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Der Zugang zu einem Asylverfahren in der EU ist ein umkämpftes soziales Gut. Die Studie zeichnet ein komplexes Bild von Ausschließungs- und Usurpationsstrategien im Feld der europäischen und speziell der italienischen und deutschen Asylverwaltung zwischen 2015 und 2018. (Supra-)nationale Verwaltungs- und Vollzugsorganisationen versuchen Flüchtende von dem Verwaltungsakt abzuhalten und entwickeln territoriale und administrative Exklusionsstrategien, um Fluchtmobilität und Asyl zu verwehren. Gleichzeitig erkämpfen Seenotrettungs- und Kirchenorganisationen den Zugang zum Asylverfahren, indem sie sich mit Flüchtenden solidarisieren und diesen eine Partizipation an öffentlichen Gütern und Rechten der Aufnahmegesellschaft ermöglichen. Für Flüchtende wird der formale Zugang zu und die temporäre Mitgliedschaft in einer Aufnahmegesellschaft in konfliktreichen und inter-organisationalen Entscheidungen ausgehandelt. Die formale Organisation wird zum Ort der Schließungskämpfe, indemsie als Schließungsakteur und zwischengesellschaftliches Schließungssystem formale Interaktionen zwischen Geflüchteten und Aufnahmegesellschaft ermöglicht oder verhindert. Die Synthese von schließungs- und organisationstheoretischen Perspektiven trägt dazu bei, dass gesellschaftliche Ordnungsbildung organisationssoziologisch erklärbar wird.
Aims/hypothesis
Studies suggest decreased mortality risk among people who are overweight or obese compared with individuals with normal weight in type 2 diabetes (obesity paradox). However, the relationship between body weight or weight change and microvascular vs macrovascular complications of type 2 diabetes remains unresolved. We investigated the association between BMI and BMI change with long-term risk of microvascular and macrovascular complications in type 2 diabetes in a prospective cohort study.
Methods
We studied participants with incident type 2 diabetes from the European Prospective Investigation into Cancer and Nutrition (EPIC)-Potsdam cohort, who were free of cancer, cardiovascular disease and microvascular disease at diagnosis (n = 1083). Pre-diagnosis BMI and relative annual change between pre- and post-diagnosis BMI were evaluated in multivariable-adjusted Cox models.
Results
There were 85 macrovascular (myocardial infarction and stroke) and 347 microvascular events (kidney disease, neuropathy and retinopathy) over a median follow-up of 10.8 years. Median pre-diagnosis BMI was 29.9 kg/m(2) (IQR 27.4-33.2), and the median relative annual BMI change was -0.4% (IQR -2.1 to 0.9). Higher pre-diagnosis BMI was positively associated with total microvascular complications (multivariable-adjusted HR per 5 kg/m(2) [95% CI]: 1.21 [1.07, 1.36], kidney disease 1.39 [1.21, 1.60] and neuropathy 1.12 [0.96, 1.31]) but not with macrovascular complications (HR 1.05 [95% CI 0.81, 1.36]). Analyses according to BMI categories corroborated these findings. Effect modification was not evident by sex, smoking status or age groups. In analyses according to BMI change categories, BMI loss of more than 1% indicated a decreased risk of total microvascular complications (HR 0.62 [95% CI 0.47, 0.80]), kidney disease (HR 0.57 [95% CI 0.40, 0.81]) and neuropathy (HR 0.73 [95% CI 0.52, 1.03]), compared with participants with a stable BMI; no clear association was observed for macrovascular complications (HR 1.04 [95% CI 0.62, 1.74]). The associations between BMI gain compared with stable BMI and diabetes-related vascular complications were less apparent. Associations were consistent across strata of sex, age, pre-diagnosis BMI or medication but appeared to be stronger among never-smokers compared with current or former smokers.
Conclusions/interpretation
Among people with incident type 2 diabetes, pre-diagnosis BMI was positively associated with microvascular complications, while a reduced risk was observed with weight loss when compared with stable weight. The relationships with macrovascular disease were less clear.
Self-assembly of plasmonic nanoantenna-waveguide structures for subdiffractional chiral sensing
(2021)
Spin-momentum locking is a peculiar effect in the near-field of guided optical or plasmonic modes. It can be utilized to map the spinning or handedness of electromagnetic fields onto the propagation direction. This motivates a method to probe the circular dichroism of an illuminated chiral object. In this work, we demonstrate local, subdiffraction limited chiral coupling of light and propagating surface plasmon polaritons in a self-assembled system of a gold nanoantenna and a silver nanowire. A thin silica shell around the nanowire provides precise distance control and also serves as a host for fluorescent molecules, which indicate the direction of plasmon propagation. We characterize our nanoantenna-nanowire systems comprehensively through correlated electron microscopy, energy-dispersive X-ray spectroscopy, dark-field, and fluorescence imaging. Three-dimensional numerical simulations support the experimental findings. Besides our measurement of far-field polarization, we estimate sensing capabilities and derive not only a sensitivity of 1 mdeg for the ellipticity of the light field, but also find 10(3) deg cm(2)/dmol for the circular dichroism of an analyte locally introduced in the hot spot of the antenna-wire system. Thorough modeling of a prototypical design predicts on-chip sensing of chiral analytes. This introduces our system as an ultracompact sensor for chiral response far below the diffraction limit.
We present a reconstruction of the dynamics of the radiation belts from solar cycles 17 to 24 which allows us to study how radiation belt activity has varied between the different solar cycles. The radiation belt simulations are produced using the Versatile Electron Radiation Belt (VERB)-3D code. The VERB-3D code simulations incorporate radial, energy, and pitch angle diffusion to reproduce the radiation belts. Our simulations use the historical measurements of Kp (available since solar cycle 17, i.e., 1933) to model the evolution radiation belt dynamics between L* = 1-6.6. A nonlinear auto regressive network with exogenous inputs (NARX) neural network was trained off GOES 15 measurements (January 2011-March 2014) and used to supply the upper boundary condition (L* = 6.6) over the course of solar cycles 17-24 (i.e., 1933-2017). Comparison of the model with long term observations of the Van Allen Probes and CRRES demonstrates that our model, driven by the NARX boundary, can reconstruct the general evolution of the radiation belt fluxes. Solar cycle 24 (January 2008-2017) has been the least active of the considered solar cycles which resulted in unusually low electron fluxes. Our results show that solar cycle 24 should not be used as a representative solar cycle for developing long term environment models. The developed reconstruction of fluxes can be used to develop or improve empirical models of the radiation belts.
Fast Holocene slip and localized strain along the Liquiñe-Ofqui strike-slip fault system, Chile
(2021)
In active tectonic settings dominated by strike-slip kinematics, slip partitioning across subparallel faults is a common feature; therefore, assessing the degree of partitioning and strain localization is paramount for seismic hazard assessments. Here, we estimate a slip rate of 18.8 +/- 2.0 mm/year over the past 9.0 +/- 0.1 ka for a single strand of the Liquirie-Ofqui Fault System, which straddles the Main Cordillera in Southern Chile. This Holocene rate accounts for similar to 82% of the trench-parallel component of oblique plate convergence and is similar to million-year estimates integrated over the entire fault system. Our results imply that strain localizes on a single fault at millennial time scale but over longer time scales strain localization is not sustained. The fast millennial slip rate in the absence of historical Mw> 6.5 earthquakes along the Liquine-Ofqui Fault System implies either a component of aseismic slip or Mw similar to 7 earthquakes involving multi-trace ruptures and > 150-year repeat times. Our results have implications for the understanding of strike-slip fault system dynamics within volcanic arcs and seismic hazard assessments.
Militär und Moral sind scheinbar zwei sich gegenseitig ausschließende Begriffe. Kriegerische Konflikte und die Tötung von Menschen kommen uns gänzlich unmoralisch vor. Wenn überhaupt, ist die Kampfmoral (Biehl, Heiko. 2012. Einsatzmotivation und Kampfmoral. In Militärsoziologie – Eine Einführung. 2., aktualisierte und ergänzte Aufl., Hrsg. Nina Leonhard und Ines-Jacqueline Werkner, 447–474. Wiesbaden: VS Verlag für Sozialwissenschaften.) ein gängiges Konzept. Nichtsdestotrotz wird im vorliegenden Beitrag angenommen, dass das Militär moralisch handeln kann. Es wird argumentiert, dass das Militär mit widersprüchlichen moralischen und rechtlichen Erwartungshaltungen konfrontiert wird und diese Erwartungen in Entscheidungen übersetzt. Dadurch gerät das Militär jedoch stetig in moralische Entscheidungsdilemmata. Am Beispiel der Seenotrettung im Mittelmeer zwischen 2015 und 2018 soll exemplarisch gezeigt werden, dass das Militär sowohl eine Situationsmoral und moralische Routinen entwickelt als auch Vermeidungsstrategien verfolgt, die jegliche Moralerwartungen von der Organisation fernhalten. Der Beitrag arbeitet hierbei mit einem Moralbegriff philosophischer Provenienz und zeigt verschiedene analytische Dimensionen auf, die zur Analyse von Moral von Organisationen beitragen können.
Rupture directivity, implying a predominant earthquake rupture propagation direction, is typically inferred upon the identification of 2D azimuthal patterns of seismic observations for weak to large earthquakes using surface-monitoring networks. However, the recent increase of 3D monitoring networks deployed in the shallow subsurface and underground laboratories toward the monitoring of microseismicity allows to extend the directivity analysis to 3D modeling, beyond the usual range of magnitudes. The high-quality full waveforms recorded for the largest, decimeter-scale acoustic emission (AE) events during a meter-scale hydraulic fracturing experiment in granites at similar to 410 m depth allow us to resolve the apparent durations observed at each AE sensor to analyze 3D-directivity effects. Unilateral and (asymmetric) bilateral ruptures are then characterized by the introduction of a parameter kappa, representing the angle between the directivity vector and the station vector. While the cloud of AE activity indicates the planes of the hydrofractures, the resolved directivity vectors show off-plane orientations, indicating that rupture planes of microfractures on a scale of centimeters have different geometries. Our results reveal a general alignment of the rupture directivity with the orientation of the minimum horizontal stress, implying that not only the slip direction but also the fracture growth produced by the fluid injections is controlled by the local stress conditions.
In vitro thrombogenicity test systems require co-cultivation of endothelial cells and platelets under blood flow-like conditions. Here, a commercially available perfusion system is explored using plasma-treated cyclic olefin copolymer (COC) as a substrate for the endothelial cell layer. COC was characterized prior to endothelialization and co-cultivation with platelets under static or flow conditions. COC exhibits a low roughness and a moderate hydrophilicity. Flow promoted endothelial cell growth and prevented platelet adherence. These findings show the suitability of COC as substrate and the importance of blood flow-like conditions for the assessment of the thrombogenic risk of drugs or cardiovascular implant materials.
After initial detection of target archival DNA of a 116-year-old syntype specimen of the smooth lantern shark, Etmopterus pusillus, in a single-stranded DNA library, we shotgun-sequenced additional 9 million reads from this same DNA library. Sequencing reads were used for extracting mitochondrial sequence information for analyses of mitochondrial DNA characteristics and reconstruction of the mitochondrial genome. The archival DNA is highly fragmented. A total of 4599 mitochondrial reads were available for the genome reconstruction using an iterative mapping approach. The resulting genome sequence has 12 times coverage and a length of 16 741 bp. All 37 vertebrate mitochondrial loci plus the control region were identified and annotated. The mitochondrial NADH2 gene was subsequently used to place the syntype haplotype in a network comprising multiple E. pusillus samples from various distant localities as well as sequences from a morphological similar species, the shortfin smooth lantern shark Etmopterus joungi. Results confirm the almost global distribution of E. pusillus and suggest E. joungi to be a junior synonym of E. pusillus. As mitochondrial DNA often represents the only available reference information in non-model organisms, this study illustrates the importance of mitochondrial DNA from an aged, wet collection type specimen for taxonomy.
This paper presents two new pollen records and quantitative climate reconstructions from northern Chukotka documenting environmental changes over the last 27.9 ka. Open tundra- and steppe-like habitats dominated between 27.9 and 18.7 cal. ka BP. Betula and Alnus shrubs might have grown in sheltered microhabitats but disappeared after 18.7 cal. ka BP. Although the climate was rather harsh, local herb-dominated communities supported herbivores as is evident by the presence of coprophilous spores in the sediments. The increase in Salix and Cyperaceae similar to 16.1 cal. ka BP suggests climate amelioration. Shrub Betula appeared similar to 15.9 cal. ka BP, and became dominant after similar to 15.52 cal. ka BP, whilst typical steppe communities drastically reduced. Very high presence of Botryococcus in the Lateglacial sediments reflects widespread shallow habitats, probably due to lake level increase. Shrub Alnus became common after similar to 13 cal. ka BP reflecting further climate amelioration. Simultaneously, herb communities gradually decreased in the vegetation reaching a minimum similar to 11.8 cal. ka BP. A gradual decrease of algae remains suggests a reduction of shallow-water habitats. Shrubby and graminoid tundra was dominant similar to 11.8-11.1 cal. ka BP, later Salix stands significantly decreased. The forest-tundra ecotone established in the Early Holocene, shortly after 11.1 cal. ka BP. Low contents of green algae in the Early Holocene sediments likely reflect deeper aquatic conditions. The most favourable climate conditions were between similar to 10.6 and 7 cal. ka BP. Vegetation became similar to the modern after similar to 7 cal. ka BP but Pinus pumila came to the Ilirney area at about 1.2 cal. ka BP. It is important to emphasize that the study area provided refugia for Betula and Alnus during MIS 2. It is also notable that our records do not reflect evidence of Younger Dryas cooling, which is inconsistent with some regional environmental records but in good accordance with some others.
