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- relative clauses (8)
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- Morphology (7)
- Movement (7)
- Myodes glareolus (7)
- México (7)
- NICS (7)
- Netzwerke des Wissens (7)
- Overweight (7)
- Palaeoclimate (7)
- Physical activity (7)
- Polymer (7)
- Principal component analysis (7)
- Randomized controlled trial (7)
- Reading motivation (7)
- Russland (7)
- Schulforschung (7)
- Soil (7)
- Southeast Asia (7)
- Spain (7)
- Spectroscopy (7)
- Statistical seismology (7)
- Synchronization (7)
- Synthetic methods (7)
- Tolkien (7)
- Water quality (7)
- X-ray refraction (7)
- X-ray structure (7)
- abiotic stress (7)
- amerikanische Reisetagebücher (7)
- aphasia (7)
- behavior (7)
- binaries: eclipsing (7)
- biosensor (7)
- carbon (7)
- catalogs (7)
- charge transfer (7)
- charge transport (7)
- climate-change mitigation (7)
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- convection (7)
- cooperation (7)
- copper (7)
- culture (7)
- cyberbullying (7)
- cytotoxicity (7)
- decision-making (7)
- deep biosphere (7)
- democracy (7)
- didactics (7)
- digital transformation (7)
- electron transfer (7)
- embodiment (7)
- empathy (7)
- enzyme catalysis (7)
- epidemiology (7)
- evaluation (7)
- event-related potentials (7)
- exhumation (7)
- extinction (7)
- fitness (7)
- galaxies: dwarf (7)
- galaxies: starburst (7)
- gene flow (7)
- global warming (7)
- gold nanoparticles (7)
- inclusion (7)
- inclusive education (7)
- inequality (7)
- inflection (7)
- inhibition (7)
- interaction (7)
- interactions (7)
- ion mobility spectrometry (7)
- iron (7)
- justice sensitivity (7)
- landscape evolution (7)
- low back pain (7)
- magnetosphere (7)
- masked priming (7)
- mass spectrometry (7)
- movement (7)
- neural networks (7)
- neuroimaging (7)
- numerical modeling (7)
- peptides (7)
- perception (7)
- phenotypic plasticity (7)
- plasticity (7)
- polymerization (7)
- protein (7)
- public health (7)
- pulsars: general (7)
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- resistance (7)
- retrieval (7)
- ring-opening polymerization (7)
- rodents (7)
- runoff (7)
- seasonality (7)
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- soil moisture (7)
- solar wind (7)
- species richness (7)
- speech and language therapy (7)
- sphingolipids (7)
- stars: emission-line, Be (7)
- strength (7)
- sunspots (7)
- surface chemistry (7)
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- time (7)
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- 1829 (6)
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- Ellenberg indicator values (6)
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- FRET (6)
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- Gene-environment interaction (6)
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- Globalisierung (6)
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- H II regions (6)
- HIV (6)
- Hertzsprung-Russell and C-M diagrams (6)
- Heterogenität (6)
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- Humboldt (6)
- ISM: kinematics and dynamics (6)
- Indian Summer Monsoon (6)
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- Inklusion (6)
- Instructional quality (6)
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- Lepus europaeus (6)
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- Norway (6)
- Oxygen heterocycles (6)
- PHREEQC (6)
- Paris Agreement (6)
- Perceptual span (6)
- Phenotypic plasticity (6)
- Phosphorus (6)
- Phylogeography (6)
- Prediction (6)
- Prenatal stress (6)
- Professional development (6)
- Professionsorientierung (6)
- Prunus avium L. (6)
- Pseudomonas aeruginosa (6)
- Reinforcement learning (6)
- Reliability (6)
- Resilience (6)
- Rezeptionsgeschichte (6)
- Ring current effect (6)
- Russian (6)
- Seasonality (6)
- Security (6)
- Self-efficacy (6)
- Soil moisture (6)
- South America (6)
- Speech perception (6)
- Sphingosine 1-phosphate (6)
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- colonialism (3)
- color (3)
- comets: individual: 67P/Churyumov-Gerasimenko (3)
- community (3)
- comorbidity (3)
- competencies (3)
- complexity (3)
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- computed tomography (3)
- conditions (3)
- conductivity (3)
- confinement (3)
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- correlations (3)
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- demography (3)
- dependence (3)
- deutsch-jüdische Geschichte (3)
- developmental dyscalculia (3)
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- edge effect (3)
- effect (3)
- efficiency (3)
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- ellipsis processing (3)
- ellipsometry (3)
- emotional intelligence (3)
- employment (3)
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- energy (3)
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- stars: (3)
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- upper mantle (3)
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- (Anti)aromaticity (2)
- ) (2)
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- Multilevel modeling (2)
- Multimodal analysis (2)
- Multimodality (2)
- Multiple Spell-Out (2)
- Multiple sclerosis (2)
- Multiple zeta values (2)
- Multiplex mutagenesis (2)
- Multivariate data analysis (2)
- Muscle (2)
- Music (2)
- Music cognition (2)
- Mycotoxins (2)
- Mysticism (2)
- Mündlichkeit (2)
- N ligands (2)
- N-2 reduction (2)
- N2 (2)
- NAC (2)
- NAC transcription factor (2)
- NAP-XPS (2)
- NCA (2)
- NF1 (2)
- NOR (2)
- NP-completeness (2)
- NW Iran (2)
- Nachlass (2)
- Nachruf (2)
- Nachwuchsförderung (2)
- Nanohybrid (2)
- Nanoparticle (2)
- Nanoparticle uptake (2)
- Nanotechnology (2)
- Nanotoxicology (2)
- National Socialism (2)
- Natural products (2)
- Naturbegriff (2)
- Naturwissenschaftler (2)
- Near East (2)
- Neoliberalism (2)
- Nest predation (2)
- Nested graph conditions (2)
- Network (2)
- Network reconstruction (2)
- Network structure (2)
- Networked foresight (2)
- Neu-Spanien (2)
- Neuplatonismus (2)
- Neuropeptide Y (2)
- Neutral tone (2)
- New business formation (2)
- New institutionalism (2)
- Nicolai Hartmann (2)
- Niedersorbische Sprache (2)
- Nigeria (2)
- Niobium (2)
- Nitrate (2)
- Nitrogen-limitation hypothesis (2)
- Non-canonical sentences (2)
- Non-fluent aphasia (2)
- Non-independent mate choice (2)
- Non-monotonic reasoning (2)
- Non-stationarity (2)
- Non-target terrestrial plants (2)
- Nonlinear coupling (2)
- Nordeste (2)
- North America (2)
- North Anatolian Fault (2)
- North Tabriz Fault (2)
- Numerical experiment (2)
- Numerical modelling (2)
- Nursing home (2)
- NutriAct Family Study (2)
- Nutrient (2)
- Nutritional quality (2)
- Nyctereutes procyonoides (2)
- O-serotyping (2)
- OCD (2)
- OSL dating (2)
- Object Shift (2)
- Offending (2)
- Office chair (2)
- Oligo(epsilon-caprolactone) (2)
- Oligopoly competition (2)
- Onsager-Machlup functional (2)
- Open source (2)
- Ophrys (2)
- Opposition (2)
- Optionality (2)
- Orchestia montagui (2)
- Order-preserving transformations (2)
- Organic carbon (2)
- Organic electronics (2)
- Organic geochemistry (2)
- Organic matter (2)
- Organic semiconductors (2)
- Organic solar cells (2)
- Organization theory (2)
- Organizations (2)
- Organogenesis (2)
- Orientalismus (2)
- Orinoco (2)
- Orogenic wedge (2)
- Oryctolagus cuniculus (2)
- Oscillator ensembles (2)
- Ostracods (2)
- Othering (2)
- Ottmar Ette (2)
- Outcrossing (2)
- Outflows (2)
- Output-Analyse (2)
- Outputanalyse (2)
- Oxygen (2)
- Ozone (2)
- P ligands (2)
- P(VDF-TrFE-CFE) terpolymer (2)
- P-waves (2)
- P300 (2)
- PCLake (2)
- PCR (2)
- PER (2)
- PET (2)
- PI3K (2)
- Pak choi (2)
- Palaeoclimatology (2)
- Palaeoecology (2)
- Palaeoenvironmental reconstruction (2)
- Paleoceanography (2)
- Paleoecology (2)
- Paleoenvironment (2)
- Paleohydrology (2)
- Palmitate (2)
- Paläontologie (2)
- Panama (2)
- Parameterized complexity (2)
- Paratethys (2)
- Parents (2)
- Paris agreement (2)
- Paris-Edinburgh press (2)
- Parkinson disease (2)
- Parkinson's disease (2)
- Pastoralism (2)
- Pasture (2)
- Path modelling (2)
- Patterning (2)
- Peat (2)
- Pedagogical content knowledge (2)
- Pedagogical issues (2)
- Perceived ankle instability (2)
- Periphyton (2)
- Peronosporaceae (2)
- Perovskites (2)
- Personalauswahl (2)
- Personalised medicine (2)
- Personality traits (2)
- Personalized medicine (2)
- Perylene (2)
- Petrography (2)
- Pfadmodell (2)
- Pharmacokinetics (2)
- Phase morphology (2)
- Phase variation (2)
- Phenological modelling (2)
- Phenylpropanoids (2)
- Philippe Aldas (2)
- Philologie (2)
- Philosophical anthropology (2)
- Phonology (2)
- Phosphate (2)
- Phospholipids (2)
- Phosphorus limitation (2)
- Photoelectron spectroscopy (2)
- Photosensitive polymer brushes (2)
- Physical exercise (2)
- Physik (2)
- Picard-Fuchs equations (2)
- Pickering emulsions (2)
- Pierre-Simon Laplace (2)
- Pigments (2)
- Pioniere (2)
- Pipe networks (2)
- Pitch (2)
- Planar polarity (2)
- Planspiel (2)
- Plant community (2)
- Plant community model (2)
- Plant functional groups (2)
- Plant height (2)
- Plant macrofossils (2)
- Plant performance (2)
- Plant-based diet (2)
- Plate tectonics (2)
- Platform economy (2)
- Plato (2)
- Pliny the Younger (2)
- Pliocene (2)
- Pluralism (2)
- Plyometric exercise (2)
- Poeciliidae (2)
- Poincare inequality (2)
- Point-based rendering (2)
- Point-light action (2)
- Pointing (2)
- Polarization (2)
- Policy (2)
- Policy change (2)
- Pollen record (2)
- Poly(epsilon-caprolactone) (2)
- Polyampholytes (2)
- Polyethyleneimine (2)
- Polymer dispersions (2)
- Polymerization (2)
- Polynomial regression (2)
- Ponds (2)
- Pontides (2)
- Population density (2)
- Population structure (2)
- Population viability analysis (2)
- Porosity (2)
- Porous silicon (2)
- Porphyrins (2)
- Position Generator (2)
- Positive selection (2)
- Postural stability (2)
- Potassium (2)
- Power (2)
- Praktikum im In- und Ausland (2)
- Praxisphasen (2)
- Precipitation gradient (2)
- Precise Point Positioning (2)
- Predator-prey interactions (2)
- Prediabetes (2)
- Predictability (2)
- Predictor (2)
- Preference (2)
