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Sediments of a thermokarst system on the north-eastern Tibetan Plateau were studied to infer changes in the lacustrine depositional environment related to climatic changes since the early Holocene. The thermokarst pond with a length of 360 m is situated in a 14.5 x 6 km tectonically unaffected intermontane basin, which is underlain by discontinuous permafrost.
A lake sediment core and bankside lacustrine onshore deposits were analysed. Additionally, fossil lake sediments were investigated, which document a former lake-level high stand. The sediments are mainly composed of marls with variable amounts of silt carbonate micrite, and organic matter.
On the basis of sedimentological (grain size data), geochemical (XRF), mineralogical (XRD) and micropaleontological data (ostracods and chironomide assemblages) a reconstruction of a paleolake environment was achieved.
Lacustrine sediments with endogenic carbonate precipitation suggest a lacustrine environment since at least 19.0 cal ka BP. However, because of relocation and reworking processes in the lake, the sediments did not provide distinct information about the ultimate formation of the lake. The high amount of endogenic carbonate suggests prolonged still-water conditions at about 9.3 cal ka BP. Ostracod shells and chironomid head capsules in fossil lake sediments indicate at least one former lake-level high stand, which were developed between the early and middle Holocene. From the late Holocene the area was possibly characterized by a lake-level decline, documented by a hiatus between lacustrine sediments and a reworked loess or loess-like horizon. After the lake-level decline and the following warming period, the area was affected by thermally-induced subsidence and a re-flooding of the basin because of thawing permafrost.
Ostracod shells in surface sediments from Ulungur Lake (Xinjiang, China) belong mainly to Limnocythere inopinata as the dominant species, and Candona neglecta and Darwinula stevensoni as accompanying, less abundant taxa. Shells of an additional nine species were recorded only sporadically. The three most abundant ostracods have wide tolerance ranges in terms of salinity, substrate and water depth. The similarly recorded bivalve Pisidium subtruncatum, and the gastropods Gyraulus chinensis and Radix auricularia belong to the most tolerant representatives of the genera. The bivalve and gastropods, in addition to the ostracod assemblage, reflect the fact that Ulungur Lake has experienced strong lake level and salinity variations due to water withdrawal in the catchment and the counteracting diversion of river waters to the lake in recent decades. The substrate in Ulungur Lake is typically fine-grained, apart from the delta region of the Ulungur River channel, which is marked by relatively coarse-grained detrital sediments barren of ostracod shells. This channel was created 40 years ago to divert water to Ulungur Lake and support its local fisheries and recreational facilities. A reassessed Holocene ostracod record from the lake shows that a significantly higher salinity and lower lake level existed in the early Holocene before 6.0 ka in response to the regional climate. In contrast, a higher lake level and lowest salinity is inferred for the late Holocene period between ca. 3.6 and 1.3 ka before present. Afterwards, the lake level declined and salinity increased in response to regional moisture reduction, although conditions similar to the early Holocene lake status were not re-established. Our surface-sediment-derived data provide a baseline for analysis of future environmental variations due to global climate change and regional water management.
Radiocarbon dating of lake sediments is often hampered by the presence of a lake reservoir effect (LRE, also 'dead carbon' or 'old carbon' effect) especially in dry and cold regions with a sparse plant cover in the catchment. The Tibetan Plateau became a hotspot of the palaeoenvironmental and climate research community in recent years and the assessment of present-day LREs is a crucial prerequisite for the establishment of reliable radiocarbon age depth relationships for lake sediment cores. This paper examines the spatial variability of LREs within individual lakes, through a discussion of new data for Lake Donggi Cona and a compilation of previously published data for five additional lakes where LRE data are available for different sites. Lake reservoir effects for Lake Donggi Cona on the northeastern Tibetan Plateau were determined for shells of aquatic snails collected alive close to the lake's shore. The largest determined LRE of 20,000 C-14 years is significantly larger than previously reported LREs from the central part of the lake, and larger than any previously published LRE for the Tibetan Plateau. Relatively low LREs in the central regions of lakes, higher LREs towards the margins, and high LREs in tributaries and spring waters are apparently a common pattern of Tibetan Plateau lakes. The differences in LREs within individual lakes or catchment areas are attributed to the more prolonged exchange of the lake water's dissolved inorganic carbon with the atmospheric CO2 in central lake regions on the one hand and the increasing influence of C-14 free or poor stream and groundwater due to the dissolution of carbonaceous basement rocks towards its margins. Generally higher LREs were recorded in the three tectonically active lake regions of the six examined catchments, and it is speculated that rising crustal CO2 further contributes to the LREs in these catchments. In addition to these observations and inferences, elevated C-14 levels of the atmosphere as a result of nuclear bomb testing are often ignored if LREs for modern materials are reported by convention relative to the atmospheric C-14 activity of the year 1950. LRE data reported in this way represent unrealistic minimum estimates. (C) 2013 Elsevier Ltd and INQUA.