Perovskite/silicon tandem photovoltaics (PVs) promise to accelerate the decarbonization of our energy systems. Here, we present a thorough subcell diagnosis methodology to reveal deep insights into the practical efficiency limitations of state-of-the-art perovskite/silicon tandem PVs. Our subcell selective intensity-dependent photoluminescence (PL) and injection-dependent electroluminescence (EL) measurements allow independent assessment of pseudo-V-OC and power conversion efficiencies (PCEs) for both subcells. We reveal identical metrics from PL and EL, which implies well-aligned energy levels throughout the entire cell. Relatively large ideality factors and insufficient charge extraction, however, cause each a fill factor penalty of about 6% (absolute). Using partial device stacks, we then identify significant losses in standard perovskite subcells due to bulk and interfacial recombination. Lastly, we present strategies to minimize these losses using triple halide (CsFAPb(IBrCI)(3)) based perovskites. Our results give helpful feedback for device development and lay the foundation toward advanced perovskite/silicon tandem PVs capable of exceeding 33% PCE.
Der Artikel analysiert aus organisationssoziologischer Perspektive wie die Bundeswehr Gleichstellungsrecht umsetzt. Das zentrale Argument lautet, dass die Bundeswehr das Gleichstellungsrecht managerialisiert, indem sie institutionalisierte Praktiken adaptiert, die es erlauben, das Gleichstellungsrecht für den Zweck der Personalgewinnung auszudeuten. Die Adaption dieser Praktiken wird maßgeblich dadurch begünstigt, dass sich das Gleichstellungsrecht als Lösung mit dem Problem der zukünftigen Personalgewinnung verknüpfen lässt, nachdem die Bundesregierung die Wehrpflicht aussetzte und beschloss, die Bundeswehr wieder zu vergrößern. Der beschriebene Prozess führt auch dazu, dass die Bundeswehr in der Umsetzung des Gleichstellungsrechtes zunehmend großen Unternehmen ähnlicher wird. Insgesamt leistet die vorliegende Studie einen Beitrag zur Analyse der Beziehung staatlicher Organisationen zu ihrer rechtlichen Umwelt.
The H alpha spectral line is a well-studied absorption line revealing properties of the highly structured and dynamic solar chromosphere. Typical features with distinct spectral signatures in H alpha include filaments and prominences, bright active-region plages, superpenumbrae around sunspots, surges, flares, Ellerman bombs, filigree, and mottles and rosettes, among others. This study is based on high-spectral resolution H alpha spectra obtained with the Echelle spectrograph of the Vacuum Tower Telescope (VTT) located at Observatorio del Teide, Tenerife, Spain. The t-distributed stochastic neighbor embedding (t-SNE) is a machine-learning algorithm, which is used for nonlinear dimensionality reduction. In this application, it projects H alpha spectra onto a two-dimensional map, where it becomes possible to classify the spectra according to results of cloud model (CM) inversions. The CM parameters optical depth, Doppler width, line-of-sight velocity, and source function describe properties of the cloud material. Initial results of t-SNE indicate its strong discriminatory power to separate quiet-Sun and plage profiles from those that are suitable for CM inversions. In addition, a detailed study of various t-SNE parameters is conducted, the impact of seeing conditions on the classification is assessed, results for various types of input data are compared, and the identified clusters are linked to chromospheric features. Although t-SNE proves to be efficient in clustering high-dimensional data, human inference is required at each step to interpret the results. This exploratory study provides a framework and ideas on how to tailor a classification scheme toward specific spectral data and science questions.
Das Buch analysiert die sicherheitsbehördlichen Ermittlungen zu der rechten Terrorgruppe „Nationalsozialistischer Untergrund“ aus einer Routine- und Lernperspektive. Im Fokus stehen die Ermittlungen der thüringischen Sicherheitsbehörden ab 1998 sowie die bundesweiten polizeilichen Ermittlungen ab 2000. Die Analyse zeigt, dass es jeweils organisationale Faktoren waren, die den Misserfolg der Ermittlungen begünstigten: die sicherheitsbehördlichen Ermittlungsroutinen wurden durch Aufmerksamkeitsverschiebungen unsystematisch, durch mikropolitische Konflikte beeinträchtigt und durch vergangene Erfahrungen limitiert, die zu enge Prämissen für gegenwärtige Ermittlungen setzten. Insgesamt verdeutlicht die Studie, dass eine organisationssoziologische Perspektive auf die Ermittlungen einen entscheidenden Beitrag zum Verständnis des NSU-Komplexes bietet.
- der Ermittlungsfall NSU erstmal organisationssoziologisch analysisiert
- Untersuchung von Führungsfragen und Polizeikultur
- theoretischer innovativer Ansatz in der Polizeiforschung
Despite advanced seismological techniques, automatic source characterization for microseismic earthquakes remains difficult and challenging since current inversion and modelling of high-frequency signals are complex and time consuming. For real-time applications such as induced seismicity monitoring, the application of standard methods is often not fast enough for true complete real-time information on seismic sources. In this paper, we present an alternative approach based on recent advances in deep learning for rapid source-parameter estimation of microseismic earthquakes. The seismic inversion is represented in compact form by two convolutional neural networks, with individual feature extraction, and a fully connected neural network, for feature aggregation, to simultaneously obtain full moment tensor and spatial location of microseismic sources. Specifically, a multibranch neural network algorithm is trained to encapsulate the information about the relationship between seismic waveforms and underlying point-source mechanisms and locations. The learning-based model allows rapid inversion (within a fraction of second) once input data are available. A key advantage of the algorithm is that it can be trained using synthetic seismic data only, so it is directly applicable to scenarios where there are insufficient real data for training. Moreover, we find that the method is robust with respect to perturbations such as observational noise and data incompleteness (missing stations). We apply the new approach on synthesized and example recorded small magnitude (M <= 1.6) earthquakes at the Hellisheioi geothermal field in the Hengill area, Iceland. For the examined events, the model achieves excellent performance and shows very good agreement with the inverted solutions determined through standard methodology. In this study, we seek to demonstrate that this approach is viable for microseismicity real-time estimation of source parameters and can be integrated into advanced decision-support tools for controlling induced seismicity.
In this study, we reassessed the taxonomic position of Typhlomys (Rodentia: Platacanthomyidae) from Huangshan, Anhui, China, based on morphological and molecular evidence. Results suggested that Typhlomys is comprised of up to six species, including four currently recognized species ( Typhlomys cinereus, T. chapensis, T. daloushanensis, and T. nanus), one unconfirmed candidate species, and one new species ( Typhlomys huangshanensis sp. nov.). Morphological analyses further supported the designation of the Huangshan specimens found at mid-elevations in the southern Huangshan Mountains (600 m to 1 200 m a.s.l.) as a new species.
The determination of residual stresses becomes more complicated with increasing complexity of the structures investigated. Additive manufacturing techniques generally allow the production of 'lattice structures' without any additional manufacturing step. These lattice structures consist of thin struts and are thus susceptible to internal stress-induced distortion and even cracks. In most cases, internal stresses remain locked in the structures as residual stress. The determination of the residual stress in lattice structures through nondestructive neutron diffraction is described in this work. It is shown how two difficulties can be overcome: (a) the correct alignment of the lattice structures within the neutron beam and (b) the correct determination of the residual stress field in a representative part of the structure. The magnitude and the direction of residual stress are discussed. The residual stress in the strut was found to be uniaxial and to follow the orientation of the strut, while the residual stress in the knots was more hydrostatic. Additionally, it is shown that strain measurements in at least seven independent directions are necessary for the estimation of the principal stress directions. The measurement directions should be chosen according to the sample geometry and an informed choice on the possible strain field. If the most prominent direction is not measured, the error in the calculated stress magnitude increases considerably.
We investigate the effects of Markovian resetting events on continuous time random walks where the waiting times and the jump lengths are random variables distributed according to power-law probability density functions.
We prove the existence of a nonequilibrium stationary state and finite mean first arrival time.
However, the existence of an optimum reset rate is conditioned to a specific relationship between the exponents of both power-law tails.
We also investigate the search efficiency by finding the optimal random walk which minimizes the mean first arrival time in terms of the reset rate, the distance of the initial position to the target, and the characteristic transport exponents.
Many adults older than 60 yr experience mobility limitations. Although physical exercise improves older adults' mobility, differences in baseline mobility produce large variations in individual responses to interventions, and these responses could further vary by the type and dose of exercise. Here, we propose an exercise prescription model for older adults based on their current mobility status.
Structure, mechanical properties and degradation behavior of electrospun PEEU fiber meshes and films
(2021)
The capability of a degradable implant to provide mechanical support depends on its degradation behavior. Hydrolytic degradation was studied for a polyesteretherurethane (PEEU70), which consists of poly(p-dioxanone) (PPDO) and poly(epsilon-caprolactone) (PCL) segments with a weight ratio of 70:30 linked by diurethane junction units. PEEU70 samples prepared in the form of meshes with average fiber diameters of 1.5 mu m (mesh1.5) and 1.2 mu m (mesh1.2), and films were sterilized and incubated in PBS at 37 degrees C with 5 vol% CO2 supply for 1 to 6 weeks. Degradation features, such as cracks or wrinkles, became apparent from week 4 for all samples. Mass loss was found to be 11 wt%, 6 wt%, and 4 wt% for mesh1.2, mesh1.5, and films at week 6. The elongation at break decreased to under 20% in two weeks for mesh1.2. In case of the other two samples, this level of degradation was achieved after 4 weeks. The weight average molecular weight of both PEEU70 mesh and film samples decreased to below 30 kg/mol when elongation at break dropped below 20%. The time period of sustained mechanical stability of PEEU70-based meshes depends on the fiber diameter and molecular weight.
Data driven high resolution modeling and spatial analyses of the COVID-19 pandemic in Germany
(2021)
The SARS-CoV-2 virus has spread around the world with over 100 million infections to date, and currently many countries are fighting the second wave of infections. With neither sufficient vaccination capacity nor effective medication, non-pharmaceutical interventions (NPIs) remain the measure of choice.
However, NPIs place a great burden on society, the mental health of individuals, and economics. Therefore the cost/benefit ratio must be carefully balanced and a target-oriented small-scale implementation of these NPIs could help achieve this balance.
To this end, we introduce a modified SEIRD-class compartment model and parametrize it locally for all 412 districts of Germany. The NPIs are modeled at district level by time varying contact rates. This high spatial resolution makes it possible to apply geostatistical methods to analyse the spatial patterns of the pandemic in Germany and to compare the results of different spatial resolutions.
We find that the modified SEIRD model can successfully be fitted to the COVID-19 cases in German districts, states, and also nationwide. We propose the correlation length as a further measure, besides the weekly incidence rates, to describe the current situation of the epidemic.
Woody plants are expanding into the Arctic in response to the warming climate. The impact on arctic plant communities is not well understood due to the limited knowledge about plant assembly rules.
Records of past plant diversity over long time series are rare. Here, we applied sedimentary ancient DNA metabarcoding targeting the P6 loop of the chloroplast trnL gene to a sediment record from Lake Ilirney (central Chukotka, Far Eastern Russia) covering the last 28 thousand years.
Our results show that forb-rich steppe-tundra and dwarf-shrub tundra dominated during the cold climate before 14 ka, while deciduous erect-shrub tundra was abundant during the warm period since 14 ka. Larix invasion during the late Holocene substantially lagged behind the likely warmest period between 10 and 6 ka, where the vegetation biomass could be highest.
We reveal highest richness during 28-23 ka and a second richness peak during 13-9 ka, with both periods being accompanied by low relative abundance of shrubs. During the cold period before 14 ka, rich plant assemblages were phylogenetically clustered, suggesting low genetic divergence in the assemblages despite the great number of species. This probably originates from environmental filtering along with niche differentiation due to limited resources under harsh environmental conditions. In contrast, during the warmer period after 14 ka, rich plant assemblages were phylogenetically overdispersed.
This results from a high number of species which were found to harbor high genetic divergence, likely originating from an erratic recruitment process in the course of warming. Some of our evidence may be of relevance for inferring future arctic plant assembly rules and diversity changes. By analogy to the past, we expect a lagged response of tree invasion. Plant richness might overshoot in the short term; in the long-term, however, the ongoing expansion of deciduous shrubs will eventually result in a phylogenetically more diverse community.
