, emphasizing the close link between assumptions from theoretical syntax and empirical research.
To manage tabular data files and leverage their content in a given downstream task, practitioners often design and execute complex transformation pipelines to prepare them. The complexity of such pipelines stems from different factors, including the nature of the preparation tasks, often exploratory or ad-hoc to specific datasets; the large repertory of tools, algorithms, and frameworks that practitioners need to master; and the volume, variety, and velocity of the files to be prepared. Metadata plays a fundamental role in reducing this complexity: characterizing a file assists end users in the design of data preprocessing pipelines, and furthermore paves the way for suggestion, automation, and optimization of data preparation tasks.
Previous research in the areas of data profiling, data integration, and data cleaning, has focused on extracting and characterizing metadata regarding the content of tabular data files, i.e., about the records and attributes of tables. Content metadata are useful for the latter stages of a preprocessing pipeline, e.g., error correction, duplicate detection, or value normalization, but they require a properly formed tabular input. Therefore, these metadata are not relevant for the early stages of a preparation pipeline, i.e., to correctly parse tables out of files. In this dissertation, we turn our focus to what we call the structure of a tabular data file, i.e., the set of characters within a file that do not represent data values but are required to parse and understand the content of the file. We provide three different approaches to represent file structure, an explicit representation based on context-free grammars; an implicit representation based on file-wise similarity; and a learned representation based on machine learning.
In our first contribution, we use the grammar-based representation to characterize a set of over 3000 real-world csv files and identify multiple structural issues that let files deviate from the csv standard, e.g., by having inconsistent delimiters or containing multiple tables. We leverage our learnings about real-world files and propose Pollock, a benchmark to test how well systems parse csv files that have a non-standard structure, without any previous preparation. We report on our experiments on using Pollock to evaluate the performance of 16 real-world data management systems.
Following, we characterize the structure of files implicitly, by defining a measure of structural similarity for file pairs. We design a novel algorithm to compute this measure, which is based on a graph representation of the files' content. We leverage this algorithm and propose Mondrian, a graphical system to assist users in identifying layout templates in a dataset, classes of files that have the same structure, and therefore can be prepared by applying the same preparation pipeline.
Finally, we introduce MaGRiTTE, a novel architecture that uses self-supervised learning to automatically learn structural representations of files in the form of vectorial embeddings at three different levels: cell level, row level, and file level. We experiment with the application of structural embeddings for several tasks, namely dialect detection, row classification, and data preparation efforts estimation.
Our experimental results show that structural metadata, either identified explicitly on parsing grammars, derived implicitly as file-wise similarity, or learned with the help of machine learning architectures, is fundamental to automate several tasks, to scale up preparation to large quantities of files, and to provide repeatable preparation pipelines.
The landscape of software self-adaptation is shaped in accordance with the need to cost-effectively achieve and maintain (software) quality at runtime and in the face of dynamic operation conditions. Optimization-based solutions perform an exhaustive search in the adaptation space, thus they may provide quality guarantees. However, these solutions render the attainment of optimal adaptation plans time-intensive, thereby hindering scalability. Conversely, deterministic rule-based solutions yield only sub-optimal adaptation decisions, as they are typically bound by design-time assumptions, yet they offer efficient processing and implementation, readability, expressivity of individual rules supporting early verification. Addressing the quality-cost trade-of requires solutions that simultaneously exhibit the scalability and cost-efficiency of rulebased policy formalism and the optimality of optimization-based policy formalism as explicit artifacts for adaptation. Utility functions, i.e., high-level specifications that capture system objectives, support the explicit treatment of quality-cost trade-off. Nevertheless, non-linearities, complex dynamic architectures, black-box models, and runtime uncertainty that makes the prior knowledge obsolete are a few of the sources of uncertainty and subjectivity that render the elicitation of utility non-trivial.
This thesis proposes a twofold solution for incremental self-adaptation of dynamic architectures. First, we introduce Venus, a solution that combines in its design a ruleand an optimization-based formalism enabling optimal and scalable adaptation of dynamic architectures. Venus incorporates rule-like constructs and relies on utility theory for decision-making. Using a graph-based representation of the architecture, Venus captures rules as graph patterns that represent architectural fragments, thus enabling runtime extensibility and, in turn, support for dynamic architectures; the architecture is evaluated by assigning utility values to fragments; pattern-based definition of rules and utility enables incremental computation of changes on the utility that result from rule executions, rather than evaluating the complete architecture, which supports scalability. Second, we introduce HypeZon, a hybrid solution for runtime coordination of multiple off-the-shelf adaptation policies, which typically offer only partial satisfaction of the quality and cost requirements. Realized based on meta-self-aware architectures, HypeZon complements Venus by re-using existing policies at runtime for balancing the quality-cost trade-off.
