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Business process management (BPM) is a systematic and structured approach to model, analyze, control, and execute business operations also referred to as business processes that get carried out to achieve business goals. Central to BPM are conceptual models. Most prominently, process models describe which tasks are to be executed by whom utilizing which information to reach a business goal. Process models generally cover the perspectives of control flow, resource, data flow, and information systems.
Execution of business processes leads to the work actually being carried out. Automating them increases the efficiency and is usually supported by process engines. This, though, requires the coverage of control flow, resource assignments, and process data. While the first two perspectives are well supported in current process engines, data handling needs to be implemented and maintained manually. However, model-driven data handling promises to ease implementation, reduces the error-proneness through graphical visualization, and reduces development efforts through code generation.
This thesis addresses the modeling, analysis, and execution of data in business processes and presents a novel approach to execute data-annotated process models entirely model-driven. As a first step and formal grounding for the process execution, a conceptual framework for the integration of processes and data is introduced. This framework is complemented by operational semantics through a Petri net mapping extended with data considerations. Model-driven data execution comprises the handling of complex data dependencies, process data, and data exchange in case of communication between multiple process participants. This thesis introduces concepts from the database domain into BPM to enable the distinction of data operations, to specify relations between data objects of the same as well as of different types, to correlate modeled data nodes as well as received messages to the correct run-time process instances, and to generate messages for inter-process communication. The underlying approach, which is not limited to a particular process description language, has been implemented as proof-of-concept.
Automation of data handling in business processes requires data-annotated and correct process models. Targeting the former, algorithms are introduced to extract information about data nodes, their states, and data dependencies from control information and to annotate the process model accordingly. Usually, not all required information can be extracted from control flow information, since some data manipulations are not specified. This requires further refinement of the process model. Given a set of object life cycles specifying allowed data manipulations, automated refinement of the process model towards containment of all data manipulations is enabled. Process models are an abstraction focusing on specific aspects in detail, e.g., the control flow and the data flow views are often represented through activity-centric and object-centric process models. This thesis introduces algorithms for roundtrip transformations enabling the stakeholder to add information to the process model in the view being most appropriate.
Targeting process model correctness, this thesis introduces the notion of weak conformance that checks for consistency between given object life cycles and the process model such that the process model may only utilize data manipulations specified directly or indirectly in an object life cycle. The notion is computed via soundness checking of a hybrid representation integrating control flow and data flow correctness checking. Making a process model executable, identified violations must be corrected. Therefore, an approach is proposed that identifies for each violation multiple, alternative changes to the process model or the object life cycles.
Utilizing the results of this thesis, business processes can be executed entirely model-driven from the data perspective in addition to the control flow and resource perspectives already supported before. Thereby, the model creation is supported by algorithms partly automating the creation process while model consistency is ensured by data correctness checks.
This thesis investigates the application of polyelectrolyte multilayers in plasmonics and picosecond acoustics. The observed samples were fabricated by the spin-assisted layer-by-layer deposition technique that allowed a precise tuning of layer thickness in the range of few nanometers.
The first field of interest deals with the interaction of light-induced localized surface plasmons (LSP) of rod-shaped gold nanoparticles with the particles' environment. The environment consists of an air phase and a phase of polyelectrolytes, whose ratio affects the spectral position of the LSP resonance.
Measured UV-VIS spectra showed the shift of the LSP absorption peak as a function of the cover layer thickness of the particles. The data are modeled using an average dielectric function instead of the dielectric functions of air and polyelectrolytes. In addition using a measured dielectric function of the gold nanoparticles, the position of the LSP absorption peak could be simulated with good agreement to the data.
The analytic model helps to understand the optical properties of metal nanoparticles in an inhomogeneous environment.
The second part of this work discusses the applicability of PAzo/PAH and dye-doped PSS/PAH polyelectrolyte multilayers as transducers to generate hypersound pulses. The generated strain pulses were detected by time-domain Brillouin scattering (TDBS) using a pump-probe laser setup. Transducer layers made of polyelectrolytes were compared qualitatively to common aluminum transducers in terms of measured TDBS signal amplitude, degradation due to laser excitation, and sample preparation.
The measurements proved that fast and easy prepared polyelectrolyte transducers provided stronger TDBS signals than the aluminum transducer. AFM topography measurements showed a degradation of the polyelectrolyte structures, especially for the PAzo/PAH sample.
To quantify the induced strain, optical barriers were introduced to separate the transducer material from the medium of the hypersound propagation. Difficulties in the sample preparation prohibited a reliable quantification. But the experiments showed that a coating with transparent polyelectrolytes increases the efficiency of aluminum transducers and modifies the excited phonon distribution.
The adoption of polyelectrolytes to the scientific field of picosecond acoustics enables a cheap and fast fabrication of transducer layers on most surfaces. In contrast to aluminum layers the polyelectrolytes are transparent over a wide spectral range. Thus, the strain modulation can be probed from surface and back.
This thesis investigates temporal and aspectual reference in the typologically unrelated African languages Hausa (Chadic, Afro–Asiatic) and Medumba (Grassfields Bantu).
It argues that Hausa is a genuinely tenseless language and compares the interpretation of temporally unmarked sentences in Hausa to that of morphologically tenseless sentences in Medumba, where tense marking is optional and graded.
The empirical behavior of the optional temporal morphemes in Medumba motivates an analysis as existential quantifiers over times and thus provides new evidence suggesting that languages vary in whether their (past) tense is pronominal or quantificational (see also Sharvit 2014).
The thesis proposes for both Hausa and Medumba that the alleged future tense marker is a modal element that obligatorily combines with a prospective future shifter (which is covert in Medumba). Cross-linguistic variation in whether or not a future marker is compatible with non-future interpretation is proposed to be predictable from the aspectual architecture of the given language.
We study segregation of the subducted oceanic crust (OC) at the core mantle boundary and its ability to accumulate and form large thermochemical piles (such as the seismically observed Large Low Shear Velocity Provinces - LLSVPs). Our high-resolution numerical simulations suggest that the longevity of LLSVPs for up to three billion years, and possibly longer, can be ensured by a balance in the rate of segregation of high-density OC-material to the CMB, and the rate of its entrainment away from the CMB by mantle upwellings.
For a range of parameters tested in this study, a large-scale compositional anomaly forms at the CMB, similar in shape and size to the LLSVPs. Neutrally buoyant thermochemical piles formed by mechanical stirring - where thermally induced negative density anomaly is balanced by the presence of a fraction of dense anomalous material - best resemble the geometry of LLSVPs. Such neutrally buoyant piles tend to emerge and survive for at least 3Gyr in simulations with quite different parameters. We conclude that for a plausible range of values of density anomaly of OC material in the lower mantle - it is likely that it segregates to the CMB, gets mechanically mixed with the ambient material, and forms neutrally buoyant large scale compositional anomalies similar in shape to the LLSVPs.
We have developed an efficient FEM code with dynamically adaptive time and space resolution, and marker-in-cell methodology. This enabled us to model thermochemical mantle convection at realistically high convective vigor, strong thermally induced viscosity variations, and long term evolution of compositional fields.
