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A fine-grained slope that exhibits slow movement rates was investigated to understand how geohydrological processes contribute to a consecutive development of mass movements in the Vorarlberg Alps, Austria. For that purpose intensive hydrometeorological, hydrogeological and geotechnical observations as well as surveying of surface movement rates were conducted during 1998–2001. Subsurface water dynamics at the creeping slope turned out to be dominated by a three-dimensional pressure system. The pressure reaction is triggered by fast infiltration of surface water and subsequent lateral water flow in the south-western part of the hillslope. The related pressure signal was shown to propagate further downhill, causing fast reactions of the piezometric head at 5Ð5 m depth on a daily time scale. The observed pressure reactions might belong to a temporary hillslope water body that extends further downhill. The related buoyancy forces could be one of the driving forces for the mass movement. A physically based hydrological model was adopted to model simultaneously surface and subsurface water dynamics including evapotranspiration and runoff production. It was possible to reproduce surface runoff and observed pressure reactions in principle. However, as soil hydraulic functions were only estimated on pedotransfer functions, a quantitative comparison between observed and simulated subsurface dynamics is not feasible. Nevertheless, the results suggest that it is possible to reconstruct important spatial structures based on sparse observations in the field which allow reasonable simulations with a physically based hydrological model. Copyright 2005 John Wiley & Sons, Ltd. KEY WORDS rainfall-induced landslides; soil creep; hydrological modelling; Vorarlberg; Austria; pressure propagation
We analyse different Gibbsian properties of interactive Brownian diffusions X indexed by the lattice $Z^{d} : X = (X_{i}(t), i ∈ Z^{d}, t ∈ [0, T], 0 < T < +∞)$. In a first part, these processes are characterized as Gibbs states on path spaces of the form $C([0, T],R)Z^{d}$. In a second part, we study the Gibbsian character on $R^{Z}^{d}$ of $v^{t}$, the law at time t of the infinite-dimensional diffusion X(t), when the initial law $v = v^{0}$ is Gibbsian.
The aim of this paper is to demonstrate that nonparametric smoothing methods for estimating functions can be an useful tool in the analysis of life time data. After stating some basic notations we will present a data example. Applying standard parametric methods to these data we will see that this approach fails - basic features of the underlying functions are not reflected by their estimates. Our proposal is to use nonparametric estimation methods. These methods are explained in section 2. Nonparametric approaches are better in the sense that they are more flexible, and misspecifications of the model are avoided. But, parametric models have the advantage that the parameters can be interpreted. So, finally, we will formulate a test procedure to check whether a parametric or a nonparametric model is appropriate.
We give a necessary and sufficient condition for the existence of an increasing coupling of N (N >= 2) synchronous dynamics on S-Zd (PCA). Increasing means the coupling preserves stochastic ordering. We first present our main construction theorem in the case where S is totally ordered; applications to attractive PCAs are given. When S is only partially ordered, we show on two examples that a coupling of more than two synchronous dynamics may not exist. We also prove an extension of our main result for a particular class of partially ordered spaces.
We first introduce some coupling of a finite number of Probabilistic Cellular Automata dynamics (PCA), preserving the stochastic ordering. Using this tool, for a general attractive probabilistic cellular automata on SZd, where S is finite, we prove that a condition (A) is equivalent to the (time-) convergence towards equilibrium of this Markovian parallel dynamics, in the uniform norm, exponentially fast. This condition (A) means the exponential decay of the influence from the boundary for the invariant measures of the system restricted to finite ‘box’-volume. For a class of reversible PCA dynamics on {−1, +1}Zd , with a naturally associated Gibbsian potential ϕ, we prove that a Weak Mixing condition for ϕ implies the validity of the assumption (A); thus the ‘exponential ergodicity’ of the dynamics towards the unique Gibbs measure associated to ϕ holds. On some particular examples of this PCA class, we verify that our assumption (A) is weaker than the Dobrushin-Vasershtein ergodicity condition. For some special PCA, the ‘exponential ergodicity’ holds as soon as there is no phase transition.
The two and k-sample tests of equality of the survival distributions against the alternatives including cross-effects of survival functions, proportional and monotone hazard ratios, are given for the right censored data. The asymptotic power against approaching alternatives is investigated. The tests are applied to the well known chemio and radio therapy data of the Gastrointestinal Tumor Study Group. The P-values for both proposed tests are much smaller then in the case of other known tests. Differently from the test of Stablein and Koutrouvelis the new tests can be applied not only for singly but also to randomly censored data.
The article starts with an overview of modernization theories, its history of ups and downs as well as its present status. This first part is followed by an analysis of basic social structure distributions and trends in human development in selected countries. One major focal point of the paper is the Non-Western world and the Arab countries, in particular. The author looks at modernization and modernity in that region and comes to the conclusion that the Western world can no longer expect to be able to simply export its own values and its way of life to the rest of the world.
This paper offers a new theoretical framework for studying the problem of generations and social change in contemporary Iran. It offers a model which is called „articulation of cultural modes“. The paper agrees with Ronald Inglehart that ‘culture’ is now playing a more dominant role in the social formation of current societies, as ‘technology’ once did in the modern era. But it goes one step further by arguing that culture cannot be approached as a holistic concept building on a comprehensive theoretical framework.
For the first time when the new Islamic councils began their Operation, many intellectuals and politicians proclaimed that there would be no room for the young Islamic councils to proceed. In political terms, because of the new challenges between the rightists and leftists, many people had no hope to see the results of the councils. Still others believed that under the dominating ruling system of Iran there is no space for public opinion and participation in local decision-making. This paper focuses on the role of the Islamic Councils as a new form of social democracy, which decentralizes power and creates good local governance. The paper also discusses the obstacles for the Councils in the development of the region.
Executive responsibility for EU policies is by tradition delegated to the member states and their internal administrative bodies. It is therefore of outmost importance that the new Central and East European members have the capacity to administer the acquis communitaire once they are full members of the EU. Based on a survey among current and former top-level decision-makers (ministers), this article argues that although there are significant implementation problems, efficiency gains can be made through administrative reform and not the least education aimed at changing the worldview and knowledge of the individual civil servant. However, there seem to be significant differences in how these countries tackle implementation problems and administrative reform.
Berlin : look to the world!
(2004)
In the spring 2004 issue of WeltTrends, Professor Gunther Hellmann made a „plea for offensive idealism“ and „against the power political resocialization of German foreign policy“. To a long-time outside observer of that foreign policy, this plea is unsurprising, but depressing. In keeping with Professor Hellmann’s own willingness, „notwendige Differenzierungen [zu] vernachlässigen zugunsten einer bewussten Zuspitzung“ I will comment on the aspects of his argument that strike an American colleague as particularly disturbing.
Taking its departure from the debate on the Iraq war, the article examines three so-called „doctrines“ on European foreign policy. According to the first one, there is no such thing as an EU foreign policy. This may come as a surprise for policy-makers but is a common view among media commentators, analysts and some diplomats. The second doctrine holds that the EU’s foreign policy has been, is, and always will be a failure. Reasons for this gloomy view show considerable variations and are most likely unsustainable in the long run. The third approach is more optimistic, counting on the EU’s material volume, yet often ignoring the need to politically cash in if international clout is the quest.
My essay attends to a number of passages in Alexander von Humboldt’s Personal Narrative in which the Prussian explorer expresses anxiety about the apparent dangers posed by the overwhelmingly productive tropical landscapes he observes. In these passages, the excesses of an “exotic nature” threaten European identity and modes of civilization—and they trouble the accuracy of Humboldt’s own observational project. I also explore Humboldt’s related worry that South American vegetable (and visual) overload will exert a destabilizing effect on his aesthetic sensibility, disrupting his ability to represent the “New Continent” accurately in writing. Finally, I sketch the influence of Humboldt’s representations of tropical excess on nineteenth-century British cultural thought and literary practice. Studying the instabilities experienced by Personal Narrative’s expatriates and colonists promises to draw out important tensions latent in Humboldt’s treatment of tropical landscape and to illuminate broader epistemological and aesthetic shifts being worked out during the period.
This document presents the results of the seminar "Coneptual Arachitecture Patterns" of the winter term 2002 in the Hasso-Plattner-Institute. It is a compilation of the student's elaborations dealing with some conceptual architecture patterns which can be found in literature. One important focus laid on the runtime structures and the presentation of the patterns. 1. Introduction 1.1. The Seminar 1.2. Literature 2 Pipes and Filters (André Langhorst and Martin Steinle) 3 Broker (Konrad Hübner and Einar Lück) 4 Microkernel (Eiko Büttner and Stefan Richter) 5 Component Configurator (Stefan Röck and Alexander Gierak) 6 Interceptor (Marc Förster and Peter Aschenbrenner) 7 Reactor (Nikolai Cieslak and Dennis Eder) 8 Half–Sync/Half–Async (Robert Mitschke and Harald Schubert) 9 Leader/Followers (Dennis Klemann and Steffen Schmidt)
This document is an analysis of the 'Java Language Conversion Assistant'. Itr will also cover a language analysis of the Java Programming Language as well as a survey of related work concerning Java and C# interoperability on the one hand and language conversion in general on the other. Part I deals with language analysis. Part II covers the JLCA tool and tests used to analyse the tool. Additionally, it gives an overview of the above mentioned related work. Part III presents a complete project that has been translated using the JLCA.