The twofold solution of this thesis is integrated in an adaptation engine that leverages state- and event-based principles for incremental execution, therefore, is scalable for large and dynamic software architectures with growing size and complexity. The utility elicitation challenge is resolved by defining a methodology to train utility-change prediction models. The thesis addresses the quality-cost trade-off in adaptation of dynamic software architectures via design-time combination (Venus) and runtime coordination (HypeZon) of rule- and optimization-based policy formalisms, while offering supporting mechanisms for optimal, cost-effective, scalable, and robust adaptation. The solutions are evaluated according to a methodology that is obtained based on our systematic literature review of evaluation in self-healing systems; the applicability and effectiveness of the contributions are demonstrated to go beyond the state-of-the-art in coverage of a wide spectrum of the problem space for software self-adaptation.
Sigmund Freud, the founder of psychoanalysis, began his intellectual life with the Jewish Bible and also ended it with it. He began by reading the Philippson Bible together, especially with his father Jacob Freud, and ended by studying the figure of Moses. This study systematically traces this preoccupation and shows that the Jewish Bible was a constant reference for Freud and determined his Jewish identity. This is shown by analysing family documents, religious instruction and references to the Bible in Freud's writings and correspondence.
Concepts and techniques for 3D-embedded treemaps and their application to software visualization
(2024)
This thesis addresses concepts and techniques for interactive visualization of hierarchical data using treemaps. It explores (1) how treemaps can be embedded in 3D space to improve their information content and expressiveness, (2) how the readability of treemaps can be improved using level-of-detail and degree-of-interest techniques, and (3) how to design and implement a software framework for the real-time web-based rendering of treemaps embedded in 3D. With a particular emphasis on their application, use cases from software analytics are taken to test and evaluate the presented concepts and techniques.
Concerning the first challenge, this thesis shows that a 3D attribute space offers enhanced possibilities for the visual mapping of data compared to classical 2D treemaps. In particular, embedding in 3D allows for improved implementation of visual variables (e.g., by sketchiness and color weaving), provision of new visual variables (e.g., by physically based materials and in situ templates), and integration of visual metaphors (e.g., by reference surfaces and renderings of natural phenomena) into the three-dimensional representation of treemaps.
For the second challenge—the readability of an information visualization—the work shows that the generally higher visual clutter and increased cognitive load typically associated with three-dimensional information representations can be kept low in treemap-based representations of both small and large hierarchical datasets. By introducing an adaptive level-of-detail technique, we cannot only declutter the visualization results, thereby reducing cognitive load and mitigating occlusion problems, but also summarize and highlight relevant data. Furthermore, this approach facilitates automatic labeling, supports the emphasis on data outliers, and allows visual variables to be adjusted via degree-of-interest measures.
The third challenge is addressed by developing a real-time rendering framework with WebGL and accumulative multi-frame rendering. The framework removes hardware constraints and graphics API requirements, reduces interaction response times, and simplifies high-quality rendering. At the same time, the implementation effort for a web-based deployment of treemaps is kept reasonable.
The presented visualization concepts and techniques are applied and evaluated for use cases in software analysis. In this domain, data about software systems, especially about the state and evolution of the source code, does not have a descriptive appearance or natural geometric mapping, making information visualization a key technology here. In particular, software source code can be visualized with treemap-based approaches because of its inherently hierarchical structure. With treemaps embedded in 3D, we can create interactive software maps that visually map, software metrics, software developer activities, or information about the evolution of software systems alongside their hierarchical module structure.
Discussions on remaining challenges and opportunities for future research for 3D-embedded treemaps and their applications conclude the thesis.
The increasing number of known exoplanets raises questions about their demographics and the mechanisms that shape planets into how we observe them today. Young planets in close-in orbits are exposed to harsh environments due to the host star being magnetically highly active, which results in high X-ray and extreme UV fluxes impinging on the planet. Prolonged exposure to this intense photoionizing radiation can cause planetary atmospheres to heat up, expand and escape into space via a hydrodynamic escape process known as photoevaporation. For super-Earth and sub-Neptune-type planets, this can even lead to the complete erosion of their primordial gaseous atmospheres. A factor of interest for this particular mass-loss process is the activity evolution of the host star. Stellar rotation, which drives the dynamo and with it the magnetic activity of a star, changes significantly over the stellar lifetime. This strongly affects the amount of high-energy radiation received by a planet as stars age. At a young age, planets still host warm and extended envelopes, making them particularly susceptible to atmospheric evaporation. Especially in the first gigayear, when X-ray and UV levels can be 100 - 10,000 times higher than for the present-day sun, the characteristics of the host star and the detailed evolution of its high-energy emission are of importance.