Reconstructing climate from the Dead Sea sediment record using high-resolution micro-facies analyses
(2015)
The sedimentary record of the Dead Sea is a key archive for reconstructing climate in the eastern Mediterranean region, as it stores the environmental and tectonic history of the Levant for the entire Quaternary. Moreover, the lake is located at the boundary between Mediterranean sub-humid to semi-arid and Saharo-Arabian hyper-arid climates, so that even small shifts in atmospheric circulation are sensitively recorded in the sediments. This DFG-funded doctoral project was carried out within the ICDP Dead Sea Deep Drilling Project (DSDDP) that intended to gain the first long, continuous and high-resolution sediment core from the deep Dead Sea basin. The drilling campaign was performed in winter 2010-11 and more than 700 m of sediments were recovered. The main aim of this thesis was (1) to establish the lithostratigraphic framework for the ~455 m long sediment core from the deep Dead Sea basin and (2) to apply high-resolution micro-facies analyses for reconstructing and better understanding climate variability from the Dead Sea sediments.
Addressing the first aim, the sedimentary facies of the ~455 m long deep-basin core 5017-1 were described in great detail and characterised through continuous overview-XRF element scanning and magnetic susceptibility measurements. Three facies groups were classified: (1) the marl facies group, (2) the halite facies group and (3) a group involving different expressions of massive, graded and slumped deposits including coarse clastic detritus. Core 5017-1 encompasses a succession of four main lithological units. Based on first radiocarbon and U-Th ages and correlation of these units to on-shore stratigraphic sections, the record comprises the last ca 220 ka, i.e. the upper part of the Amora Formation (parts of or entire penultimate interglacial and glacial), the last interglacial Samra Fm. (~135-75 ka), the last glacial Lisan Fm. (~75-14 ka) and the Holocene Ze’elim Formation. A major advancement of this record is that, for the first time, also transitional intervals were recovered that are missing in the exposed formations and that can now be studied in great detail.
Micro-facies analyses involve a combination of high-resolution microscopic thin section analysis and µXRF element scanning supported by magnetic susceptibility measurements. This approach allows identifying and characterising micro-facies types, detecting event layers and reconstructing past climate variability with up to seasonal resolution, given that the analysed sediments are annually laminated. Within this thesis, micro-facies analyses, supported by further sedimentological and geochemical analyses (grain size, X-ray diffraction, total organic carbon and calcium carbonate contents) and palynology, were applied for two time intervals:
(1) The early last glacial period ~117-75 ka was investigated focusing on millennial-scale hydroclimatic variations and lake level changes recorded in the sediments. Thereby, distinguishing six different micro-facies types with distinct geochemical and sedimentological characteristics allowed estimating relative lake level and water balance changes of the lake. Comparison of the results to other records in the Mediterranean region suggests a close link of the hydroclimate in the Levant to North Atlantic and Mediterranean climates during the time of the build-up of Northern hemisphere ice sheets during the early last glacial period.
(2) A mostly annually laminated late Holocene section (~3700-1700 cal yr BP) was analysed in unprecedented detail through a multi-proxy, inter-site correlation approach of a shallow-water core (DSEn) and its deep-basin counterpart (5017-1). Within this study, a ca 1500 years comprising time series of erosion and dust deposition events was established and anchored to the absolute time-scale through 14C dating and age modelling. A particular focus of this study was the characterisation of two dry periods, from ~3500 to 3300 and from ~3000 to 2400 cal yr BP, respectively. Thereby, a major outcome was the coincidence of the latter dry period with a period of moist and cold climate in Europe related to a Grand Solar Minimum around 2800 cal yr BP and an increase in flood events despite overall dry conditions in the Dead Sea region during that time. These contrasting climate signatures in Europe and at the Dead Sea were likely linked through complex teleconnections of atmospheric circulation, causing a change in synoptic weather patterns in the eastern Mediterranean.
In summary, within this doctorate the lithostratigraphic framework of a unique long sediment core from the deep Dead Sea basin is established, which serves as a base for any further high-resolution investigations on this core. It is demonstrated in two case studies that micro-facies analyses are an invaluable tool to understand the depositional processes in the Dead Sea and to decipher past climate variability in the Levant on millennial to seasonal time-scales. Hence, this work adds important knowledge helping to establish the deep Dead Sea record as a key climate archive of supra-regional significance.
The present study addresses the question of how German vowels are perceived and produced by Polish learners of German as a Foreign Language. It comprises three main experiments: a discrimination experiment, a production experiment, and an identification experiment. With the exception of the discrimination task, the experiments further investigated the influence of orthographic marking on the perception and production of German vowel length. It was assumed that explicit markings such as the Dehnungs-h ("lengthening h") could help Polish GFL learners in perceiving and producing German words more correctly.
The discrimination experiment with manipulated nonce words showed that Polish GFL learners detect pure length differences in German vowels less accurately than German native speakers, while this was not the case for pure quality differences. The results of the identification experiment contrast with the results of the discrimination task in that Polish GFL learners were better at judging incorrect vowel length than incorrect vowel quality in manipulated real words. However, orthographic marking did not turn out to be the driving factor and it is suggested that metalinguistic awareness can explain the asymmetry between the two perception experiments. The production experiment supported the results of the identification task in that lengthening h did not help Polish learners in producing German vowel length more correctly. Yet, as far as vowel quality productions are concerned, it is argued that orthography does influence L2 sound productions because Polish learners seem to be negatively influenced by their native grapheme-to-phoneme correspondences.
It is concluded that it is important to differentiate between the influence of the L1 and L2 orthographic system. On the one hand, the investigation of the influence of orthographic vowel length markers in German suggests that Polish GFL learners do not make use of length information provided by the L2 orthographic system. On the other hand, the vowel quality data suggest that the L1 orthographic system plays a crucial role in the acquisition of a foreign language. It is therefore proposed that orthography influences the acquisition of foreign sounds, but not in the way it was originally assumed.
Effect of mass wasting on soil organic carbon storage and coastal erosion in permafrost environments
(2015)
Accelerated permafrost thaw under the warming Arctic climate can have a significant impact on Arctic landscapes. Areas underlain by permafrost store high amounts of soil organic carbon (SOC). Permafrost disturbances may contribute to increased release of carbon dioxide and methane to the atmosphere. Coastal erosion, amplified through a decrease in Arctic sea-ice extent, may also mobilise SOC from permafrost. Large expanses of permafrost affected land are characterised by intense mass-wasting processes such as solifluction, active-layer detachments and retrogressive thaw slumping. Our aim is to assess the influence of mass wasting on SOC storage and coastal erosion.
We studied SOC storage on Herschel Island by analysing active-layer and permafrost samples, and compared non-disturbed sites to those characterised by mass wasting. Mass-wasting sites showed decreased SOC storage and material compaction, whereas sites characterised by material accumulation showed increased storage. The SOC storage on Herschel Island is also significantly correlated to catenary position and other slope characteristics. We estimated SOC storage on Herschel Island to be 34.8 kg C m-2. This is comparable to similar environments in northwest Canada and Alaska.