Context
Thermonuclear supernovae (SNe), a subset of which are the highly important SNe Type Ia, remain one of the more poorly understood phenomena known to modern astrophysics.
In recent years, the single degenerate helium (He) donor channel, where a white dwarf star accretes He-rich matter from a hydrogen-depleted companion, has emerged as a promising candidate progenitor scenario for these events.
An unresolved question in this scenario is the fate of the companion star, which would be evident as a runaway hot subdwarf O/B stars (He sdO/B) in the aftermath of the SN event.
Aims
Previous studies have shown that the kinematic properties of an ejected companion provide an opportunity to closer examine the properties of an SN progenitor system. However, with the number of observed objects not matching predictions by theory, the viability of this mechanism is called into question.
In this study, we first synthesize a population of companion stars ejected by the aforementioned mechanism, taking into account predicted ejection velocities, the inferred population density in the Galactic mass distribution, and subsequent kinematics in the Galactic potential. We then discuss the astrometric properties of this population.
Methods
We present 10(6) individual ejection trajectories, which were numerically computed with a newly developed, lightweight simulation framework. Initial conditions were randomly generated, but weighted according to the Galactic mass density and ejection velocity data. We then discuss the bulk properties (Galactic distribution and observational parameters) of our sample.
Results
Our synthetic population reflects the Galactic mass distribution.
A peak in the density distribution for close objects is expected in the direction of the Galactic centre. Higher mass runaways should outnumber lower mass ones. If the entire considered mass range is realised, the radial velocity distribution should show a peak at 500 km s(-1).
If only close US 708 analogues are considered, there should be a peak at (similar to 750-850) km s(-1). In either case, US 708 should be a member of the high-velocity tail of the distribution.
Conclusions
We show that the puzzling lack of confirmed surviving companion stars of thermonuclear SNe, though possibly an observation-related selection effect, may indicate a selection against high mass donors in the SD He donor channel.
Human induced pluripotent stem cells (hiPSCs) are a promising cell source to generate the patient-specific lung organoid given their superior differentiation potential. However, the current 3D cell culture approach is tedious and time-consuming with a low success rate and high batch-to-batch variability.
Here, we explored the establishment of lung bud organoids by systematically adjusting the initial confluence levels and homogeneity of cell distribution.
The efficiency of single cell seeding and clump seeding was compared. Instead of the traditional 3D culture, we established a 2.5D organoid culture to enable the direct monitoring of the internal structure via microscopy.
It was found that the cell confluence and distribution prior to induction were two key parameters, which strongly affected hiPSC differentiation trajectories. Lung bud organoids with positive expression of NKX 2.1, in a single-cell seeding group with homogeneously distributed hiPSCs at 70% confluence (SC 70% hom) or a clump seeding group with heterogeneously distributed cells at 90% confluence (CL 90% het), can be observed as early as 9 days post induction.
These results suggest that a successful lung bud organoid formation with single-cell seeding of hiPSCs requires a moderate confluence and homogeneous distribution of cells, while high confluence would be a prominent factor to promote the lung organoid formation when seeding hiPSCs as clumps. 2.5D organoids generated with defined culture conditions could become a simple, efficient, and valuable tool facilitating drug screening, disease modeling and personalized medicine.
Semi-distributed hydrological and water quality models are increasingly used as innovative and scientific-based management tools.
However, their application is usually restricted to the gauging stations where they are originally calibrated, limiting their spatial capability.
In this study, the semi-distributed hydrological water quality model HYPE (HYdrological Predictions for the Environment) was tested spatially to represent nitrate-N (NO3- N) and total phosphorus (TP) concentrations and loads of the nested and heterogeneous Selke catchment (463 km(2)) in central Germany.
First, an automatic calibration procedure and uncertainty analysis were conducted using the DiffeRential Evolution Adaptive Metropolis (DREAM) tool to simulate discharge, NO3--N and TP concentrations. A multi-site and multi-objective calibration approach was applied using three main gauging stations, covering the most important hydro-meteorological and physiographical characteristics of the whole catchment. Second, the model's capability was tested to represent further internal stations, which were not initially considered for calibration. Results showed that discharge was well represented by the model at all three main stations during both calibration (1994-1998) and validation (1999-2014) periods with lowest Nash-Sutcliffe Efficiency (NSE) of 0.71 and maximum Percentage BIAS (PBIAS) of 18.0%.
The model was able to reproduce the seasonal dynamics of NO3--N and TP concentrations with low predictive uncertainty at the three main stations, reflected by PBIAS values in the ranges from 16.1% to 6.4% and from 20.0% to 11.5% for NO3--N and TP load simulations, respectively.
At internal stations, the model could represent reasonably well the seasonal variation of nutrient concentrations with PBIAS values in the ranges from 9.0% to 14.2% for NO3--N and from 25.3% to 34.3% for TP concentration simulations.
Overall, results suggested that the spatial validation of a nutrient transport model can be better ensured when a multi-site and multi-objective calibration approach using archetypical gauging stations is implemented.
Further, results revealed that the delineation of sub-catchments should put more focus on hydro-meteorological conditions than on land-use features.
Previous research has found that comprehenders sometimes predict information that is grammatically unlicensed by sentence constraints. An open question is why such grammatically unlicensed predictions occur. We examined the possibility that unlicensed predictions arise in situations of information conflict, for instance when comprehenders try to predict upcoming words while simultaneously building dependencies with previously encountered elements in memory.
German possessive pronouns are a good testing ground for this hypothesis because they encode two grammatically distinct agreement dependencies: a retrospective one between the possessive and its previously mentioned referent, and a prospective one between the possessive and its following nominal head. In two visual world eye-tracking experiments, we estimated the onset of predictive effects in participants' fixations.
The results showed that the retrospective dependency affected resolution of the prospective dependency by shifting the onset of predictive effects.
We attribute this effect to an interaction between predictive and memory retrieval processes.
Three mitochondrial genomes of early-winged insects (Ephemeroptera: Baetidae and Leptophlebiidae)
(2021)
Mayflies (Ephemeroptera) are a semi-aquatic insect order with comparatively few genomic data available despite their phylogenetic position at the root of the winged-insects and possession of ancestral traits.
Here, we provide three mitochondrial genomes (mtgenomes) from representatives of the two most species-rich families, Baetis rutilocylindratus and Cloeon dipterum (Baetidae), and Habrophlebiodes zijinensis (Leptophlebiidae).
All mtgenomes had a complete set of 13 protein-coding genes and a conserved orientation except for two inverted tRNAs in H. zijinensis.
Phylogenetic reconstructions using 21 mayfly mtgenomes and representatives of seven additional orders recovered both Baetidae and Leptophlebiidae as well supported monophyletic clades, with Ephemeroptera as the sister-taxon to all other winged insects (i.e. Odonata and Neoptera).
Studies conducted in Bangladesh so far did not unequivocally identify the modus operandi of local farmers to perceive and experience the climate variability at a national scale. Hence, this study aims to decipher local farmer's perception on climate variability for the last 10 years, by constructing climate variability index (CVI). Additionally, this study demystified the socio-economic determinants for influencing farmer perception regarding climate variability as well as its impact on their livelihoods. The study was designed on a cross-sectional data through a country-wide primary survey of 16,053 households who were largely dependent on agriculture. A weighted index was constructed for mapping the regional climate variability using model-builder programming in ArcGIS. Also, a multivariable probit model was employed to identify the factors influencing farmers' perception and resulting impact of climate variability on their livelihoods. According to local farmer's perception, the CVI mapping identified that Bangladesh experienced variegated climatic variability since last 10 years. However, local farmer's perception varied with different socio-economic factors like gender, education, farmer's category, credit, monthly income and access to media. Moreover, landless, small and medium farm holders were more aware of the local climate variability and eventually, they also experienced the higher influence of climate variability on their livelihoods. Since an effective mapping of regional climate variability is a sine qua non to devise region specific policies, this study will facilitate the government to determine its priorities, formulate efficacious strategies and thereby help to adapt with future climate-induced risks and vulnerabilities.
Growth differentiation factor 15 (GDF15) is a cytokine best known for affecting systemic energy metabolism through its anorectic action. GDF15 expression and secretion from various organs and tissues is induced in different physiological and pathophysiological states, often linked to mitochondrial stress, leading to highly variable circulating GDF15 levels.
In skeletal muscle and the heart, the basal expression of GDF15 is very low compared to other organs, but GDF15 expression and secretion can be induced in various stress conditions, such as intense exercise and acute myocardial infarction, respectively. GDF15 is thus considered as a myokine and cardiokine. GFRAL, the exclusive receptor for GDF15, is expressed in hindbrain neurons and activation of the GDF15-GFRAL pathway is linked to an increased sympathetic outflow and possibly an activation of the hypothalamic-pituitary-adrenal (HPA) stress axis.
There is also evidence for peripheral, direct effects of GDF15 on adipose tissue lipolysis and possible autocrine cardiac effects. Metabolic and behavioral outcomes of GDF15 signaling can be beneficial or detrimental, likely depending on the magnitude and duration of the GDF15 signal.
This is especially apparent for GDF15 production in muscle, which can be induced both by exercise and by muscle disease states such as sarcopenia and mitochondrial myopathy.
Informatische Bildung spielt eine immer zentralere Rolle in der Bildung einer Gesellschaft des 21. Jahrhunderts. Für den Chemieunterricht ergeben sich daraus zwei Aspekte: Einerseits können Konzepte der informatischen Bildung dabei helfen, chemie- und naturwissenschaftsspezifische Denk- und Arbeitsweisen zu fördern. Andererseits kann der Chemieunterricht einen Beitrag für die informatische Bildung leisten. Dieser Artikel geht auf beide Aspekte ein und versucht die gegenseitigen Vorteile der informatischen Bildung und der naturwissenschaftlichen Bildung im Chemieunterricht darzustellen.
Background
Static stretching (SS) can impair performance and increase range of motion of a non-exercised or non-stretched muscle, respectively. An underdeveloped research area is the effect of unilateral stretching on non-local force output.
Objective
The objective of this review was to describe the effects of unilateral SS on contralateral, non-stretched, muscle force and identify gaps in the literature.
Methods
A systematic literature search following preferred reporting items for systematic review and meta-analyses Protocols guidelines was performed according to prescribed inclusion and exclusion criteria. Weighted means and ranges highlighted the non-local force output response to unilateral stretching. The physiotherapy evidence database scale was used to assess study risk of bias and methodological quality.
Results
Unilateral stretching protocols from six studies involved 6.3 +/- 2 repetitions of 36.3 +/- 7.4 s with 19.3 +/- 5.7 s recovery between stretches. The mean stretch-induced force deficits exhibited small magnitude effect sizes for both the stretched (-6.7 +/- 7.1%, d = -0.35: 0.01 to -1.8) and contralateral, non-stretched, muscles (-4.0 +/- 4.9%, d = , 0.22: 0.08 to 1.1). Control measures exhibited trivial deficits.
Conclusion
The limited literature examining non-local effects of prolonged SS revealed that both the stretched and contralateral, non-stretched, limbs of young adults demonstrate small magnitude force deficits. However, the frequency of studies with these effects were similar with three measures demonstrating deficits, and four measures showing trivial changes. These results highlight the possible global (non-local) effects of prolonged SS. Further research should investigate effects of lower intensity stretching, upper versus lower body stretching, different age groups, incorporate full warm-ups, and identify predominant mechanisms among others.
Background:
Office workers near retirement tend to be sedentary and can be prone to mobility limitations and diseases. We examined the dose effects of exergaming volume and duration of detraining on motor and cognitive function in office workers at late midlife to reduce sedentariness and mobility limitations.
Methods:
In an assessor-blinded randomized trial, 160 workers aged 55-65 years performed physically active video games in a nonimmersive form of virtual reality (exergaming) in small, supervised groups for 1 h, 1x, 2x, or 3x/week for 8 weeks followed by detraining for 8 and 16 weeks. Exergaming comprises high-intensity, full-body sensorimotor coordination, balance, endurance, and strengthening exercises. The primary outcome was the 6-minute walk test (6MWT), and secondary outcomes were body mass, self-reported physical activity, sleep quality, Berg Balance Scale, Short Physical Performance Battery, fast gait speed, dynamic balance, heart rate recovery after step test, and 6 cognitive tests.
Results:
The 3 groups were not different in any of the outcomes at baseline (all p > 0.05). The outcomes were stable and had acceptable reliability (intraclass correlation coefficients >= 0.334) over an 8-week control period. Training produced an inverted U-shaped dose response of no (1x), most (2x), and medium (3x/week) effects of exergaming volume in most motor and selected cognitive outcomes. The distance walked in the 6MWT (primary outcome) increased most (94 m, 19%, p < 0.05), medium (57 m, 12%, p < 0.05), and least (4 m, 1%) after exergaming 2x, 3x, or 0x (control) (all different p < 0.05). The highest responders tended to retain the exercise effects over 8 weeks of detraining, independent of training volume. This maintenance effect was less consistent after 16 weeks of detraining.