In this thesis, I study the impact of stellar activity evolution on the high-energy-induced atmospheric mass loss of young exoplanets. The PLATYPOS code was developed as part of this thesis to calculate photoevaporative mass-loss rates over time. The code, which couples parameterized planetary mass-radius relations with an analytical hydrodynamic escape model, was used, together with Chandra and eROSITA X-ray observations, to investigate the future mass loss of the two young multiplanet systems V1298 Tau and K2-198. Further, in a numerical ensemble study, the effect of a realistic spread of activity tracks on the small-planet radius gap was investigated for the first time. The works in this thesis show that for individual systems, in particular if planetary masses are unconstrained, the difference between a young host star following a low-activity track vs. a high-activity one can have major implications: the exact shape of the activity evolution can determine whether a planet can hold on to some of its atmosphere, or completely loses its envelope, leaving only the bare rocky core behind. For an ensemble of simulated planets, an observationally-motivated distribution of activity tracks does not substantially change the final radius distribution at ages of several gigayears. My simulations indicate that the overall shape and slope of the resulting small-planet radius gap is not significantly affected by the spread in stellar activity tracks. However, it can account for a certain scattering or fuzziness observed in and around the radius gap of the observed exoplanet population.
Organic-inorganic hybrids based on P3HT and mesoporous silicon for thermoelectric applications
(2024)
This thesis presents a comprehensive study on synthesis, structure and thermoelectric transport properties of organic-inorganic hybrids based on P3HT and porous silicon. The effect of embedding polymer in silicon pores on the electrical and thermal transport is studied. Morphological studies confirm successful polymer infiltration and diffusion doping with roughly 50% of the pore space occupied by conjugated polymer. Synchrotron diffraction experiments reveal no specific ordering of the polymer inside the pores. P3HT-pSi hybrids show improved electrical transport by five orders of magnitude compared to porous silicon and power factor values comparable or exceeding other P3HT-inorganic hybrids. The analysis suggests different transport mechanisms in both materials. In pSi, the transport mechanism relates to a Meyer-Neldel compansation rule. The analysis of hybrids' data using the power law in Kang-Snyder model suggests that a doped polymer mainly provides charge carriers to the pSi matrix, similar to the behavior of a doped semiconductor. Heavily suppressed thermal transport in porous silicon is treated with a modified Landauer/Lundstrom model and effective medium theories, which reveal that pSi agrees well with the Kirkpatrick model with a 68% percolation threshold. Thermal conductivities of hybrids show an increase compared to the empty pSi but the overall thermoelectric figure of merit ZT of P3HT-pSi hybrid exceeds both pSi and P3HT as well as bulk Si.
The present paper proposes a novel approach for equilibrium selection in the infinitely repeated prisoner’s dilemma where players can communicate before choosing their strategies. This approach yields a critical discount factor that makes different predictions for cooperation than the usually considered sub-game perfect or risk dominance critical discount factors. In laboratory experiments, we find that our factor is useful for predicting cooperation. For payoff changes where the usually considered factors and our factor make different predictions, the observed cooperation is consistent with the predictions based on our factor.
It is a common finding that preschoolers have difficulties in identifying who is doing what to whom in non-canonical sentences, such as (object-verb-subject) OVS and passive sentences in German. This dissertation investigates how German monolingual and German-Italian simultaneous bilingual children process German OVS sentences in Study 1 and German passives in Study 2. Offline data (i.e., accuracy data) and online data (i.e., eye-gaze and pupillometry data) were analyzed to explore whether children can assign thematic roles during sentence comprehension and processing. Executive functions, language-internal and -external factors were investigated as potential predictors for children’s sentence comprehension and processing.
Throughout the literature, there are contradicting findings on the relation between language and executive functions. While some results show a bilingual cognitive advantage over monolingual speakers, others suggest there is no relationship between bilingualism and executive functions. If bilingual children possess more advanced executive function abilities than monolingual children, then this might also be reflected in a better performance on linguistic tasks. In the current studies monolingual and bilingual children were tested by means of two executive function tasks: the Flanker task and the task-switching paradigm. However, these findings showed no bilingual cognitive advantages and no better performance by bilingual children in the linguistic tasks. The performance was rather comparable between bilingual and monolingual children, or even better for the monolingual group. This may be due to cross-linguistic influences and language experience (i.e., language input and output). Italian was used because it does not syntactically overlap with the structure of German OVS sentences, and it only overlapped with one of the two types of sentence condition used for the passive study - considering the subject-(finite)verb alignment. The findings showed a better performance of bilingual children in the passive sentence structure that syntactically overlapped in the two languages, providing evidence for cross-linguistic influences.