- Preferential flow (2)
- Preprocessing (2)
- Pressure distribution (2)
- Preterm birth (2)
- Primary care (2)
- Priming (2)
- Prior knowledge (2)
- Privatisierung (2)
- Proactive/reactive balance (2)
- Probability (2)
- Probability distributions (2)
- Problem solving (2)
- Process (2)
- Process modeling (2)
- Processes (2)
- Procrustes rotation (2)
- Professional Knowledge (2)
- Professional knowledge (2)
- Progesterone (2)
- Prognosis (2)
- Programming (2)
- Projektevaluation (2)
- Proliferation (2)
- Prominences, active (2)
- Pronoun resolution (2)
- Prosodic boundaries (2)
- Proteasome (2)
- Protein complexes (2)
- Protein expression (2)
- Protein oxidation (2)
- Protein restriction (2)
- Protein secondary structure (2)
- Proteins (2)
- Prototyping (2)
- Proxy (2)
- Pseudomonas syringae (2)
- Psycholinguistics (2)
- Psychological functioning (2)
- Psychologiestudierende (2)
- Psychology (2)
- Psychopathology (2)
- Psychophysiology (2)
- Psychosocial stress (2)
- Psychotherapie (2)
- Psychotherapierichtlinie (2)
- Public administration (2)
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- Public sector (2)
- Publikationsfonds (2)
- Pump-probe (2)
- Puna Plateau (2)
- Push-pull character (2)
- Push-pull effect (2)
- QTL (2)
- Qaidam Basin (2)
- Quality assurance (2)
- Quantitative Trait Locus (2)
- Quantitative Trait Locus analysis (2)
- Quantum dots (2)
- Quantum dynamics (2)
- Quasilinear equations (2)
- Query optimization (2)
- Questionnaire (2)
- Questionnaires (2)
- Quito (2)
- R (2)
- R Shiny (2)
- RAFT (2)
- RCT (2)
- REDD+ (2)
- REE (2)
- REMPI (2)
- RNA-guided Cas9 (2)
- RP2 (2)
- Radiation belts (2)
- Radiogenic isotopes (2)
- Rainfall (2)
- Rainfall gradient (2)
- Raman imaging (2)
- Raman microspectroscopy (2)
- Random Forest (2)
- Randomized-controlled trial (2)
- Ranking (2)
- Rapeseed oil (2)
- Rapid automatized naming (2)
- Rationality (2)
- Rattus norvegicus (2)
- Rayleigh waves (2)
- Real time (2)
- Reanalysis (2)
- Rearing experiment (2)
- Rearrangement (2)
- Reasoning (2)
- Rechtschreibkompetenz (2)
- Recurrence plot (2)
- Redox polymer (2)
- Reflexionsförderung (2)
- Reflexionsqualität (2)
- Reflexivität (2)
- Reformation (2)
- Reformbereitschaft (2)
- Region (2)
- Regionalization (2)
- Regression (2)
- Rehearsal (2)
- Reisebegleiter (2)
- Reisen (2)
- Reisetagebücher (2)
- Reiterstandbild (2)
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- Relative clause (2)
- Relative clauses (2)
- Release (2)
- Religionsfreiheit (2)
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- Removable sets (2)
- Renal failure (2)
- Renal function (2)
- Renewable resources (2)
- Replication (2)
- Reproducibility (2)
- ResNet (2)
- Residual stresses (2)
- Resilienz (2)
- Resistance (2)
- Resonanzenergietransfer (2)
- Resurvey (2)
- Retention (2)
- Retina (2)
- Retinol (2)
- Retrieval (2)
- Rezeption (2)
- Ring tensiometry (2)
- Ring-opening polymerization (2)
- Rio Grande (2)
- Risk factor (2)
- Risk factors (2)
- Risk perception (2)
- River (2)
- River restoration (2)
- Rock magnetism (2)
- Rodent (2)
- Rome (2)
- Rossby waves (2)
- Rotifera (2)
- Rougon-Macquart (2)
- Royden boundary (2)
- Run time analysis (2)
- Running (2)
- Runtime analysis (2)
- Russlandreise (2)
- S receiver functions (2)
- SAMT (2)
- SARS-CoV-2 (2)
- SAUR (2)
- SDG interactions (2)
- SDS PAGE (2)
- SEIRA spectroelectrochemistry (2)
- SEMG-pattern (2)
- SEPE (2)
- SES (2)
- SIMS (2)
- SLA (2)
- SMARC (2)
- SMEs (2)
- SOEP (2)
- SPARQL (2)
- SQL (2)
- SRTM (2)
- SSW (2)
- Salmonella Typhimurium (2)
- Sampling (2)
- Sampling rate (2)
- Sarcopenia (2)
- Satellite magnetics (2)
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- Scaling (2)
- Scattering theory (2)
- Scenario (2)
- Scenario planning (2)
- Schrodinger equation (2)
- Schrodinger operators (2)
- Schule (2)
- Schulpraktikum (2)
- Scientific discovery learning (2)
- Scientific understanding of Information (2)
- Sclerochronology (2)
- Seawater intrusion (2)
- Second Empire (2)
- Secret society of torturers (2)
- Secularism (2)
- Security Council (2)
- Sediment Transport (2)
- Sediment fingerprinting (2)
- Sediment geochemistry (2)
- Sedimentary basin (2)
- Sedimentology (2)
- Sediments (2)
- Seed mass (2)
- Seismic interferometry (2)
- Seismic monitoring and test-ban treaty verification (2)
- Seismology (2)
- Seismotectonic segmentation (2)
- Seismotectonics (2)
- Selection (2)
- Selection vs. age-class forests (2)
- Self (2)
- Self-assembly (2)
- Self-concept (2)
- Self-harm (2)
- Self-organization (2)
- Self-reflection (2)
- Self-stigmatization (2)
- Semantic preview benefit (2)
- Semantic priming (2)
- Semantics (2)
- Semi-arid (2)
- Semiconductors (2)
- Seminarkonzept (2)
- Semitic (2)
- Sensor fusion (2)
- Sensors (2)
- Sentence-picture matching (2)
- Sentinel-2 (2)
- Sequence analysis (2)
- Sequential instruction (2)
- Serotonin (2)
- Service-oriented computing (2)
- Sesia Zone (2)
- Sexual conflict (2)
- Sexual dimorphism (2)
- Shame (2)
- Shannon diversity (2)
- Shannon entropy (2)
- Shape-memory effect (2)
- Shape-memory polymer (2)
- Shire River (2)
- Shona (2)
- Shrews (2)
- Si fractions (2)
- Signal detection theory (2)
- Signal transduction (2)
- Signaling (2)
- Signalling (2)
- Silicon isotopes (2)
- Simulation model (2)
- Single/dual tasking (2)
- Site characterization (2)
- Site response (2)
- Situated cognition (2)
- Siwaliks (2)
- Skeletal muscle (2)
- Skin (2)
- Skin nanocarrier (2)
- Skin penetration (2)
- Sklavenhandel (2)
- Slavic countries (2)
- Slope (2)
- Slope exposure (2)
- Small (2)
- Small for gestational age (2)
- Small mammals (2)
- Smart micro-grids (2)
- Smoking (2)
- Social (2)
- Social Inequality (2)
- Social cognition (2)
- Social cues (2)
- Social environment (2)
- Social inequality (2)
- Social learning (2)
- Social origin (2)
- Software (2)
- Soil function (2)
- Soil heterogeneity (2)
- Soil texture (2)
- Solanum tuberosum (2)
- Solidago gigantea (2)
- Solvent effects (2)
- Solvents (2)
- Solvothermal synthesis (2)
- Somatoform disorder (2)
- Sorbian history of church (2)
- Sorbian history of music (2)
- Sorbische Kirchengeschichte (2)
- Sorbische Musikgeschichte (2)
- South American Monsoon System (2)
- South American monsoon system (2)
- Southern Italy (2)
- Soziale Herkunft (2)
- Sozialer Survey Österreich (2)
- Sozialkapital (2)
- Space geodetic surveys (2)
- Spanische Kolonien in Südamerika (2)
- Spatial analysis (2)
- Spatial autocorrelation (2)
- Spatial bias (2)
- Spatial distribution (2)
- Spatial-numerical associations (2)
- Species co-existence (2)
- Species comparison (2)
- Species complex (2)
- Species distribution models (2)
- Species loss (2)
- Specific entropy (2)
- Spectral analysis (2)
- Spectrophotometry (2)
- Speech production (2)
- Speed (2)
- Speleothems (2)
- Spin probes (2)
- Spiralcurriculum (2)
- Splicing (2)
- Sprachwandel (2)
- Squeak (2)
- St. Petersburg (2)
- Staatsbibliothek zu Berlin (2)
- Staatsrecht (2)
- Stable carbon isotope (2)
- Standard deviation (2)
- Standardization (2)
- Starch (2)
- Statistical techniques (2)
- Statistics (2)
- Steady-state balance (2)
- Stemflow (2)
- Steric effect (2)
- Sterols (2)
- Stochastic differential equations (2)
- Stottern (2)
- Strain (2)
- Strategie (2)
- Stress pattern (2)
- Stress response (2)
- Stroke (2)
- Strong-motion (2)
- Structural equation modeling (2)
- Structural health monitoring (2)
- Student motivation (2)
- Studienabbruch (2)
- Studienerfolg (2)
- Sturmhochwasser (2)
- Subarctic North Pacific (2)
- Subsampling (2)
- Subsurface biosphere (2)
- Suguta Valley (2)
- Sulfate (2)
- Sulphoxide (2)
- Sumatra (2)
- Sun: UV radiation (2)
- Sun: filaments (2)
- Sun: heliosphere (2)
- Sun: magnetic topology (2)
- Sun: sunspots (2)
- Supernatural (2)
- Supernova remnants (2)
- Superoxide (2)
- Supervision (2)
- Support (2)
- Supramolecular chemistry (2)
- Surface composition (2)
- Surface exudates (2)
- Surface functionalization (2)
- Surface relief grating (2)
- Surface treatment (2)
- Surfactant (2)
- Surfactants (2)
- Survival (2)
- Sustainable (2)
- Sustainable development (2)
- Swarm constellation (2)
- Swedish (2)
- Syllabic tone (2)
- Synchronization control (2)
- Synchrotron (2)
- Syntax-semantics interface (2)
- Synthetic biology (2)
- Systematic review (2)
- Systematics (2)
- TGF-beta 1 (2)
- TMAO reductase (2)
- TMR (2)
- TPACK (2)
- TRLFS (2)
- TRP channels (2)
- TRPC6 (2)
- Taft equation (2)
- Tailspike protein (2)
- Talik (2)
- Talmud (2)
- TanDEM-X (2)
- Tanzania (2)
- Taphonomy (2)
- Tasks (2)
- Teacher Beliefs (2)
- Teacher beliefs (2)
- Teacher educator (2)
- Teacher enthusiasm (2)
- Teacher judgments (2)
- Teacher learning (2)
- Teaching quality (2)
- Team sports (2)
- Teamarbeit (2)
- Technical enzymes (2)
- Telehealth (2)
- Temperate forest (2)
- Temperature-memory effect (2)
- Tendinopathy (2)
- Tense (2)
- Tephrosia purpurea (2)
- TerraSAR-X (2)
- Terrestrial Si cycle (2)
- Test-retest (2)
- Text difficulty (2)
- Textbooks (2)
- Theorie von Förster (2)
- Therapie (2)
- Thermal effects (2)
- Thermal field (2)
- Thin films (2)
- Thiomersal (2)
- Threat (2)
- Threshold (2)
- Tibet (2)
- Tibetan plateau (2)
- Tight integration (2)
- Time of flight (2)
- Time-resolved spectroscopy (2)
- Toeplitz operators (2)
- Tomography (2)
- Tools (2)
- Torture (2)
- Total hip replacement (2)
- Total knee replacement (2)
- Total organic carbon (2)
- Toxicokinetics (2)
- Trace element geochemistry (2)
- Tracheostomy (2)
- Tracheotomie (2)
- Tracking (2)
- Training (2)
- Trans-European Suture Zone (2)
- Transcription factors (2)
- Transdisziplinarität (2)
- Transform faults (2)
- Transhimalaya (2)
- Transition metals (2)
- Translocation (2)
- Transnational History (2)
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- Transzendenz (2)
- Trauma (2)
- Treadmill walking (2)
- Tree allometry (2)
- Triticum aestivum L. (2)
- Trochaic Law (2)
- Trophic interactions (2)
- Tropical lake (2)
- Trumponomics (2)
- Trunk muscle strength (2)
- Turbulence (2)
- Turkish German (2)
- Turkish-German bilingualism (2)
- Turnover (2)
- Two forms of isometric muscle action (2)
- U-Pb geochronology (2)
- UAV (2)
