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For the first time, a rain signature in Global Navigation Satellite System Reflectometry (GNSS-R) observations is demonstrated. Based on the argument that the forward quasi-specular scattering relies upon surface gravity waves with lengths larger than several wavelengths of the reflected signal, a commonly made conclusion is that the scatterometric GNSS-R measurements are not sensitive to the surface small-scale roughness generated by raindrops impinging on the ocean surface. On the contrary, this study presents an evidence that the bistatic radar cross section sigma(0) derived from TechDemoSat-1 data is reduced due to rain at weak winds, lower than approximate to 6 m/s. The decrease is as large as approximate to 0.7 dB at the wind speed of 3 m/s due to a precipitation of 0-2 mm/hr. The simulations based on the recently published scattering theory provide a plausible explanation for this phenomenon which potentially enables the GNSS-R technique to detect precipitation over oceans at low winds.