The Apache Modeling Project
(2004)
This document presents an introduction to the Apache HTTP Server, covering both an overview and implementation details. It presents results of the Apache Modelling Project done by research assistants and students of the Hasso–Plattner–Institute in 2001, 2002 and 2003. The Apache HTTP Server was used to introduce students to the application of the modeling technique FMC, a method that supports transporting knowledge about complex systems in the domain of information processing (software and hardware as well). After an introduction to HTTP servers in general, we will focus on protocols and web technology. Then we will discuss Apache, its operational environment and its extension capabilities— the module API. Finally we will guide the reader through parts of the Apache source code and explain the most important pieces.
Content: 1 The Typology 1.1 Object Placement 2 Treatment of StG in terms of LF Movement – with and without Head Movement 3 An OT-solution in terms of linearisation (‘LF-to-PF-Mapping’) 3.1 The trigger for additional orders: Focus 3.2 Competitions 3.3 Summary 4 RP 4.1 LF Movement – with and without Head Movement 4.2 The OT-account for RP 4.3 Competitions 5 Summary
Content: 0 Introduction 1 Elements that block verb raising – a discussion 1.1 Haider’s observation 1.2 The other constructions 1.3 A possible explanation 1.4 Riemsdijk’s grafting approach as a possible alternative? 1.5 Intermediate Summary 2 Parsing problems with speech act adverbials in the pre-field
Content: 1 Introduction 2 A restrictive theory of head movement 2.1 Preliminary Remarks 2.2 Theoretical Problems of Head Movement 2.3 Remnant Phrasal Movement 2.4 Münchhausen Style Head Movement 3 Verb Second Movement 3.1 Introductory Remarks 3.2 Problems of V/2 constructions: Does V really move to Comp? 3.3 The preverbal position 3.4 The Second Position 4 References
We study mixed boundary value problems for an elliptic operator A on a manifold X with boundary Y , i.e., Au = f in int X, T±u = g± on int Y±, where Y is subdivided into subsets Y± with an interface Z and boundary conditions T± on Y± that are Shapiro-Lopatinskij elliptic up to Z from the respective sides. We assume that Z ⊂ Y is a manifold with conical singularity v. As an example we consider the Zaremba problem, where A is the Laplacian and T− Dirichlet, T+ Neumann conditions. The problem is treated as a corner boundary value problem near v which is the new point and the main difficulty in this paper. Outside v the problem belongs to the edge calculus as is shown in [3]. With a mixed problem we associate Fredholm operators in weighted corner Sobolev spaces with double weights, under suitable edge conditions along Z \ {v} of trace and potential type. We construct parametrices within the calculus and establish the regularity of solutions.
Green operators on manifolds with edges are known to be an ingredient of parametrices of elliptic (edge-degenerate) operators. They play a similar role as corresponding operators in boundary value problems. Close to edge singularities the Green operators have a very complex asymptotic behaviour. We give a new characterisation of Green edge symbols in terms of kernels with discrete and continuous asymptotics in the axial variable of local model cones.
The ellipticity of operators on a manifold with edge is defined as the bijectivity of the components of a principal symbolic hierarchy σ = (σψ, σ∧), where the second component takes value in operators on the infinite model cone of the local wedges. In general understanding of edge problems there are two basic aspects: Quantisation of edge-degenerate operators in weighted Sobolev spaces, and verifying the elliptcity of the principal edge symbol σ∧ which includes the (in general not explicitly known) number of additional conditions on the edge of trace and potential type. We focus here on these queations and give explicit answers for a wide class of elliptic operators that are connected with the ellipticity of edge boundary value problems and reductions to the boundary. In particular, we study the edge quantisation and ellipticity for Dirichlet-Neumann operators with respect to interfaces of some codimension on a boundary. We show analogues of the Agranovich-Dynin formula for edge boundary value problems, and we establish relations of elliptic operators for different weights, via the spectral flow of the underlying conormal symbols.
We prove the existence of sectors of minimal growth for general closed extensions of elliptic cone operators under natural ellipticity conditions. This is achieved by the construction of a suitable parametrix and reduction to the boundary. Special attention is devoted to the clarification of the analytic structure of the resolvent.
We study the Neumann problem for the de Rham complex in a bounded domain of Rn with singularities on the boundary. The singularities may be general enough, varying from Lipschitz domains to domains with cuspidal edges on the boundary. Following Lopatinskii we reduce the Neumann problem to a singular integral equation of the boundary. The Fredholm solvability of this equation is then equivalent to the Fredholm property of the Neumann problem in suitable function spaces. The boundary integral equation is explicitly written and may be treated in diverse methods. This way we obtain, in particular, asymptotic expansions of harmonic forms near singularities of the boundary.
Given a system of entire functions in Cn with at most countable set of common zeros, we introduce the concept of zeta-function associated with the system. Under reasonable assumptions on the system, the zeta-function is well defined for all s ∈ Zn with sufficiently large components. Using residue theory we get an integral representation for the zeta-function which allows us to construct an analytic extension of the zeta-function to an infinite cone in Cn.
Contents: Chapter 6: Elliptic Theory on Manifolds with Edges Introduction 6.1. Motivation and Main Constructions 6.1.1. Manifolds with edges 6.1.2. Edge-degenerate differential operators 6.1.3. Symbols 6.1.4. Elliptic problems 6.2. Pseudodifferential Operators 6.2.1. Edge symbols 6.2.2. Pseudodifferential operators 6.2.3. Quantization 6.3. Elliptic Morphisms and the Finiteness Theorem 6.3.1. Matrix Green operators 6.3.2. General morphisms 6.3.3. Ellipticity, Fredholm property, and smoothness Appendix A. Fiber Bundles and Direct Integrals A.1. Local theory A.2. Globalization A.3. Versions of the Definition of the Norm
Edge representations of operators on closed manifolds are known to induce large classes of operators that are elliptic on specific manifolds with edges, cf. [9]. We apply this idea to the case of boundary value problems. We establish a correspondence between standard ellipticity and ellipticity with respect to the principal symbolic hierarchy of the edge algebra of boundary value problems, where an embedded submanifold on the boundary plays the role of an edge. We first consider the case that the weight is equal to the smoothness and calculate the dimensions of kernels and cokernels of the associated principal edge symbols. Then we pass to elliptic edge operators for arbitrary weights and construct the additional edge conditions by applying relative index results for conormal symbols.
In this article we study the geometry associated with the sub-elliptic operator ½ (X²1 +X²2), where X1 = ∂x and X2 = x²/2 ∂y are vector fields on R². We show that any point can be connected with the origin by at least one geodesic and we provide an approximate formula for the number of the geodesics between the origin and the points situated outside of the y-axis. We show there are in¯nitely many geodesics between the origin and the points on the y-axis.
Contents: Chapter 7: The Index Problemon Manifolds with Singularities Preface 7.1. The Simplest Index Formulas 7.1.1. General properties of the index 7.1.2. The index of invariant operators on the cylinder 7.1.3. Relative index formulas 7.1.4. The index of general operators on the cylinder 7.1.5. The index of operators of the form 1 + G with a Green operator G 7.1.6. The index of operators of the form 1 + G on manifolds with edges 7.1.7. The index on bundles with smooth base and fiber having conical points 7.2. The Index Problem for Manifolds with Isolated Singularities 7.2.1. Statement of the index splitting problem 7.2.2. The obstruction to the index splitting 7.2.3. Computation of the obstruction in topological terms 7.2.4. Examples. Operators with symmetries 7.3. The Index Problem for Manifolds with Edges 7.3.1. The index excision property 7.3.2. The obstruction to the index splitting 7.4. Bibliographical Remarks
We study the dynamics of four wave interactions in a nonlinear quantum chain of oscillators under the "narrow packet" approximation. We determine the set of times for which the evolution of decay processes is essentially specified by quantum effects. Moreover, we highlight the quantum increment of instability.
For each compact subset K of the complex plane C which does not surround zero, the Riemann surface Sζ of the Riemann zeta function restricted to the critical half-strip 0 < Rs < 1/2 contains infinitely many schlicht copies of K lying ‘over’ K. If Sζ also contains at least one such copy, for some K which surrounds zero, then the Riemann hypothesis fails.
Let X be a smooth n -dimensional manifold and D be an open connected set in X with smooth boundary ∂D. Perturbing the Cauchy problem for an elliptic system Au = f in D with data on a closed set Γ ⊂ ∂D we obtain a family of mixed problems depending on a small parameter ε > 0. Although the mixed problems are subject to a non-coercive boundary condition on ∂D\Γ in general, each of them is uniquely solvable in an appropriate Hilbert space DT and the corresponding family {uε} of solutions approximates the solution of the Cauchy problem in DT whenever the solution exists. We also prove that the existence of a solution to the Cauchy problem in DT is equivalent to the boundedness of the family {uε}. We thus derive a solvability condition for the Cauchy problem and an effective method of constructing its solution. Examples for Dirac operators in the Euclidean space Rn are considered. In the latter case we obtain a family of mixed boundary problems for the Helmholtz equation.