- UN (2)
- UV (2)
- UV femtosecond laser ablation (2)
- UV irradiation (2)
- UV-vis spectroscopy (2)
- Ulcerative colitis (2)
- Ulrike Leitner (2)
- Ultrafast X-ray diffraction (2)
- Ultrasonography (2)
- Uncertainties (2)
- Uncertainty quantification (2)
- Understanding (2)
- Unemployment (2)
- Unique column combination (2)
- Unmanaged vs. managed forests (2)
- Unsaturated zone (2)
- Unterrichtsanalyse (2)
- Unterrichtsreflexion (2)
- Unterrichtsvideos (2)
- Upper Cambrian (2)
- Upper Cretaceous (2)
- Ursus arctos (2)
- VERB code (2)
- VIIRS DNB (2)
- Validität (2)
- Values (2)
- Variance (2)
- Vegetation (2)
- Vegetation dynamics (2)
- Ventral striatum (2)
- Verb doubling (2)
- Verbal cues (2)
- Verbalflexion (2)
- Verbs (2)
- Verhalten (2)
- Verification (2)
- Vermögen (2)
- Versalzung (2)
- Vertragsarbeit (2)
- Vibrio cholerae (2)
- Victimization (2)
- Video games (2)
- VideoScan technology (2)
- Vignetten (2)
- Virtualization (2)
- Viscoelasticity (2)
- Visual representations (2)
- Visual search (2)
- Visual system (2)
- Vitamin D-binding protein (2)
- Vogtland (2)
- Volatilization (2)
- Volcanic activity (2)
- Volcano monitoring (2)
- Voles (2)
- Vorschulalter (2)
- Vulkanismus (2)
- Vulpes vulpes (2)
- WKB-expansion (2)
- Walvis Ridge (2)
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- Water Science and Technology (2)
- Water distribution systems (2)
- Water management (2)
- Water resources (2)
- Waveform inversion (2)
- Weakly electric fish (2)
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- Weather (2)
- Wechselwirkungsabstand (2)
- Wehrmacht (2)
- Weight loss (2)
- Weight management trial (2)
- Weight stigma (2)
- Weight/shape concern (2)
- Well-being (2)
- West Africa (2)
- Western Central Africa (2)
- Western Europe (2)
- Wetter (2)
- Whey protein (2)
- Wicked problems (2)
- Widerstandsrecht (2)
- William James (2)
- Wissenschaftstheorie (2)
- Word learning (2)
- Word order (2)
- Word recognition (2)
- Work-anxiety (2)
- Wortschatz (2)
- X-ray computed tomography (CT) (2)
- X-ray crystallography (2)
- XAS (2)
- XES (2)
- Xanthomonas (2)
- Xylanase (2)
- Yamabe operator (2)
- Young adulthood (2)
- Young athletes (2)
- Yttria stabilized zirconia (2)
- Yucatan Peninsula (2)
- Yucatecan Spanish (2)
- Zahlentheorie (2)
- Zaremba problem (2)
- Zea mays (2)
- Zebrafish (2)
- Zechstein salt (2)
- Zenobia (2)
- Zinc homeostasis (2)
- Zoologie (2)
- Zootoca vivipara (2)
- [4+2] cycloaddition (2)
- a priori (2)
- ability differentiation (2)
- aboveground biomass (2)
- abstract concepts (2)
- academic entrepreneurship (2)
- academic performance (2)
- accelerated globalization (2)
- acceptability judgments (2)
- accommodation (2)
- accounting (2)
- accumulation (2)
- accuracy (2)
- achievement (2)
- achievement emotions (2)
- achilles tendinopathy (2)
- acidophile (2)
- actin (2)
- action language (2)
- action processing (2)
- action recognition (2)
- activated carbon (2)
- active transport (2)
- activity preference (2)
- actor (2)
- acute coronary syndrome (2)
- adaptability (2)
- adaptive estimation (2)
- adaptive force (2)
- additive particles (2)
- adjustment (2)
- administration (2)
- administrative culture (2)
- administrative reforms (2)
- adolescent athletes (2)
- adolescent growth (2)
- adolescent immigrants (2)
- advertisement (2)
- aerosol (2)
- affective (2)
- afforestation (2)
- age differentiation (2)
- agent-based model (2)
- agent-based models (2)
- aggressive behavior (2)
- aggressive cognitions (2)
- aggressive peers (2)
- aggressive sexual fantasies (2)
- agitation (2)
- agreement (2)
- agricultural landscapes (2)
- airborne (2)
- albuminuria (2)
- alcohol consumption (2)
- aldehyde oxidase (2)
- aldehydes (2)
- allocation policies (2)
- alpha-stable Levy process (2)
- alternaria group (2)
- ambient noise (2)
- amino acid (2)
- amitriptyline (2)
- ammonia synthesis (2)
- amperometry (2)
- amplitude (2)
- anachronism (2)
- anaphors (2)
- anatexis (2)
- and prediction (2)
- anger regulation (2)
- angiotensin receptor blockers (2)
- animal behavior (2)
- animal behaviour (2)
- animal models (2)
- anisotropic effects (2)
- anthracene (2)
- anthropogenic environment (2)
- anthropometric measures (2)
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- maximum a posteriori (2)
- maximum magnitude (2)
- measles virus (2)
- measurement error (2)
- mechanical (2)
- mechanical properties (2)
- mechanical tendinous oscillations (2)
- media (2)
- membrane proteins (2)
- memory and delay (2)
- memory studies (2)
- mental imagery (2)
- mental simulation (2)
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- metaanalysis (2)
- metabolic disease (2)
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- metabolic network (2)
- metacommunity (2)
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- metal coordination (2)
- metal-organic frameworks (2)
- metaphor (2)
- methane (2)
- method comparison (2)
- methodological quality (2)
- methyl orange (2)
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- methylmercury (2)
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- mica (2)
- micelles (2)
- micro-CT (2)
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- microbes (2)
- microbial (2)
- microbial communities (2)
- microbial diversity (2)
- microbial interactions (2)
- microclimate (2)
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- microemulsion (2)
- microscopy (2)
- microtubule-organization (2)
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- mild cognitive impairment (2)
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- minimal pairs (2)
- minimax convergence rates (2)
- minorities (2)
- mirror (2)
- mirror illusion (2)
- mirror therapy (2)
- miscellaneous (2)
- miscibility gap (2)
- missing-VP effect (2)
- mitochondrial dysfunction (2)
- mitochondrial function (2)
- mitogenome (2)
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- mixtures (2)
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- modal verbs (2)
- modality compatibility (2)
- model coupling (2)
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- modeling language (2)
- modern art (2)
- modified Mannich reaction (2)
- modular production (2)
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- molecular weight (2)
- molecules (2)
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- monomers (2)
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- morphological decomposition (2)
- morphological priming (2)
- morphologically complex words (2)
- motion analysis (2)
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- motor system (2)
- mouse (2)
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- mowing (2)
- multi-agent system (2)
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- multiple (2)
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- muscle metabolism (2)
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- mutants (2)
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- need satisfaction (2)
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- network analysis (2)
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- neurodegenerative diseases (2)
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- neutrality (2)
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- niche width (2)
- nitrile (2)
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- oil palm (2)
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- online learning (2)
- ontogenesis (2)
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- open (2)
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- oppositions (2)
- optical imaging (2)
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- optics (2)
- optimality theory (2)
- optimism (2)
- orbifolds (2)
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- organic carbon (2)
- organic chemistry (2)
- organic electronics (2)
- organizations (2)
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- osteoblast (2)
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- outbreak (2)
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- overland flow (2)
- oxidation state (2)
- oxygen heterocycles (2)
- oxygen plasma (2)
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- p53 (2)
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- parameter (2)
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- parchment (2)
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- parents (2)
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- politische Eliten (2)
- politische Ideologie (2)
- politische Philosophie (2)
- pollination (2)
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- poly(epsilon-caprolactone) (2)
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- protein-protein (2)
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- pubertal timing (2)
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- pulling isometric muscle action (PIMA) (2)
- pulsars: individual: PSR B0833-45 (2)
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- queer (2)
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- radiation mechanisms: nonthermal (2)
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- radiative forcing (2)
- radiogenic isotopes (2)
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- rainfall (2)
- rainfall gradient (2)
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- redox state (2)
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- relations (2)
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- relative clause (2)
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- renormalization Hopf algebra (2)
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- reproducing kernel Hilbert space (2)
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- sanctions (2)
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- semi-parliamentary government (2)
- semiconducting polymers (2)
- semiconductor lasers (2)
- sensor (2)
- sensor alignment (2)
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- sentence parsing (2)
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- serum (2)
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- short-read mapping (2)