A 352 cm long sediment core from Hersek Lagoon (Gulf of Izmit) was investigated for its ostracod species composition in order to evaluate the potential of ostracods to detect tsunami deposits in coastal environments. The Gulf of Izmit is the eastern bay of the Marmara Sea which is tectonically controlled by the North Anatolian Fault. Ostracod shells are rare in the lower third of the core, which probably represents a coastal wetland environment. According to radiocarbon dating of terrestrial plant remains, this unit was deposited between AD 500 and AD 800. Above, ostracod shells are abundant and dominantly monospecific, composed almost exclusively of the widespread brackish water ostracod Cyprideis torosa. This almost monospecific occurrence indicates the establishment and maintenance of the Hersek Lagoon after AD 800. Three distinct layers of mollusc shells and fragments contain ostracod shells of marine and to a lesser extent non-marine origin in addition to those of C. torosa. The shell layers are further characterized by significant maxima in total ostracod shell numbers. The high concentration of ostracod shells, the higher species numbers and the mixture of marine, lagoonal and non-marine ostracod shells shows that shell layers were formed as high-energy deposits resulting from tsunamis or large storms in the Marmara Sea. The partial occurrence of non-marine ostracod shells in the shell layers possibly indicates that tsunamis with extensive run-ups and significant backwash flows caused the high-energy deposits rather than large storms. The investigated sediments show that lagoonal ostracods can serve as good proxies for tsunamis or large storms through significant variations in total shell numbers, species numbers and the mixing of shells of different origin.
Sedimentological, palaeontological and mineralogical analyses of sediments from the endorheic Al Jafr Basin were conducted to better understand the depositional and hydrological conditions on the southern Jordan Plateau in the late Quaternary. Surficially exposed carbonate-rich sediments in the western part of the basin contain ostracod (micro-crustacean) shells of Ilyocypris cf. bradyi, Candona neglecta, Heterocypris salina, Fabaeformiscandona fabaeformis, Pseudocandona sp. and Herpetocypris brevicaudata. The shells of these and other more rare species, and charophyte and mollusc remains indicate that the sediments were formed in a wetland setting of shallow freshwater to slightly oligohaline ponds, streams and swamps. The present more northern distribution of some of the recorded taxa implies that climate conditions were probably cooler during the wetland formation. Radiocarbon age data for biogenic carbonate from two locations suggest that the wetland setting existed during the second half of Marine Isotope Stage (MIS) 3 or possibly earlier. A significantly higher water table must have existed in the basin during wetland formation; and wetter climate conditions are inferred for the catchment or at least for its highest and most humid westernmost part. Deflation and local sediment accumulation by wind and occasional sheet-wash events apparently prevailed in the region since MIS 2. Our newly presented data and inferences do not support the reconstruction of a previously reported large and relatively deep Pleistocene lake in the Al Jafr Basin. However, more extensive studies are certainly required for a detailed assessment of the Quaternary hydrological conditions in southern Jordan. (C) 2014 Elsevier Ltd and INQUA. All rights reserved.