Ellipticity of operators on manifolds with conical singularities or parabolicity on space-time cylinders are known to be linked to parameter-dependent operators (conormal symbols) on a corresponding base manifold. We introduce the conormal symbolic structure for the case of corner manifolds, where the base itself is a manifold with edges and boundary. The specific nature of parameter-dependence requires a systematic approach in terms of meromorphic functions with values in edge-boundary value problems. We develop here a corresponding calculus, and we construct inverses of elliptic elements.
Phase synchronization analysis, including our recently introduced multivariate approach, is applied to event-related EEG data from an experiment on language processing, following a classic psycholinguistic paradigm. For the two types of experimental manipulation distinct effects in overall synchronization are found; for one of them they can also be localized. The synchronization effects occur earlier than those found by the conventional analysis method, indicating that the new approach provides additional information on the underlying neuronal process.
A method for the multivariate analysis of statistical phase synchronization phenomena in empirical data is presented. A first statistical approach is complemented by a stochastic dynamic model, to result in a data analysis algorithm which can in a specific sense be shown to be a generic multivariate statistical phase synchronization analysis. The method is applied to EEG data from a psychological experiment, obtaining results which indicate the relevance of this method in the context of cognitive science as well as in other fields.
We present different tests for phase synchronization which improve the procedures currently used in the literature. This is accomplished by using a two-samples test setup and by utilizing insights and methods from directional statistics and bootstrap theory. The tests differ in the generality of the situation in which they can be applied as well as in their complexity, including computational cost. A modification of the resampling technique of the bootstrap is introduced, making it possible to fully utilize data from time series.
How do children determine the syntactic category of novel words? In this article we present the results of 2 experiments that investigated whether German children between 12 and 16 months of age can use distributional knowledge that determiners precede nouns and subject pronouns precede verbs to syntactically categorize adjacent novel words. Evidence from the head-turn preference paradigm shows that, although 12- to 13-month-olds cannot do this, 14- to 16-month-olds are able to use a determiner to categorize a following novel word as a noun. In contrast, no categorization effect was found for a novel word following a subject pronoun. To understand this difference we analyzed adult child-directed speech. This analysis showed that there are in fact stronger co-occurrence relations between determiners and nouns than between subject pronouns and verbs. Thus, in German determiners may be more reliable cues to the syntactic category of an adjacent novel word than are subject pronouns. We propose that the capacity to syntactically categorize novel words, demonstrated here for the first time in children this young, mediates between the recognition of the specific morphosyntactic frame in which a novel word appears and the word-to-world mapping that is needed to build up a semantic representation for the novel word.
Table of contens 1 Introduction 2 The concept of sustainability 2.1 Ecological sustainability 2.2 Social sustainability 2.3 Economic sustainability 2.4 The sustainability strategy of the german government 3 Effects of energy use on the enviromment 4 Requirements of the SSGG for energy policy 4.1 Ecological implications of thr SSGG 4.2 Social and economic requirements of the SSGG 5 The German Renewable Energies Act 5.1 Objectives 5.2 Design and mechanisms 5.3 Fees-in tariffs 6 Does the EEG meet the sustainability requirements of the SSGG? 6.1 Management rules 6.2 Social sustainability 6.3 Economic sustainability 6.4 Development tendencis 7 Possible amendments for more sustainability 7.1 Changing the promotional system 7.2 A European regulation
Social segregation in cities takes place where different household groups exist and when, according to Schelling, their location choice either minimizes the number of differing households in their neighborhood or maximizes their own group. In this contribution an evolutionary simulation based on a monocentric city model with externalities among households is used to discuss the spatial segregation patterns of four groups. The resulting complex spatial patterns can be shown as graphic animations. They can be applied as initial situation for the analysis of the effects a rent control has on segregation.
Optimal spatial patterns of two, three and four segregated household groups in a monocentric city
(2004)
Usually, in monocentric city models the spatial patterns of segregated household groups are assumed to be ring-shaped, while early in the 1930ies Hoyt showed that wedge-shaped areas empirically predominate. This contribution presents a monocentric city model with different household groups generating positive externalities within the groups. At first, border length is founded as a criterion of optimality. Secondly, it is shown that mixed patterns of concentric and wedge-shaped areas represent multiple equilibria if more than two groups of households are being considered. The welfare optimal segregated pattern depends on the relative purchasing power of different household groups.
Usually, in monocentric city models, the spatial patterns of segregated ethnic groups are assumed to be ring-shaped, whereas in the 1930ies Hoyt showed that empirically wedge-shaped areas predominate. In contrast to Rose-Ackerman.s discussion of the in.uence within a ring-shaped pattern which the aversion which different households in the context of racism have, Yinger showed that, depending on the population mix, a wedge-shaped pattern may arise if it is border length which causes the spatial pattern. In this contribution, a simulation based on a monocentric city model with two or more different household groups is used to derive spatial patterns. Wedge-shaped segregation is shown to be the result of positive externalities among similar households. Differences between households only lead to ring-shaped patterns if the e¤ect of a city center on spatial structure dominates neighborhood e¤ects. If more than two groups of households are being considered, mixed patterns of concentric and wedge-shaped areas arise.
Economy vs. history
(2004)
The aim of this study is to examine in which cases economic forces or historical singularities prevail in the determination of the long-run distribution of firms. We develop a relatively general model of heterogenous firms' location choice in discrete space. The main force towards an agglomerated structure is the reduction of transaction costs for consumers if firms are located closely, whilst competition and transport costs work towards a more disperse structure. We then assess the importance of the initial conditions by simulating and comparing the resulting distribution of firms for identical economic parameters but varying initial settings. If the equilibrium distributions of firms are similar we conclude that economic forces have prevailed, while differences in the resulting distributions indicate that 'history' is more important. The (dis)similarity of distributions of firms is calculated by means of a measure, which exhibits a number of desirable features.
In the recent years there are many researchs discussing the effects of trade policy (tariffs, subsidies etc.) in international trade. The results are manifold. Some authors show that trade policy has negative effects on welfare, some spatial economists demonstrate that trade policy can have positive effects on welfare. This paper considers the effects of the trade policy made by both countries participating in international trade in a spatial economic model. It can be showed that trade policy of both trade partners (tariffs of one country and export subsidies of the other country) can improve the world welfare in comparison with free trade.
Table of contents 1 Introduction 2 Ecological regulation and cost effectiveness 2.1 Climate policy 2.2 Promotion of renewable energies 3 Ecological regulation and security of supply 3.1 Climate policy 3.2 Promotion of renewable energies 4 The German Renewable Energies Act (EEG) 4.1 Objectives 4.2 Design and mechanisms 5 The European emissions trading system (EETS) 5.1 Objectives 5.2 Framework 6 The EEG and the EETS: trade off between ecological objectivesand cost effectiveness, innovation and security of supply? 6.1 EEG 6.2 EETS 6.3 Comparison between the approaches of the EEG and the EETS 7 Conclusions and outlook
Contents: Introduction Experimental Techniques: The LIF demonstrator unit - The LIF demonstrator unit - The mobile LIF spectrometer OPTIMOS - Investigated petroleum products and soil samples Results and Discussion: Photophysical properties of the petroleum products LIF spectroscopic investigations of oil-spiked samples LIF spectroscopic investigations of real-world soils Conclusions
The drift time spectra of polycyclic aromatic hydrocarbons (PAH), alkylbenzenes and alkylphenylethers were recorded with a laser-based ion mobility (IM) spectrometer. The ion mobilities of all compounds were determined in helium as drift gas. This allows the calculation of the diffusion cross sections (Omegacalc) on the basis of the exact hard sphere scattering model (EHSSM) and their comparison with the experimentally determined diffusion cross sections (Omegaexp). These Omegaexp/Omegacalc-correlations are presented for molecules with a rigid structure like PAH and prove the reliability of the theoretical model and experimental method. The increase of the selectivity of IM spectrometry is demonstrated using resonance enhanced multiphoton ionisation (REMPI) at atmospheric pressure, realized by tuneable lasers. The REMPI spectra of nine alkylbenzenes and alkylphenylethers are investigated. On the basis of these spectra, the complete qualitative distinction of eight compounds in a mixture is shown. These experiments are extended to alkylbenzene isomer mixtures.