Coastal erosion was analysed using high resolution digital elevation models (DEMs). Two LIDAR scanning of the Yukon Coast were done in 2012 and 2013. Two DEMs with 1 m horizontal resolution were generated and used to analyse elevation changes along the coast. The results indicate considerable spatial variability in short-term coastline erosion and progradation. The high variability was related to the presence of mass-wasting processes. Erosion and deposition extremes were recorded where the retrogressive thaw slump (RTS) activity was most pronounced. Released sediment can be transported by longshore drift and affects not only the coastal processes in situ but also along adjacent coasts.
We also calculated volumetric coastal erosion for Herschel Island by comparing a stereo-photogrammetrically derived DEM from 2004 with LIDAR DEMs. We compared this volumetric erosion to planimetric erosion, which was based on coastlines digitised from satellite imagery. We found a complex relationship between planimetric and volumetric coastal erosion, which we attribute to frequent occurrence of mass-wasting processes along the coasts. Our results suggest that volumetric erosion corresponds better with environmental forcing and is more suitable for the estimation of organic carbon fluxes than planimetric erosion.
Mass wasting can decrease SOC storage by several mechanisms. Increased aeration following disturbance may increase microbial activity, which accelerates organic matter decomposition. New hydrological conditions that follow the mass wasting event can cause leaching of freshly exposed material. Organic rich material can also be directly removed into the sea or into a lake. On the other hand the accumulation of mobilised material can result in increased SOC storage. Mass-wasting related accumulations of mobilised material can significantly impact coastal erosion in situ or along the adjacent coast by longshore drift. Therefore, the coastline movement observations cannot completely resolve the actual sediment loss due to these temporary accumulations. The predicted increase of mass-wasting activity in the course of Arctic warming may increase SOC mobilisation and coastal erosion induced carbon fluxes.
Magnetite nanoparticles and their assembly comprise a new area of development for new technologies. The magnetic particles can interact and assemble in chains or networks. Magnetotactic bacteria are one of the most interesting microorganisms, in which the assembly of nanoparticles occurs. These microorganisms are a heterogeneous group of gram negative prokaryotes, which all show the production of special magnetic organelles called magnetosomes, consisting of a magnetic nanoparticle, either magnetite (Fe3O4) or greigite (Fe3S4), embedded in a membrane. The chain is assembled along an actin-like scaffold made of MamK protein, which makes the magnetosomes to arrange in mechanically stable chains. The chains work as a compass needle in order to allow cells to orient and swim along the magnetic field of the Earth.
The formation of magnetosomes is known to be controlled at the molecular level. The physico–chemical conditions of the surrounding environment also influence biomineralization. The work presented in this manuscript aims to understand how such external conditions, in particular the extracellular oxidation reduction potential (ORP) influence magnetite formation in the strain Magnetospirillum magneticum AMB-1. A controlled cultivation of the microorganism was developed in a bioreactor and the formation of magnetosomes was characterized.
Different techniques have been applied in order to characterize the amount of iron taken up by the bacteria and in consequence the size of magnetosomes produced at different ORP conditions. By comparison of iron uptake, morphology of bacteria, size and amount of magnetosomes per cell at different ORP, the formation of magnetosomes was inhibited at ORP 0 mV, whereas reduced conditions, ORP – 500 mV facilitate biomineralization process.
Self-assembly of magnetosomes occurring in magnetotactic bacteria became an inspiration to learn from nature and to construct nanoparticles assemblies by using the bacteriophage M13 as a template. The M13 bacteriophage is an 800 nm long filament with encapsulated single-stranded DNA that has been recently used as a scaffold for nanoparticle assembly. I constructed two types of assemblies based on bacteriophages and magnetic nanoparticles. A chain – like assembly was first formed where magnetite nanoparticles are attached along the phage filament. A sperm – like construct was also built with a magnetic head and a tail formed by phage filament.
The controlled assembly of magnetite nanoparticles on the phage template was possible due to two different mechanism of nanoparticle assembly. The first one was based on the electrostatic interactions between positively charged polyethylenimine coated magnetite nanoparticles and negatively charged phages. The second phage –nanoparticle assembly was achieved by bioengineered recognition sites. A mCherry protein is displayed on the phage and is was used as a linker to a red binding nanobody (RBP) that is fused to the one of the proteins surrounding the magnetite crystal of a magnetosome.
Both assemblies were actuated in water by an external magnetic field showing their swimming behavior and potentially enabling further usage of such structures for medical applications. The speed of the phage - nanoparticles assemblies are relatively slow when compared to those of microswimmers previously published. However, only the largest phage-magnetite assemblies could be imaged and it is therefore still unclear how fast these structures can be in their smaller version.
This work investigates the influence of the Coriolis force on mass motion related to the Rheasilvia impact basin on asteroid (4) Vesta's southern hemisphere. The giant basin is 500km in diameter, with a centre which nearly coincides with the rotation axis of Vesta. The Rheasilvia basin partially overlaps an earlier, similarly large impact basin, Veneneia.
Mass motion within and in the vicinity of the Rheasilvia basin includes slumping and landslides, which, primarily due to their small linear extents, have not been noticeably affected by the Coriolis force. However, a series of ridges related to the basin exhibit significant curvature, which may record the effect of the Coriolis force on the mass motion which generated them.
In this thesis 32 of these curved ridges, in three geologically distinct regions, were examined. The mass motion velocities from which the ridge curvatures may have resulted during the crater modification stage were investigated. Velocity profiles were derived by fitting inertial circles along the curved ridges and considering both the current and past rotation states of Vesta. An iterative, statistical approach was used, whereby the radii of inertial circles were obtained through repeated fitting to triplets of points across the ridges. The most frequently found radius for each central point was then used for velocity derivation at that point.
The results of the velocity analysis are strongly supportive of a Coriolis force origin for the curved ridges. Derived velocities (29.6 ± 24.6 m/s) generally agree well with previously published predictions from numerical simulations of mass motion during the impact process. Topographical features such as local slope gradient and mass deposition regions on the curved ridges also independently agree with regions in which the calculated mass motion accelerates or decelerates.
Sections of constant acceleration, deceleration and constant velocity are found, showing that mass motion is being governed by varying conditions of topography, regolith structure and friction. Estimates of material properties such as the effective viscosities (1.9-9.0·10⁶ Pa·s) and coefficients of friction (0.02-0.81) are derived from the velocity profile information in these sections. From measured accelerations of mass motions on the crater wall, it is also shown that the crater walls must have been locally steeper at the time of the mass motion.
Together with these novel insights into the state and behaviour of material moving during the modification stage of Rheasilvia's formation, this work represents the first time that the Coriolis Effect on mass motions during crater formation has been shown to result in diagnostic features preserved until today.
Peak oil is forcing our society to shift from fossil to renewable resources. However, such renewable resources are also scarce, and they too must be used in the most efficient and sustainable way possible. Biorefining is a concept that represents both resource efficiency and sustainability. This approach initiates a cascade use, which means food and feed production before material use, and an energy-related use at the end of the value-added chain. However, sustainability should already start in the fields, on the agricultural side, where the industrially-used biomass is produced. Therefore, the aim of my doctoral thesis is to analyse the sustainable feedstock supply for biorefineries. In contrast to most studies on biorefineries, I focus on the sustainable provision of feedstock and not on the bioengineering processing of whatever feedstock is available.