The Shell Bar in the Qaidam Basin, China, is a prominent geological feature composed of millions of densely packed Corbicula shells. Since the mid 1980s, it has been regarded as evidence for existence of a large lake during Marine Isotope Stage (MIS) 3 in the presently hyper-arid Qaidam Basin. Early studies suggested the bivalve shells accumulated at the shore of a large lake, whereas more recent work led to the conclusion that the Shell Bar was formed within a deeper water body. Based on our re-assessment of sediments and fossils from the Shell Bar, investigation of exposed fluvio-lacustrine sections upstream of the Shell Bar and study of nearby modern streams, we infer that the Shell Bar represents a stream deposit. Corbicula is a typical stream-dweller around the world. Preservation of Corbicula shells of different sizes, as well as occurrence of many articulated shells, provide evidence against post-mortem transport and accumulation along a lake shore. Additionally, the SE-NW alignment of the Shell Bar is similar to modern intermittent stream beds in its vicinity and corresponds to the present-day slope towards the basin centre further NW, and furthermore, the predominantly sandy sediments also indicate that the Shell Bar was formed in a stream. Abundant ostracod shells in the Shell Bar sediments originated from stream-dwelling species that are abundant in modern streams in the vicinity of the Shell Bar, or in part from fluvio-lacustrine sediments exposed upstream of the Shell Bar, as a result of erosion and re-deposition. Deflation of alluvial fine-grained sediments in the Shell Bar region and protection of the stream deposits by the large and thick-walled Corbicula shells reversed the former channel relief and yielded the modern exposure, which is a prominent morphological feature. Occurrence of Corbicula shells in the Qaidam Basin indicates climate was apparently warmer than present during the formation of the Shell Bar because Corbicula does not live at similar or higher altitudes in the region today. Because the Shell Bar is no longer considered a deposit formed within a lake, its presence does not indicate paleoclimate conditions wetter than today.
Radiocarbon and optically stimulated luminescence dating of sediments from Lake Karakul, Tajikistan
(2017)
Lake Karakul in the eastern Pamirs is a large and closed-basin lake in a partly glaciated catchment. Two parallel sediment cores were collected from 12 m water depth. The cores were correlated using XRF analysis and dated using radiocarbon and OSL techniques. The age results of the two dating methods are generally in agreement. The correlated composite core of 12.26 m length represents continuous accumulation of sediments in the lake basin since 31 ka. The lake reservoir effect (LRE) remained relatively constant over this period. High sediment accumulation rates (SedARs) were recorded before 23 ka and after 6.5 ka. The relatively close position of the coring location near the eastern shore of the lake implies that high SedARs resulted from low lake levels. Thus, high SedARs and lower lake levels before 23 ka probably reflect cold and dry climate conditions that inhibited the arrival of moist air at high elevation in the eastern Pamirs. Low lake levels after 6.5 ka were probably caused by declining temperatures after the warmer early Holocene, which had caused a reduction in water resources stored as snow, ice and frozen ground in the catchment. Low SedARs during 23-6.5 ka suggest increased lake levels in Lake Karakul. A short-lived increase of SedARs at 15 ka probably corresponds to the rapid melting of glaciers in the Karakul catchment during the Greenland Interstadial le, shortly after glaciers in the catchment had reached their maximum extents. The sediment cores from Lake Karakul represent an important climate archive with robust chronology for the last glacial interglacial cycle from Central Asia. (C) 2017 Elsevier B.V. All rights reserved.
Ostracods from water bodies in hyperarid Israel and Jordan as habitat and water chemistry indicators
(2012)
The hyperarid region of Israel and Jordan covers a large area where numerous sites of Pleistocene lake sediments suggest that climate conditions were significantly wetter during the Pleistocene. This region experienced a significant increase in aridity in recent decades and the number of existing surface waters is diminishing rapidly. We studied ostracod shells from 49 pond and stream sites to determine the species distribution and to infer ecological preferences especially with respect to general differences in water movement, conductivity and ion composition. Twenty-two ostracod species were identified in total of which 12 taxa occur at three or more sites. Among the rarer species. Cyprinotus scholiosus was identified for the first time after two records from Plio- and Pleistocene sites in Yemen and Saudi Arabia. Further, Paracypretta amati was recorded and its ecological preferences discussed for the first time following the description of the species from its type locality in Sudan. Cypridopsis elongata is the only typical inhabitant of lotic habitats, strictly preferring freshwater conditions and waters with an alkalinity/Ca ratio around 1 and cations dominated by Ca(2+) and anions by HCO(3)(-). In contrast, Cyprideis torosa, Limnocythere inopinata and Heterocypris incongruens apparently prefer waters dominated by Na(+) associated with cations and Cl(-) associated with anions. Heterocypris salina and C. torosa occur over a wide conductivity (or salinity) range and in waters with alkalinity/Ca ratios around 1 and with significant alkalinity depletion. Humphcypris subterranea, Ilyocypris spp. and H. sauna are the only taxa which do not show any preference with respect to both the cation and anion dominance of the waters. The ecological preferences of the ostracod species from water bodies in the study area are discussed in detail and can be used for a qualitative assessment of the hydrodynamical and hydrochemical conditions of former water bodies in the presently hyperarid environment based on ostracod species composition analysis of Pleistocene aquatic sediments.