Contents: 1. Introduction 2. Migration and Assimilation – Theoretical Approaches 2.1 Meaning and Definition of the Terms Migration and Migrant 2.2 Milton M. Gordon – Sub Processes of Assimilation 2.3 Hartmut Esser - Acculturation, Integration, and Assimilation 2.4 The Concept of Integration and Assimilation 2.5 Straight–line Assimilation and its Implications 2.6 Segmented Assimilation and its Implications 3. Social Inequality and Welfare – Theoretical Approaches 3.1 Dimensions of Inequality 3.2 Welfare Regimes and Social Inequality 3.3 Migration, Assimilation and Inequality 4. Research Design 4.1 Research Question and General Proceeding 4.2 Sample and Data Base 4.3 Operationalisation and Indicators 5. Migration, Welfare and Inequality in Three European Countries 6. Empirical Results 6.1 Performance of Migrants Compared With Natives 6.2 Different Trajectories of Assimilation 6.3 Trajectories of Segmented Assimilation and their Determinants 6.4 Policies, Attitudes and Assimilation – An Aggregate Analysis 6.5 Summary – What Determines the Performance of Migrants? 7. Discussion of Empirical Results in Terms of Theoretical Approaches 7.1 The Situation of Migrants in Three European Countries 7.2 Assessment of the Trajectories of Assimilation 8. Conclusion – Future Prospects of Migration in Europe
This volume offers new arguments and perspectives in the ongoing debate about the optimal analysis of verb movement, mainly, but not exclusively, in German. Fanselow and Meinunger deal with verb second (V2) movement in German main clauses. Fanselow argues that head movement of the substitution type follows the standard minimalist conceptions of Merge and Move and is therefore not subject to the same objections as head movement as head adjunction which violates Chomsky's minimalist extension condition, operates countercyclically, and fails to let the moved head c-command its trace. Fanselow argues for V2 movement as head movement of the substitution type. Meinunger discusses a restriction on V2 movement imposed by phrases like "mehr als" ('more than'), as in "Der Wert hat sich weit mehr als verdreifacht" ('the value has far more than tripled') where V2 movement is ruled out (cf. *"Der Wert verdreifachte sich mehr als"). Meinunger claims that this restriction is best analysed in phonological terms: the preposition/complementiser "als" acts as a prefixal clitic to its host, the finite verb, which therefore may not move without it. With respect to the V2 debate, Meinunger argues for an interface perspective. He shows that V2 is restricted from both the conceptual and the phonological interface. Vogel, finally, discusses the syntax of clause-final verbal complexes and their dialectal variation in German. He compares three different syntactic analyses, a minimalist head movement analysis, a minimalist XP movement analysis, and an Optimality theoretic PF movement analysis. The three accounts are evaluated relative to the additional assumptions they have to make, the complications they face and how they fit the observations. Vogel argues in favour of the phonologically oriented OT analysis because of its ability to create a direct link between the coming about of a particular word order pattern and its basically phonological trigger. Each of the three papers recognises the relevance of surface forms in the analysis of German verb movement. They differ, however in the extent to which phonological aspects take part in the explanations they offer.
The performance of a home-built tunable diode laser (TDL) spectrometer, aimed at multi-line detection of carbon dioxide, has been evaluated and optimized. In the regime of the (30<SUP>0</SUP>1)<SUB>III</SUB> / (000) band of <SUP>12</SUP>CO<SUB>2</SUB> around 1.6 μm, the dominating isotope species <SUP>12</SUP>CO<SUB>2</SUB>, <SUP>13</SUP>CO<SUB>2</SUB>, and <SUP>12</SUP>C<SUP>18</SUP>O<SUP>16</SUP>O were detected simultaneously without interference by water vapor. Detection limits in the range of few ppmv were obtained for each species utilizing wavelength modulation (WM) spectroscopy with balanced detection in a long-path absorption cell set-up. High sensitivity in conjunction with high precision —typically ±1‰ and ±6‰ for 3% and 0.7% of CO<SUB>2</SUB>, respectively— renders this experimental approach a promising analytical concept for isotope-ratio determination of carbon dioxide in soil and breath gas. For a moderate <SUP>12</SUP>CO<SUB>2</SUB> line, the pressure dependence of the line profile was characterized in detail, to account for pressure effects on sensitive measurements.
The performance of a home-built tunable diode laser (TDL) spectrometer has been optimized regarding multi-line detection of carbon dioxide in natural gases. In the regime of the (30<SUP>0</SUP>1)<SUB>III</SUB> ← (000) band of <SUP>12</SUP>CO<SUB>2</SUB> around 1.6 μm, the dominating isotope species <SUP>12</SUP>CO<SUB>2</SUB>, <SUP>13</SUP>CO<SUB>2</SUB>, and <SUP>12</SUP>C<SUP>18</SUP>O<SUP>16</SUP>O were detected simultaneously. In contrast to most established techniques, selective measurements are performed without any sample preparation. This is possible since the CO<SUB>2</SUB> detection is free of interference from water, ubiquitous in natural gases. Detection limits in the range of a few ppmv were obtained for each species utilizing wavelength modulation (WM) spectroscopy with balanced detection in a long-path absorption cell set-up. Linear calibration plots cover a dynamic range of four orders of magnitude, allowing for quantitative CO<SUB>2</SUB> detection in various samples, like soil and breath gas. High isotopic resolution enables the excellent selectivity, sensitivity, and stability of the chosen analytical concept. The obtained isotopic resolution of typically ± 1.0 ‰ and ± 1.5 ‰ (for 3 vol. % and 0.7 vol. % of CO<SUB>2</SUB>, respectively) offers a promising analytical tool for isotope-ratio determination of carbon dioxide in soil gas. Preliminary experiments on soil respiration for the first time combine the on-line quantification of the overall carbon dioxide content with an optode sensor and isotopic determination (TDL system) of natural gas species.
Islamic movements in Iran
(2004)
The modernist Islamic Movement sought to reconcile modern values and Islamic faith and attempted to express these values through an Islamic discourse and to reform political, religious and educational institutions along modernist lines. However, such a movement in the Islamic Republic of Iran raised controversy among the traditional leadership and secular intellectual groups. The aim of this paper is to discuss how far modernist Islam could progress in an islamic republic with an old tradition.
Revisiting public investment
(2004)
The consumption equivalence method is the theoretical basis of public cost-benefit analysis. Consumption equivalence public capital prices are explicitly introduces in order to sufficiently care for the opportunity cost of public expenditure. This can solve the dispute about the social rate of discount within public cost-benefit analysis witch was generated on a criterion looking similar to the capital value formula, known as Lind’s approach. The social rate of discount is liberated from opportunity costs considerations and the discounting away of the effects for future welfare vanishes. The corresponding question whether one should accept a positive value of the pure rate of social time preference is an old issue. Its current state between the prescriptive and descriptive view can also be interpreted as a consequence of the oversimplification of standard cost– benefit analysis. But apart from an economic self-process the pure rate of social time preference is also defined as a business-as-usual value of social distance discounting. Hence, a political choice has to be made about this rate which is free in principal.
An exhaustive and disjoint decomposition of social choice situations is derived in a general set theoretical framework using the new tools of the Lifted Pareto relation on the power set of social states representing a pre-choice comparison of choice option sets. The main result is the classification of social choice situations which include three types of social choice problems. First, we usually observe the common incompleteness of the Pareto relation. Second, a kind of non-compactness problem of a choice set of social states can be generated. Finally, both can be combined. The first problem root can be regarded as natural everyday dilemma of social choice theory whereas the second may probably be much more due to modeling technique implications. The distinction is enabled at a very general set theoretical level. Hence, the derived classification of social choice situations is applicable on almost every relevant economic model.
Contents: Actors, Markets and Interest Groups in Health Services Private and Social Health Insurance in a Simple Model Misallocation and Malpractice in Social Health Care and Insurances -The UK Health Care System -The German Social Health Insurance System -Current Discussions: Intertemporal Perspective and Fundamental Change Interplay of Public and Private Health Insurance: Lessons for Countries in Transition Summary: The Necessary Steps to a Fundamental Reform
Contents: Targets, Means and Benefits of Social Protection Standard Risks and Possible Institutional Settings for Social Protection -Market Structure for Pension and Health Insurance -Systems of Social Protection and Security -Replacement Ratios and Income Taxation Social Protection in Selected European Countries: Germany, Austria, The Netherlands, United Kingdom -Pension System -Health System -Unemployment Insurance -Accident Insurance -Basic Security System -Taxation of Wages and Profits The Overall Burden of Taxes and Social Protection Expenses Necessary Reforms, Lessons for Russia and a Basic Approach for a Blueprint -Basic Features of the Reform Process -Reforms within the Branches of Social Protection -Integrated Tax and Transfer Reform -Empirical Evaluation of Tax and Transfer Reforms
ANNIS
(2004)
In this paper, we discuss the design and implementation of our first version of the database "ANNIS" ("ANNotation of Information Structure"). For research based on empirical data, ANNIS provides a uniform environment for storing this data together with its linguistic annotations. A central database promotes standardized annotation, which facilitates interpretation and comparison of the data. ANNIS is used through a standard web browser and offers tier-based visualization of data and annotations, as well as search facilities that allow for cross-level and cross-sentential queries. The paper motivates the design of the system, characterizes its user interface, and provides an initial technical evaluation of ANNIS with respect to data size and query processing.
Focus strategies in chadic
(2004)
We argue that the standard focus theories reach their limits when confronted with the focus systems of the Chadic languages. The backbone of the standard focus theories consists of two assumptions, both called into question by the languages under consideration. Firstly, it is standardly assumed that focus is generally marked by stress. The Chadic languages, however, exhibit a variety of different devices for focus marking. Secondly, it is assumed that focus is always marked. In Tangale, at least, focus is not marked consistently on all types of constituents. The paper offers two possible solutions to this dilemma.