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- singularity (2)
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- skill (2)
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- sodium hydroxide etching (2)
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- soil aggregation (2)
- soil fatigue (2)
- soil landscape (2)
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- solubility (2)
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- somatic variables (2)
- source parameters (2)
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- soy protein (2)
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- spatial scales (2)
- spatial statistics (2)
- spatial vision (2)
- spatially explicit model (2)
- speakers (2)
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- species recognition (2)
- specific developmental disorder (2)
- specific language impairment (2)
- specificity (2)
- specifier proteins (2)
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- speech motor control (2)
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- speed-accuracy trade-off (2)
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- sphingomyelin (2)
- spider silk (2)
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- spiral curriculum (2)
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- stars: individual ([HD 36486]delta Ori A) (2)
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- stars: variables: Cepheids (2)
- state (2)
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- statistische Modelle (2)
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- students (2)
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- virus (2)
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Institute
- Institut für Physik und Astronomie (4084)
- Institut für Biochemie und Biologie (3674)
- Institut für Geowissenschaften (2696)
- Institut für Chemie (2373)
- Department Psychologie (1736)
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Sharing marketplaces emerged as the new Holy Grail of value creation by enabling exchanges between strangers. Identity reveal, encouraged by platforms, cuts both ways: While inducing pre-transaction confidence, it is suspected of backfiring on the information senders with its discriminative potential. This study employs a discrete choice experiment to explore the role of names as signifiers of discriminative peculiarities and the importance of accompanying cues in peer choices of a ridesharing offer. We quantify users' preferences for quality signals in monetary terms and evidence comparative disadvantage of Middle Eastern descent male names for drivers and co-travelers. It translates into a lower willingness to accept and pay for an offer. Market simulations confirm the robustness of the findings. Further, we discover that females are choosier and include more signifiers of involuntary personal attributes in their decision-making. Price discounts and positive information only partly compensate for the initial disadvantage, and identity concealment is perceived negatively.
Nowadays, production planning and control must cope with mass customization, increased fluctuations in demand, and high competition pressures. Despite prevailing market risks, planning accuracy and increased adaptability in the event of disruptions or failures must be ensured, while simultaneously optimizing key process indicators. To manage that complex task, neural networks that can process large quantities of high-dimensional data in real time have been widely adopted in recent years. Although these are already extensively deployed in production systems, a systematic review of applications and implemented agent embeddings and architectures has not yet been conducted. The main contribution of this paper is to provide researchers and practitioners with an overview of applications and applied embeddings and to motivate further research in neural agent-based production. Findings indicate that neural agents are not only deployed in diverse applications, but are also increasingly implemented in multi-agent environments or in combination with conventional methods — leveraging performances compared to benchmarks and reducing dependence on human experience. This not only implies a more sophisticated focus on distributed production resources, but also broadening the perspective from a local to a global scale. Nevertheless, future research must further increase scalability and reproducibility to guarantee a simplified transfer of results to reality.
In nowadays production, fluctuations in demand, shortening product life-cycles, and highly configurable products require an adaptive and robust control approach to maintain competitiveness. This approach must not only optimise desired production objectives but also cope with unforeseen machine failures, rush orders, and changes in short-term demand. Previous control approaches were often implemented using a single operations layer and a standalone deep learning approach, which may not adequately address the complex organisational demands of modern manufacturing systems. To address this challenge, we propose a hyper-heuristics control model within a semi-heterarchical production system, in which multiple manufacturing and distribution agents are spread across pre-defined modules. The agents employ a deep reinforcement learning algorithm to learn a policy for selecting low-level heuristics in a situation-specific manner, thereby leveraging system performance and adaptability. We tested our approach in simulation and transferred it to a hybrid production environment. By that, we were able to demonstrate its multi-objective optimisation capabilities compared to conventional approaches in terms of mean throughput time, tardiness, and processing of prioritised orders in a multi-layered production system. The modular design is promising in reducing the overall system complexity and facilitates a quick and seamless integration into other scenarios.
Algorithmic management
(2022)
Clubs of autocrats
(2021)
While scholars have argued that membership in Regional Organizations (ROs) can increase the likelihood of democratization, we see many autocratic regimes surviving in power albeit being members of several ROs. This article argues that this is the case because these regimes are often members in "Clubs of Autocrats" that supply material and ideational resources to strengthen domestic survival politics and shield members from external interference during moments of political turmoil. The argument is supported by survival analysis testing the effect of membership in autocratic ROs on regime survival between 1946 to 2010. It finds that membership in ROs composed of more autocratic member states does in fact raise the likelihood of regime survival by protecting incumbents against democratic challenges such as civil unrest or political dissent. However, autocratic RO membership does not help to prevent regime breakdown due to autocratic challenges like military coups, potentially because these types of threats are less likely to diffuse to other member states. The article thereby adds to our understanding of the limits of democratization and potential reverse effects of international cooperation, and contributes to the literature addressing interdependences of international and domestic politics in autocratic regimes.
Major international organizations (IOs) are heavily contested, but they are rarely dissolved. Scholars have focused on their longevity, making institutional arguments about replacement costs and institutional assets as well as IO agency to adapt and resist challenges. This article analyzes the limits of institutional stickiness by focusing on outlier cases. While major IOs are dissolved at considerably lower rates than minor IOs, the article nevertheless identifies twenty-one cases where major IOs have died since 1815. These are tough cases as they do not conform to our institutionalist expectations. To better understand these rare but important events, the article provides case illustrations from the League of Nations and International Refugee Organization, which were dissolved due to their perceived underperformance and a disappearing demand for cooperation. These cases show the limits of the institutional theories of IO stickiness: sometimes member states find high replacement costs justified or consider assets as sunk costs, and IOs may lack agency to strategically respond. This article refines theories of institutional stickiness and contributes to the institutional theory of the life and death of IOs.
Les principales organisations internationales (OI) sont fortement contestées, mais rarement dissoutes. Pour expliquer leur longévité, les chercheurs ont avancé des arguments institutionnels concernant les coûts de remplacement et les actifs de l'institution, mais aussi la capacité des OI à s'adapter et à résister aux défis. Cet article analyse les limites de la persistance des institutions en se concentrant sur des cas particuliers. Tandis que les principales OI sont dissoutes bien moins fréquemment que des OI moins importantes, cet article identifie néanmoins 21 cas de disparition d'OI principales depuis 1815. Ces derniers sont particulièrement difficiles, car ils ne correspondent pas à nos attentes en termes d'institutions. Afin de mieux comprendre ces événements rares, mais non moins importants, l'article propose comme illustrations de cas la Société des Nations et l'Organisation internationale pour les réfugiés, qui ont été dissoutes à cause de leur manque apparent de résultats et de la disparition de la demande de coopération. Ces cas mettent en évidence les limites des théories institutionnelles de persistance des OI : parfois, les États membres considèrent les coûts de remplacement élevés justifiés ou les actifs comme des coûts irrécupérables, et les OI n'ont peut-être pas la capacité de leur répondre de manière stratégique. Le présent article affine les théories de persistance institutionnelle et contribue à la théorie institutionnelle de vie et de mort des OI.