Ostracod shells from the archaeological site Gesher BenotYa'aqov (GBY) in the upper Jordan River Valley (Israel) were investigated to improve the understanding of the environmental conditions of the Acheulian occupation site during the early-mid Pleistocene transition (0.78 Ma). The diverse ostracod assemblage consists of 28 species. The distribution of most of the recorded species in the region today shows that the hydrological conditions at the early-mid Pleistocene transition were not fundamentally different from the modern ones. However, the predominance of Candona neglecta shells in the GBY sequence probably indicates cooler climatic conditions than today. Shells of Candona angulata in the artefact-richer upper half of the sequence suggest a slight salinity increase in the ancient Hula Lake from pure freshwater to slightly oligohaline conditions. This shift probably resulted from wetter conditions and a more stable lake environment with increased residence time of the lake water and stronger influence of evaporation. Shells of the brackish water ostracod Cyprideis torosa and the slightly halophilic Heterocypris sauna and Plesiocypridopsis newtoni were recorded only rarely suggesting that the lake maintained an outlet through the entire period represented by the GBY sequence. Shells of Gomphocythere ortali in GBY cycles 1 and 2 imply that a permanent freshwater stream existed close to the site. Humphcypris subterranea shells in cycles 3-5 provide further evidence that a tributary entered the lake from the south in contrast to the modern setting with the north-south flowing Jordan River at GBY. Statistical analysis of the quantitative ostracod data from GBY identified a group of samples from layers containing more abundant stone artefacts and another group of samples from layers with scarce artefacts. Samples from layers containing more abundant artefacts have relatively high abundances of C. angulata, Darwinula stevensoni and Physocypria kraepelini shells and include rare shells of Ilyocypris hartmanni, Ilyocypris salebrosa, Heterocypris incongniens and Pseudocandona sp. 2 which do not occur in the other samples. The presence of P. kraepelini and H. incongruens shells in artefact-richer sediments possibly indicates poor bottom water oxygenation in the ancient Hula lake sometimes during the periods of Acheulian occupation. However, more detailed studies are required to assess whether lower dissolved oxygen levels in the lake resulted from a slight lake level rise and possibly higher nutrient flux to the lake during wetter conditions or whether hominins already impacted lake's nutrient status by butchering at its shore or by burning of near-shore vegetation. (c) 2014 Elsevier B.V. All rights reserved.
An expanded ostracod-based conductivity transfer function for climate reconstruction in the Levant
(2014)
We present the first modern calibration dataset linking ostracod assemblage composition to water chemistry, and other site-specific variables, in the hydrologically and geopolitically sensitive southern Levant region. A total of 42 ostracod taxa were recorded from the 178 sampled sites in Israel and Jordan. Ilyocypris spp., Heterocypris salina and Cypridopsis vidua are the most abundant taxa. Species strictly confined to freshwater conditions are Prionocypris zenkeri, Gomphocythere ortali and Prionocypris olivaceus. In contrast, H. sauna, Bradleytriebella lineata and Cyprideis torosa show high frequencies in brackish waters (waters with higher conductivity). Humphcypris subterranea, G. ortali, P. olivaceus and Cypridopsis elongata apparently prefer flowing waters. Specific conductivity optima and tolerance ranges were calculated for the recorded ostracod species and may be used for the palaeoenvironmental assessment of fossil ostracod assemblages. In addition, a transfer-function for quantitative specific conductivity estimation based on 141 samples was established with weighted averaging partial least squares regression (WA-PLS). The resulting coefficient of determination r(2) between observed and predicted conductivity values (0.72) and the root-mean-square error of prediction (RMSEP) in % gradient length (13.1) indicate that conductivity may be reliably estimated from ostracod assemblage data. The transfer function was first applied to last glacial ostracod assemblage data from an archaeological trench in the Sea of Galilee (northern Israel). Relatively large conductivity fluctuations between ca 1 and 7 mS cm(-1) were inferred for the period 24-20 cal ka BP. In addition, four episodes of freshwater influx near the site of the trench were identified from the presence of shells of freshwater and stream-dwelling species intermingled with very abundant shells of Cyprideis torosa. The results of our study allow a better use of Quaternary ostracods from the Levant as palaeoenvironmental indicators of water-body types and past conductivity levels and will contribute to a better understanding of Quaternary environmental and climate change in the Levant. (C) 2014 Elsevier Ltd. All rights reserved.