Grasslands provide a high biomass potential. They are often inefficiently used, so a new utilisation concept based on the biorefining approach can increase the added value from grasslands. Fodder legumes from temporary and permanent grasslands were chosen for this study. Previous research shows that they are a promising feedstock for industrial uses, and their positive environmental impact is an important byproduct to promote sustainable agricultural production systems.
Green Biorefineries are a class of biorefineries that use fresh green biomass, such as grasses or fodder legumes, as feedstock. After fractionation, an organic solution (press juice) forms; this is used for the production of organic acids, chemicals and extracts, as well as fertilisers. A fibre component (press cake) is also created to produce feed, biomaterials and biogas. This thesis examines a specific value chain, using alfalfa and clover/grass as feedstock and generating lactic acid and one type of cattle feed from it. The research question is if biomass production needs to be adapted for the utilisation of fodder legumes in the Green Biorefinery approach. I have attempted to give a holistic analysis of cultivation, processing and utilisation of two specific grassland crops. Field trials with alfalfa and clover/grass at different study sites were carried out to obtain information on biomass quality and quantity depending on the crop, study site and harvest time. The fresh biomass was fractionated with a screw press and the composition of press juices and cakes was analysed. Fermentation experiments took place to determine the usability of press juices for lactic acid production. The harvest time is not of high importance for the quality of press juices as a fermentation medium. For permanent grasslands, late cuts, often needed for reasons of nature conservation, are possible without a major influence on feedstock quality. The press cakes were silaged for feed-value determination.
Following evidence that both intermediate products are suitable feedstocks in the Green Biorefinery approach, I developed a cost-benefit analysis, comparing different production scenarios on a farm. Two standard crop rotations for Brandenburg, producing either only market crops or market crops and fodder legumes for ruminant feed production, were compared to a system that uses the cultivated fodder legumes for the Green Biorefinery value chain instead of only feed production. Timely processing of the raw material is important to maintain quality for industrial uses, so on-site processing at the farm is assumed in Green Biorefinery scenario. As a result, more added value stays in the rural area. Two farm sizes, common for many European regions, were chosen to examine the influence of scale. The cost site of farmers has also been analysed in detail to assess which farm characteristics make production of press juices for biochemical industries viable. Results show that for large farm sizes in particular, the potential profits are high. Additionally, the wider spectrum of marketable products generates new sources of income for farmers.
The holistic analysis of the supply chain provides evidence that the cultivation processes for fodder legumes do not need to be adapted for use in Green Biorefineries. In fact, the new utilisation approach even widens the cultivation and processing spectrum and can increase economic viability of fodder legume production in conventional farming.
Two of the most controversial issues concerning the late Cenozoic evolution of the Andean orogen are the timing of uplift of the intraorogenic Puna plateau and its eastern border, the Eastern Cordillera, and ensuing changes in climatic and surface-process conditions in the intermontane basins of the NW-Argentine Andes. The Eastern Cordillera separates the internally drained, arid Puna from semi-arid intermontane basins and the humid sectors of the Andean broken foreland and the Subandean fold-and-thrust belt to the east. With elevations between 4,000 and 6,000 m the eastern flanks of the Andes form an efficient orographic barrier with westward-increasing elevation and asymmetric rainfall distribution and amount with respect to easterly moisture-bearing winds. This is mirrored by pronounced gradients in the efficiency of surface processes that erode and re-distribute sediment from the uplifting ranges. Although the overall pattern of deformation and uplift in this sector of the southern central Andes shows an eastward migration of deformation, a well-developed deformation front does not exist and uplift and associated erosion and sedimentary processes are highly disparate in space and time. In addition, periodic deformation within intermontane basins, and continued diachronous foreland uplifts associated with the reactivation of inherited basement structures furthermore make a rigorous assessment of the spatiotemporal uplift patterns difficult.
This thesis focuses on the tectonic evolution of the Eastern Cordillera of NW Argentina, the depositional history of its intermontane sedimentary basins, and the regional topographic evolution of the eastern flank of the Puna Plateau. The intermontane basins of the Eastern Cordillera and the adjacent morphotectonic provinces of the Sierras Pampeanas and the Santa Bárbara System are akin to reverse fault bounded, filled, and partly coalesced sedimentary basins of the Puna Plateau. In contrast to the Puna basins, however, which still form intact morphologic entities, repeated deformation, erosion, and re-filling have impacted the basins in the Eastern Cordillera. This has resulted in a rich stratigraphy of repeated basin fills, but many of these basins have retained vestiges of their early depositional history that may reach back in time when these areas were still part of a contiguous and undeformed foreland basin. Fortunately, these strata also contain abundant volcanic ashes that are not only important horizons to decipher tectono-sedimentary events through U-Pb geochronology and geochemical correlation, but they also represent terrestrial recorders of the hydrogen-isotope composition of ancient meteoric waters that can be compared to the isotopic composition of modern meteoric water. The ash horizons are thus unique recorders of past environmental conditions and lend themselves to tracking the development of rainfall barriers and tectonically forced climate and environmental change through time.
U-Pb zircon geochronology and paleocurrent reconstructions of conglomerate sequences in the Humahuaca Basin of the Eastern Cordillera at 23.5° S suggest that the basin was an integral part of a largely unrestricted depositional system until 4.2 Ma, which subsequently became progressively decoupled from the foreland by range uplifts to the east that forced easterly moisture-bearing winds to precipitate in increasingly eastward locations. Multiple cycles of severed hydrological conditions and drainage re-capture are identified together with these processes that were associated with basin filling and sediment evacuation, respectively. Moreover, systematic relationships among faults, regional unconformities and deformed landforms reveal a general pattern of intra-basin deformation that appears to be linked with basin-internal deformation during or subsequent to episodes of large-scale sediment removal. Some of these observations are supported by variations in the hydrogen stable isotope composition of volcanic glass from the Neogene to Quaternary sedimentary record, which can be related to spatiotemporal changes in topography and associated orographic effects. δDg values in the basin strata reveal two main trends associated with surface uplift in the catchment area between 6.0 and 3.5 Ma and the onset of semiarid conditions in the basin following the attainment of threshold elevations for effective orographic barriers to the east after 3.5 Ma. The disruption of sediment supply from western sources after 4.2 Ma and subsequent hinterland aridification, moreover, emphasize the possibility that these processes were related to lateral orogenic growth of the adjacent Puna Plateau. As a result of the hinterland aridification the regions in the orogen interior have been characterized by an inefficient fluvial system, which in turn has helped maintaining internal drainage conditions, sediment storage, and relief reduction within high-elevation basins.