Las organizaciones internacionales (OI) más importantes son muy cuestionadas, pero rara vez se disuelven. Los investigadores se han centrado en la longevidad de las IO, formulando argumentos institucionales sobre los costes de sustitución y los activos institucionales, así como sobre la capacidad de adaptación y resistencia de las organizaciones internacionales. Este artículo analiza los límites de la rigidez institucional centrándose en casos atípicos. Aunque las OI más importantes se disuelven en proporciones considerablemente menores que las OI de menor importancia, el artículo identifica 21 casos en los que OI más importantes desaparecieron desde 1815. Se trata de casos difíciles, ya que no se ajustan a nuestras expectativas institucionalistas. Para comprender mejor estos raros pero importantes acontecimientos, el artículo ofrece ejemplos de casos de la Sociedad de Naciones y de la, Organización Internacional para los Refugiados que se disolvieron debido a su bajo desempeño percibido y a la desaparición de la demanda de cooperación. Estos casos muestran los límites de las teorías institucionales sobre la rigidez de las OI: En ocasiones, los Estados miembros consideran justificados los elevados costes de sustitución o consideran que los activos son costes irrecuperables, y las OI pueden no disponer de capacidad de respuesta estratégica. Este artículo profundiza en las teorías de la rigidez institucional y contribuye a la teoría institucional de la vida y la muerte de las organizaciones internacionales.
Biological maturation has been shown to affect male youths' responses to plyometric training (PT). However, to date, no researcher has examined the effect of maturation on the effects of PT in female youth. We undertook the first controlled intervention study to examine this, focusing on adaptive responses to countermovement jump (CMJ), reactive strength index (RSI), and change of direction (COD) performance in groups of female youth divided by maturation status (years from peak height velocity [PHV]). The training program lasted 7 weeks with subjects undertaking 2 sessions of PT per week. In the mid-PHV group, there was a small increase (effect size; 90% confidence interval = 0.40; -0.23 to 1.03) in CMJ performance. No changes were observed in the post-PHV group (0.02; -0.68 to 0.72). For RSI, there was a moderate increase in the mid-PHV group (0.94; 0.29-1.59) with only a trivial increase in the post-PHV group (0.06; -0.65 to 0.76). The intervention exerted no positive effect on COD performance in any group. Plyometric training seems to enhance CMJ and RSI in female youth, although the magnitude of adaptation could be affected by maturation status. A twice-per-week program of multidirectional jumping and hopping, with bilateral and unilateral components, can be used as a preparatory precursor to physical education classes or recreational sport.
Uruguay River is the most important river in western Rio Grande do Sul, separating Brazil from Argentina and Uruguay. However, its pollution is of great concern due to agricultural activities in the region and the extensive use of pesticides. In a long term, this practice leads to environmental pollution, especially to the aquatic system. The objective of this study was to analyze the physicochemical characteristics, metals and pesticides levels in water samples obtained before and after the planting and pesticides' application season from three sites: Uruguay River and two minor affluents, Mezomo Dam and Salso Stream. For biomonitoring, the free-living nematode Caenorhabditis elegans was used, which were exposed for 24 h. We did not find any significant alteration in physicochemical parameters. In the pre- and post-pesticides' samples we observed a residual presence of three pesticides (tebuconazole, imazethapyr, and clomazone) and metals which levels were above the recommended (As, Hg, Fe, and Mn). Exposure to both pre- and post-pesticides' samples impaired C. elegans reproduction and post-pesticides samples reduced worms' survival rate and lifespan. PCA analysis indicated that the presence of metals and pesticides are important variables that impacted C. elegans biological endpoints. Our data demonstrates that Uruguay River and two affluents are contaminated independent whether before or after pesticides' application season. In addition, it reinforces the usefulness of biological indicators, since simple physicochemical analyses are not sufficient to attest water quality and ecological safety.
Die Herstellung von Produkten bindet Energie sowie auch materielle Ressourcen. Viel zu langsam entwickeln sich sowohl das Bewusstsein der Konsumenten sowie der Produzenten als auch gesetzgebende Aktivitäten, um zu einem nachhaltigen Umgang mit den zur Verfügung stehenden Ressourcen zu gelangen. In diesem Beitrag wird ein lokaler Remanufacturing-Ansatz vorgestellt, der es ermöglicht, den Ressourcenverbrauch zu reduzieren, lokale Unternehmen zu fördern und effiziente Lösungen für die regionale Wieder- und Weiterverwendung von Gütern anzubieten.
Strategic social media use positively influences organizational goals such as the long-term accrual of social capital, and thus social media information governance has become an increasingly important organizational objective. It is particularly important for humanitarian nongovernmental organizations (HNGOs), whose work relies on accurate and timely information regarding socially altruistic behavior (donations, volunteerism, etc.). Despite the potential of social media for increasing social capital, tensions in governing social media information across an organization's different operational levels (regional, intermediate, and national) pose a difficult challenge. Prominent governance frameworks offer little guidance, as their focus on control and incremental policymaking is largely incompatible with the processes, roles, standards, and metrics needed for managing self-governing social media. This study offers a notion of dynamic and co-evolutionary process management of multi-level organizations as a means of conceptualizing social media information governance for the accrual of organizational social capital. Based on interviews with members of HNGOs, this study reveals tensions that emerge within eight focus areas of accruing social capital in multi-level organizations, explains how dynamic process management can ease those tensions, and proposes corresponding strategy recommendations.
AUKUS und die strukturellen Veränderungen der sicherheitspolitischen Lage im indo-pazifischen Raum
(2022)
Many international organisations (IOs) are currently challenged, yet are they also in decline? Despite much debate on the crisis of liberal international order, con-testation, loss of legitimacy, gridlock, pathologies and exiting member states, there is little research on IO decline. This article seeks to clarify this concept and argues that decline can be considered in absolute and relative terms. Absolute decline involves a decrease in the number of IOs and their authority, member-ship and output, whereas relative decline concerns a decrease in the centrality of IOs in international relations. Reviewing a wide range of indicators, this article argues that, whereas there is limited decline in absolute terms since 1945, there may well be important decline in relative terms. Relative decline is more difficult to measure, but to probe its significance this article presents data from speeches during the United Nations General Assembly General Debate. It shows that IOs were most often mentioned in 1996 and that there has been a decline since. These findings indicate that, whereas IOs might survive as institutions, they are decreasingly central to international relations.
Governance abhors a vacuum
(2023)
International organisations have become increasingly contested resulting in worries about their decline and termination. While international organisation termination is indeed a regular event in international relations, this article shows that other institutions carry the legacy of terminated international organisations. We develop the novel concept of international organisation afterlife and suggest indicators to systematically assess it. Our analysis of 26 major terminated international organisations reveals legal-institutional and asset continuity in 21 cases. To further illustrate this point, the article zooms in on the afterlife of the International Institute of Agriculture in the Food and Agriculture Organization, the International Refugee Organization in the United Nations High Commissioner for Refugees, and the Western European Union in the European Union. In these three cases, international organisation afterlife inspired and structured the design of their successor institutions. While specific international organisations might be terminated, international cooperation therefore often lives on in other institutions.
Better land stewardship is needed to achieve the Paris Agreement's temperature goal, particularly in the tropics, where greenhouse gas emissions from the destruction of ecosystems are largest, and where the potential for additional land carbon storage is greatest. As countries enhance their nationally determined contributions (NDCs) to the Paris Agreement, confusion persists about the potential contribution of better land stewardship to meeting the Agreement's goal to hold global warming below 2 degrees C. We assess cost-effective tropical country-level potential of natural climate solutions (NCS)-protection, improved management and restoration of ecosystems-to deliver climate mitigation linked with sustainable development goals (SDGs). We identify groups of countries with distinctive NCS portfolios, and we explore factors (governance, financial capacity) influencing the feasibility of unlocking national NCS potential. Cost-effective tropical NCS offers globally significant climate mitigation in the coming decades (6.56 Pg CO(2)e yr(-1) at less than 100 US$ per Mg CO(2)e). In half of the tropical countries, cost-effective NCS could mitigate over half of national emissions. In more than a quarter of tropical countries, cost-effective NCS potential is greater than national emissions. We identify countries where, with international financing and political will, NCS can cost-effectively deliver the majority of enhanced NDCs while transforming national economies and contributing to SDGs. This article is part of the theme issue 'Climate change and ecosystems: threats, opportunities and solutions'.
As autotrophic organisms, plants capture light energy to convert carbon dioxide into ATP, nicotinamide adenine dinucleotide phosphate (NADPH), and sugars, which are essential for the biosynthesis of building blocks, storage, and growth. At night, metabolism and growth can be sustained by mobilizing carbon (C) reserves. In response to changing environmental conditions, such as light-dark cycles, the small-molecule regulation of enzymatic activities is critical for reprogramming cellular metabolism. We have recently demonstrated that proteogenic dipeptides, protein degradation products, act as metabolic switches at the interface of proteostasis and central metabolism in both plants and yeast. Dipeptides accumulate in response to the environmental changes and act via direct binding and regulation of critical enzymatic activities, enabling C flux distribution. Here, we provide evidence pointing to the involvement of dipeptides in the metabolic rewiring characteristics for the day-night cycle in plants. Specifically, we measured the abundance of 13 amino acids and 179 dipeptides over short- (SD) and long-day (LD) diel cycles, each with different light intensities. Of the measured dipeptides, 38 and eight were characterized by day-night oscillation in SD and LD, respectively, reaching maximum accumulation at the end of the day and then gradually falling in the night. Not only the number of dipeptides, but also the amplitude of the oscillation was higher in SD compared with LD conditions. Notably, rhythmic dipeptides were enriched in the glucogenic amino acids that can be converted into glucose. Considering the known role of Target of Rapamycin (TOR) signaling in regulating both autophagy and metabolism, we subsequently investigated whether diurnal fluctuations of dipeptides levels are dependent on the TOR Complex (TORC). The Raptor1b mutant (raptor1b), known for the substantial reduction of TOR kinase activity, was characterized by the augmented accumulation of dipeptides, which is especially pronounced under LD conditions. We were particularly intrigued by the group of 16 dipeptides, which, based on their oscillation under SD conditions and accumulation in raptor1b, can be associated with limited C availability or photoperiod. By mining existing protein-metabolite interaction data, we delineated putative protein interactors for a representative dipeptide Pro-Gln. The obtained list included enzymes of C and amino acid metabolism, which are also linked to the TORC-mediated metabolic network. Based on the obtained results, we speculate that the diurnal accumulation of dipeptides contributes to its metabolic adaptation in response to changes in C availability. We hypothesize that dipeptides would act as alternative respiratory substrates and by directly modulating the activity of the focal enzymes.