Conclusion:
Less was more during training and lasted longer after detraining. A medium dose volume of exergaming produced the largest clinically meaningful improvements in mobility and selected cognitive tests in 60-year-old office workers with mild mobility limitations and intact cognition.
Seeing beyond the outcrop
(2021)
Paleokarst breccias are a common feature of sedimentary rift basins. The Billefjorden Trough in the High Arctic archipelago of Svalbard is an example of such a rift. Here the Carboniferous stratigraphy exhibits intervals of paleokarst breccias formed by gypsum dissolution. In this study we integrate digital outcrop models (DOMs) with a 2D ground penetrating radar (GPR) survey to extrapolate external irregular paleokarst geometries beyond the 2D outcrops. DOMs are obtained through combining a series of overlapping photographs with structure-frommotion photogrammetry, to create mmto dm-resolution georeferenced DOMs. GPR is typically used for surveying the shallow subsurface and relies on detecting the contrasts in electro-magnetic permittivity. We defined three geophysical facies based on their appearance in GPR. By integrating subsurface geophysical data with DOMs we were able to correlate reflection patterns in GPR with outcrop features. The chaotic nature of paleokarst breccias is seen both in outcrop and GPR. Key horizons in outcrop and the GPR profiles allow tying together observations between these methods. Furthermore, we show that this technique expands the twodimensional outcrop surface into a three-dimensional domain, thus complementing, strengthening and extending outcrop interpretations.
In this work we consider the first encounter problems between a fixed and/or mobile target A and a moving trap B on Bethe lattices and Cayley trees. The survival probabilities (SPs) of the target A on the both kinds of structures are considered analytically and compared. On Bethe lattices, the results show that the fixed target will still prolong its survival time, whereas, on Cayley trees, there are some initial positions where the target should move to prolong its survival time. The mean first encounter time (MFET) for mobile target A is evaluated numerically and compared with the mean first passage time (MFPT) for the fixed target A. Different initial settings are addressed and clear boundaries are obtained. These findings are helpful for optimizing the strategy to prolong the survival time of the target or to speed up the search process on Cayley trees, in relation to the target's movement and the initial position configuration of the two walkers. We also present a new method, which uses a small amount of memory, for simulating random walks on Cayley trees. (C) 2020 Elsevier B.V. All rights reserved.
This cross-country comparison of administrative responses to the COVID-19 pandemic in France, Germany and Sweden is aimed at exploring how institutional contexts and administrative cultures have shaped strategies of problem-solving and governance modes during the pandemic, and to what extent the crisis has been used for opportunity management. The article shows that in France, the central government reacted determinedly and hierarchically, with tough containment measures. By contrast, the response in Germany was characterized by an initial bottom-up approach that gave way to remarkable federal unity in the further course of the crisis, followed again by a return to regional variance and local discretion. In Sweden, there was a continuation of 'normal governance' and a strategy of relying on voluntary compliance largely based on recommendations and less - as in Germany and France - on a strategy of imposing legally binding regulations. The comparative analysis also reveals that relevant stakeholders in all three countries have used the crisis as an opportunity for changes in the institutional settings and administrative procedures.
Points for practitioners
COVID-19 has shown that national political and administrative standard operating procedures in preparation for crises are, at best, partially helpful. Notwithstanding the fact that dealing with the unpredictable is a necessary part of crisis management, a need to further improve the institutional preparedness for pandemic crises in all three countries examined here has also become clear. This should be done particularly by way of shifting resources to the health and care sectors, strengthening the decentralized management of health emergencies, stocking and/or self-producing protection material, assessing the effects of crisis measures, and opening the scientific discourse to broader arenas of experts.
Seismic scattering and absorption of oceanic lithospheric S waves in the Eastern North Atlantic
(2021)
The scattering and absorption of high-frequency seismic waves in the oceanic lithosphere is to date only poorly constrained by observations. Such estimates would not only improve our understanding of the propagation of seismic waves, but also unravel the small-scale nature of the lithosphere and its variability. Our study benefits from two exceptional situations: (1) we deployed over 10 months a mid-aperture seismological array in the central part of the Eastern North Atlantic in 5 km water depth and (2) we could observe in total 340 high-frequency (up to 30 Hz) Po and So arrivals with tens to hundreds of seconds long seismic coda from local and regional earthquakes in a wide range of backazimuths and epicentral distances up to 850 km with a travel path in the oceanic lithosphere. Moreover, the array was located about 100 km north of the Gloria fault, defining the plate boundary between the Eurasian and African plates at this location which also allows an investigation of the influence of an abrupt change in lithospheric age (20 Ma in this case) on seismic waves. The waves travel with velocities indicating upper-mantle material. We use So waves and their coda of pre-selected earthquakes to estimate frequency-dependent seismic scattering and intrinsic attenuation parameters. The estimated scattering attenuation coefficients are between 10(-4) and 4 x 10(-5) m(-1) and are typical for the lithosphere or the upper mantle. Furthermore, the total quality factors for So waves below 5 Hz are between 20 and 500 and are well below estimates from previous modelling for observations in the Pacific Ocean. This implies that the Atlantic Ocean is more attenuative for So waves compared to the Pacific Ocean, which is inline with the expected behaviour for the lithospheric structures resulting from the slower spreading rates in the Atlantic Ocean. The results for the analysed events indicate that for frequencies above 3 Hz, intrinsic attenuation is equal to or slightly stronger than scattering attenuation and that the So-wave coda is weakly influenced by the oceanic crust. Both observations are in agreement with the proposed propagation mechanism of scattering in the oceanic mantle lithosphere. Furthermore, we observe an age dependence which shows that an increase in lithospheric age is associated with a decrease in attenuation. However, we also observe a trade-off of this age-dependent effect with either a change in lithospheric thickness or thermal variations, for example due to small-scale upwellings in the upper mantle in the southeast close to Madeira and the Canaries. Moreover, the influence of the nearby Gloria fault is visible in a reduction of the intrinsic attenuation below 3 Hz for estimates across the fault. This is the first study to estimate seismic scattering and absorption parameters of So waves for an area with several hundreds of kilometres radius centred in the Eastern North Atlantic and using them to characterize the nature of the oceanic lithosphere.
forum:logopädie 35.2021, 1
(2021)
forum:logopädie 35.2021, 2
(2021)
forum:logopädie 35.2021, 3
(2021)
forum:logopädie 35.2021, 4
(2021)
forum:logopädie 35.2021, 5
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forum:logopädie 35.2021, 6
(2021)
The investigation of stresses, faults, structure and seismic hazards requires a good understanding and mapping of earthquake rupture and slip. Constraining the finite source of earthquakes from seismic and geodetic waveforms is challenging because the directional effects of the rupture itself are small and dynamic numerical solutions often include a large number of free parameters. The computational effort is large and therefore difficult to use in an exploratory forward modelling or inversion approach. Here, we use a simplified self-similar fracture model with only a few parameters, where the propagation of the fracture front is decoupled from the calculation of the slip. The approximative method is flexible and computationally efficient. We discuss the strengths and limitations of the model with real-case examples of well-studied earthquakes. These include the M-w 8.3 2015 Illapel, Chile, megathrust earthquake at the plate interface of a subduction zone and examples of continental intraplate strike-slip earthquakes like the M-w 7.1 2016 Kumamoto, Japan, multisegment variable slip event or the M-w 7.5 2018 Palu, Indonesia, supershear earthquake. Despite the simplicity of the model, a large number of observational features ranging from different rupture-front isochrones and slip distributions to directional waveform effects or high slip patches are easy to model. The temporal evolution of slip rate and rise time are derived from the incremental growth of the rupture and the stress drop without imposing other constraints. The new model is fast and implemented in the open-source Python seismology toolbox Pyrocko, ready to study the physics of rupture and to be used in finite source inversions.
Electronic databases of landslides seldom include the triggering mechanisms, rendering these inventories unusable for landslide hazard modeling. We present a method for classifying the triggering mechanisms of landslides in existing inventories, thus, allowing these inventories to aid in landslide hazard modeling corresponding to the correct event chain. Our method uses various geometric characteristics of landslides as the feature space for the machine-learning classifier random forest, resulting in accurate and robust classifications of landslide triggers. We applied the method to six landslide inventories spread over the Japanese archipelago in several different tests and training configurations to demonstrate the effectiveness of our approach. We achieved mean accuracy ranging from 67% to 92%. We also provide an illustrative example of a real-world usage scenario for our method using an additional inventory with unknown ground truth. Furthermore, our feature importance analysis indicates that landslides having identical trigger mechanisms exhibit similar geometric properties.
Pressure induced structural changes in silicate melts have a great impact on their physico-chemical properties and hence on their behaviour in the deep Earth's interior. In order to gain a deeper understanding we have studied the densification mechanism in multicomponent aluminosilicate glasses (albitic and albit-diopside composition) by means of extended X-ray absorption fine structure spectroscopy coupled to a diamond anvil cell up to 164 GPa. We have monitored the structural modifications from the network-former Ge as well as the network-modifier Sr. Notably, we tracked the evolution of Ge-O and Sr-O bond lengths (RGe-O, RSr-O) and their coordination number with pressure. We show that RGe-O increases strongly up to about 32 GPa, whereas RSr-O increases only slightly up to similar to 26 GPa. We assign these extensions to the increase of the coordination number from 4 to 6 (Ge) and from similar to 6 to at least 9 (Sr). Upon further compression RGe-O and RSr-O exhibit a continuous decrease to the highest probed pressure. These bond contractions, notably of RGe-O, that are continuous and exceed the one observed in pure SiO2 and GeO2, reflect a higher structural flexibility of multi-component glasses compared to those simple systems. Particularly, the high fraction of non-bridging oxygen atoms due to the presence of Na, Sr, Ca, Mg in the studied glasses, favours the simple compression of the highly-coordinated polyhedra of Si and Ge at pressure greater than 30 GPa. This is in strong contrast to pure oxides where cation polyhedral distortions govern the densification mechanism of the glass. The results of this study demonstrate that low field-strength alkali and alkaline earth cations, ubiquitous in deep Earth's melts, have a profound influence on the densification mechanism of glasses. Our results provide important constrains for interpreting the observed low velocity anomalies at the Earth's core-mantle boundary that have been, beyond others, referred to the presence of high-density melts. The hypothesis that non-buoyant melts at the Earth's core-mantle boundary can be formed by peculiar structural transformations in melts leading to higher coordination numbers compared to their crystalline equivalents is not supported from the present observations. The present results rather suggest that if velocity anomalies are to be explained by melts, these likely have considerable differences in chemical composition to the surrounding crystalline phase assemblage.
Gender at the crossroads
(2021)
Since the early 2000s, the United Nations (UN) global counterterrorism architecture has seen significant changes towards increased multilateralism, a focus on prevention, and inter-institutional coordination across the UN’s three pillars of work. Throughout this reform process, gender aspects have increasingly become presented as a “cross-cutting” theme. In this article, I investigate the role of gender in the UN’s counterterrorism reform process at the humanitarian-development-peace nexus, or “triple nexus”, from a feminist institutionalist perspective. I conduct a feminist discourse analysis of the counterterrorism discourses of three UN entities, which represent the different UN pillars of peace and security (DPO), development (UNDP), and humanitarianism and human rights (OHCHR). The article examines the role of gender in the inter-institutional reform process by focusing on the changes, overlaps and differences in the discursive production of gender in the entities’ counterterrorism agendas over time and in two recent UN counterterrorism conferences. I find that gendered dynamics of nested newness and institutional layering have played an essential role both as a justification for the involvement of individual entities in counterterrorism and as a vehicle for inter-institutional cooperation and struggle for discursive power.
How related are the ergodic properties of the over- and underdamped Langevin equations driven by fractional Gaussian noise? We here find that for massive particles performing fractional Brownian motion (FBM) inertial effects not only destroy the stylized fact of the equivalence of the ensemble-averaged mean-squared displacement (MSD) to the time-averaged MSD (TAMSD) of overdamped or massless FBM, but also dramatically alter the values of the ergodicity-breaking parameter (EB). Our theoretical results for the behavior of EB for underdamped or massive FBM for varying particle mass m, Hurst exponent H, and trace length T are in excellent agreement with the findings of stochastic computer simulations. The current results can be of interest for the experimental community employing various single-particle-tracking techniques and aiming at assessing the degree of nonergodicity for the recorded time series (studying, e.g., the behavior of EB versus lag time). To infer FBM as a realizable model of anomalous diffusion for a set single-particle-tracking data when massive particles are being tracked, the EBs from the data should be compared to EBs of massive (rather than massless) FBM.