During the last glacial period lake Kinneret (the Sea of Galilee) fluctuated between high and low water levels reflecting the hydrological conditions of the lake watershed. Here, we focus on the hydrology of the lake after its retreat from the last glacial MIS2 (similar to 27-25 ka BP) highest stand of similar to 170 m below mean sea level (m bsl) to the low stand of similar to 214 m bsl at similar to 24-21 ka BP. The limnological-hydrological history of this time interval is recovered from trench and borehole that were dug and drilled in the southwestern shore of the lake at Ohalo-II archeological site. Cyprideis torosa (Ostracoda) recovered from the trench yielded elemental, Sr-87/Sr-86 and delta O-18 isotope data that provide information on the shore environment during the low stand period. The Sr-87/Sr-86 and Sr/Ca ratios in the ostracods, varying between similar to 0.70789 and similar to 0.70815 and 0.0017 and 0.0030, respectively indicate contributions of waters from the last glacial lake and regional runoff. The increase in the Sr-87/Sr-86 ratios reflects the decreasing effect of the last glacial Lake Kinneret waters and enhanced contribution of local runoff that washed down dried mountain soils that were previously developed during the wet and vegetated glacial. The lake retreat at similar to 24 ka BP coincided with the Heinrich event H2 at the northern Atlantic. H2 was expressed by severe aridity in Lake Kinneret-Dead Sea watershed. The limnological-hydrological change at post H2 was accompanied by 2% decrease in the delta O-18 value from -2% to -4% reflecting the change in the composition of the east Mediterranean rain sources.
The last glacial lake Sr-87/Sr-86 ratio is similar to the Tiberias Spa saline waters and distinctly different from the modern Lake Kinneret fresh waters: Sr-87/Sr-86 similar to 0.70785 compared to similar to 0.70760, respectively. This difference is explained by enhanced contribution of Ca-chloride brines with high Sr-87/Sr-86 values to the last glacial lake and reduced Jordan River contribution due to cold freezing conditions at its headwaters, while the modern Lake Kinneret is more affected by low Sr-87/Sr-86 freshwater from the Jordan watershed.
A geological feature in the Qaidam Basin known as the "Shell Bar" contains millions of freshwater clam shells buried in situ. Since the 1980s, this feature in the now hyper-arid basin has been interpreted to be lake deposits that provide evidence for a warmer and more humid climate than present during late marine isotope stage 3 (MIS 3). Global climate during late MIS 3 and the last glacial maximum, however, was cold and dry, with much lower sea levels. We re-investigated the feature geomorphologically and sedimentologically, and employed optically stimulated luminescence (OSL) dating to verify the chronology of the sediments. We interpret the Shell Bar to be a remnant of a river channel formed by a stream that ran across an exposed lake bed during a regressive lake phase. Deflation of the surrounding older, fine-grained lacustrine deposits has left the fluvial channel sediments topographically inverted, indicating the erosive nature of the landscape. Luminescence ages place the formation of the Shell Bar in MIS 5 (similar to 113-99 ka), much older than previous radiocarbon ages of < 40 ka BP, but place the paleoclimatic inferences more in accord with other regional and global climate proxy records. We present a brief review of the age differences derived from C-14 and OSL dating of some critical sections that were thought to represent a warmer and more humid climate than present during late MIS 3. We attribute the differences to underestimation of C-14 ages. We suggest that C-14 ages older than similar to 25 ka BP may require re-investigation, especially dates on samples from arid regions.