The existence of cancer stem cells (CSCs) poses a major obstacle for the success of current cancer therapies, especially the fact that non-CSCs can spontaneously turn into CSCs, which lead to the failure of the treatment and tumor relapse. Therefore, it is very important to develop effective strategies for the eradication of the CSCs. In this work, we have developed a CSCs-specific targeted, retinoic acid (RA)-loaded gold nanostars-dendritic polyglycerol (GNSs-dPG) nanoplatform for the efficient eradication of CSCs. The nanocomposites possess good biocompatibility and exhibit effective CSCs-specific multivalent targeted capability due to hyaluronic acid (HA) decorated on the multiple attachment sites of the bioinert dendritic polyglycerol (dPG). With the help of CSCs differentiation induced by RA, the self-renewal of breast CSCs and tumor growth were suppressed by the high therapeutic efficacy of photothermal therapy (PTT) in a synergistic inhibitory manner. Moreover, the stemness gene expression and CSC-driven tumorsphere formation were significantly diminished. In addition, the in vivo tumor growth and CSCs were also effectively eliminated, which indicated superior anticancer activity, effective CSCs suppression, and prevention of relapse. Taken together, we developed a CSCs-specific targeted, RA-loaded GNSs-dPG nanoplatform for the targeted eradication of CSCs and for preventing the relapse.
The control of residual stress (RS) remains a challenge in the manufacturing of metallic parts using the laser powder bed fusion process (LPBF). This layer-by-layer manufacturing approach gives rise to complex triaxial RS distributions, which require extensive characterization effort for a broader acceptance of LPBF in industry. This study focuses on the distribution of bulk triaxial RS and surface RS in LPBF austenitic steel 316L. The RS are determined by X-ray and neutron diffraction to characterize the RS distribution. Variations in the LPBF parameters interlayer time (ILT) and scanning velocity and their influence on the temperature distribution and resulting RS is investigated using thermographic data from in situ process monitoring. The RS in the LPBF 316L is tensile at the surface and compressive in the bulk. The RS is directly related to the thermal history of the part as shown by the in situ thermography data. Shorter ILT leads to higher temperatures of the part during the manufacturing, which decrease the RS and RS formation mechanisms. Interestingly, the surface RS does not agree with this observation. This study highlights the benefit of using multiple RS determination methods and in situ thermography monitoring to characterize the RS in LPBF processed parts.
The most complex but potentially most severe impacts of climate change are caused by extreme weather events. In a globally connected economy, damages can cause remote perturbations and cascading consequences-a ripple effect along supply chains. Here we show an economic ripple resonance that amplifies losses when consecutive or overlapping weather extremes and their repercussions interact. This amounts to an average amplification of 21% for climate-induced heat stress, river floods, and tropical cyclones. Modeling the temporal evolution of 1.8 million trade relations between >7000 regional economic sectors, we find that the regional responses to future extremes are strongly heterogeneous also in their resonance behavior. The induced effect on welfare varies between gains due to increased demand in some regions and losses due to demand or supply shortages in others. Within the current global supply network, the ripple resonance effect of extreme weather is strongest in high-income economies-an important effect to consider when evaluating past and future economic climate impacts.
Visible light is shown to create a transient metallic S-Mo-S surface layer on bulk semiconducting p-doped indirect-bandgap 2H-MoS2. Optically created electron-hole pairs separate in the surface band bending region of the p-doped semiconducting crystal causing a transient accumulation of electrons in the surface region. This triggers a reversible 2H-semiconductor to 1T-metal phase-transition of the surface layer. Electron-phonon coupling of the indirect-bandgap p-doped 2H-MoS2 enables this efficient pathway even at a low density of excited electrons with a distinct optical excitation threshold and saturation behavior. This mechanism needs to be taken into consideration when describing the surface properties of illuminated p-doped 2H-MoS2. In particular, light-induced increased charge mobility and surface activation can cause and enhance the photocatalytic and photoassisted electrochemical hydrogen evolution reaction of water on 2H-MoS2. Generally, it opens up for a way to control not only the surface of p-doped 2H-MoS2 but also related dichalcogenides and layered systems. The findings are based on the sensitivity of time-resolved electron spectroscopy for chemical analysis with photon-energy-tuneable synchrotron radiation.
Rapid migration of mesenchymal stem cells (MSCs) on device surfaces could support in vivo tissue integration and might facilitate in vitro organoid formation. Here, polydopamine (PDA) is explored as a biofunctional coating to effectively promote MSC motility. It is hypothesized that PDA stimulates fibronectin deposition and in this way enhances integrin-mediated migration capability. The random and directional cell migration was investigated by time-lapse microscopy and gap closure assay respectively, and analysed with softwares as computational tools. A higher amount of deposited fibronectin was observed on PDA substrate, compared to the non-coated substrate. The integrin beta 1 activation and focal adhesion kinase (FAK) phosphorylation at Y397 were enhanced on PDA substrate, but the F-actin cytoskeleton was not altered, suggesting MSC migration on PDA was regulated by integrin initiated FAK signalling. This study strengthens the biofunctionality of PDA coating for regulating stem cells and offering a way of facilitating tissue integration of devices.
The enhancement and control of the electrical conductivity of organic semiconductors is fundamental for their use in optoelectronic applications and can be achieved by molecular doping, which introduces additional charge carriers through electron transfer between a dopant molecule and the organic semiconductor. Here, we use Electron Paramagnetic Resonance (EPR) spectroscopy to characterise the unpaired spins associated with the charges generated by molecular doping of the prototypical organic semiconductor poly(3-hexylthiophene) (P3HT) with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F(4)TCNQ) and tris(pentafluorophenyl)borane (BCF). The EPR results reveal the P3HT radical cation as the only paramagnetic species in BCF-doped P3HT films and show evidence for increased mobility of the detected spins at high doping concentrations as well as formation of antiferromagnetically coupled spin pairs leading to decreased spin concentrations at low temperatures. The EPR signature for F(4)TCNQ-doped P3HT is found to be determined by spin exchange between P3HT radical cations and F(4)TCNQ radical anions. Results from continuous-wave and pulse EPR measurements suggest the presence of the unpaired spin on P3HT in a multitude of environments, ranging from free P3HT radical cations with similar properties to those observed in BCF-doped P3HT, to pairs of dipolar and exchange-coupled spins on P3HT and the dopant anion. Characterisation of the proton hyperfine interactions by ENDOR allowed quantification of the extent of spin delocalisation and revealed reduced delocalisation in the F(4)TCNQ-doped P3HT films.
We study a heterogeneous diffusion process (HDP) with position-dependent diffusion coefficient and Poissonian stochastic resetting.
We find exact results for the mean squared displacement and the probability density function. The nonequilibrium steady state reached in the long time limit is studied.
We also analyse the transition to the non-equilibrium steady state by finding the large deviation function.
We found that similarly to the case of the normal diffusion process where the diffusion length grows like t (1/2) while the length scale xi(t) of the inner core region of the nonequilibrium steady state grows linearly with time t, in the HDP with diffusion length increasing like t ( p/2) the length scale xi(t) grows like t ( p ).
The obtained results are verified by numerical solutions of the corresponding Langevin equation.
Here we show that microgels trapped at a solid wall can issue liquid flow and transport over distances several times larger than the particle size.
The microgel consists of cross-linked poly(N-isopropylacrylamide-co-acrylic acid) (PNIPAM-AA) polymer chains loaded with cationic azobenzene-containing surfactant, which can assume either a trans-or a cis-state depending on the wavelength of the applied irradiation. The microgel, being a selective absorber of trans-isomers, responds by changing its volume under irradiation with light of appropriate wavelength at which the cis-isomers of the surfactant molecules diffuse out of the particle interior.
Together with the change in particle size, the expelled cis-isomers form an excess of the concentration and subsequent gradient in osmotic pressure generating a halo of local light-driven diffusioosmotic (l-LDDO) flow. The direction and the strength of the l-LDDO depends on the intensity and irradiation wavelength, as well as on the amount of surfactant absorbed by the microgel.
The flow pattern around a microgel is directed radially outward and can be maintained quasi-indefinitely under exposure to blue light when the trans-/cis-ratio is 2/1, establishing a photostationary state.
Irradiation with UV light, on the other hand, generates a radially transient flow pattern, which inverts from inward to outward over time at low intensities.
By measuring the displacement of tracer particles around neutral microgels during a temperature-induced collapse, we can exclude that a change in particle shape itself causes the flow, i.e., just by expulsion or uptake of water.
Ultimately, it is its ability to selectively absorb two isomers of photosensitive surfactant under different irradiation conditions that leads to an effective pumping caused by a self-induced diffusioosmotic flow.
Extracting information about past tectonic or climatic environmental changes from sedimentary records is a key objective of provenance research. Interpreting the imprint of such changes remains challenging as signals might be altered in the sediment-routing system.