In this paper we review the current state of research on the issue of discourse structure (DS)/information structure (IS) interface. This field has received a lot of attention from discourse semanticists and pragmatists, and has made substantial progress in recent years. In this paper we summarize the relevant studies. In addition, we look at the issue of DS/ISinteraction at a different level - that of phonetics. It is known that both information structure and discourse structure can be realized prosodically, but the issue of phonetic interaction between the prosodic devices they employ has hardly ever been discussed in this context. We think that a proper consideration of this aspect of DS/IS-interaction would enrich our understanding of the phenomenon, and hence we formulate some related research-programmatic positions.
Prosody by phase
(2004)
Japanese wh-questions always exhibit focus intonation (FI). Furthermore, the domain of FI exhibits a correspondence to the wh-scope. I propose that this phonology-semantics correspondence is a result of the cyclic computation of FI, which is explained under the notion of Multiple Spell-Out in the recent Minimalist framework. The proposed analysis makes two predictions: (1) embedding of an FI into another is possible; (2) (overt) movement of a wh-phrase to a phase edge position causes a mismatch between FI and wh-scope. Both predictions are tested experimentally, and shown to be borne out.
We argue that there is a crucial difference between determiner and adverbial quantification. Following Herburger [2000] and von Fintel [1994], we assume that determiner quantifiers quantify over individuals and adverbial quantifiers over eventualities. While it is usually assumed that the semantics of sentences with determiner quantifiers and those with adverbial quantifiers basically come out the same, we will show by way of new data that quantification over events is more restricted than quantification over individuals. This is because eventualities in contrast to individuals have to be located in time which is done using contextual information according to a pragmatic resolution strategy. If the contextual information and the tense information given in the respective sentence contradict each other, the sentence is uninterpretable. We conclude that this is the reason why in these cases adverbial quantification, i.e. quantification over eventualities, is impossible whereas quantification over individuals is fine.
This paper investigates the nature of the attraction of XPs to clauseinitial position in German (and other languages). It argues that there are two different types of preposing. First, an XP can move when it is attracted by an EPP-like feature of Comp. Comp can, however, also attract elements that bear the formal marker of some semantic or pragmatic (information theoretic) function. This second type of movement is driven by the attraction of a formal property of the moved element. It has often been misanalysed as “operator” movement in the past. Japanese wh-questions always exhibit focus intonation (FI). Furthermore, the domain of FI exhibits a correspondence to the wh-scope. I propose that this phonology-semantics correspondence is a result of the cyclic computation of FI, which is explained under the notion of Multiple Spell-Out in the recent Minimalist framework. The proposed analysis makes two predictions: (1) embedding of an FI into another is possible; (2) (overt) movement of a wh-phrase to a phase edge position causes a mismatch between FI and wh-scope. Both predictions are tested experimentally, and shown to be borne out.
Results of a production experiment on the placement of sentence accent in German are reported. The hypothesis that German fulfills some of the most widely accepted rules of accent assignment— predicting focus domain integration—was only partly confirmed. Adjacency between argument and verb induces a single accent on the argument, as recognized in the literature, but interruption of this sequence by a modifier often induces remodeling of the accent pattern with a single accent on the modifier. The verb is rarely stressed. All models based on linear alignment or adjacency between elements belonging to a single accent domain fail to account for this result. A cyclic analysis of prosodic domain formation is proposed in an optimality-theoretic framework that can explain the accent pattern. Japanese wh-questions always exhibit focus intonation (FI). Furthermore, the domain of FI exhibits a correspondence to the wh-scope. I propose that this phonology-semantics correspondence is a result of the cyclic computation of FI, which is explained under the notion of Multiple Spell-Out in the recent Minimalist framework. The proposed analysis makes two predictions: (1) embedding of an FI into another is possible; (2) (overt) movement of a wh-phrase to a phase edge position causes a mismatch between FI and wh-scope. Both predictions are tested experimentally, and shown to be borne out.
Interdisciplinary studies on information structure : ISIS ; working papers of the SFB 632. - Vol. 1
(2004)
Contents: A1: Phonology and syntax of focussing and topicalisation: Gisbert Fanselow: Cyclic Phonology–Syntax-Interaction: Movement to First Position in German Caroline Féry and Laura Herbst: German Sentence Accent Revisited Shinichiro Ishihara: Prosody by Phase: Evidence from Focus Intonation–Wh-scope Correspondence in Japanese A2: Quantification and information structure: Cornelia Endriss and Stefan Hinterwimmer: The Influence of Tense in Adverbial Quantification A3: Rhetorical Structure in Spoken Language: Modeling of Global Prosodic Parameters: Ekaterina Jasinskaja, Jörg Mayer and David Schlangen: Discourse Structure and Information Structure: Interfaces and Prosodic Realization B2: Focussing in African Tchadic languages: Katharina Hartmann and Malte Zimmermann: Focus Strategies in Chadic: The Case of Tangale Revisited D1: Linguistic database for information structure: Annotation and retrieval: Stefanie Dipper, Michael Götze, Manfred Stede and Tillmann Wegst: ANNIS: A Linguistic Database for Exploring Information Structure
Ergodicity of PCA
(2004)
For a general attractive Probabilistic Cellular Automata on S-Zd, we prove that the (time-) convergence towards equilibrium of this Markovian parallel dynamics, exponentially fast in the uniform norm, is equivalent to a condition (A). This condition means the exponential decay of the influence from the boundary for the invariant measures of the system restricted to finite boxes. For a class of reversible PCA dynamics on {1,+1}(Zd), wit a naturally associated Gibbsian potential rho, we prove that a (spatial-) weak mixing condition (WM) for rho implies the validity of the assumption (A); thus exponential (time-) ergodicity of these dynamics towards the unique Gibbs measure associated to rho hods. On some particular examples we state that exponential ergodicity holds as soon as there is no phase transition.
We develop a cluster expansion in space-time for an infinite-dimensional system of interacting diffusions where the drift term of each diffusion depends on the whole past of the trajectory; these interacting diffusions arise when considering the Langevin dynamics of a ferromagnetic system submitted to a disordered external magnetic field.
The authors analyse different Gibbsian properties of interactive Brownian diffusions X indexed by the d-dimensional lattice. In the first part of the paper, these processes are characterized as Gibbs states on path spaces. In the second part of the paper, they study the Gibbsian character on R^{Z^d} of the law at time t of the infinite-dimensional diffusion X(t), when the initial law is Gibbsian. AMS Classifications: 60G15 , 60G60 , 60H10 , 60J60
We prove in this paper an existence result for infinite-dimensional stationary interactive Brownian diffusions. The interaction is supposed to be small in the norm ||.||∞ but otherwise is very general, being possibly non-regular and non-Markovian. Our method consists in using the characterization of such diffusions as space-time Gibbs fields so that we construct them by space-time cluster expansions in the small coupling parameter.
Time series analysis
(2004)
Consumer attitudes towards genetically modified foods in Europe : structure and changeability
(2004)
Genetically modified foods have been at the center of debate in European consumer policy in the last two decades. Although the quasi-moratorium has been lifted in May 2004 and the road to the market is in principle reopened, strategies for product introduction are lacking. The aim of the research is to assess potential barriers in the area of consumer acceptance and suggest ways in which they can be overcome. After a short history of the genetically modified foods debate in Europe, the existing literature is reviewed. Although previous research converges in its central results, issues that are more fundamental have remained unresolved. Based on classical approaches in attitude research and modern theories of social cognition, a general model of the structure, function and dynamics of whole systems of attitudes is developed. The predictions of the model are empirically tested based on an attitude survey (N = 2000) and two attitude change experiments (N = 1400 and N = 750). All three studies were conducted in parallel in four EU member states. The results show that consumer attitudes towards genetically modified foods are embedded into a structured system of general socio-political attitudes. The system operates as a schema through which consumers form global evaluations of the technology. Specific risk and benefit judgments are mere epiphenomena of this process. Risk-benefit trade-offs, as often presupposed in the literature, do not appear to enter the process. The attitudes have a value-expressive function; their purpose is not just a temporary reduction of complexity. These properties render the system utterly resistant to communicative interventions. At the same time, it exerts stong anchoring effects on the processing of new information. Communication of benefit arguments can trigger boomerang effects and backfire on the credibility of the communicator when the arguments contrast with preexisting attitudes held by the consumer. Only direct sensory experience with high-quality products can partially bypass the system and lead to the formation of alternative attitude structures. Therefore, the recommended market introduction strategy for genetically modified foods is the simultaneous and coordinated launch of many high-quality products. Point of sale promotions should be the central instrument. Information campaigns, on the other hand, are not likely to have an effect on the product and technology acceptance of European consumers.