In this paper we present the sedimentary features and the luminescence chronology for Nahal Mahanayeem Outlet (NMO), an archaeological open air site at the southern margin of the Hula Basin (Northern Jordan Rift Valley, Israel). The site is characterized by a lithic assemblage ascribed primarily to the Middle Paleolithic Mousterian tradition, and by an excellent preservation of floral and faunal remains.
Six geological units forming the stratigraphic sequence of the site were distinguished: (Unit 6) archaeologically sterile, light-colored limnic carbonates; (Unit 5) conglomerates of rounded basalt boulders and cobbles forming a hill-like topography; (Unit 4 and Unit 3) a sequence of similar dark silty sediments, attached to and overlaying the conglomerates, containing the archaeological horizons of the site; (Unit 2) a number of channels cutting into the top of Unit 3, filled with coarse sand and rounded basalt and limestone gravels of fluvial origin; and (Unit 1) a thin sand layer laid down by the present-day Jordan River covering another unconformity as a result of heavy machinery drainage operations in 1999.
The OSL age for Unit 6 yielded a minimum age older than 460 ka. Sedimentary features and the embedded fossils suggest that Unit 1 can be linked to the Early Pleistocene Gadot Chalk. Unit 5 represents a local geological feature and could be an indicator for a period of increased erosion with formation of coarse grained sediments. The archaeological horizons form the lower parts of Unit 4 and yielded OSL-ages between 55 and 65 ka, indicating an affiliation to the sediments called "Ashmura Formation" with an Upper Pleistocene age for the site. The channel fills of Unit 2 can be dated by the recovered artifacts. These range in age from the Upper Paleolithic (Aurignacian) to historic times. Unit 1 is recent.
The study of the complex NMO stratigraphy, combined with coherent OSL chronology, has enabled us to reconstruct parts of the geological history of the Hula Basin during the Late Pleistocene. It is this history that forms the background for the human migration and utilization of natural resources in the Upper Jordan Rift Valley. (C) 2013 Elsevier Ltd and INQUA. All rights reserved.
We present ostracod data from the Middle Palaeolithic open air site of Nahal Mahanayeem Outlet (NMO) at the southern edge of the Hula Basin, northern Israel.
Sediments of two Pleistocene water bodies are exposed at the site. The first one is an archaeologically sterile, light-colored limnic carbonate with an Early Pleistocene age. It contains an ostracod fauna assemblage dominated by Candona neglecta, Candonopsis kingsleii, and Pseudocandona sp., and, in minor abundances, Cypria ophtalmica, Cyprideis sp., Humphcypris sp., Fabaeformiscandona cf. fabaeformis and Ilyocypris sp. These sediments were deposited in a shallow, freshwater to oligohaline lake under stable conditions.
Sediments of the second water body are silty and dark-colored with a depositional age of 65 ka, belonging to the Late Pleistocene Ashmura Formation. The unit covers a geologically complex topography of tectonically uplifted limnic deposits and a hill-like gravel bar at the site. The most important archaeological layer is situated at its base, containing a lithic assemblage ascribed primarily to the Middle Palaeolithic Mousterian tradition and very well preserved flora and fauna. In the sediments from the archaeological layers, the brackish water ostracod Cyprideis torosa and the foraminifer Ammonia tepida could be identified. In sediments of the Ashmura Formation taken near the site, C. neglecta, Candona angulata, Ilyogpris sp., C kingsleii, Pseudocandona sp., C ophtalmica, Darwinula stevensoni, Trajancypris sp. and Potamogpris smaragdina were found, indicating a freshwater to slightly oligohaline stagnant water body. The ostracod fauna of the NMO site, together with geochemical data, allow us to reconstruct a depositional environment of the margin at a shallow lake with brackish or saline springs nearby during the site's occupation by Middle Palaeolithic humans.
Additionally, Candona weltneri, Candona cf. meerfeldiana, C kingsleii, Cyclocypris laevis, C ophtalmica, Cyprideis sp., Fabaeformiscandona cf. fabaeformis, P. smaragdina, Pseudocandona depressa, Trajancypris sp, Zonocypris cf. costata and A. tepida could be recorded for the first time for the Pleistocene limnic strata of the Hula Basin. (C) 2014 Elsevier Ltd. All rights reserved.
