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Two of the main physical parameters that govern the massive star evolution, the mass and the mass-loss rate, are still poorly determined from the observational point of view. Only binary systems could provide well constrained masses and colliding-wind binaries could bring some constraints on the mass-loss rate. Therefore, colliding-wind binaries turn out to be very promising objects. In this framework, we present detailed studies of basic observational data obtained with the XMM-Newton facility and combined with ground-based observations and other data. We expose the results for two particularly interesting WR+O colliding-wind binaries: WR22 and WR21a.