A seed sowing experiment was conducted in a mixed secondary woodland on acidic soils in NE Germany with Melampyrum pratense, an annual ant-dispersed forest herb which lacks a natural population in the study area, but is abundant in similar habitats. Each set of 300 seeds was sown within one square metre at three sites in 1997, and the development of the populations was recorded from 1998 onward. Additionally, seed fall patterns were studied in a natural population by means of adhesive cardboard. All trials resulted in the recruitment of populations, which survived and increased in both individual number and area, up to the year 2001. Thus, local distribution of Melampyrum pratense is dispersallimited. Total individual number increased from 105 to 3,390, and total population area from 2.07 to 109.04 m². Migration occurred in all directions. Mean migration rate was 0.91 m per year, and the highest migration rate was 6.48 m. No individual was recorded beyond 7.63 m from the centres of the sawn squares after three years, suggesting exclusive short-distance dispersal. As primary dispersal enables only distances of up to 0.25 m, ants are presumed to be the main dispersal vectors. Despite differences in individual number and colonization patterns, migration rates did not differ significantly between the populations, but were significantly higher in 2001 due to an increased population size. Colonization patterns were characterized by a rapid, negative exponential decrease of population density with increasing distance from the sown plot, suggesting a colonization by establishment of more or less isolated outposts of individuals and a subsequent gradual infill of the gaps between. My results resemble myrmecochorous dispersal distances in temperate woodlands, and migration rates and patterns across ecotones from ancient to recent deciduous forests. They may function as a colonization model of Melampyrum pratense after accidental long-distance dispersal.
Structure and reactivity of a biological soil crust from a xeric sandy soil in Central Europe
(2004)
The investigation was designed to explore the structure, composition and activity of a biological soil crust on an acidic, sandy soil from a temperate climate. The crust covers several hundreds of square meters on the hilltop of a large terminal moraine. The conjugate alga Zygogonium ericetorum forms the essential matrix for the crust, a dense web of algal filaments with interspersed lichens and mosses. The crust is composed of three layers, with an uppermost layer consisting nearly entirely of a dense algal mat. In lower layers, a parasitic fungus, penetrating the algal cells, is another important component of the crust community. In this soil crust, photosynthetic and respiratory activity is stabilized at low water activities.
This book is about inventing successes and good practices of governments that are "closer to the people". Numerous examples throughout Latin America indicate-often despite macroeconomic instability, high inflation, and strong top-down regulation-that subnational actors have repeatedly achieved what their central counterparts preached: sound policymaking, better administration, better services, more participation, and sustained economic development. But what makes some governments change course and move toward innovation? What triggers experimentation and, eventually, turns ordinary practice into good practice? The book answers some of these questions. It goes beyond a mere documentation of good and best practice, which is increasingly provided through international networks and Internet sites. Instead, it seeks a better understanding of the origins and fates of such successes at the micro level. The case studies and analytical chapters seek to explain: How good practice is born at the local level; Where innovative ideas come from; How such ideas are introduced in a new context, successfully implemented, and propagated locally and beyond; What donors can do to effectively assist processes of self-induced and bottom-up change.
Variation in nitrogen deposition and available soil nitrogen in a forest–grassland ecotone in Canada
(2004)
Regional variation in nitrogen (N) deposition increases plant productivity and decreases species diversity, but landscape- or local-scale influences on N deposition are less well-known. Using ion-exchange resin, we measured variation of N deposition and soil N availability within Elk Island National Park in the ecotone between grassland and boreal forest in western Canada. The park receives regionally high amounts of atmospheric N deposition (22 kg ha⁻¹ yr⁻¹). N deposition was on average higher ton clayrich luvisols than on brunisols, and areas burned 1 – 15 years previously received more atmospheric N than unburned sites. We suggest that the effects of previous fires and soil type on deposition rate act through differences in canopy structure. The magnitude of these effects varied with the presence of ungulate grazers (bison, moose, elk) and vegetation type (forest, shrubland, grassland). Available soil N (ammonium and nitrate) was higher in burned than unburned sites in the absence of grazing, suggesting an effect of deposition. On grazed sites, differences between fire treatments were small, presumably because the removal of biomass by grazers reduced the effect of fire. Aspen invades native grassland in this region, and our results suggest that fire without grazing might reinforce the expansion of forest into grassland facilitated by N deposition.
Electrets are materials capable of storing oriented dipoles or an electric surplus charge for long periods of time. The term "electret" was coined by Oliver Heaviside in analogy to the well-known word "magnet". Initially regarded as a mere scientific curiosity, electrets became increasingly imporant for applications during the second half of the 20th century. The most famous example is the electret condenser microphone, developed in 1962 by Sessler and West. Today, these devices are produced in annual quantities of more than 1 billion, and have become indispensable in modern communications technology. Even though space-charge electrets are widely used in transducer applications, relatively little was known about the microscopic mechanisms of charge storage. It was generally accepted that the surplus charges are stored in some form of physical or chemical traps. However, trap depths of less than 2 eV, obtained via thermally stimulated discharge experiments, conflicted with the observed lifetimes (extrapolations of experimental data yielded more than 100000 years). Using a combination of photostimulated discharge spectroscopy and simultaneous depth-profiling of the space-charge density, the present work shows for the first time that at least part of the space charge in, e.g., polytetrafluoroethylene, polypropylene and polyethylene terephthalate is stored in traps with depths of up to 6 eV, indicating major local structural changes. Based on this information, more efficient charge-storing materials could be developed in the future. The new experimental results could only be obtained after several techniques for characterizing the electrical, electromechanical and electrical properties of electrets had been enhanced with in situ capability. For instance, real-time information on space-charge depth-profiles were obtained by subjecting a polymer film to short laser-induced heat pulses. The high data acquisition speed of this technique also allowed the three-dimensional mapping of polarization and space-charge distributions. A highly active field of research is the development of piezoelectric sensor films from electret polymer foams. These materials store charges on the inner surfaces of the voids after having been subjected to a corona discharge, and exhibit piezoelectric properties far superior to those of traditional ferroelectric polymers. By means of dielectric resonance spectroscopy, polypropylene foams (presently the most widely used ferroelectret) were studied with respect to their thermal and UV stability. Their limited thermal stability renders them unsuitable for applications above 50 °C. Using a solvent-based foaming technique, we found an alternative material based on amorphous Teflon® AF, which exhibits a stable piezoelectric coefficient of 600 pC/N at temperatures up to 120 °C.
We study a natural Dirac operator on a Lagrangian submanifold of a Kähler manifold. We first show that its square coincides with the Hodge - de Rham Laplacian provided the complex structure identifies the Spin structures of the tangent and normal bundles of the submanifold. We then give extrinsic estimates for the eigenvalues of that operator and discuss some examples.
This paper focuses on mysteries written by the Afro-American women authors Barbara Neely and Valerie Wilson Wesley. Both authors place a black woman in the role of the detective - an innovative feature not only in the realm of female detective literature of the past two decades but also with regard to the current discourse about race and class in US-American society. This discourse is important because detective novels are considered popular literature and thus a mass product designed to favor commercial instead of literary claims. Thus, the focus is placed on the development of the two protagonists, on their lives as detectives and as black women, in order to find out whether or not and how the genre influences the depiction of Afro-American experiences. It appears that both of these detective series represent Afro-American culture in different ways, which confirms a heterogenic development of this ethnic group. However, the protagonist's search for identity and their relationships to white people could be identified as a major unifying claim of Afro-American literature. With differing intensity, the authors Neely and Wesley provide the white or mainstream reader with insight into their culture and confront the reader's ignorance of black culture. In light of this, it is a great achievement that Neely and Wesley have reached not only a black audience but also a growing number of white readers.
Even though the structure of the plant cell wall is by and large quite well characterized, its synthesis and regulation remains largely obscure. However, it is accepted that the building blocks of the polysaccharidic part of the plant cell wall are nucleotide sugars. Thus to gain more insight into the cell wall biosynthesis, in the first part of this thesis, plant genes possibly involved in the nucleotide sugar interconversion pathway were identified using a bioinformatics approach and characterized in plants, mainly in Arabidopsis. For the computational identification profile hidden markov models were extracted from the Pfam and TIGR databases. Mainly with these, plant genes were identified facilitating the “hmmer” program. Several gene families were identified and three were further characterized, the UDP-rhamnose synthase (RHM), UDP-glucuronic acid epimerase (GAE) and the myo-inositol oxygenase (MIOX) families. For the three-membered RHM family relative ubiquitous expression was shown using variuos methods. For one of these genes, RHM2, T-DNA lines could be obtained. Moreover, the transcription of the whole family was downregulated facilitating an RNAi approach. In both cases a alteration of cell wall typic polysaccharides and developmental changes could be shown. In the case of the rhm2 mutant these were restricted to the seed or the seed mucilage, whereas the RNAi plants showed profound changes in the whole plant. In the case of the six-membered GAE family, the gene expressed to the highest level (GAE6) was cloned, expressed heterologously and its function was characterized. Thus, it could be shown that GAE6 encodes for an enzyme responsible for the conversion of UDP-glucuronic acid to UDP-galacturonic acid. However, a change in transcript level of variuos GAE family members achieved by T-DNA insertions (gae2, gae5, gae6), overexpression (GAE6) or an RNAi approach, targeting the whole family, did not reveal any robust changes in the cell wall. Contrary to the other two families the MIOX gene family had to be identified using a BLAST based approach due to the lack of enough suitable candidate genes for building a hidden markov model. An initial bioinformatic characterization was performed which will lead to further insights into this pathway. In total it was possible to identify the two gene families which are involved in the synthesis of the two pectin backbone sugars galacturonic acid and rhamnose. Moreover with the identification of the MIOX genes a genefamily, important for the supply of nucleotide sugar precursors was identified. In a second part of this thesis publicly available microarray datasets were analyzed with respect to co-responsive behavior of transcripts on a global basis using nearly 10,000 genes. The data has been made available to the community in form of a database providing additional statistical and visualization tools (http://csbdb.mpimp-golm.mpg.de). Using the framework of the database to identify nucleotide sugar converting genes indicated that co-response might be used for identification of novel genes involved in cell wall synthesis based on already known genes.