This paper aims to highlight the potential of using elemental and stable isotope analyses of aquatic macrophytes in palaeolimnological studies. Potamogeton pectinatus material was collected from modem plants (n=68) and from late glacial and Holocene-aged sediments from Koucha Lake (northeastern Tibetan Plateau; 34.0 degrees N; 97.2 degrees E; 4540 m a.s.l.). It was analyzed for delta C-13(Potamogeton) (modern: -23 to 0 parts per thousand, fossil: -19 to -4 parts per thousand) and delta N-15(Potamogeton) (modern: -11.0 to +13.8 parts per thousand, fossil: -9.5 to +6.7 parts per thousand) in addition to elemental carbon and nitrogen (modem C/N-Potamogeton: 7 to 29; fossil: 13 to 68) and sulfur (fossil: 188-899 mu mol/g dry weight). Fossil data were interpreted in terms of palaeo-nutrient availability and palaeo-productivity based on the modem relationships between various proxies and certain environmental data. Productivity of Potamogeton pectinatus mats at Koucha Lake as indicated by palaeo-epsilon(Potamogeton-TIC) (i.e. the enrichment of delta C-13(Potamogeton) relative to the delta(CTIC)-C-13) was reduced during periods of high conductivity, especially between 10.3 and 7.4 cal kyr BP. Potamogeton pectinatus material from these periods was also characterized by high S-Potamogeton indicating high sulfide concentrations and anoxic conditions within the sediments. However, C/N- Potamogeton ratios and delta N-15(Potamogeton) from the lower core section were found to have been altered by decompositional processes. A pronounced shift in the aquatic productivity of Lake Koucha occurred at similar to 7.4 cal kyr BP when the hydrological conditions shifted towards an open lake system and water depth increased. At this time a strong increase in productivity led to a strong decrease in the water HCO3- concentration as inferred from the application of a epsilon-(Potamogeton-TIC)-InHCO3- transfer function. A comparison of reconstructed productivity changes from Koucha Lake with further environmental proxies suggests that primary productivity changes are probably a function of internal lake dynamics and were only indirectly triggered by climate change.
The apparent isotope enrichment factor epsilon(macrophyte) of submerged plants (epsilon(macrophyte-DIC) = delta C-13(macrophyte) - delta C-13(DIC)) is indicative of dissolved inorganic carbon (DIC) supply in neutral to alkaline waters and is related to variations in aquatic productivity (Papadimitriou et al. in Limnol Oceanogr 50:1084-1095, 2005). This paper aims to evaluate the usage of epsilon(macrophyte) inferred from isotopic analyses of submerged plant fossils in addition to analyses of lake carbonate as a palaeolimnological proxy for former HCO3 (-) concentrations. Stable carbon isotopic analysis of modern Potamogeton pectinatus leaves and its host water DIC from the Tibetan Plateau and Central Yakutia (Russia) yielded values between -23.3 and +0.4aEuro degrees and between +14.0 and +6.5aEuro degrees, respectively. Values of epsilon (Potamogeton-DIC) (range -15.4 to +1.1aEuro degrees) from these lakes are significantly correlated with host water HCO3 (-) concentration (range 78-2,200 mg/l) (r = -0.86; P < 0.001), thus allowing for the development of a transfer function. Palaeo-epsilon (Potamogeton-ostracods) values from Luanhaizi Lake on the NE Tibetan Plateau, as inferred from the stable carbon isotope measurement of fossil Potamogeton pectinatus seeds (range -24 to +2.8aEuro degrees) and ostracods (range -7.8 to +7.5%) range between -14.8 and 1.6aEuro degrees. Phases of assumed disequilibrium between delta C-13(DIC) and delta C-13(ostracods) known to occur in charophyte swards (as indicated by the deposition of charophyte fossils) were excluded from the analysis of palaeo-epsilon. The application of the epsilon (Potamogeton-DIC)-HCO3 (-) transfer function yielded a median palaeo-HCO3 (-) -concentration of 290 mg/l. Variations in the dissolved organic carbon supply compare well with aquatic plant productivity changes and lake level variability as inferred from a multiproxy study of the same record including analyses of plant macrofossils, ostracods, carbonate and organic content.