The diachronous nature of basin formation and impacts on the fluvial system in the adjacent broken foreland is underscored by the results of detailed sediment provenance and paleocurrent analyses, as well as U-Pb zircon geochronology in the Lerma and Metán basins at ca. 25° S. This is particularly demonstrated by the isolated uplift of the Metán range at ~10 Ma, which is more than 50 km away from the presently active orogenic front along the eastern Puna margin and the Eastern Cordillera to the west. At about 5 Ma, Puna-sourced sediments disappear from the foreland record, documenting further range uplifts in the Eastern Cordillera and hydrological isolation of the neighboring Angastaco Basin from the foreland. Finally, during the late Pliocene and Quaternary, deformation has been accommodated across the entire foreland and is still active. To elucidate the interactions between tectonically controlled changes in elevation and their impact on atmospheric circulation processes in this region, this thesis provides additional, temporally well-constrained hydrogen stable isotope results of volcanic glass samples from the broken foreland, including the Angastaco Basin, and other intermontane basins farther south. The results suggest similar elevations of intermontane basins and the foreland sectors prior to ca. 7 Ma. In case of the Angastaco Basin the region was affected by km-scale surface uplift of the basin. A comparison with coeval isotope data collected from sedimentary sequences in the Puna plateau explains rapid shifts in the intermontane δDg record and supports the notion of recurring phases of enhanced deep convection during the Pliocene, and thus climatic conditions during the middle to late Pliocene similar to the present day.
Combined, field-based and isotope geochemical methods used in this study of the NW-Argentine Andes have thus helped to gain insight into the systematics, rate changes, interactions, and temporal characteristics among tectonically controlled deformation patterns, the build-up of topography impacting atmospheric processes, the distribution of rainfall, and resulting surface processes in a tectonically active mountain belt. Ultimately, this information is essential for a better understanding of the style and the rates at which non-collisional mountain belts evolve, including the development orogenic plateaus and their bordering flanks. The results presented in this study emphasize the importance of stable isotope records for paleoaltimetric and paleoenvironmental studies in mountain belts and furnishes important data for a rigorous interpretation of such records.
Anthropogenic activities have transformed the Earth's environment, not only on local level, but on the planetary-scale causing global change. Besides industrialization, agriculture is a major driver of global change. This change in turn impairs the agriculture sector, reducing crop yields namely due to soil degradation, water scarcity, and climate change. However, this is a more complex issue than it appears. Crop yields can be increased by use of agrochemicals and fertilizers which are mainly produced by fossil energy. This is important to meet the increasing food demand driven by global demographic change, which is further accelerated by changes in regional lifestyles. In this dissertation, we attempt to address this complex problem exploring agricultural potential globally but on a local scale. For this, we considered the influence of lifestyle changes (dietary patterns) as well as technological progress and their effects on climate change, mainly greenhouse gas (GHG) emissions. Furthermore, we examined options for optimizing crop yields in the current cultivated land with the current cropping patterns by closing yield gaps. Using this, we investigated in a five-minute resolution the extent to which food demand can be met locally, and/or by regional and/or global trade. Globally, food consumption habits are shifting towards calorie rich diets. Due to dietary shifts combined with population growth, the global food demand is expected to increase by 60-110% between 2005 and 2050. Hence, one of the challenges to global sustainability is to meet the growing food demand, while at the same time, reducing agricultural inputs and environmental consequences. In order to address the above problem, we used several freely available datasets and applied multiple interconnected analytical approaches that include artificial neural network, scenario analysis, data aggregation and harmonization, downscaling algorithm, and cross-scale analysis.
Globally, we identified sixteen dietary patterns between 1961 and 2007 with food intakes ranging from 1,870 to 3,400 kcal/cap/day. These dietary patterns also reflected changing dietary habits to meat rich diets worldwide. Due to the large share of animal products, very high calorie diets that are common in the developed world, exhibit high total per capita emissions of 3.7-6.1 kg CO2eq./day. This is higher than total per capita emissions of 1.4-4.5 kg CO2eq./day associated with low and moderate calorie diets that are common in developing countries. Currently, 40% of the global crop calories are fed to livestock and the feed calorie use is four times the produced animal calories. However, these values vary from less than 1 kcal to greater 10 kcal around the world. On the local and national scale, we found that the local and national food production could meet demand of 1.9 and 4.4 billion people in 2000, respectively. However, 1 billion people from Asia and Africa require intercontinental agricultural trade to meet their food demand. Nevertheless, these regions can become food self-sufficient by closing yield gaps that require location specific inputs and agricultural management strategies. Such strategies include: fertilizers, pesticides, soil and land improvement, management targeted on mitigating climate induced yield variability, and improving market accessibility. However, closing yield gaps in particular requires global N-fertilizer application to increase by 45-73%, P2O5 by 22-46%, and K2O by 2-3 times compare to 2010. Considering population growth, we found that the global agricultural GHG emissions will approach 7 Gt CO2eq./yr by 2050, while the global livestock feed demand will remain similar to 2000. This changes tremendously when diet shifts are also taken into account, resulting in GHG emissions of 20 Gt CO2eq./yr and an increase of 1.3 times in the crop-based feed demand between 2000 and 2050. However, when population growth, diet shifts, and technological progress by 2050 were considered, GHG emissions can be reduced to 14 Gt CO2eq./yr and the feed demand to nearly 1.8 times compare to that in 2000. Additionally, our findings shows that based on the progress made in closing yield gaps, the number of people depending on international trade can vary between 1.5 and 6 billion by 2050. In medium term, this requires additional fossil energy. Furthermore, climate change, affecting crop yields, will increase the need for international agricultural trade by 4% to 16%.
In summary, three general conclusions are drawn from this dissertation. First, changing dietary patterns will significantly increase crop demand, agricultural GHG emissions, and international food trade in the future when compared to population growth only. Second, such increments can be reduced by technology transfer and technological progress that will enhance crop yields, decrease agricultural emission intensities, and increase livestock feed conversion efficiencies. Moreover, international trade dependency can be lowered by consuming local and regional food products, by producing diverse types of food, and by closing yield gaps. Third, location specific inputs and management options are required to close yield gaps. Sustainability of such inputs and management largely depends on which options are chosen and how they are implemented. However, while every cultivated land may not need to attain its potential yields to enable food security, closing yield gaps only may not be enough to achieve food self-sufficiency in some regions. Hence, a combination of sustainable implementations of agricultural intensification, expansion, and trade as well as shifting dietary habits towards a lower share of animal products is required to feed the growing population.
Development of geophysical methods to characterize methane hydrate reservoirs on a laboratory scale
(2015)
Gas hydrates are crystalline solids composed of water and gas molecules. They are stable at elevated pressure and low temperatures. Therefore, natural gas hydrate deposits occur at continental margins, permafrost areas, deep lakes, and deep inland seas. During hydrate formation, the water molecules rearrange to form cavities which host gas molecules. Due to the high pressure during hydrate formation, significant amounts of gas can be stored in hydrate structures. The water-gas ratio hereby can reach up to 1:172 at 0°C and atmospheric pressure. Natural gas hydrates predominantly contain methane. Because methane constitutes both a fuel and a greenhouse gas, gas hydrates are a potential energy resource as well as a potential source for greenhouse gas.
This study investigates the physical properties of methane hydrate bearing sediments on a laboratory scale. To do so, an electrical resistivity tomography (ERT) array was developed and mounted in a large reservoir simulator (LARS). For the first time, the ERT array was applied to hydrate saturated sediment samples under controlled temperature, pressure, and hydrate saturation conditions on a laboratory scale. Typically, the pore space of (marine) sediments is filled with electrically well conductive brine. Because hydrates constitute an electrical isolator, significant contrasts regarding the electrical properties of the pore space emerge during hydrate formation and dissociation. Frequent measurements during hydrate formation experiments permit the recordings of the spatial resistivity distribution inside LARS. Those data sets are used as input for a new data processing routine which transfers the spatial resistivity distribution into the spatial distribution of hydrate saturation. Thus, the changes of local hydrate saturation can be monitored with respect to space and time.