In this study, the kinetics of the adsorption of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F(4)TCNQ) on the surface of Ag nanoparticles (Ag NPs) in chloroform has been intensively investigated, as molecular doping is known to play a crucial role in organic electronic devices. Based on the results obtained from UV-visible (vis)-near-infrared (NIR) absorption spectroscopy, cryogenic transmission electron microscopy, scanning nanobeam electron diffraction, and electron energy loss spectroscopy, a two-step interaction kinetics has been proposed for the Ag NPs and F(4)TCNQ molecules, which includes the first step of electron transfer from Ag NPs to F(4)TCNQ indicated by the ionization of F(4)TCNQ and the second step of the formation of a Ag-F(4)TCNQ complex. The whole process has been followed via UV-vis-NIR absorption spectroscopy, which reveals distinct kinetics at two stages: the instantaneous ionization and the long-term complex formation. The kinetics and the influence of the molar ratio of Ag NPs/F(4)TCNQ molecules on the interaction between Ag NPs and F(4)TCNQ molecules in an organic solution are reported herein for the first time. Furthermore, the control experiment with silica-coated Ag NPs manifests that the charge transfer at the surface between Ag NPs and F(4)TCNQ molecules is prohibited by a silica layer of 18 nm.
The within-site variability in site response is the randomness in site response at a given site from different earthquakes and is treated as aleatory variability in current seismic hazard/risk analyses.
In this study, we investigate the single-station variability in linear site response at K-NET and KiK-net stations in Japan using a large number of earthquake recordings.
We found that the standard deviation of the horizontal-to-vertical Fourier spectral ratio at individual sites, that is single-station horizontal-to-vertical spectral ratio (HVSR) sigma sigma(HV,s), approximates the within-site variability in site response quantified using surface-to-borehole spectral ratios (for oscillator frequencies higher than the site fundamental frequency) or empirical ground-motion models.
Based on this finding, we then utilize the single-station HVSR sigma as a convenient tool to study the site-response variability at 697 KiK-net and 1169 K-NET sites.
Our results show that at certain frequencies, stiff, rough and shallow sites, as well as small and local events tend to have a higher sigma(HV,s).
However, when being averaged over different sites, the single-station HVSR sigma, that is sigma(HV), increases gradually with decreasing frequency. In the frequency range of 0.25-25 Hz, sigma(HV) is centred at 0.23-0.43 in ln scales (a linear scale factor of 1.26-1.54) with one standard deviation of less than 0.1. sigma(HV) is quite stable across different tectonic regions, and we present a constant, as well as earthquake magnitude- and distance-dependent sigma(HV) models.
We employ Langevin-dynamics simulations to unveil non-Brownian and non-Gaussian center-of-mass self-diffusion of massive flexible dumbbell-shaped particles in crowded two-dimensional solutions. We study the intradumbbell dynamics of the relative motion of the two constituent elastically coupled disks. Our main focus is on effects of the crowding fraction phi and of the particle structure on the diffusion characteristics. We evaluate the time-averaged mean-squared displacement (TAMSD), the displacement probability-density function (PDF), and the displacement autocorrelation function (ACF) of the dimers. For the TAMSD at highly crowded conditions of dumbbells, e.g., we observe a transition from the short-time ballistic behavior, via an intermediate subdiffusive regime, to long-time Brownian-like spreading dynamics. The crowded system of dimers exhibits two distinct diffusion regimes distinguished by the scaling exponent of the TAMSD, the dependence of the diffusivity on phi, and the features of the displacement-ACF. We attribute these regimes to a crowding-induced transition from viscous to viscoelastic diffusion upon growing phi. We also analyze the relative motion in the dimers, finding that larger phi suppress their vibrations and yield strongly non-Gaussian PDFs of rotational displacements. For the diffusion coefficients D(phi) of translational and rotational motion of the dumbbells an exponential decay with phi for weak and a power-law variation D(phi) proportional to (phi - phi(star))(2.4) for strong crowding is found. A comparison of simulation results with theoretical predictions for D(phi) is discussed and some relevant experimental systems are overviewed.
We consider the spatiotemporal states of an ensemble of nonlocally coupled nonidentical phase oscillators, which correspond to different regimes of the long-term evolution of such a system. We have obtained homogeneous, twisted, and nonhomogeneous stationary solutions to the Ott-Antonsen equations corresponding to key variants of the realized collective rotational motion of elements of the medium in question with nonzero mesoscopic characteristics determining the degree of coherence of the dynamics of neighboring particles. We have described the procedures of the search for the class of nonhomogeneous solutions as stationary points of the auxiliary point map and of determining the stability based on analysis of the eigenvalue spectrum of the composite operator. Static and breather cluster regimes have been demonstrated and described, as well as the regimes with an irregular behavior of averaged complex fields including, in particular, the local order parameter.
Don’t settle for less
(2021)
Bewertung ausgewählter Aspekte des neuen „Gesetzes zum Schutz von Geschäftsgeheimnissen“ (GeschGehG)
(2021)
Durch die steigende Bedeutung von grenzüberschreitendem Unternehmensverkehr, Globalisierung und Outsourcing sowie dem Einsatz von Telekommunikationsmitteln ist eine effektive und einheitliche Regelung zum Schutz von Geschäftsgeheimnissen unentbehrlich, da infolge einer Zunahme von Praktiken, wie Wirtschaftsspionage und Verletzungen von Geheimhaltungspflichten, welche eine rechtswidrige Aneignung von
Geschäftsgeheimnissen bezwecken, eine verstärkte Gefährdungslage für die Geheimhaltung von Geschäftsgeheimnissen besteht. Insbesondere deshalb soll dieser Beitrag die Frage beantworten, ob die Richtlinie (EU) 2016/943 (Geheimnisschutzrichtlinie) europarechtskonform in das Gesetz zum Schutz von Geschäftsgeheimnissen (GeschGehG) umgesetzt worden ist (zur Historie I.). Der Schwerpunkt liegt hierbei auf dem Schutzbereich (II.) und vornehmlich auf der Frage, wie das Merkmal des kommerziellen Wertes zu verstehen ist, ob jegliche Geheimnisse eines Unternehmens geschützt sind und inwiefern sich der Geheimnisschutz durch die geforderten angemessenen Geheimhaltungsmaßnahmen für Geheimnisinhaber verändert. Betrachtet wird ebenfalls, ob der deutsche Gesetzgeber befugt ist, ein berechtigtes Interesse an der Geheimhaltung zu fordern. Spätestens seit Snowdens Enthüllungen genießt die Aufdeckung von unethischen oder illegalen Verhaltensweisen
gesteigerte Aufmerksamkeit in der Bevölkerung und Rechtswissenschaft. Für den Hinweisgeberschutz ergeben sich durch das GeschGehG Neuerungen. Hinsichtlich des umfassenden Schutzbereiches des GeschGehG wird betrachtet, ob und wann eine unternehmensexterne Offenlegung von Geschäftsgeheimnissen zulässig ist (III.). Hierzu wird beantwortet, ob die bisherige Rechtsprechung zum sog. Eskalationsmodell
weiterhin angewandt werden muss und wie sich das Verhältnis zur allgemeinen arbeitsvertraglichen Verschwiegenheitspflicht aus § 241 Abs. 2 BGB, sowohl aus dem laufenden als auch dem beendeten Arbeitsverhältnis, darstellt. Eine abschließende Bewertung (IV.) vervollständigt den Beitrag.
PC2P
(2021)
Motivation:
Prediction of protein complexes from protein-protein interaction (PPI) networks is an important problem in systems biology, as they control different cellular functions. The existing solutions employ algorithms for network community detection that identify dense subgraphs in PPI networks. However, gold standards in yeast and human indicate that protein complexes can also induce sparse subgraphs, introducing further challenges in protein complex prediction.
Results:
To address this issue, we formalize protein complexes as biclique spanned subgraphs, which include both sparse and dense subgraphs. We then cast the problem of protein complex prediction as a network partitioning into biclique spanned subgraphs with removal of minimum number of edges, called coherent partition. Since finding a coherent partition is a computationally intractable problem, we devise a parameter-free greedy approximation algorithm, termed Protein Complexes from Coherent Partition (PC2P), based on key properties of biclique spanned subgraphs. Through comparison with nine contenders, we demonstrate that PC2P: (i) successfully identifies modular structure in networks, as a prerequisite for protein complex prediction, (ii) outperforms the existing solutions with respect to a composite score of five performance measures on 75% and 100% of the analyzed PPI networks and gold standards in yeast and human, respectively, and (iii,iv) does not compromise GO semantic similarity and enrichment score of the predicted protein complexes. Therefore, our study demonstrates that clustering of networks in terms of biclique spanned subgraphs is a promising framework for detection of complexes in PPI networks.
In recent years, many efforts have been made to apply image processing techniques for plant leaf identification. However, categorizing leaf images at the cultivar/variety level, because of the very low inter-class variability, is still a challenging task. In this research, we propose an automatic discriminative method based on convolutional neural networks (CNNs) for classifying 12 different cultivars of common beans that belong to three various species. We show that employing advanced loss functions, such as Additive Angular Margin Loss and Large Margin Cosine Loss, instead of the standard softmax loss function for the classification can yield better discrimination between classes and thereby mitigate the problem of low inter-class variability. The method was evaluated by classifying species (level I), cultivars from the same species (level II), and cultivars from different species (level III), based on images from the leaf foreside and backside. The results indicate that the performance of the classification algorithm on the leaf backside image dataset is superior. The maximum mean classification accuracies of 95.86, 91.37 and 86.87% were obtained at the levels I, II and III, respectively. The proposed method outperforms the previous relevant works and provides a reliable approach for plant cultivars identification.
Carbonate minerals are common in both marine and lacustrine records, and are frequently used for paleoenvironmental reconstructions. The sedimentary sequence of the endorheic Dead Sea and its precursors contain aragonite laminae that provide a detailed sedimentary archive of climatic, hydrologic, limnologic and environmental conditions since the Pleistocene. However, the interpretation of these archives requires a detailed understanding of the constraints and mechanisms affecting CaCO3 precipitation, which are still debated. The implications of aragonite precipitation in the Dead Sea and in its late Pleistocene predecessor (Lake Lisan) were investigated in this study by mixing natural and synthetic brines with a synthetic bicarbonate solution that mimics flash-floods composition, with and without the addition of extracellular polymeric substances (EPS). Aragonite precipitation was monitored, and precipitation rates and carbonate yields were calculated and are discussed with respect to modern aquatic environments. The experimental insights on aragonite precipitation are then integrated with microfacies analyses in order to reconstruct and constrain prevailing limnogeological processes and their hydroclimatic drivers under low (interglacial) and high (glacial) lake level stands. Aragonite precipitation took place within days to several weeks after the mixing of the brines with a synthetic bicarbonate solution. Incubation time was proportional to bicarbonate concentration, and precipitation rates were partially influenced by ionic strength. Additionally, extracellular polymeric substances inhibited aragonite precipitation for several months. As for the lake's water budget, our calculations suggest that the precipitation of a typical aragonite lamina (0.5 mm thick) during high lake stand requires unreasonable freshwater inflow from either surface or subsurface sources. This discrepancy can be resolved by considering one or a combination of the following scenarios; (1) discontinuous aragonite deposition over parts of the lake floor; (2) supply of additional carbonate flux (or fluxes) to the lake from aeolian dust and the remobilization and dissolution of dust deposits at the watershed; (3) carbonate production via oxidation of organic carbon by sulfate-reducing bacteria. Altogether, it is suggested that aragonite laminae thickness cannot be directly interpreted for quantitatively reconstructing the hydrological balance for the entire lake, they may still prove valuable for identifying inherent hydroclimatic periodicities at a single site.
In this introductory article to the special issue, we ask what role sexuality plays in the reproduction and contestation of border regimes and think sexuality towards its various entanglements with border control. As borders have been understood as a method for reproducing racialized distinctions, we argue that sexuality is also a method of bordering and illustrate how sexuality works as a key strategy for the capture, containment and regulation of mobility and movement. Taking a transnational approach, we bring together queer scholarship on borders and migration with the rich archive of feminist, Black, Indigenous and critical border perspectives to suggest that these strategies need to be understood in close relation to the (I) intersecting dynamics of colonial histories of racialization, (II) national regimes of reproductive control and (III) the containment of contagion, disease and sexual deviance.
This study examines the institutionalization of information technologies for policy formulation by investigating the case of eNAP. The digital tool was introduced in the spring of 2018 with the aim of supporting and improving sustainability impact assessments (SIAs) within the German Federal Government. Applying a neo-institutional perspective, this study shows how a tool like eNAP is embedded into prevailing regulative, normative, and cultural–cognitive structures. Findings from 10 semi-structured interviews indicate that the application of eNAP varies according to intra-ministerial coordination practices and portfolio-specific information-processing schemata. Overall, the tool serves to translate the abstract regulation to conduct an SIA, as well as to translate the vague norm of “sustainability” into a concrete assessment requirement, thereby helping increase policy officials’ awareness of sustainability goals. However, consistent with previous studies, great importance is not attached to SIAs in policy formulation, and prevailing norms and routines make the implementation of eNAP to increase the use of evidence or in-depth considerations of policy alternatives and their consequences unlikely.