Further factors for children’s sentence comprehension were considered. The parents’ education, the number of older siblings and language experience variables were derived from a language background questionnaire completed by parents. Scores of receptive vocabulary and grammar, visual and short-term memory and reasoning ability were measured by means of standardized tests. It was shown that higher German language experience by bilinguals correlates with better accuracy in German OVS sentences but not in passive sentences. Memory capacity had a positive effect on the comprehension of OVS and passive sentences in the bilingual group. Additionally, a role was played by executive function abilities in the comprehension of OVS sentences and not of passive sentences. It is suggested that executive function abilities might help children in the sentence comprehension task when the linguistic structures are not yet fully mastered.
Altogether, these findings show that bilinguals’ poorer performance in the comprehension and processing of German OVS is mainly due to reduced language experience in German, and that the different performance of bilingual children with the two types of passives is mainly due to cross-linguistic influences.
Protected cultivation in greenhouses or polytunnels offers the potential for sustainable production of high-yield, high-quality vegetables. This is related to the ability to produce more on less land and to use resources responsibly and efficiently. Crop yield has long been considered the most important factor. However, as plant-based diets have been proposed for a sustainable food system, the targeted enrichment of health-promoting plant secondary metabolites should be addressed. These metabolites include carotenoids and flavonoids, which are associated with several health benefits, such as cardiovascular health and cancer protection.
Cover materials generally have an influence on the climatic conditions, which in turn can affect the levels of secondary metabolites in vegetables grown underneath. Plastic materials are cost-effective and their properties can be modified by incorporating additives, making them the first choice. However, these additives can migrate and leach from the material, resulting in reduced service life, increased waste and possible environmental release. Antifogging additives are used in agricultural films to prevent the formation of droplets on the film surface, thereby increasing light transmission and preventing microbiological contamination.
This thesis focuses on LDPE/EVA covers and incorporated antifogging additives for sustainable protected cultivation, following two different approaches. The first addressed the direct effects of leached antifogging additives using simulation studies on lettuce leaves (Lactuca sativa var capitata L). The second determined the effect of antifog polytunnel covers on lettuce quality. Lettuce is usually grown under protective cover and can provide high nutritional value due to its carotenoid and flavonoid content, depending on the cultivar.
To study the influence of simulated leached antifogging additives on lettuce leaves, a GC-MS method was first developed to analyze these additives based on their fatty acid moieties. Three structurally different antifogging additives (reference material) were characterized outside of a polymer matrix for the first time. All of them contained more than the main fatty acid specified by the manufacturer. Furthermore, they were found to adhere to the leaf surface and could not be removed by water or partially by hexane.
The incorporation of these additives into polytunnel covers affects carotenoid levels in lettuce, but not flavonoids, caffeic acid derivatives and chlorophylls. Specifically, carotenoids were higher in lettuce grown under polytunnels without antifog than with antifog. This has been linked to their effect on the light regime and was suggested to be related to carotenoid function in photosynthesis.
In terms of protected cultivation, the use of LDPE/EVA polytunnels affected light and temperature, and both are closely related. The carotenoid and flavonoid contents of lettuce grown under polytunnels was reversed, with higher carotenoid and lower flavonoid levels. At the individual level, the flavonoids detected in lettuce did not differ however, lettuce carotenoids adapted specifically depending on the time of cultivation. Flavonoid reduction was shown to be transcriptionally regulated (CHS) in response to UV light (UVR8). In contrast, carotenoids are thought to be regulated post-transcriptionally, as indicated by the lack of correlation between carotenoid levels and transcripts of the first enzyme in carotenoid biosynthesis (PSY) and a carotenoid degrading enzyme (CCD4), as well as the increased carotenoid metabolic flux. Understanding the regulatory mechanisms and metabolite adaptation strategies could further advance the strategic development and selection of cover materials.
The African weakly electric fishes (Mormyridae) exhibit a remarkable adaptive radiation possibly due to their species-specific electric organ discharges (EODs). It is produced by a muscle-derived electric organ that is located in the caudal peduncle. Divergence in EODs acts as a pre-zygotic isolation mechanism to drive species radiations. However, the mechanism behind the EOD diversification are only partially understood.
The aim of this study is to explore the genetic basis of EOD diversification from the gene expression level across Campylomormyrus species/hybrids and ontogeny. I firstly produced a high quality genome of the species C. compressirostris as a valuable resource to understand the electric fish evolution.