This study shows that the developed tomography yielded good data quality and resolved even small amounts of hydrate saturation inside the sediment sample. The conversion algorithm transforming the spatial resistivity distribution into local hydrate saturation values yielded the best results using the Archie-var-phi relation. This approach considers the increasing hydrate phase as part of the sediment frame, metaphorically reducing the sample’s porosity. In addition, the tomographical measurements showed that fast lab based hydrate formation processes cause small crystallites to form which tend to recrystallize.
Furthermore, hydrate dissociation experiments via depressurization were conducted in order to mimic the 2007/2008 Mallik field trial. It was observed that some patterns in gas and water flow could be reproduced, even though some setup related limitations arose.
In two additional long-term experiments the feasibility and performance of CO2-CH4 hydrate exchange reactions were studied in LARS. The tomographical system was used to monitor the spatial hydrate distribution during the hydrate formation stage. During the subsequent CO2 injection, the tomographical array allowed to follow the CO2 migration front inside the sediment sample and helped to identify the CO2 breakthrough.
During the last two decades, instability training devices have become a popular means in athletic training and rehabilitation of mimicking unstable surfaces during movements like vertical jumps. Of note, under unstable conditions, trunk muscles seem to have a stabilizing function during exercise to facilitate the transfer of torques and angular momentum between the lower and upper extremities. The present thesis addresses the acute effects of surface instability on performance during jump-landing tasks. Additionally, the long-term effects (i.e., training) of surface instability were examined with a focus on the role of the trunk in athletic performance/physical fitness.
Healthy adolescent, and young adult subjects participated in three cross-sectional and one longitudinal study, respectively. Performance in jump-landing tasks on stable and unstable surfaces was assessed by means of a ground reaction force plate. Trunk muscle strength (TMS) was determined using an isokinetic device or the Bourban TMS test. Physical fitness was quantified by standing long jump, sprint, stand-and-reach, jumping sideways, Emery balance, and Y balance test on stable surfaces. In addition, activity of selected trunk and leg muscles and lower limb kinematics were recorded during jump-landing tasks.
When performing jump-landing tasks on unstable compared to stable surfaces, jump performance and leg muscle activity were significantly lower. Moreover, significantly smaller knee flexion angles and higher knee valgus angles were observed when jumping and landing on unstable compared to stable conditions and in women compared to men. Significant but small associations were found between behavioral and neuromuscular data, irrespective of surface condition. Core strength training on stable as well as on unstable surfaces significantly improved TMS, balance and coordination.
The findings of the present thesis imply that stable rather than unstable surfaces provide sufficient training stimuli during jump exercises (i.e., plyometrics). Additionally, knee motion strategy during plyometrics appears to be modified by surface instability and sex. Of note, irrespective of surface condition, trunk muscles only play a minor role for leg muscle performance/activity during jump exercises. Moreover, when implemented in strength training programs (i.e., core strength training), there is no advantage in using instability training devices compared to stable surfaces in terms of enhancement of athletic performance.
The high-latitudinal thermospheric processes driven by the solar wind and Interplanetary Magnetic Field (IMF) interaction with the Earth magnetosphere are highly variable parts of the complex dynamic plasma environment, which represent the coupled Magnetosphere – Ionosphere – Thermosphere (MIT) system. The solar wind and IMF interactions transfer energy to the MIT system via reconnection processes at the magnetopause. The Field Aligned Currents (FACs) constitute the energetic links between the magnetosphere and the Earth ionosphere. The MIT system depends on the highly variable solar wind conditions, in particular on changes of the strength and orientation of the IMF.
In my thesis, I perform an investigation on the physical background of the complex MIT system using the global physical - numerical, three-dimensional, time-dependent and self-consistent Upper Atmosphere Model (UAM). This model describes the thermosphere, ionosphere, plasmasphere and inner magnetosphere as well as the electrodynamics of the coupled MIT system for the altitudinal range from 80 (60) km up to the 15 Earth radii.
In the present study, I developed and investigated several variants of the high-latitudinal electrodynamic coupling by including the IMF dependence of FACs into the UAM model. For testing, the various variants were applied to simulations of the coupled MIT system for different seasons, geomagnetic activities, various solar wind and IMF conditions. Additionally, these variants of the theoretical model with the IMF dependence were compared with global empirical models. The modelling results for the most important thermospheric parameters like neutral wind and mass density were compared with satellite measurements. The variants of the UAM model with IMF dependence show a good agreement with the satellite observations. In comparison with the empirical models, the improved variants of the UAM model reproduce a more realistic meso-scale structures and dynamics of the coupled MIT system than the empirical models, in particular at high latitudes. The new configurations of the UAM model with IMF dependence contribute to the improvement of space weather prediction.
Welfare states and policies have changed greatly over the past decades, mostly characterized by retrenchments in terms of government spending or in terms of restricted access to certain benefits. In the area of family policies, however, a lot of countries have simultaneously expanded provisions and transfers for families. Bringing together the macro analysis of policy variation and household income changes on the micro-level, the main research question of the dissertation is to what extent economic consequences following separation and divorce in families with children have changed between the 1980s and the 2000s in Germany and the United States. The second research question of the dissertation regards the differences in dissolution outcomes between married and cohabiting parents in Germany.
The dissertation thus aims to link institutional regulations of welfare states with the actual income situation of families. To achieve this, a research design was developed that has never been used for the analysis of the economic consequences of family dissolution. For this, the two longest running panel datasets, German Socio-economic Panel (GSOEP) and the US American Panel Study of Income Dynamics (PSID), have been used. The analytic strategy applied to estimate the effects of family dissolution on household income is a difference-in-difference design combined with coarsened exact matching (CEM).
To begin with, the dissertation confirmed many findings of previous research, for example regarding the gender differences in family dissolution outcomes. Mothers experience clearly higher relative income losses and consequently higher risks of poverty than fathers. This finding is universal, that is it holds for both countries, for all time periods observed, and for all measures of economic outcome that were employed. Another confirmed finding is the higher level of welfare state intervention in Germany compared to the United States.
The dissertation also revealed a number of novel findings. The results show that the expansion of family policies in Germany over time has not been accompanied by substantially decreasing income losses for mothers. Though income losses have slightly decreased over time, they have become more persistent during the years following family dissolution. The impact of the German welfare state has meanwhile been quite stable.
American mothers’ income losses took place on a slightly lower level than those of German mothers. Only during the 1980s their relative losses were clearly lower than those of German mothers. And also American mothers did not recover as much from their income losses during the 2000s than they used to during the 1980s. For them, the 1996 welfare reform brought a considerable decrease in welfare state support. Accordingly, the results for American mothers can certainly be described as a shift from public to private provision.
The general finding of previous studies that fathers do not have to suffer income losses, or if at all rather moderate ones compared to mothers, can be confirmed. Nevertheless, both German and US American fathers face a deterioration of the economic consequences of family dissolution over time. German fathers’ relative income changes are still positive though they have decreased over time. One reason for this decrease is the increasing loss of partner earnings following union dissolution. Also among American fathers, income gains still prevail in the year of family dissolution. Two years later, however, they have been facing income losses already since the 1980s which have furthermore increased considerably over time.