Sedimentary ancient DNA-based studies have been used to probe centuries of climate and environmental changes and how they affected cyanobacterial assemblages in temperate lakes. Due to cyanobacteria containing potential bloom-forming and toxin-producing taxa, their approximate reconstruction from sediments is crucial, especially in lakes lacking long-term monitoring data. To extend the resolution of sediment record interpretation, we used high-throughput sequencing, amplicon sequence variant (ASV) analysis, and quantitative PCR to compare pelagic cyanobacterial composition to that in sediment traps (collected monthly) and surface sediments in Lake Tiefer See. Cyanobacterial composition, species richness, and evenness was not significantly different among the pelagic depths, sediment traps and surface sediments (p > 0.05), indicating that the cyanobacteria in the sediments reflected the cyanobacterial assemblage in the water column. However, total cyanobacterial abundances (qPCR) decreased from the metalimnion down the water column. The aggregate-forming (Aphanizomenon) and colony-forming taxa (Snowella) showed pronounced sedimentation. In contrast, Planktothrix was only very poorly represented in sediment traps (meta- and hypolimnion) and surface sediments, despite its highest relative abundance at the thermocline (10 m water depth) during periods of lake stratification (May-October). We conclude that this skewed representation in taxonomic abundances reflects taphonomic processes, which should be considered in future DNA-based paleolimnological investigations.
Sulfated biomolecules are known to influence numerous biological processes in all living organisms. Particularly, they contribute to prevent and inhibit the hypercoagulation condition. The failure of polymeric implants and blood contacting devices is often related to hypercoagulation and microbial contamination. Here, bioactive sulfated biomacromolecules are mimicked by sulfation of poly(glycerol glycidyl ether) (polyGGE) films. Autoclaving, gamma-ray irradiation and ethylene oxide (EtO) gas sterilization techniques were applied to functionalized materials. The sulfate group density and hydrophilicity of sulfated polymers were decreased while chain mobility and thermal degradation were enhanced post autoclaving when compared to those after EtO sterilization. These results suggest that a quality control after sterilization is mandatory to ensure the amount and functionality of functionalized groups are retained.
From laggards to leaders
(2021)
The 2015 Paris Agreement on climate change embraces the participation of non-state actors in a separate governance track – the ‘Non-state actor zone for global action’ (nazca) – that runs alongside the formal track of unfccc negotiations and the implementation of the Paris Agreement by State Parties through ‘nationally determined contributions’. unfccc Secretariat is entrusted with orchestrating non-state global and transnational initiatives, partnerships and networks. The involvement of non-state actors in the implementation of the Paris Agreement helps to address an action gap by countries that are unable or unwilling to implement ambitious ndcs.
However, the increased prominence of initiatives driven by non-state actors also increases their direct and indirect influence on processes and rules which raises a number of questions with regards to the legitimacy of action and the democratic deficit of the global climate regime. Balancing legitimacy with effectiveness requires non-state initiatives to ensure transparent and inclusive governance, and accountability towards progress against their goals and pledges.
Despite its encouragement towards private initiatives, the Paris Agreement creates surprisingly little regulatory space for non-state actors to gain hold. Neither are there measures that would link ndcs to nazca initiatives, nor are functional requirements such as transparency or reporting extended to non-state initiatives. While the Paris Agreement marks an important step towards harnessing private sector ability and ambition for climate action, more remains to be done to create a truly enabling framework for private action to strive and complement public efforts to address climate change.
The holocaust in the USSR
(2021)
This paper sketches the current status of international scholarship on the subject of the Holocaust in the USSR and its place in the wider military conflict of the Second World War. Research on this topic over the last 20 to 30 years has been truly international and the findings of this research cannot be sketched here without pointing to the contributions made by German, American, Russian, Israeli, British and Australian historians. Historians from these countries have made important contributions to our understanding of key questions relating to this subject. These questions address, among other things, pre-invasion orders issued to German units; the radicalisation of German policy, culminating in the root-and-branch extermination of Soviet Jewry; the network of ghettos set up on Soviet territory; the nature of the killing and the methods used to murder these victims; the total death toll of the Holocaust in the USSR; and the relationship between war and extermination, in which genocide can be regarded as an actual strategy of warfare pursued by the German Reich.
Land-based climate mitigation measures have gained significant attention and importance in public and private sector climate policies. Building on previous studies, we refine and update the mitigation potentials for 20 land-based measures in >200 countries and five regions, comparing “bottom-up” sectoral estimates with integrated assessment models (IAMs). We also assess implementation feasibility at the country level. Cost-effective (available up to $100/tCO2eq) land-based mitigation is 8–13.8 GtCO2eq yr−1 between 2020 and 2050, with the bottom end of this range representing the IAM median and the upper end representing the sectoral estimate. The cost-effective sectoral estimate is about 40% of available technical potential and is in line with achieving a 1.5°C pathway in 2050. Compared to technical potentials, cost-effective estimates represent a more realistic and actionable target for policy. The cost-effective potential is approximately 50% from forests and other ecosystems, 35% from agriculture, and 15% from demand-side measures. The potential varies sixfold across the five regions assessed (0.75–4.8 GtCO2eq yr−1) and the top 15 countries account for about 60% of the global potential. Protection of forests and other ecosystems and demand-side measures present particularly high mitigation efficiency, high provision of co-benefits, and relatively lower costs. The feasibility assessment suggests that governance, economic investment, and socio-cultural conditions influence the likelihood that land-based mitigation potentials are realized. A substantial portion of potential (80%) is in developing countries and LDCs, where feasibility barriers are of greatest concern. Assisting countries to overcome barriers may result in significant quantities of near-term, low-cost mitigation while locally achieving important climate adaptation and development benefits. Opportunities among countries vary widely depending on types of land-based measures available, their potential co-benefits and risks, and their feasibility. Enhanced investments and country-specific plans that accommodate this complexity are urgently needed to realize the large global potential from improved land stewardship.
Honey traceability is an important topic, especially for honeydew honeys, due to the increased incidence of adulteration. This study aimed to establish specific markers to quantify proteins in honey. A proteomics strategy to identify marker peptides from bracatinga honeydew honey was therefore developed. The proteomics approach was based on initial untargeted identification of honey proteins and peptides by LC-ESI-Triple-TOF-MS/MS, which identified the major royal jelly proteins (MRJP) presence. Afterwards, the peptides were selected by the in silico digestion. The marker peptides were quantified by the developed targeted LC-QqQ-MS/MS method, which provided good linearity and specificity, besides recoveries between 92 and 100% to quantify peptides from bracatinga honeydew honey. The uniqueness and high response in mass spectrometry were backed by further complementary protein analysis (SDS-PAGE). The selected marker peptides EALPHVPIFDR (MRJP 1), ILGANVK (MRJP 2), TFVTIER (MRJP 3), QNIDVVAR (MRJP 4), FINNDYNFNEVNFR (MRJP 5) and LLQPYPDWSWTK (MRJP 7), quantified by LC-QqQ-MS/MS, highlighted that the content of QNIDVVAR from MRJP 4 could be used to differentiate bracatinga honeydew honey from floral honeys (p < 0.05) as a potential marker for its authentication. Finally, principal components analysis highlighted the QNIDVVAR content as a good descriptor of the analyzed bracatinga honeydew honey samples.
Effectiveness
(2021)
In this article we prove upper bounds for the Laplace eigenvalues lambda(k) below the essential spectrum for strictly negatively curved Cartan-Hadamard manifolds. Our bound is given in terms of k(2) and specific geometric data of the manifold. This applies also to the particular case of non-compact manifolds whose sectional curvature tends to -infinity, where no essential spectrum is present due to a theorem of Donnelly/Li. The result stands in clear contrast to Laplacians on graphs where such a bound fails to be true in general.
Bundesrechnungshof
(2021)
Der Bundesrechnungshof schaut mittlerweile auf eine über 300 jährige Geschichte der Finanzkontrolle zurück (vgl. Engels 2014). Auch wenn Aufgaben und Organisation damaliger Rechenkammern bestenfalls rudimentär mit den Einrichtungen moderner Finanzkontrolle vergleichbar sind, so legten sie doch einst deren Grundstein. Heute ist der Bundesrechnungshof eine oberste Bundesbehörde und prüft laut Artikel 114 Abs. 2 GG die „Rechnung sowie die Wirtschaftlichkeit und Ordnungsmäßigkeit der Haushalts- und Wirtschaftsführung des Bundes.“ Weitere Regelungen für den Bundesrechnungshof finden sich in der Bundeshaushaltsordnung (BHO, hier Teil V Rechnungsprüfung bis Teil VIII Entlastung, §§ 88 bis 114) und im Bundesrechnungshofgesetz (BRHG vom 11.07.1985, mit letzter Änderung vom 05.02.2009).
Human induced pluripotent stem cells (hiPSCs) are highly sensitive to extrinsic physical and biochemical signals from their extracellular microenvironments. In this study, we analyzed the effect of cyclic temperature changes on hiPSCs behaviors, especially by means of scanning force microscopy (BIO-AFM). The alternation in cellular mechanics, as well as the secretion and pattern of deposition of extracellular matrix (ECM) protein in hiPSCs were evaluated. The arrangement of the actin cytoskeleton changed with the variation of the temperature. The rearranged cytoskeleton architecture led to the subsequent changes in cell mechanics (Young's modulus of hiPSCs). With the exposure to the cyclic cold stimuli, an increase in the average surface roughness (Ra) and roughness mean square (RMS) was detected. This observation might be at least in part due to the upregulated secretion of Laminin alpha 5 during repeated temporary cooling. The expression of pluripotent markers, NANOG and SOX2, was not impaired in hiPSCs, when exposed to the cyclic cold stimuli for 24 h. Our findings provide an insight into the effect of temperature on the hiPSC behaviors, which may contribute to a better understanding of the application of locally controlled therapeutic hypothermia.
We consider an array of nonlocally coupled oscillators on a ring, which for equally spaced units possesses a Kuramoto-Battogtokh chimera regime and a synchronous state. We demonstrate that disorder in oscillators positions leads to a transition from the synchronous to the chimera state. For a static (quenched) disorder we find that the probability of synchrony survival depends on the number of particles, from nearly zero at small populations to one in the thermodynamic limit. Furthermore, we demonstrate how the synchrony gets destroyed for randomly (ballistically or diffusively) moving oscillators. We show that, depending on the number of oscillators, there are different scalings of the transition time with this number and the velocity of the units.
Binary III-V nitrides such as AlN, GaN and InN in the wurtzite-type structure have long been considered as potent semiconducting materials because of their optoelectronic properties, amongst others. With rising concerns over the utilization of scarce elements, a replacement of the trivalent cations by others in ternary and multinary nitrides has led to the development of different variants of nitrides and oxide nitrides crystallizing in lower-symmetry variants of wurtzite. This work presents the symmetry relationships between these structural types specific to nitrides and oxide nitrides and updates some prior work on this matter. The non-existence of compounds crystallizing in Pmc2(1), formally the highest subgroup of the wurtzite type fulfilling Pauling's rules for 1:1:2 stoichiometries, has been puzzling scientists for a while; a rationalization is given, from a crystallographic basis, of why this space group is unlikely to be adopted.
1. Microplastics in soils have become an important threat for terrestrial systems as they may potentially alter the geochemical/biophysical soil environment and can interact with drought. As microplastics may affect soil water content, this could exacerbate the well-known negative effects of drought on ecosystem functionality. Thus, functions including litter decomposition, soil aggregation or those related with nutrient cycling can be altered. Despite this potential interaction, we know relatively little about how microplastics, under different soil water conditions, affect ecosystem functions and multifunctionality.
2. To address this gap, we performed an experiment using grassland plant communities growing in microcosms. Microplastic fibres (absent, present) and soil water conditions (well-watered, drought) were applied in a fully factorial design. At harvest, we measured soil ecosystem functions related to nutrient cycling (beta-glucosaminidase, beta-D-cellobiosidase, phosphatase, beta-glucosidase enzymes), respiration, nutrient retention, pH, litter decomposition and soil aggregation (water stable aggregates). As terrestrial systems provide these functions simultaneously, we also assessed ecosystem multifunctionality, an index that encompasses the array of ecosystem functions measured here.
3. We found that the interaction between microplastic fibres and drought affected ecosystem functions and multifunctionality. Drought had negatively affected nutrient cycling by decreasing enzymatic activities by up to similar to 39%, while microplastics increased soil aggregation by similar to 18%, soil pH by similar to 4% and nutrient retention by up to similar to 70% by diminishing nutrient leaching. Microplastic fibres also impacted soil enzymes, respiration and ecosystem multifunctionality, but importantly, the direction of these effects depended on soil water status. That is, under well-watered conditions, these functions decreased with microplastic fibres by up to similar to 34% while under drought they had similar values irrespective of the microplastic presence, or tended to increase with microplastics. Litter decomposition had a contrary pattern increasing with microplastics by similar to 6% under well-watered conditions while decreasing to a similar percentage under drought.
