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One of the mechanisms for sudden particle release is a decrease in groundwater salt concentration to below the critical salt concentration (CSC), where repulsion forces between fine particles and matrix surfaces exceed binding forces. In this paper, an attempt was made to determine the CSC with both batch and column experiments. Two types of sediments were tested: (a) homogeneous quartz sand and (b) mineralogically heterogeneous sediment, taken from the Hanford formation in southeast Washington. Stepwise decreasing concentrations of NaNO3 solution were applied until fine particles were released from the sediments and the CSC was determined. Two methods were used to minimize the interference of particle release due to physical forces (shear stress) in the batch experiments: (a) postexperimental correction for mechanical effects, and (b) minimization of shear stress on the sediments during the experiment. CSCs from batch experiments were compared to those obtained from column experiments. It was found that both the amount of particles released and the CSC were an order of magnitude higher for the Hanford sediment than for the Sand. Moreover, particle detachment above the CSC was observed for the Hanford sediment. This suggests that the concept of sharp CSCs could be problematic in natural heterogeneous sediments where fine particles may mobilize at salt concentrations significantly above the CSC, thus unexpectedly enhancing colloid-facilitated transport of contaminants. (C) 2004 Elsevier B.V. All rights reserved
Veränderung der Abflüsse
(2005)
The scope of this study is to investigate the environmental change in the German part of the Elbe river basin, whereby the focus is on two water related problems: having too little water and having water of poor quality. The Elbe region is representative of humid to semi-humid landscapes in central Europe, where water availability during the summer season is the limiting factor for plant growth and crop yields, especially in the loess areas, where the annual precipitation is lower than 500 mm. It is most likely that water quantity problems will accelerate in future, because both the observed and the projected climate trend show an increase in temperature and a decrease in annual precipitation, especially in the summer. Another problem is nutrient pollution of rivers and lakes. In the early 1990s, the Elbe was one of the most heavily polluted rivers in Europe. Even though nutrient emissions from point sources have notably decreased in the basin due to reduction of industrial sources and introduction of new and improved sewage treatment facilities, the diffuse sources of pollution are still not sufficiently controlled. The investigations have been done using the eco-hydrological model SWIM (Soil and Water Integrated Model), which has been embedded in a model framework of climate and agro-economic models. A global scenario of climate and agro-economic change has been regionalized to generate transient climate forcing data and land use boundary conditions for the model. The model was used to transform the climate and land use changes into altered evapotranspiration, groundwater recharge, crop yields and river discharge, and to investigate the development of water quality in the river basin. Particular emphasis was given to assessing the significance of the impacts on the hydrology, taking into account in the analysis the inherent uncertainty of the regional climate change as well as the uncertainty in the results of the model. The average trend of the regional climate change scenario indicates a decrease in mean annual precipitation up to 2055 of about 1.5 %, but with high uncertainty (covering the range from -15.3 % to +14.8 %), and a less uncertain increase in temperature of approximately 1.4 K. The relatively small change in precipitation in conjunction with the change in temperature leads to severe impacts on groundwater recharge and river flow. Increasing temperature induces longer vegetation periods, and the seasonality of the flow regime changes towards longer low flow spells in summer. As a results the water availability will decrease on average of the scenario simulations by approximately 15 %. The increase in temperatures will improve the growth conditions for temperature limited crops like maize. The uncertainty of the climate trend is particularly high in regions where the change is the highest. The simulation results for the Nuthe subbasin of the Elbe indicate that retention processes in groundwater, wetlands and riparian zones have a high potential to reduce the nitrate concentrations of rivers and lakes in the basin, because they are located at the interface between catchment area and surface water bodies, where they are controlling the diffuse nutrient inputs. The relatively high retention of nitrate in the Nuthe basin is due to the long residence time of water in the subsurface (about 40 years), with good conditions for denitrification, and due to nitrate retention and plant uptake in wetlands and riparian zones. The concluding result of the study is that the natural environment and communities in parts of Central Europe will have considerably lower water resources under scenario conditions. The water quality will improve, but due to the long residence time of water and nutrients in the subsurface, this improvement will be slower in areas where the conditions for nutrient turn-over in the subsurface are poor.
Landschaft
(2005)
Zusammenfassung und Fazit Über die im ROG ausgewiesenen Möglichkeiten, Minderungs-, Ausgleichs- und Ersatzmaß-nahmen in die Entwicklung der anzustrebenden Freiraumstruktur einzubinden sowie mittels der entsprechenden Aussagemöglichkeiten v. a. der überörtlichen Landschaftsplanung las-sen sich für die Eingriffsregelung Verknüpfungen zur regionalen Ebene herstellen. Nicht nur die viel beklagte und durch exemplarische Auswertungen des brandenburgischen Eingriffs- und Kompensationsflächenkatasters (EKIS) z. T. auch tatsächlich nachweisbare Zersplitte-rung der Kompensationsflächen, sondern auch künftige Anforderungen zur Umsetzung eines Biotopverbunds nach $ 3 BNatSchG und der europäischen Wasserrahmenrichtlinie sowie die Sicherung des kohärenten Netzes NATURA 2000 machen die Notwendigkeit deutlich, die rechtlich angelegten Möglichkeiten einer übergreifenden, auf regionaler Ebene ansetzenden Lenkung von Kompensationsmaßnahmen stärker auszuschöpfen. Gesehen werden muss jedoch auch, dass ein solches stärker konzeptionell ("Top- down") bestimmtes Herangehen zwar fachlich wünschenswert ist, konkrete Erfahrungen aus der wissenschaftlichen Begleitung zum regionalen Flächenpool "Kulturlandschaft Mittlere Havel" jedoch darauf hindeuten, dass bei der Konzeption und Umsetzung regionaler Flächenpools zwei naturschutzfachliche Ebenen zu unterscheiden sind: Zum Einen besagte konzeptionell-strategische Planung und Vorbereitung auf der Zielebene, zum Anderen die Klärung der Ver-fügbarkeit einzelner Flächen und die konkrete, ins Detail gehende Maßnahmenplanung. Es ist wohl nur eingeschränkt realistisch, regionale Flächenpools ausschließlich über eine hie-rarchische "Top-down-Steuerung" mittels der Maßgaben von Landschaftsplanung und Raumordnung zu installieren, sondern im Gegenzug müssen im konkreten Flächenbezug die Klärung standörtlicher Flächeneignungen, der jeweiligen Flächenverfügbarkeiten, die Entwicklung örtlicher Projektgebiete sowie kooperative Verhandlungen mit den einzelnen örtli-chen Akteuren und Grundstückseigentümern erfolgen. Daraus lässt sich die Forderung ablei-ten, dass in der Diskussion um regionale Flächenpools neben der konzeptionellen Steuerung der Ebene der konkreten Maßnahmenspezifizierung und -durchführung verstärkte Aufmerk-samkeit gewidmet werden sollte, um im Zusammenwirken von "Top-Down"- und "Bottom- up"-Ansätzen zu einem effektiven Kompensationsmanagement zu gelangen.