The past decades are characterized by various efforts to provide complete sequence information of genomes regarding various organisms. The availability of full genome data triggered the development of multiplex high-throughput assays allowing simultaneous measurement of transcripts, proteins and metabolites. With genome information and profiling technologies now in hand a highly parallel experimental biology is offering opportunities to explore and discover novel principles governing biological systems. Understanding biological complexity through modelling cellular systems represents the driving force which today allows shifting from a component-centric focus to integrative and systems level investigations. The emerging field of systems biology integrates discovery and hypothesis-driven science to provide comprehensive knowledge via computational models of biological systems. Within the context of evolving systems biology, investigations were made in large-scale computational analyses on transcript co-response data through selected prokaryotic and plant model organisms. CSB.DB - a comprehensive systems-biology database - (http://csbdb.mpimp-golm.mpg.de/) was initiated to provide public and open access to the results of biostatistical analyses in conjunction with additional biological knowledge. The database tool CSB.DB enables potential users to infer hypothesis about functional interrelation of genes of interest and may serve as future basis for more sophisticated means of elucidating gene function. The co-response concept and the CSB.DB database tool were successfully applied to predict operons in Escherichia coli by using the chromosomal distance and transcriptional co-responses. Moreover, examples were shown which indicate that transcriptional co-response analysis allows identification of differential promoter activities under different experimental conditions. The co-response concept was successfully transferred to complex organisms with the focus on the eukaryotic plant model organism Arabidopsis thaliana. The investigations made enabled the discovery of novel genes regarding particular physiological processes and beyond, allowed annotation of gene functions which cannot be accessed by sequence homology. GMD - the Golm Metabolome Database - was initiated and implemented in CSB.DB to integrated metabolite information and metabolite profiles. This novel module will allow addressing complex biological questions towards transcriptional interrelation and extent the recent systems level quest towards phenotyping.
Adverb positioning is guided by syntactic, semantic, and pragmatic considerations and is subject to cross-linguistic as well as language-specific variation. The goal of the thesis is to identify the factors that determine adverb placement in general (Part I) as well as in constructions in which the adverb's sister constituent is deprived of its phonetic material by movement or ellipsis (gap constructions, Part II) and to provide an Optimality Theoretic approach to the contrasts in the effects of these factors on the distribution of adverbs in English, French, and German. In Optimality Theory (Prince & Smolensky 1993), grammaticality is defined as optimal satisfaction of a hierarchy of violable constraints: for a given input, a set of output candidates are produced out of which that candidate is selected as grammatical output which optimally satisfies the constraint hierarchy. Since grammaticality crucially relies on the hierarchic relations of the constraints, cross-linguistic variation can be traced back to differences in the language-specific constraint rankings. Part I shows how diverse phenomena of adverb placement can be captured by corresponding constraints and their relative rankings: - contrasts in the linearization of adverbs and verbs/auxiliaries in English and French - verb placement in German and the filling of the prefield position - placement of focus-sensitive adverbs - fronting of topical arguments and adverbs Part II extends the analysis to a particular phenomenon of adverb positioning: the avoidance of adverb attachment to a phonetically empty constituent (gap). English and French are similar in that the acceptability of pre-gap adverb placement depends on the type of adverb, its scope, and the syntactic construction (English: wh-movement vs. topicalization / VP Fronting / VP Ellipsis, inverted vs. non-inverted clauses; French: CLLD vs. Cleft, simple vs. periphrastic tense). Yet, the two languages differ in which strategies a specific type of adverb may pursue to escape placement in front of a certain type of gap. In contrast to English and French, placement of an adverb in front of a gap never gives rise to ungrammaticality in German. Rather, word ordering has to obey the syntactic, semantic, and pragmatic principles discussed in Part I; whether or not it results in adverb attachment to a phonetically empty constituent seems to be irrelevant: though constraints are active in every language, the emergence of a visible effect of their requirements in a given language depends on their relative ranking. The complex interaction of the diverse factors as well as their divergent effects on adverb placement in the various languages are accounted for by the universal constraints and their language-specific hierarchic relations in the OT framework.
Fault planes of large earthquakes incorporate inhomogeneous structures. This can be observed in teleseismic studies through the spatial distribution of slip and seismic moment release caused by the mainshock. Both parameters are often concentrated on patches on the fault plane with much higher values for slip and moment release than their adjacent areas. These patches are called asperities which obviously have a strong influence on the mainshock rupture propagation. Condition and properties of structures in the fault plane area, which are responsible for the evolution of such asperities or their significance on damage distributions of future earthquakes, are still not well understood and subject to recent geo-scientific studies. In the presented thesis asperity structures are identified on the fault plane of the Mw=8.0 Antofagasta earthquake in northern Chile which occurred on 30th of July, 1995. It was a thrust-type event in the seismogenic zone between the subducting pacific Nazca plate and the overriding South American plate. In cooperation of the German Task Force for Earthquakes and the CINCA'95 project a network of up to 44 seismic stations was set up to record the aftershock sequence. The seaward extension of the network with 9 OBH stations increased significantly the precision of hypocenter determinations. They were distributed mainly on the fault plane itself around the city of Antofagasta and Mejillones Peninsula. The asperity structures were recognized here by the spatial variations of local seismological parameters; at first by the spatial distribution of the seismic b-value on the fault plane, derived from the magnitude-frequency relation of Gutenberg-Richter. The correlation of this b-value map with other parameters like the mainshock source time function, the gravity isostatic residual anomalies, the aftershock radiated seismic energy distribution and the vp/vs ratios from a local earthquake tomograhpy study revealed some ideas about the composition and asperity generating processes. The investigation of 295 aftershock focal mechanism solutions supported the resulting fault plane structure and proposed a 3D similar stress state in the area of the Antofagasta fault plane.
Environmental stresses such as drought, high salt and low temperature affect plant growth and decrease crop productivity extremely. It is important to improve stress tolerance of the crop plant to increase crop yield under stress conditions. The Arabidopsis thaliana salt tolerance 1 gene (AtSTO1) was originally identified by Lippuner et al., (1996). In this study around 27 members of STO-like proteins were identified in Arabidopsis thaliana, rice and other plant species. The STO proteins have two consensus motifs (CCADEAAL and FCV(L)EDRA). The STO family members can be regarded as a distinct class of C2C2 proteins considering their low sequence similarity to other GATA like proteins and poor conservation in the C-terminus. AtSTO1 was found to be induced by salt, cold and drought in leaves and roots of 4-week-old Arabidopsis thaliana wild-type plants. The expression of AtSTO1 under salt and cold stress was more pronounced in roots than in leaves. The data provided here revealed that the AtSTO1 protein is localized in the nucleus. The observation that AtSTO1 localizes in the nucleus is consistent with its proposed function as a transcription factor. AtSTO1-dependent phenotypes were observed when plant were grown at 50 mM NaCl on agar plates. Leaves of AtSTO1 overexpression lines were bigger with dark green coloration, whereas stunted growth and yellowish leaves were observed in wild-type and RNAi plants. Also, the AtSTO1 overexpression plants when exposed to long-term cold stress had a red leaf coloration which was much stronger than in wild-type and RNAi lines. Growth of AtSTO1 overexpression lines in long term under salt and cold stress was always associated with long roots which was more pronounced than in wild-type and RNAi lines. Proline accumulation increased more strongly in leaves and roots of AtSTO1 overexpression lines than in tissues of wild-type and RNAi lines when treated with 200 mM NaCl, exposed to cold stress or when watering was prevented for one day or two weeks. Also, soluble sugar content increased to higher levels under salt, cold and drought stress in AtSTO1 overexpression lines when compared to wild-type and RNAi lines. The increase in soluble sugar content was detected in AtSTO1 overexpression lines after long-term (2 weeks) growth of plants under these stresses. Anthocyanins accumulated in leaves of AtSTO1 overexpression lines when exposed to long term salt stress (200 mM NaCl for 2 weeks) or to 4°C for 6 and 8 weeks. Also, anthocyanin content was increased in flowers of AtSTO1 overexpression plants kept at 4°C for 8 weeks. Taken together these data indicate that overexpression of AtSTO1 enhances abiotic stress toleranc via a more pronounced accumulation of compatible solutes under stress.