We investigate the sedimentary provenance of the Oligocene/Miocene Upper Austrian Northern Alpine Foreland Basin and its response to the tectonically driven exhumation of the Tauern Window metamorphic dome (28 +/- 1 Ma) in the Eastern European Alps by using the unprecedented combination of Nd isotopic composition of bulk-rock clay-sized samples and partly previously published multi-proxy (Nd isotopic composition, trace-element geochemistry, U-Pb dating) sand-sized apatite single-grain analysis.
The basin offers an excellent opportunity to investigate environmental signal propagation into the sedimentary record because comprehensive stratigraphic and seismic datasets can be combined with present research results. The bulk-rock clay-sized fraction epsilon Nd values of well-cutting samples from one well on the northern basin slope remained stable at similar to-9.7 from 27 to 19 Ma but increased after 19 Ma to similar to-9.1. In contrast, apatite single-grain distributions, which were extracted from 22 drill-core samples, changed significantly around 23.3 Ma from apatites dominantly from low-grade (<upper amphibolite-facies) metamorphic sources with Permo-Mesozoic and late Variscan U-Pb ages and epsilon Nd values of -4.4 to dominantly high-grade metamorphic apatites with late Variscan U-Pb ages and epsilon Nd values of -2.2.
The change in apatite single-grain distributions at 23.3 Ma is interpreted to result from the exposure of a new Upper Austroalpine source nappe with less negative epsilon Nd values triggered by the ongoing Tauern Window exhumation. Combining these data with the clay-sized bulk-rock epsilon Nd values reveals that the provenance changed 4-5 Myrs later at 19 Ma in the clay-sized fraction.
Reasons for the delayed provenance-change recording are rooted in the characteristics of the applied methods.
Whereas single-grain distributions of orogen-wide sediment-routing systems can be dominated by geographically small areas with high erosion and mineral fertility rates, bulk-rock methods integrate over the entire drainage basin, thus diminishing extreme values. Hence, by combining these two methods, spatial information are uncovered, enabling a previously unattained understanding of the underlying environmental change.
Jurisdiction
(2022)
Since the beginning of the recent global refugee crisis, researchers have been tackling many of its associated aspects, investigating how we can help to alleviate this crisis, in particular, using ICTs capabilities. In our research, we investigated the use of ICT solutions by refugees to foster the social inclusion process in the host community. To tackle this topic, we conducted thirteen interviews with Syrian refugees in Germany. Our findings reveal different ICT usages by refugees and how these contribute to feeling empowered. Moreover, we show the sources of empowerment for refugees that are gained by ICT use. Finally, we identified the two types of social inclusion benefits that were derived from empowerment sources. Our results provide practical implications to different stakeholders and decision-makers on how ICT usage can empower refugees, which can foster the social inclusion of refugees, and what should be considered to support them in their integration effort.
Mit dem Klima wandelt sich auch notwendig die offene Gesellschaft. Und mit ihr wandelt sich wiederum auch die Verfassung(-sinterpretation). Periodisch wiederkehrende Gesundheits- und Sicherheitskrisen fordern eine dynamische Reaktion des Grundgesetzes auf mit ihnen einhergehende Probleme. In andauernden Krisen wie der Umweltkrise muss die Verfassung gleichzeitig in vielerlei Hinsicht nachhaltig sein. Dabei muss das, was wir unter Freiheit, Klima‑, Umwelt- oder Tierschutz verstehen, immer im Wandel bleiben.
BACKGROUND: The orbitofrontal cortex (OFC) is implicated in depression. The hypothesis investigated was whether the OFC sensitivity to reward and nonreward is related to the severity of depressive symptoms.
METHODS: Activations in the monetary incentive delay task were measured in the IMAGEN cohort at ages 14 years (n = 1877) and 19 years (n = 1140) with a longitudinal design. Clinically relevant subgroups were compared at ages 19 (high-severity group: n = 116; low-severity group: n = 206) and 14.
RESULTS: The medial OFC exhibited graded activation increases to reward, and the lateral OFC had graded activation increases to nonreward. In this general population, the medial and lateral OFC activations were associated with concurrent depressive symptoms at both ages 14 and 19 years. In a stratified high-severity depressive symptom group versus control group comparison, the lateral OFC showed greater sensitivity for the magnitudes of activations related to nonreward in the high-severity group at age 19 (p = .027), and the medial OFC showed decreased sensitivity to the reward magnitudes in the high-severity group at both ages 14 (p = .002) and 19 (p = .002). In a longitudinal design, there was greater sensitivity to nonreward of the lateral OFC at age 14 for those who exhibited high depressive symptom severity later at age 19 (p = .003).
CONCLUSIONS: Activations in the lateral OFC relate to sensitivity to not winning, were associated with high depressive symptom scores, and at age 14 predicted the depressive symptoms at ages 16 and 19. Activations in the medial OFC were related to sensitivity to winning, and reduced reward sensitivity was associated with concurrent high depressive symptom scores.
White mica and tourmaline are the dominant hydrothermal alteration minerals at the world-class Panasqueira W-Sn-Cu deposit in Portugal. Thus, understanding the controls on their chemical composition helps to constrain ore formation processes at this deposit and determine their usefulness as pathfinder minerals for mineralization in general. We combine whole-rock geochemistry of altered and unaltered metasedimentary host rocks with in situ LA-ICP-MS measurements of tourmaline and white mica from the alteration halo. Principal component analysis (PCA) is used to better identify geochemical patterns and trends of hydrothermal alteration in the datasets. The hydrothermally altered metasediments are enriched in As, Sn, Cs, Li, W, F, Cu, Rb, Zn, Tl, and Pb relative to unaltered samples. In situ mineral analyses show that most of these elements preferentially partition into white mica over tourmaline (Li, Rb, Cs, Tl, W, and Sn), whereas Zn is enriched in tourmaline. White mica has distinct compositions in different settings within the deposit (greisen, vein selvages, wall rock alteration zone, late fault zone), indicating a compositional evolution with time. In contrast, tourmaline from different settings overlaps in composition, which is ascribed to a stronger dependence on host rock composition and also to the effects of chemical zoning and microinclusions affecting the LA-ICP-MS analyses. Hence, in this deposit, white mica is the better recorder of the fluid composition. The calculated trace-element contents of the Panasqueira mineralizing fluid based on the mica data and estimates of mica-fluid partition coefficients are in good agreement with previous fluid-inclusion analyses. A compilation of mica and tourmaline trace-element compositions from Panasqueira and other W-Sn deposits shows that white mica has good potential as a pathfinder mineral, with characteristically high Li, Cs, Rb, Sn, and W contents. The trace-element contents of hydrothermal tourmaline are more variable. Nevertheless, the compiled data suggest that high Sn and Li contents are distinctive for tourmaline from W-Sn deposits.
In nature, plants are constantly exposed to many transient, but recurring, stresses. Thus, to complete their life cycles, plants require a dynamic balance between capacities to recover following cessation of stress and maintenance of stress memory. Recently, we uncovered a new functional role for macroautophagy/autophagy in regulating recovery from heat stress (HS) and resetting cellular memory of HS inArabidopsis thaliana. Here, we demonstrated that NBR1 (next to BRCA1 gene 1) plays a crucial role as a receptor for selective autophagy during recovery from HS. Immunoblot analysis and confocal microscopy revealed that levels of the NBR1 protein, NBR1-labeled puncta, and NBR1 activity are all higher during the HS recovery phase than before. Co-immunoprecipitation analysis of proteins interacting with NBR1 and comparative proteomic analysis of annbr1-null mutant and wild-type plants identified 58 proteins as potential novel targets of NBR1. Cellular, biochemical and functional genetic studies confirmed that NBR1 interacts with HSP90.1 (heat shock protein 90.1) and ROF1 (rotamase FKBP 1), a member of the FKBP family, and mediates their degradation by autophagy, which represses the response to HS by attenuating the expression ofHSPgenes regulated by the HSFA2 transcription factor. Accordingly, loss-of-function mutation ofNBR1resulted in a stronger HS memory phenotype. Together, our results provide new insights into the mechanistic principles by which autophagy regulates plant response to recurrent HS.
Copolyesterurethanes (PDLCLs) based on oligo(epsilon-caprolactone) (OCL) and oligo(omega-pentadecalactone) (OPDL) segments are biodegradable thermoplastic temperature-memory polymers. The temperature-memory capability in these polymers with crystallizable control units is implemented by a thermomechanical programming process causing alterations in the crystallite arrangement and chain organization. These morphological changes can potentially affect degradation. Initial observations on the macroscopic level inspire the hypothesis that switching of the controlling units causes an accelerated degradation of the material, resulting in programmable degradation by sequential coupling of functions. Hence, detailed degradation studies on Langmuir films of a PDLCL with 40 wt% OPDL content are carried out under enzymatic catalysis. The temperature-memory creation procedure is mimicked by compression at different temperatures. The evolution of the chain organization and mechanical properties during the degradation process is investigated by means of polarization-modulated infrared reflection absorption spectroscopy, interfacial rheology and to some extend by X-ray reflectivity. The experiments on PDLCL Langmuir films imply that degradability is not enhanced by thermal switching, as the former depends on the temperature during cold programming. Nevertheless, the thin film experiments show that the leaching of OCL segments does not induce further crystallization of the OPDL segments, which is beneficial for a controlled and predictable degradation.
Kurzarbeitergeld
(2020)
Das Kurzarbeitergeld (nachfolgend: KuG) ist eines der wichtigsten Instrumente zur Überwindung der aktuellen Corona-Krise. Der Staat übernimmt einen Teil der Lohnkosten und hilft so, gleichzeitig Arbeitsplätze zu erhalten und die Unternehmen zu entlasten. Kurzarbeit ist die vorübergehende Kürzung der betriebsüblichen normalen Arbeitszeit wegen Mangels an Arbeit bei entsprechender Minderung der Entgeltansprüche. Das KuG ersetzt den Teil des Entgelts, der in Folge des Arbeitsausfalls nicht erarbeitet und ausgezahlt werden kann. Ohne KuG läge das Wirtschaftsrisiko beim Arbeitgeber. Könnte er seine Mitarbeiter wegen der Corona-Krise nicht beschäftigen, würde er nach § 615 Satz 1 BGB den vollen Annahmeverzugslohn schulden. Davon entlastet ihn das Instrument der Kurzarbeit. Das KuG deckt die sog. „Nettoentgeltdifferenz“ zwischen dem bisherigen „Soll-Entgelt“ und dem nach Reduzierung von Arbeitszeit verbleibenden „Ist- Entgelt“ in Höhe von 60 % bzw. bei Arbeitnehmern mit Kindern 67 % ab. Schon in der Finanzkrise 2008/2009 hat sich das KuG hervorragend bewährt, damit Unternehmen ihre Belegschaft behalten können, um nach Ende der Krise wieder voll „durchzustarten“.