Zooming in on Germany, family dissolution outcomes by marital status show negligible differences between cohabiting and married mothers in disposable income, but considerable differences in losses of income before taxes and transfers. It is the impact of the welfare state that equalizes the differences in income losses between these two groups of mothers. For married mothers, losses are not as high in the year of event but they have difficulties to recover from these losses. Without the income buffering of the welfare state, married mothers would, three years after family dissolution, remain with relative income losses double as high as for cohabiting mothers.
Compared to mothers, differences between married and cohabiting fathers are visible in changes of income before as well as after taxes and transfers. The welfare state does not alter the difference between the two groups of fathers. With regard to both income concepts, cohabiting fathers fare worse than married fathers. Cohabiting fathers suffer moderate income losses of disposable income while married fathers experience moderate income gains. Accounting for support payments is decisive for fathers’ income changes. If these payments are not deducted from disposable income, both married and cohabiting fathers experience gains in disposable income following family dissolution.
Plant cell walls are complex structures that underpin plant growth and are widely exploited in diverse human activities thus placing them with a central importance in biology. Cell walls have been a prominent area of research for a long time, but the chemical complexity and diversity of cell walls not just between species, but also within plants, between cell-types, and between cell wall micro-domains pose several challenges. Progress accelerated several-fold in cell wall biology owing to advances in sequencing technology, aided soon thereafter by advances in omics and imaging technologies. This development provides additional perspectives of cell walls across a rapidly growing number of species, highlighting a myriad of architectures, compositions, and functions.
Furthermore, rather than the component centric view, integrative analysis of the different cell wall components across system-levels help to gain a more in-depth understanding of the structure and biosynthesis of the cell envelope and its interactions with the environment.
To this end, in this work three case studies are detailed, all pertaining to the integrative analysis of heterogeneous cell wall related data arising from different system-levels and analytical techniques. A detailed account of multiblock methods is provided and in particular canonical correlation and regression methods of data integration are discussed. In the first integrative analysis, by employing canonical correlation analysis - a multivariate statistical technique to study the association between two datasets - novel insight to the relationship between glycans and phenotypic traits is gained. In addition, sparse partial least squares regression approach that adapts Lasso penalization and allows for the selection of a subset of variables was employed. The second case study focuses on an integrative analysis of images obtained from different spectroscopic techniques. By employing yet another multiblock approach - multiple co-inertia analysis, insitu biochemical composition of cell walls from different cell-types is studied thereby highlighting the common and complementary parts of the two hyperspectral imaging techniques. Finally, the third integrative analysis facilitates gene expression analysis of the Arabidopsis root transcriptome and translatome for the identification of cell wall related genes and compare expression patterns of cell wall synthesis genes. The computational analysis considered correlation and variation of expression across cell-types at both system-levels, and also provides insight into the degree of co-regulatory relationships that are preserved between the two processes.
The integrative analysis of glycan data and phenotypic traits in cotton fibers using canonical methods led to the identification of specific polysaccharides which may play a major role during fiber development for the final fiber characteristics. Furthermore, this analysis provides a base for future studies on glycan arrays in case of developing cotton fibers. The integrative analysis of images from infrared and Raman spectroscopic approaches allowed the coupling of different analytical techniques to characterize complex biological material, thereby, representing various facets of their chemical properties. Moreover, the results from the co-inertia analysis demonstrated that the study was well adapted as it is relevant for coupling data tables in a symmetric way. Several indicators are proposed to investigate how the global and block scores are related. In addition, studying the root cells of \textit{Arabidopsis thaliana} allowed positing a novel pipeline to systematically investigate and integrate the different levels of information available at the global and single-cell level. The conducted analysis also confirms that previously identified key transcriptional activators of secondary cell wall development display highly conserved patterns of transcription and translation across the investigated cell-types. Moreover, the biological processes that display conserved and divergent patterns based on the cell-type-specific expression and translation levels are identified.
The dissertation proposes that the spread of photography and popular cinema in 19th- and 20th-century-India have shaped an aesthetic and affective code integral to the reading and interpretation of Indian English novels, particularly when they address photography and/or cinema film, as in the case of the four corpus texts. In analyzing the nexus between ‘real’ and ‘reel’, the dissertation shows how the texts address the reader as media consumer and virtual image projector. Furthermore, the study discusses the Indian English novel against the backdrop of the cultural and medial transformations of the 20th century to elaborate how these influenced the novel’s aesthetics. Drawing upon reception aesthetics, the author devises the concept of the ‘implied spectator’ to analyze the aesthetic impact of the novels’ images as visual textures.
No God in Sight (2005) by Altaf Tyrewala comprises of a string of 41 interior monologues, loosely connected through their narrators’ random encounters in Mumbai in the year 2000. Although marked by continuous perspective shifts, the text creates a sensation of acute immediacy. Here, the reader is addressed as implied spectator and is sutured into the narrated world like a film spectator ― an effect created through the use of continuity editing as a narrative technique.
Similarly, Ruchir Joshi’s The Last Jet Engine Laugh (2002) coll(oc)ates disparate narrative perspectives and explores photography as an artistic practice, historiographic recorder and epistemological tool. The narrative appears guided by the random viewing of old photographs by the protagonist and primary narrator, the photographer Paresh Bhatt. However, it is the photographic negative and the practice of superimposition that render this string of episodes and different perspectives narratively consequential and cosmologically meaningful. Photography thus marks the perfect symbiosis of autobiography and historiography.
Tabish Khair’s Filming. A Love Story (2007) immerses readers in the cine-aesthetic of 1930s and 40s Bombay film, the era in which the embedded plot is set. Plotline, central scenes and characters evoke the key films of Indian cinema history such as Satyajit Ray’s “Pather Panchali” or Raj Kapoor’s “Awara”. Ultimately, the text written as film dissolves the boundary between fiction and (narrated) reality, reel and real, thereby showing that the images of individual memory are inextricably intertwined with and shaped by collective memory. Ultimately, the reconstruction of the past as and through film(s) conquers trauma and endows the Partition of India as a historic experience of brutal contingency with meaning.
The Bioscope Man (Indrajit Hazra, 2008) is a picaresque narrative set in Calcutta - India’s cultural capital and birthplace of Indian cinema at the beginning of the 20th century. The autodiegetic narrator Abani Chatterjee relates his rise and fall as silent film star, alternating between the modes of tell and show. He is both autodiegetic narrator and spectator or perceiving consciousness, seeing himself in his manifold screen roles. Beyond his film roles however, the narrator remains a void. The marked psychoanalytical symbolism of the text is accentuated by repeated invocations of dark caves and the laterna magica. Here too, ‘reel life’ mirrors and foreshadows real life as Indian and Bengali history again interlace with private history. Abani Chatterjee thus emerges as a quintessentially modern man of no qualities who assumes definitive shape only in the lost reels of the films he starred in.