4. Synthesis and applications. Single ecosystem functions can be positively or negatively affected by microplastics fibres depending on soil water status. However, our results suggest that microplastic fibres may cause negative effects on ecosystem soil multifunctionality of a similar magnitude as drought. Thus, strategies to counteract this new global change factor are necessary.
Satellite-measured tidal magnetic signals are of growing importance. These fields are mainly used to infer Earth's mantle conductivity, but also to derive changes in the oceanic heat content. We present a new Kalman filter-based method to derive tidal magnetic fields from satellite magnetometers: KALMAG. The method's advantage is that it allows to study a precisely estimated posterior error covariance matrix. We present the results of a simultaneous estimation of the magnetic signals of 8 major tides from 17 years of Swarm and CHAMP data. For the first time, robustly derived posterior error distributions are reported along with the reported tidal magnetic fields. The results are compared to other estimates that are either based on numerical forward models or on satellite inversions of the same data. For all comparisons, maximal differences and the corresponding globally averaged RMSE are reported. We found that the inter-product differences are comparable with the KALMAG-based errors only in a global mean sense. Here, all approaches give values of the same order, e.g., 0.09 nT-0.14 nT for M2. Locally, the KALMAG posterior errors are up to one order smaller than the inter-product differences, e.g., 0.12 nT vs. 0.96 nT for M2.
Infection is a common and often deadly complication after burn injury. A major underlying factor is burn-induced immune dysfunction, particularly with respect to neutrophils as the primary responders to infection. Temporally after murine scald injury, we demonstrate impaired bone marrow neutrophil chemotaxis toward CXCL1 ex vivo. Additionally, we observed a reduced recruitment of neutrophils to the peritoneal after elicitation 7 days after injury. We demonstrate that neutrophil ceramide levels increase after burn injury, and this is associated with decreased expression of CXCR2 and blunted chemotaxis. A major signaling event upon CXCR2 activation is Akt phosphorylation and this was reduced when ceramide was elevated. In contrast, PTEN levels were elevated and PTEN-inhibition elevated phospho-Akt levels and mitigated the burn-induced neutrophil chemotaxis defect. Altogether, this study identifies a newly described pathway of ceramide-mediated suppression of neutrophil chemotaxis after burn injury and introduces potential targets to mitigate this defect and reduce infection-related morbidity and mortality after burn.
Full-length transcriptome
(2021)
Fish is considered as a supreme model for clarifying the evolution and regulatory mechanism of vertebrate immunity. However, the knowledge of distinct immune cell populations in fish is still limited, and further development of techniques advancing the identification of fish immune cell populations and their functions are required. Single cell RNA-seq (scRNA-seq) has provided a new approach for effective in-depth identification and characterization of cell subpopulations. Current approaches for scRNA-seq data analysis usually rely on comparison with a reference genome and hence are not suited for samples without any reference genome, which is currently very common in fish research. Here, we present an alternative, i.e. scRNA-seq data analysis with a full-length transcriptome as a reference, and evaluate this approach on samples from Epinephelus coioides-a teleost without any published genome. We show that it reconstructs well most of the present transcripts in the scRNA-seq data achieving a sensitivity equivalent to approaches relying on genome alignments of related species. Based on cell heterogeneity and known markers, we characterized four cell types: T cells, B cells, monocytes/macrophages (Mo/M phi) and NCC (non-specific cytotoxic cells). Further analysis indicated the presence of two subsets of Mo/M phi including M1 and M2 type, as well as four subsets in B cells, i.e. mature B cells, immature B cells, pre B cells and early-pre B cells. Our research will provide new clues for understanding biological characteristics, development and function of immune cell populations of teleost. Furthermore, our approach provides a reliable alternative for scRNA-seq data analysis in teleost for which no reference genome is currently available.
Neutrons on rails
(2021)
Large-scale measurements of the spatial distribution of water content in soils and snow are challenging for state-of-the-art hydrogeophysical methods. Cosmic-ray neutron sensing (CRNS) is a noninvasive technology that has the potential to bridge the scale gap between conventional in situ sensors and remote sensing products in both, horizontal and vertical domains. In this study, we explore the feasibility and potential of estimating water content in soils and snow with neutron detectors in moving trains. Theoretical considerations quantify the stochastic measurement uncertainty as a function of water content, altitude, resolution, and detector efficiency. Numerical experiments demonstrate that the sensitivity of measured water content is almost unperturbed by train materials. Finally, three distinct real-world experiments provide a proof of concept on short and long-range tracks. With our results a transregional observational soil moisture product becomes a realistic vision within the next years.
Teaching quality is a key factor in student academic success, but few studies have investigated how teaching quality changes at the beginning of secondary education and how such changes are predicted by dimensions of teacher motivation. This study investigated the changes in class-level student perceptions of teaching quality over one school year at the beginning of secondary school and examined how teachers? self-efficacy and enthusiasm predicted such changes. Data from 1996 students (53.8% male; mean age: 11.09 years, SD = 0.55) and their homeroom teachers (N = 105), who were surveyed at the beginning of Grades 5 and 6, were analyzed. Results showed a significant decline in class-level student-perceived emotional support, classroom management, and instructional clarity. Teacher-reported self-efficacy was not significantly related to changes in teaching quality. Teacher-reported enthusiasm buffered the decline in students? class-level classroom management.
EC 22536-5304
(2021)
Helium-burning hot subdwarf stars of spectral types O and B (sdO/B) are thought to be produced through various types of binary interactions. The helium-rich hot subdwarf star EC 22536-5304 was recently found to be extremely enriched in lead. Here, we show that EC 22536-5304 is a binary star with a metal-poor subdwarf F-type (sdF) companion. We performed a detailed analysis of high-resolution SALT/HRS and VLT/UVES spectra, deriving metal abundances for the hot subdwarf, as well as atmospheric parameters for both components. Because we consider the contribution of the sdF star, the derived lead abundance for the sdOB, + 6.3 +/- 0.3 dex relative to solar, is even higher than previously thought. We derive T-eff = 6210 +/- 70 K, log g = 4.64 +/- 0.10, [FE/H] = - 1.95 +/- 0.04, and [alpha/Fe] = + 0.40 +/- 0.04 for the sdF component. Radial velocity variations, although poorly sampled at present, indicate that the binary system has a long orbital period of about 457 days. This suggests that the system was likely formed through stable Roche lobe overflow (RLOF). A kinematic analysis shows that EC 22536-5304 is on an eccentric orbit around the Galactic centre. This, as well as the low metallicity and strong alpha enhancement of the sdF-type companion, indicate that EC 22536-5304 is part of the Galactic halo or metal-weak thick disc. As the first long-period hot subdwarf binary at [FE/H] less than or similar to- 1, EC 22536-5304 may help to constrain the RLOF mechanism for mass transfer from low-mass, low-metallicity red giant branch (RGB) stars to main-sequence companions.
Kollaborative, partizipative Instrumente zur Krisenbekämpfung haben in den letzten Jahren zunehmend an Aufmerksamkeit gewonnen. Ein Beispiel hierfür ist der #WirVsVirus-Hackathon, der als Reaktion auf die COVID-19-Pandemie durchgeführt wurde und über 28.000 Teilnehmer:innen erreichte. Bislang wurden die Auswirkungen solch groß angelegter, kollaborativer Ansätze zur Krisenbewältigung auf staatliches Krisenmanagement nur selten untersucht. Diese Studie analysiert den Hackathon und die daraus entstandenen Projekte aus der Perspektive des Open Governance-Paradigmas. Auf Grundlage von neun Experteninterviews untersuchen wir, wie sich digitale Open Governance auf die Regierungsfähigkeit und Legitimität in Krisenzeiten auswirkt. Unsere Analyse zeigt, dass digitale Open Governance zur Leistungsfähigkeit und Legitimität staatlichen Handelns in Krisenzeiten beitragen kann, da solche Projekte eine breite und diverse Teilnehmerschaft mobilisieren und in kurzer Zeit bürgerzentrierte, nutzbare Lösungen für krisenbezogene Probleme entwickeln können. Dem stehen allerdings Zweifel an der langfristigen Beständigkeit der Projekte, ihrer Skalierbarkeit, sowie Risiken hinsichtlich der Legitimität und Rechenschaftspflicht entgegen.
Development of functional and stable solid polymer electrolytes (SPEs) for battery applications is an important step towards both safer batteries and for the realization of lithium-based or anode-less batteries. The interface between the lithium and the solid polymer electrolyte is one of the bottlenecks, where severe degradation is expected. Here, the stability of three different SPEs - poly(ethylene oxide) (PEO), poly(epsilon-caprolactone) (PCL) and poly(trimethylene carbonate) (PTMC) - together with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt, is investigated after they have been exposed to lithium metal under UHV conditions. Degradation compounds, e.g. Li-O-R, LiF and LixSyOz, are identified for all SPEs using soft X-ray photoelectron spectroscopy. A competing degradation between polymer and salt is identified in the outermost surface region (<7 nm), and is dependent on the polymer host. PTMC:LiTFSI shows the most severe decomposition of both polymer and salt followed by PCL:LiTFSI and PEO:LiTFSI. In addition, the movement of lithium species through the decomposed interface shows large variation depending on the polymer electrolyte system.
Diffusion maps is a manifold learning algorithm widely used for dimensionality reduction. Using a sample from a distribution, it approximates the eigenvalues and eigenfunctions of associated Laplace-Beltrami operators. Theoretical bounds on the approximation error are, however, generally much weaker than the rates that are seen in practice. This paper uses new approaches to improve the error bounds in the model case where the distribution is supported on a hypertorus. For the data sampling (variance) component of the error we make spatially localized compact embedding estimates on certain Hardy spaces; we study the deterministic (bias) component as a perturbation of the Laplace-Beltrami operator's associated PDE and apply relevant spectral stability results. Using these approaches, we match long-standing pointwise error bounds for both the spectral data and the norm convergence of the operator discretization. We also introduce an alternative normalization for diffusion maps based on Sinkhorn weights. This normalization approximates a Langevin diffusion on the sample and yields a symmetric operator approximation. We prove that it has better convergence compared with the standard normalization on flat domains, and we present a highly efficient rigorous algorithm to compute the Sinkhorn weights.
We study the classical, two-sided stable marriage problem under pairwise preferences. In the most general setting, agents are allowed to express their preferences as comparisons of any two of their edges, and they also have the right to declare a draw or even withdraw from such a comparison. This freedom is then gradually restricted as we specify six stages of orderedness in the preferences, ending with the classical case of strictly ordered lists. We study all cases occurring when combining the three known notions of stability-weak, strong, and super-stability-under the assumption that each side of the bipartite market obtains one of the six degrees of orderedness. By designing three polynomial algorithms and two NP-completeness proofs, we determine the complexity of all cases not yet known and thus give an exact boundary in terms of preference structure between tractable and intractable cases.
Quenching mechanism of uranyl(VI) by chloride and bromide in aqueous and non-aqueous solutions
(2021)
A major hindrance in utilizing uranyl(VI) luminescence as a standard analytical tool, for example, in environmental monitoring or nuclear industries, is quenching by other ions such as halide ions, which are present in many relevant matrices of uranyl(VI) speciation. Here, we demonstrate through a combination of time-resolved laser-induced fluorescence spectroscopy, transient absorption spectroscopy, and quantum chemistry that coordinating solvent molecules play a crucial role in U(VI) halide luminescence quenching. We show that our previously suggested quenching mechanism based on an internal redox reaction of the 1:2-uranyl-halide-complex holds also true for bromide-induced quenching of uranyl(VI). By adopting specific organic solvents, we were able to suppress the separation of the oxidized halide ligand X-2(center dot-) and the formed uranyl(V) into fully solvated ions, thereby "reigniting" U(VI) luminescence. Time-dependent density functional theory calculations show that quenching occurs through the outer-sphere complex of U(VI) and halide in water, while the ligand-to-metal charge transfer is strongly reduced in acetonitrile.
Since the beginning of the Anthropocene, lacustrine biodiversity has been influenced by climate change and human activities. These factors advance the spread of harmful cyanobacteria in lakes around the world, which affects water quality and impairs the aquatic food chain. In this study, we assessed changes in cyanobacterial community dynamics via sedimentary DNA (sedaDNA) from well-dated lake sediments of Lake Tiefer See, which is part of the Klocksin Lake Chain spanning the last 350 years. Our diversity and community analysis revealed that cyanobacterial communities form clusters according to the presence or absence of varves. Based on distance-based redundancy and variation partitioning analyses (dbRDA and VPA) we identified that intensified lake circulation inferred from vegetation openness reconstructions, delta C-13 data (a proxy for varve preservation) and total nitrogen content were abiotic factors that significantly explained the variation in the reconstructed cyanobacterial community from Lake Tiefer See sediments. Operational taxonomic units (OTUs) assigned to Microcystis sp. and Aphanizomenon sp. were identified as potential eutrophication-driven taxa of growing importance since circa common era (ca. CE) 1920 till present. This result is corroborated by a cyanobacteria lipid biomarker analysis. Furthermore, we suggest that stronger lake circulation as indicated by non-varved sediments favoured the deposition of the non-photosynthetic cyanobacteria sister clade Sericytochromatia, whereas lake bottom anoxia as indicated by subrecent- and recent varves favoured the Melainabacteria in sediments. Our findings highlight the potential of high-resolution amplicon sequencing in investigating the dynamics of past cyanobacterial communities in lake sediments and show that lake circulation, anoxic conditions, and human-induced eutrophication are main factors explaining variations in the cyanobacteria community in Lake Tiefer See during the last 350 years.