The next study compared the gene expression pattern between electric organs and skeletal muscles in Campylomormyrus species/hybrids with different types of EOD duration. I identified several candidate genes with an electric organ-specific expression, e.g. KCNA7a, KLF5, KCNJ2, SCN4aa, NDRG3, MEF2. The overall genes expression pattern exhibited a significant association with EOD duration in all analyzed species/hybrids. The expression of several candidate genes, e.g. KCNJ2, KLF5, KCNK6 and KCNQ5, possibly contribute to the regulation of EOD duration in Campylomormyrus due to their increasing or decreasing expression. Several potassium channel genes showed differential expression during ontogeny in species and hybrid with EOD alteration, e.g. KCNJ2.
I next explored allele specific expression of intragenus hybrids by crossing the duration EOD species C. compressirostris with the medium duration EOD species C. tshokwe and the elongated duration EOD species C. rhynchophorus. The hybrids exhibited global expression dominance of the C. compressirostris allele in the adult skeletal muscle and electric organ, as well as in the juvenile electric organ. Only the gene KCNJ2 showed dominant expression of the allele from C. rhynchophorus, and this was increasingly dominant during ontogeny. It hence supported our hypothesis that KCNJ2 is a key gene of regulating EOD duration. Our results help us to understand, from a genetic perspective, how gene expression effect the EOD diversification in the African weakly electric fish.
Optimizing power analysis for randomized experiments: Design parameters for student achievement
(2024)
Randomized trials (RTs) are promising methodological tools to inform evidence-based reform to enhance schooling. Establishing a robust knowledge base on how to promote student achievement requires sensitive RT designs demonstrating sufficient statistical power and precision to draw conclusive and correct inferences on the effectiveness of educational programs and innovations. Proper power analysis is therefore an integral component of any informative RT on student achievement. This venture critically hinges on the availability of reasonable input variance design parameters (and their inherent uncertainties) that optimally reflect the realities around the prospective RT—precisely, its target population and outcome, possibly applied covariates, the concrete design as well as the planned analysis. However, existing compilations in this vein show far-reaching shortcomings.
The overarching endeavor of the present doctoral thesis was to substantively expand available resources devoted to tweak the planning of RTs evaluating educational interventions. At the core of this thesis is a systematic analysis of design parameters for student achievement, generating reliable and versatile compendia and developing thorough guidance to support apt power analysis to design strong RTs. To this end, the thesis at hand bundles two complementary studies which capitalize on rich data of several national probability samples from major German longitudinal large-scale assessments.
Study I applied two- and three-level latent (covariate) modeling to analyze design parameters for a wide spectrum of mathematical-scientific, verbal, and domain-general achievement outcomes. Three vital covariate sets were covered comprising (a) pretests, (b) sociodemographic characteristics, and (c) their combination. The accumulated estimates were additionally summarized in terms of normative distributions.
Study II specified (manifest) single-, two-, and three-level models and referred to influential psychometric heuristics to analyze design parameters and develop concise selection guidelines for covariate (a) types of varying bandwidth-fidelity (domain-identical, cross-domain, fluid intelligence pretests; sociodemographic characteristics), (b) combinations quantifying incremental validities, and (c) time lags of 1- to 7-year-lagged pretests scrutinizing validity degradation. The estimates for various mathematical-scientific and verbal achievement outcomes were meta-analytically integrated and employed in precision simulations.
In doing so, Studies I and II addressed essential gaps identified in previous repertoires in six major dimensions: Taken together, this thesis accumulated novel design parameters and deliberate guidance for RT power analysis (1) tailored to four German student (sub)populations across the entire school career from Grade 1 to 12, (2) matched to 21 achievement (sub)domains, (3) adjusted for 11 covariate sets enriched by empirically supported guidelines, (4) adapted to six RT designs, (5) suitable for latent and manifest analysis models, (6) which were cataloged along with quantifications of their associated uncertainties. These resources are complemented by a plethora of illustrative application examples to gently direct psychological and educational researchers through pivotal steps in the process of RT design.
The striking heterogeneity of the design parameter estimates across all these dimensions constitutes the overall, joint key result of Studies I and II. Hence, this work convincingly reinforces calls for a close match between design parameters and the specific peculiarities of the target RT’s research context.
All in all, the present doctoral thesis offers a—so far unique—nuanced and extensive toolkit to optimize power analysis for sound RTs on student achievement in the German (and similar) school context. It is of utmost importance that research does not tire to spawn robust evidence on what actually works to improve schooling. With this in mind, I hope that the emerging compendia and guidance contribute to the quality and rigor of our randomized experiments in psychology and education.