The final chapter argues that the static images and visual frames forwarded in the texts observe an integral psychological function: Premised upon linear perspective they imply a singular, static subjectivity appealing to the postmodern subject. In the corpus texts, the rise of digital technology in the 1990s thus appears not so much to have displaced older image repertories, practices and media techniques, than it has lent them greater visibility and appeal. Moreover, bricolage and pastiche emerge as cultural techniques which marked modernity from its inception. What the novels thus perpetuate is a media archeology not entirely servant to the poetics of the real. The permeable subject and the notion of the gaze as an active exchange as encapsulated in the concept of darshan - ideas informing all four texts - bespeak the resilience of a mythical universe continually re-instantiated in new technologies and uses. Eventually, the novels convey a sense of subalternity to a substantially Hindu nationalist history and historiography, the centrifugal force of which developed in the twentieth century and continues into the present.
The overarching goal of this dissertation is to provide a better understanding of the role of wind and water in shaping Earth’s Cenozoic orogenic plateaus - prominent high-elevation, low relief sectors in the interior of Cenozoic mountain belts. In particular, the feedbacks between surface uplift, the build-up of topography and ensuing changes in precipitation, erosion, and vegetation patterns are addressed in light of past and future climate change. Regionally, the study focuses on the two world’s largest plateaus, the Altiplano-Puna Plateau of the Andes and Tibetan Plateau, both characterized by average elevations of >4 km. Both plateaus feature high, deeply incised flanks with pronounced gradients in rainfall, vegetation, hydrology, and surface processes. These characteristics are rooted in the role of plateaus to act as efficient orographic barriers to rainfall and to force changes in atmospheric flow.
The thesis examines the complex topics of tectonic and climatic forcing of the surface-process regime on three different spatial and temporal scales: (1) bedrock wind-erosion rates are quantified in the arid Qaidam Basin of NW Tibet over millennial timescales using cosmogenic radionuclide dating; (2) present-day stable isotope composition in rainfall is examined across the south-central Andes in three transects between 22° S and 28° S; these data are modeled and assessed with remotely sensed rainfall data of the Tropical Rainfall Measuring Mission and the Moderate Resolution Imaging Spectroradiometer; (3) finally, a 2.5-km-long Mio-Pliocene sedimentary record of the intermontane Angastaco Basin (25°45’ S, 66°00’ W) is presented in the context of hydrogen and carbon compositions of molecular lipid biomarker, and oxygen and carbon isotopes obtained from pedogenic carbonates; these records are compared to other environmental proxies, including hydrated volcanic glass shards from volcanic ashes intercalated in the sedimentary strata.
There are few quantitative estimates of eolian bedrock-removal rates from arid, low relief landscapes. Wind-erosion rates from the western Qaidam Basin based on cosmogenic 10Be measurements document erosion rates between 0.05 to 0.4 mm/yr. This finding indicates that in arid environments with strong winds, hyperaridity, exposure of friable strata, and ongoing rock deformation and uplift, wind erosion can outpace fluvial erosion. Large eroded sediment volumes within the Qaidam Basin and coeval dust deposition on the Chinese Loess plateau, exemplify the importance of dust production within arid plateau environments for marine and terrestrial depositional processes, but also health issues and fertilization of soils.
In the south-central Andes, the analysis of 234 stream-water samples for oxygen and hydrogen reveals that areas experiencing deep convective storms do not show the commonly observed patterns of isotopic fractionation and the expected co-varying relationships between oxygen and hydrogen with increasing elevation. These convective storms are formed over semi-arid intermontane basins in the transition between the broken foreland of the Sierras Pampeanas, the Eastern Cordillera, and the Puna Plateau in the interior of the orogen. Here, convective rainfall dominates the precipitation budget and no systematic stable isotope-elevation relationship exists. Regions to the north, in the transition between the broken foreland and the Subandean foreland fold-and-thrust belt, the impact of convection is subdued, with lower degrees of storminess and a stronger expected isotope-elevation relationship. This finding of present-day fractionation trends of meteoric water is of great importance for paleoenvironmental studies in attempts to use stable isotope relationships in the reconstruction of paleoelevations.
The third part of the thesis focuses on the paleohydrological characteristics of the Mio-Pliocene (10-2 Ma) Angastaco Basin sedimentary record, which reveals far-reaching environmental changes during Andean uplift and orographic barrier formation. A precipitation- evapotranspiration record identifies the onset of a precipitation regime related to the South American Low Level Jet at this latitude after 9 Ma. Humid foreland conditions existed until 7 Ma, followed by orographic barrier uplift to the east of the present-day Angastaco Basin. This was superseded by rapid (~0.5 Myr) aridification in an intermontane basin, highlighting the effects of eastward-directed deformation. A transition in vegetation cover from a humid C3 forest ecosystem to semi-arid C4-dominated vegetation was coeval with continued basin uplift to modern elevations.
The relationship between nutrition and the development of chronic diseases including metabolic syndrome, diabetes mellitus, cancer and cardiovascular disease has been well studied. On the other hand, changes in the GH-IGF-1 axis in association with nutrition-related diseases have been reported. The interplay between GH, total IGF-1 and different inhibitory and stimulatory kinds of IGF-1 binding proteins (IGFBPs) results in IGF-1 bioactivity, the ability of IGF-1 to induce phosphorylation of its receptor and consequently its signaling. Moreover, IGF-1 bioactivity is sufficient to reflect any change in the GH-IGF-1 system. Accumulating evidence suggests that both of high protein diet, characterized by increased glucagon secretion, and insulin-induced hypoglycemia increase mortality rate and the mechanisms are unclear. However both of glucagon and insulin-induced hypoglycemia are potent stimuli of GH secretion. The aim of the current study was to identify the impact of glucagon and insulin-induced hypoglycemia on IGF-1 bioactivity as possible mechanisms. In a double-blind placebo-controlled study, glucagon was intramuscularly administrated in 13 type 1 diabetic patients (6 males /7 females; [BMI]: 24.8 ± 0.95 kg/m2), 11 obese subjects (OP; 5/ 6; 34.4 ± 1.7 kg/m2), and 13 healthy lean participants (LP; 6/ 7; 21.7 ± 0.6 kg/m2), whereas 12 obese subjects (OP; 6/ 6; 34.4 ± 1.7 kg/m2), and 13 healthy lean participants (LP; 6/ 7; 21.7 ± 0.6 kg/m2) performed insulin tolerance test in another double-blind placebo-controlled study and changes in GH, total IGF-1, IGF binding proteins (IGFBPs) and IGF-1 bioactivity, measured by the cell-based KIRA method, were investigated. In addition, the interaction between the metabolic hormones (glucagon and insulin) and the GH-IGF-1 system on the transcriptional level was studied using mouse primary hepatocytes. In this thesis, glucagon decreased IGF-1 bioactivity in humans independently of endogenous insulin levels, most likely through modulation of IGFBP-1 and-2 levels. The glucagon-induced reduction in IGF-1 bioactivity may represent a novel mechanism underlying the impact of glucagon on GH secretion and may explain the negative effect of high protein diet related to increased cardiovascular risk and mortality rate. In addition, insulin-induced hypoglycemia was correlated with a decrease in IGF-1 bioactivity through up-regulation of IGFBP-2. These results may refer to a possible and poorly explored mechanism explaining the strong association between hypoglycemia and increased cardiovascular mortality among diabetic patients.