How different are the results of constant-rate resetting of anomalous-diffusion processes in terms of their ensemble-averaged versus time-averaged mean-squared displacements (MSDs versus TAMSDs) and how does stochastic resetting impact nonergodicity? We examine, both analytically and by simulations, the implications of resetting on the MSD- and TAMSD-based spreading dynamics of particles executing fractional Brownian motion (FBM) with a long-time memory, heterogeneous diffusion processes (HDPs) with a power-law space-dependent diffusivity D(x) = D0|x|gamma and their "combined" process of HDP-FBM. We find, inter alia, that the resetting dynamics of originally ergodic FBM for superdiffusive Hurst exponents develops disparities in scaling and magnitudes of the MSDs and mean TAMSDs indicating weak ergodicity breaking. For subdiffusive HDPs we also quantify the nonequivalence of the MSD and TAMSD and observe a new trimodal form of the probability density function. For reset FBM, HDPs and HDP-FBM we compute analytically and verify by simulations the short-time MSD and TAMSD asymptotes and long-time plateaus reminiscent of those for processes under confinement. We show that certain characteristics of these reset processes are functionally similar despite a different stochastic nature of their nonreset variants. Importantly, we discover nonmonotonicity of the ergodicitybreaking parameter EB as a function of the resetting rate r. For all reset processes studied we unveil a pronounced resetting-induced nonergodicity with a maximum of EB at intermediate r and EB similar to(1/r )-decay at large r. Alongside the emerging MSD-versus-TAMSD disparity, this r-dependence of EB can be an experimentally testable prediction. We conclude by discussing some implications to experimental systems featuring resetting dynamics.
Our input is a complete graph G on n vertices where each vertex has a strict ranking of all other vertices in G. The goal is to construct a matching in G that is popular. A matching M is popular if M does not lose a head-to-head election against any matching M ': here each vertex casts a vote for the matching in {M,M '} in which it gets a better assignment. Popular matchings need not exist in the given instance G and the popular matching problem is to decide whether one exists or not. The popular matching problem in G is easy to solve for odd n. Surprisingly, the problem becomes NP-complete for even n, as we show here. This is one of the few graph theoretic problems efficiently solvable when n has one parity and NP-complete when n has the other parity.
We establish a new approach of treating elliptic boundary value problems (BVPs) on manifolds with boundary and regular corners, up to singularity order 2. Ellipticity and parametrices are obtained in terms of symbols taking values in algebras of BVPs on manifolds of corresponding lower singularity orders. Those refer to Boutet de Monvel's calculus of operators with the transmission property, see Boutet de Monvel (Acta Math 126:11-51, 1971) for the case of smooth boundary. On corner configuration operators act in spaces with multiple weights. We mainly study the case of upper left entries in the respective 2 x 2 operator block-matrices of such a calculus. Green operators in the sense of Boutet de Monvel (Acta Math 126:11-51, 1971) analogously appear in singular cases, and they are complemented by contributions of Mellin type. We formulate a result on ellipticity and the Fredholm property in weighted corner spaces, with parametrices of analogous kind.
Wildfires, as a key disturbance in forest ecosystems, are shaping the world's boreal landscapes. Changes in fire regimes are closely linked to a wide array of environmental factors, such as vegetation composition, climate change, and human activity. Arctic and boreal regions and, in particular, Siberian boreal forests are experiencing rising air and ground temperatures with the subsequent degradation of permafrost soils leading to shifts in tree cover and species composition. Compared to the boreal zones of North America or Europe, little is known about how such environmental changes might influence long-term fire regimes in Russia. The larch-dominated eastern Siberian deciduous boreal forests differ markedly from the composition of other boreal forests, yet data about past fire regimes remain sparse. Here, we present a high-resolution macroscopic charcoal record from lacustrine sediments of Lake Khamra (southwest Yakutia, Siberia) spanning the last ca. 2200 years, including information about charcoal particle sizes and morphotypes. Our results reveal a phase of increased charcoal accumulation between 600 and 900 CE, indicative of relatively high amounts of burnt biomass and high fire frequencies. This is followed by an almost 900-year-long period of low charcoal accumulation without significant peaks likely corresponding to cooler climate conditions. After 1750 CE fire frequencies and the relative amount of biomass burnt start to increase again, coinciding with a warming climate and increased anthropogenic land development after Russian colonization. In the 20th century, total charcoal accumulation decreases again to very low levels despite higher fire frequency, potentially reflecting a change in fire management strategies and/or a shift of the fire regime towards more frequent but smaller fires. A similar pattern for different charcoal morphotypes and comparison to a pollen and non-pollen palynomorph (NPP) record from the same sediment core indicate that broad-scale changes in vegetation composition were probably not a major driver of recorded fire regime changes. Instead, the fire regime of the last two millennia at Lake Khamra seems to be controlled mainly by a combination of short-term climate variability and anthropogenic fire ignition and suppression.
Halide perovskites
(2021)
Relationships between climate, species composition, and species richness are of particular importance for understanding how boreal ecosystems will respond to ongoing climate change. This study aims to reconstruct changes in terrestrial vegetation composition and taxa richness during the glacial Late Pleistocene and the interglacial Holocene in the sparsely studied southeastern Yakutia (Siberia) by using pollen and sedimentary ancient DNA (sedaDNA) records. Pollen and sedaDNA metabarcoding data using the trnL g and h markers were obtained from a sediment core from Lake Bolshoe Toko. Both proxies were used to reconstruct the vegetation composition, while metabarcoding data were also used to investigate changes in plant taxa richness. The combination of pollen and sedaDNA approaches allows a robust estimation of regional and local past terrestrial vegetation composition around Bolshoe Toko during the last similar to 35,000 years. Both proxies suggest that during the Late Pleistocene, southeastern Siberia was covered by open steppe-tundra dominated by graminoids and forbs with patches of shrubs, confirming that steppe-tundra extended far south in Siberia. Both proxies show disturbance at the transition between the Late Pleistocene and the Holocene suggesting a period with scarce vegetation, changes in the hydrochemical conditions in the lake, and in sedimentation rates. Both proxies document drastic changes in vegetation composition in the early Holocene with an increased number of trees and shrubs and the appearance of new tree taxa in the lake's vicinity. The sedaDNA method suggests that the Late Pleistocene steppe-tundra vegetation supported a higher number of terrestrial plant taxa than the forested Holocene. This could be explained, for example, by the "keystone herbivore" hypothesis, which suggests that Late Pleistocene megaherbivores were able to maintain a high plant diversity. This is discussed in the light of the data with the broadly accepted species-area hypothesis as steppe-tundra covered such an extensive area during the Late Pleistocene.
Selenium (Se) is known to contribute to several vital physiological functions in mammals: antioxidant defense, fertility, thyroid hormone metabolism, and immune response. Growing evidence indicates the crucial role of Se and Se-containing selenoproteins in the brain and brain function. As for the other essential trace elements, dietary Se needs to reach effective concentrations in the central nervous system (CNS) to exert its functions. To do so, Se-species have to cross the blood-brain barrier (BBB) and/or blood-cerebrospinal fluid barrier (BCB) of the choroid plexus. The main interface between the general circulation of the body and the CNS is the BBB. Endothelial cells of brain capillaries forming the so-called tight junctions are the primary anatomic units of the BBB, mainly responsible for barrier function. The current review focuses on Se transport to the brain, primarily including selenoprotein P/low-density lipoprotein receptor-related protein 8 (LRP8, also known as apolipoprotein E receptor-2) dependent pathway, and supplementary transport routes of Se into the brain via low molecular weight Se-species. Additionally, the potential role of Se and selenoproteins in the BBB, BCB, and neurovascular unit (NVU) is discussed. Finally, the perspectives regarding investigating the role of Se and selenoproteins in the gut-brain axis are outlined.
Both ground- and satellite-based airglow imaging have significantly contributed to understanding the low-latitude ionosphere, especially the morphology and dynamics of the equatorial ionization anomaly (EIA). The NASA Global-scale Observations of the Limb and Disk (GOLD) mission focuses on far-ultraviolet airglow images from a geostationary orbit at 47.5 degrees W. This region is of particular interest at low magnetic latitudes because of the high magnetic declination (i.e., about -20 degrees) and proximity of the South Atlantic magnetic anomaly. In this study, we characterize an exciting feature of the nighttime EIA using GOLD observations from October 5, 2018 to June 30, 2020. It consists of a wavelike structure of a few thousand kilometers seen as poleward and equatorward displacements of the EIA-crests. Initial analyses show that the synoptic-scale structure is symmetric about the dip equator and appears nearly stationary with time over the night. In quasi-dipole coordinates, maxima poleward displacements of the EIA-crests are seen at about +/- 12 degrees latitude and around 20 and 60 degrees longitude (i.e., in geographic longitude at the dip equator, about 53 degrees W and 14 degrees W). The wavelike structure presents typical zonal wavelengths of about 6.7 x 10(3) km and 3.3 x 10(3) km. The structure's occurrence and wavelength are highly variable on a day-to-day basis with no apparent dependence on geomagnetic activity. In addition, a cluster or quasi-periodic wave train of equatorial plasma depletions (EPDs) is often detected within the synoptic-scale structure. We further outline the difference in observing these EPDs from FUV images and in situ measurements during a GOLD and Swarm mission conjunction.
Mechanical behaviors of granite after thermal treatment under loading and unloading conditions
(2021)
Understanding the mechanical behaviors of granite after thermal treatment under loading and unloading conditions is of utmost relevance to deep geothermal energy recovery. In the present study, a series of loading and unloading triaxial compression tests (20, 40 and 60 MPa) on granite specimens after exposure to different temperatures (20, 200, 300, 400, 500 and 600 degrees C) was carried out to quantify the combined effects of thermal treatment and loading/unloading stress conditions on granite strength and deformation. Changes in the microstructure of granite exposed to high temperatures were revealed by optical microscopy. The experimental results indicate that both, thermal treatment and loading/unloading stress conditions, degrade the mechanical behaviors and further decrease the carrying capacity of granite. The gradual degradation of the mechanical characteristics of granite after thermal treatment is mainly associated with the evolution of thermal micro-cracks based on optical microscopy observations. The unloading stress state induces the extension of tension cracks parallel to the axial direction, and thus, the mechanical properties are degraded. Temperatures above 400 degrees C have a more significant influence on the mechanical characteristics of granite than the unloading treatment, whereby 400 degrees C can be treated as a threshold temperature for the delineation of significant deterioration. This study is expected to support feasibility and risk assessments by means of providing data for analytical calculations and numerical simulations on granite exposed to high temperatures during geothermal energy extraction.
This paper starts from the premise that Western states are connected to some of the harms refugees suffer from. It specifically focuses on the harm of acts of misrecognition and its relation to epistemic injustice that refugees suffer from in refugee camps, in detention centers, and during their desperate attempts to find refuge. The paper discusses the relation between hermeneutical injustice and acts of misrecognition, showing that these two phenomena are interconnected and that acts of misrecognition are particularly damaging when (a) they stretch over different contexts, leaving us without or with very few safe spaces, and (b) they dislocate us, leaving us without a community to turn to. The paper then considers the ways in which refugees experience acts of misrecognition and suffer from hermeneutical injustice, using the case of unaccompanied children at the well-known and overcrowded camp Moria in Greece, the case of unsafe detention centers in Libya, and the case of the denial to assistance on the Mediterranean and the resulting pushbacks from international waters to Libya as well as the preventable drowning of refugees in the Mediterranean to illustrate the arguments. Finally, the paper argues for specific duties toward refugees that result from the prior arguments on misrecognition and hermeneutical injustice.
The digitalization of public administration is increasingly moving forward. This systematic literature review analyzes empirical studies that explore the impacts of digitalization projects (n=93) in the public sector. Bibliometrically, only a few authors have published several times on this topic so far. Most studies focusing on impact come from the US or China, and are related to Computer Science. In terms of content, the majority of examined articles studies services to citizens, and therefore consider them when measuring impact. A classification of the investigated effects by dimensions of public value shows that the analysis of utilitarian-instrumental values, such as efficiency or performance, is prevalent. More interdisciplinary cooperation is needed to research the impact of digitalization in the public sector. The different dimensions of impact should be linked more closely. In addition, research should focus more on the effects of digitalization within administration.