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Speleothems, secondary cave carbonates, are important tools for climate reconstruction, especially as they often can be very precisely dated with the UTh method. If the U-Th method fails, dating becomes difficult, and often results in abandonment of samples and study sites. Radiocarbon dating is the only other radiometric dating technique applicable to the last similar to 50 ka, but presents complexities related to temporal variability of the reservoir effect in speleothems. Thus, radiocarbon dating of speleothems is not straightforward, and there are currently no publicly available tools to define proper age-depth relationships with this method. Here, we present an improved version of a previously published radiocarbon based age-depth modelling approach (star, Lechleitner et al., 2016b), which is now made freely available. The software is easy to use and provides the possibility to obtain reliable age-depth relationships, without prior knowledge of reservoir effects and their variability. In addition, star is able to detect and handle growth stops and phases with different growth rates. We test star on artificially constructed data sets and illustrate steps to improve the model performance. Furthermore, we apply the new approach to published radiocarbon data of U-Th dated stalagmites. This offers the possibility to investigate the strengths and weaknesses of the new approach with respect to potentially significant long term trends in the radiocarbon reservoir effect, which might otherwise remain undetected. In summary, we have produced a valuable software, which easily enables to construct age-depth relationships on the basis of reservoir effect disturbed radiocarbon measurements.
Marine Isotope Stage 3 (MIS 3, 57-27 ka) was characterised by numerous rapid climate oscillations (i.e., Dansgaard-Oeschger (D/O-) events), which are reflected in various climate archives. So far, MIS 3 speleothem records from central Europe have mainly been restricted to caves located beneath temperate Alpine glaciers or close to the Atlantic Ocean. Thus, MIS 3 seemed to be too cold and dry to enable speleothem growth north of the Alps in central Europe. Here we present a new speleothem record from Bunker Cave, Germany, which shows two distinct growth phases from 52.0 (+0.8, -0.5) to 50.9 (+0.6, -1.3) ka and 473 (+1.0, -0.6) to 42.8 (+/- 0.9) ka, rejecting this hypothesis. These two growth phases potentially correspond to the two warmest and most humid phases in central Europe during MIS 3, which is confirmed by pollen data from the nearby Eifel. The hiatus separating the two phases is associated with Heinrich stadial 5 (HS 5), although the growth stop precedes the onset of HS 5. The first growth phase is characterised by a fast growth rate, and Mg concentrations and Sr isotope data suggest high infiltration and the presence of soil cover above the cave. The second growth phase was characterised by drier, but still favourable conditions for speleothem growth. During this phase, the delta C-13 values show a significant decrease associated with D/O-event 12. The timing of this shift is in agreement with other MIS 3 speleothem data from Europe and Greenland ice core data. (C) 2018 Elsevier Ltd. All rights reserved.