New chain transfer agents based on dithiobenzoate and trithiocarbonate for free radical polymerization via Reversible Addition-Fragmentation chain Transfer (RAFT) were synthesized. The new compounds bear permanently hydrophilic sulfonate moieties which provide solubility in water independent of the pH. One of them bears a fluorophore, enabling unsymmetrical double end group labelling as well as the preparation of fluorescent labeled polymers. Their stability against hydrolysis in water was studied, and compared with the most frequently employed water-soluble RAFT agent 4-cyano-4-thiobenzoylsulfanylpentanoic acid dithiobenzoate, using UV-Vis and 1H-NMR spectroscopy. An improved resistance to hydrolysis was found for the new RAFT agents, providing good stabilities in the pH range between 1 and 8, and up to temperatures of 70°C. Subsequently, a series of non-ionic, anionic and cationic water-soluble monomers were polymerized via RAFT in water. In these experiments, polymerizations were conducted either at 48°C or 55°C, that are lower than the conventionally employed temperatures (>60°C) for RAFT in organic solvents, in order to minimize hydrolysis of the active chain ends (e.g. dithioester and trithiocarbonate), and thus to obtain good control over the polymerization. Under these conditions, controlled polymerization in aqueous solution was possible with styrenic, acrylic and methacrylic monomers: molar masses increase with conversion, polydispersities are low, and the degree of end group functionalization is high. But polymerizations of methacrylamides were slow at temperatures below 60°C, and showed only moderate control. The RAFT process in water was also proved to be a powerful method to synthesize di- and triblock copolymers including the preparation of functional polymers with complex structure, such as amphiphilic and stimuli-sensitive block copolymers. These include polymers containing one or even two stimuli-sensitive hydrophilic blocks. The hydrophilic character of a single or of several blocks was switched by changing the pH, the temperature or the salt content, to demonstrate the variability of the molecular designs suited for stimuli-sensitive polymeric amphiphiles, and to exemplify the concept of multiple-sensitive systems. Furthermore, stable colloidal block ionomer complexes were prepared by mixing anionic surfactants in aqueous media with a double hydrophilic block copolymer synthesized via RAFT in water. The block copolymer is composed of a noncharged hydrophilic block based on polyethyleneglycol and a cationic block. The complexes prepared with perfluoro decanoate were found so stable that they even withstand dialysis; notably they do not denaturate proteins. So, they are potentially useful for biomedical applications in vivo.
Taking inspiration from nature, where composite materials made of a polymer matrix and inorganic fillers are often found, e.g. bone, shell of crustaceans, shell of eggs, etc., the feasibility on making composite materials containing chitosan and nanosized hydroxyapatite were investigated. A new preparation approach based on a co-precipitation method has been developed. In its earlier stage of formation, the composite occurs as hydrogel as suspended in aqueous alkaline solution. In order to get solid composites various drying procedures including freeze-drying technique, air-drying at room temperature and at moderate temperatures, between 50oC and 100oC were used. Physicochemical studies showed that the composites exhibit different properties with respect to their structure and composition. IR and Raman spectroscopy probed the presence of both chitosan and hydroxyapatite in the composites. Hydroxyapatite as dispersed in the chitosan matrix was found to be in the nanosize range (15-50 nm) and occurs in a bimodal distribution with respect to its crystallite length. Two types of distribution domains of hydroxyapatite crystallites in the composite matrix such as cluster-like (200-400 nm) and scattered-like domains were identified by the transmission electron microscopy (TEM), X-ray diffraction (XRD) and by confocal scanning laser microscopy (CSLM) measurements. Relaxation NMR experiments on composite hydrogels showed the presence of two types of water sites in their gel networks, such as free and bound water. Mechanical tests showed that the mechanical properties of composites are one order of magnitude less than those of compact bone but comparable to those of porous bone. The enzymatic degradation rates of composites showed slow degradation processes. The yields of degradation were estimated to be less than 10% by loss of mass, after incubation with lysozyme, for a period of 50 days. Since the composite materials were found biocompatible by the in vivo tests, the simple mode of their fabrication and their properties recommend them as potential candidates for the non-load bearing bone substitute materials.
This thesis work describes a new experimental method for the determination of Mode II (shear) fracture toughness, KIIC of rock and compares the outcome to results from Mode I (tensile) fracture toughness, KIC, testing using the International Society of Rock Mechanics Chevron-Bend method.Critical Mode I fracture growth at ambient conditions was studied by carrying out a series of experiments on a sandstone at different loading rates. The mechanical and microstructural data show that time- and loading rate dependent crack growth occurs in the test material at constant energy requirement.The newly developed set-up for determination of the Mode II fracture toughness is called the Punch-Through Shear test. Notches were drilled to the end surfaces of core samples. An axial load punches down the central cylinder introducing a shear load in the remaining rock bridge. To the mantle of the cores a confining pressure may be applied. The application of confining pressure favours the growth of Mode II fractures as large pressures suppress the growth of tensile cracks.Variation of geometrical parameters leads to an optimisation of the PTS- geometry. Increase of normal load on the shear zone increases KIIC bi-linear. High slope is observed at low confining pressures; at pressures above 30 MPa low slope increase is evident. The maximum confining pressure applied is 70 MPa. The evolution of fracturing and its change with confining pressure is described.The existence of Mode II fracture in rock is a matter of debate in the literature. Comparison of the results from Mode I and Mode II testing, mainly regarding the resulting fracture pattern, and correlation analysis of KIC and KIIC to physico-mechanical parameters emphasised the differences between the response of rock to Mode I and Mode II loading. On the microscale, neither the fractures resulting from Mode I the Mode II loading are pure mode fractures. On macroscopic scale, Mode I and Mode II do exist.
The India-Eurasia continental collision zone provides a spectacular example of active mountain building and climatic forcing. In order to quantify the critically important process of mass removal, I analyzed spatial and temporal precipitation patterns of the oscillating monsoon system and their geomorphic imprints. I processed passive microwave satellite data to derive high-resolution rainfall estimates for the last decade and identified an abnormal monsoon year in 2002. During this year, precipitation migrated far into the Sutlej Valley in the northwestern part of the Himalaya and reached regions behind orographic barriers that are normally arid. There, sediment flux, mean basin denudation rates, and channel-forming processes such as erosion by debris-flows increased significantly. Similarly, during the late Pleistocene and early Holocene, solar forcing increased the strength of the Indian summer monsoon for several millennia and presumably lead to analogous precipitation distribution as were observed during 2002. However, the persistent humid conditions in the steep, high-elevation parts of the Sutlej River resulted in deep-seated landsliding. Landslides were exceptionally large, mainly due to two processes that I infer for this time: At the onset of the intensified monsoon at 9.7 ka BP heavy rainfall and high river discharge removed material stored along the river, and lowered the baselevel. Second, enhanced discharge, sediment flux, and increased pore-water pressures along the hillslopes eventually lead to exceptionally large landslides that have not been observed in other periods. The excess sediments that were removed from the upstream parts of the Sutlej Valley were rapidly deposited in the low-gradient sectors of the lower Sutlej River. Timing of downcutting correlates with centennial-long weaker monsoon periods that were characterized by lower rainfall. I explain this relationship by taking sediment flux and rainfall dynamics into account: High sediment flux derived from the upstream parts of the Sutlej River during strong monsoon phases prevents fluvial incision due to oversaturation the fluvial sediment-transport capacity. In contrast, weaker monsoons result in a lower sediment flux that allows incision in the low-elevation parts of the Sutlej River.
It is known that the efficiency of organic light-emitting devices (OLEDs) is strongly influenced by the ’quality′ of the thin films [1]. On the basis of this conviction, the work presented in this thesis aimed to obtain a better understanding of the structure of organic thin films of general interest in the field of organic light emitting devices by using scanning probe microscopies (SPMs). A not yet reported crystal structure of quaterthiophene film grown on potassium hydrogen (KHP) is determined by optical measurements, a simulation program, diffraction at both normal incidence and grazing angle and AFM. The crystal cell is triclinic with parameters a = 0.721 nm, b = 0.632 nm, c = 0.956 nm and a = 91°, b = 91.4°, g = 91° [2]. The morphologies of four organic thin films deposited on gold are characterized by ultra high vacuum scanning tunneling microscopy (UHV-STM). Terraces in an hexanethiol monolayer, lamellar structures in an azobenzenethiol monolayer, rods in a a poly(paraphenylenevinylene) oligomer film and a granular morphology in an oxadiazole film are shown. The topographies of a series of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT/PSS) films deposited on indium-tin oxide (ITO) and gold obtained from dispersions with PEDOT:PSS weight ratios of 1:20, 1:6 and 1:1 are investigated by AFM. It is demonstrated that the films show the same topography on gold and on ITO. It is shown that the PEDOT films eliminate the spike features of ITO. It is reported that PEDOT 1:20 and 1:6 appear indistinguishable between each other but different from PEDOT 1:1 (the most conductive). Coupling STM and I-d measurements, a not yet reported structural model of PEDOT 1:1 on gold is obtained [3]. In this model the surface presents grains and the bulk particles/domains rich in PEDOT embedded in a PEDOT-poor matrix. The equation of conductivity is derived. A STM investigation of four PEDOT films deposited on ITO obtained from dispersions with the same PEDOT:PSS weight ratio of 1:1 is carried out [4]. The films differ either for the presence of sorbitol or for a different synthetic route (and they present different conductivities). For the first time a quantitative and qualitative correlation between the nanometer-scale morphology of PEDOT films with and without sorbitol and their conductivity is established.