Symmetry and its breaking crucially define the chemical properties of molecules and their functionality. Resonant inelastic X-ray scattering is a local electronic structure probe reporting on molecular symmetry and its dynamical breaking within the femtosecond scattering duration. Here, we study pyrimidine, a system from the C-2v point group, in an aqueous solution environment, using scattering though its 2a(2) resonance. Despite the absence of clean parity selection rules for decay transitions from in-plane orbitals, scattering channels including decay from the 7b(2) and 11a(1) orbitals with nitrogen lone pair character are a direct probe for molecular symmetry. Computed spectra of explicitly solvated molecules sampled from a molecular dynamics simulation are combined with the results of a quantum dynamical description of the X-ray scattering process. We observe dominant signatures of core-excited Jahn-Teller induced symmetry breaking for resonant excitation. Solvent contributions are separable by shortening of the effective scattering duration through excitation energy detuning.
Alcohol use disorder (AUD) is the most common substance use disorder worldwide. Although dopamine-related findings were often observed in AUD, associated neurobiological mechanisms are still poorly understood. Therefore, in the present study, we investigate D2/3 receptor availability in healthy participants, participants at high risk (HR) to develop addiction (not diagnosed with AUD), and AUD patients in a detoxified stage, applying F-18-fallypride positron emission tomography (F-18-PET). Specifically, D2/3 receptor availability was investigated in (1) 19 low-risk (LR) controls, (2) 19 HR participants, and (3) 20 AUD patients after alcohol detoxification. Quality and severity of addiction were assessed with clinical questionnaires and (neuro)psychological tests. PET data were corrected for age of participants and smoking status. In the dorsal striatum, we observed significant reductions of D2/3 receptor availability in AUD patients compared with LR participants. Further, receptor availability in HR participants was observed to be intermediate between LR and AUD groups (linearly decreasing). Still, in direct comparison, no group difference was observed between LR and HR groups or between HR and AUD groups. Further, the score of the Alcohol Dependence Scale (ADS) was inversely correlated with D2/3 receptor availability in the combined sample. Thus, in line with a dimensional approach, striatal D2/3 receptor availability showed a linear decrease from LR participants to HR participants to AUD patients, which was paralleled by clinical measures. Our study shows that a core neurobiological feature in AUD seems to be detectable in an early, subclinical state, allowing more individualized alcohol prevention programs in the future.
Heteromeric HSFA2/HSFA3 complexes drive transcriptional memory after heat stress in Arabidopsis
(2021)
Adaptive plasticity in stress responses is a key element of plant survival strategies. For instance, moderate heat stress (HS) primes a plant to acquire thermotolerance, which allows subsequent survival of more severe HS conditions. Acquired thermotolerance is actively maintained over several days (HS memory) and involves the sustained induction of memory-related genes. Here we show that FORGETTER3/ HEAT SHOCK TRANSCRIPTION FACTOR A3 (FGT3/HSFA3) is specifically required for physiological HS memory and maintaining high memory-gene expression during the days following a HS exposure. HSFA3 mediates HS memory by direct transcriptional activation of memory-related genes after return to normal growth temperatures. HSFA3 binds HSFA2, and in vivo both proteins form heteromeric complexes with additional HSFs. Our results indicate that only complexes containing both HSFA2 and HSFA3 efficiently promote transcriptional memory by positively influencing histone H3 lysine 4 (H3K4) hyper-methylation. In summary, our work defines the major HSF complex controlling transcriptional memory and elucidates the in vivo dynamics of HSF complexes during somatic stress memory. Moderate heat stress primes plants to acquire tolerance to subsequent, more severe heat stress. Here the authors show that the HSFA3 transcription factor forms a heteromeric complex with HSFA2 to sustain activated transcription of genes required for acquired thermotolerance by promoting H3K4 hyper-methylation.
The transversal hypergraph problem asks to enumerate the minimal hitting sets of a hypergraph. If the solutions have bounded size, Eiter and Gottlob [SICOMP'95] gave an algorithm running in output-polynomial time, but whose space requirement also scales with the output. We improve this to polynomial delay and space. Central to our approach is the extension problem, deciding for a set X of vertices whether it is contained in any minimal hitting set. We show that this is one of the first natural problems to be W[3]-complete. We give an algorithm for the extension problem running in time O(m(vertical bar X vertical bar+1) n) and prove a SETH-lower bound showing that this is close to optimal. We apply our enumeration method to the discovery problem of minimal unique column combinations from data profiling. Our empirical evaluation suggests that the algorithm outperforms its worst-case guarantees on hypergraphs stemming from real-world databases.
The Devonian Las Chacras-Potrerillos batholith comprises six nested monzonitic to granitic intrusions with metaluminous to weakly peraluminous composition and a Sr-Nd isotopic signature indicating a dominantly juvenile mantle-derived source. The chemically most evolved units in the southern batholith contain a large number of intra-granitic, pod-shaped tourmaline-bearing pegmatites. This study uses in situ chemical and boron isotopic analyses of tourmaline from nine of these pegmatites to discuss their relationship to the respective host intrusions and the implications of their B-isotope composition for the source and evolution of the magmas. The tourmalines reveal a diversity in element composition (e.g., FeO, MgO, TiO2, CaO, MnO, F) which distinguishes individual pegmatites from one another. However, all have a narrow 5 11 B range of -13.7 to -10.5%0 (n = 100) which indicates a relatively uniform magmatic system and similar temperature conditions during tourmaline crystallization. The average delta(11) B value of -11.7%0 is typical for S-type granites and is within the range reported for peraluminous granites. pegmatites, and metamorphic units of the Ordovician basement into which the Las Chacras-Potrerillos batholith intruded. The B-isotope evidence argues for a crustal boron source like that of the Ordovician basement, in contrast to the metaluminous to weakly peraluminous composition and juvenile initial Sr and Nd isotope ratios of the Las Chacras-Potrerillos batholith magmas. We propose that the boron was not derived from the magma source region but was incorporated from dehydration melting of elastic metasedimentary rocks higher up in the crustal column.
The Altiplano-Puna Plateau holds several shallow lakes, which are very sensitive to climate changes. This work is focused on a high-altitude lake system called Lagunas de Vilama (LVS), located in a complex climatic transition area with scarcity of continuous and homogeneous instrumental records. The objective of this study is to determine the regional spatial-temporal variability of precipitation and evaluate the seasonal and interannual lake responses. We use a lake-surfaces record derived from Landsat images to investigate links with regional precipitations and different climatic forcings. The results reveal that austral summer and autumn precipitations control the variability of the annual lake-surfaces. Also, we found intra-annual and interannual lags in the lake responses to precipitations, and identified several wet and dry stages. Our results show negative trends in precipitations and lake-surfaces, whose were strengthened by a shift to a warm phase of the Atlantic Multidecadal Oscillation in the 1990s. The El Nino Southern Oscillation, Pacific Decadal Oscillation, and Southern Annular Mode also exert a strong influence in the region. This study demonstrates that the variability of LVS lakes is strongly related to the South American Monsoon System dynamics and large-scale climate fordngs from the Pacific and Atlantic Oceans. This work provides novel indices which demonstrated to be good indicators of regional hydroclimatological variability for this region of South America.
The Arnoldi process can be applied to inexpensively approximate matrix functions of the form f (A)v and matrix functionals of the form v*(f (A))*g(A)v, where A is a large square non-Hermitian matrix, v is a vector, and the superscript * denotes transposition and complex conjugation. Here f and g are analytic functions that are defined in suitable regions in the complex plane. This paper reviews available approximation methods and describes new ones that provide higher accuracy for essentially the same computational effort by exploiting available, but generally not used, moment information. Numerical experiments show that in some cases the modifications of the Arnoldi decompositions proposed can improve the accuracy of v*(f (A))*g(A)v about as much as performing an additional step of the Arnoldi process.
Background and aims:
The objective of the present work was to determine to what extent sleep quality may mediate the association between chronodisruption (CD) and metabolic syndrome (MS), and between CD and body composition (BC).
Methodology:
Cross-sectional study which included 300 adult health workers, 150 of whom were night shift workers and thereby exposed to CD. Diagnosis of MS was made based on Adult Treatment Panel III criteria. Sleep quality was measured using the Pittsburgh Sleep Quality Index. Body mass index (BMI), fat mass percentage, and visceral fat percentage were measured as indicators of body composition (BC). Data were analyzed using logistic, linear regression and structural equation models.
Results:
The odds of health workers exposed to CD to suffer MS was 22.13 (IC95 8.68-66.07) when the model was adjusted for age, gender, physical activity and energy consumption. CD was also significantly associated with an increase in fat mass and visceral fat percentages, but not to BMI. Surprisingly, there was not enough evidence supporting the hypothesis that sleep quality contributes to the association between CD and MS or between CD and BC.
Conclusions:
Sleep quality does not mediate the negative effects of CD on MS nor on BC.
Based on suggested interactions of potential tipping elements in the Earth's climate and in ecological systems, tipping cascades as possible dynamics are increasingly discussed and studied. The activation of such tipping cascades would impose a considerable risk for human societies and biosphere integrity. However, there are ambiguities in the description of tipping cascades within the literature so far. Here we illustrate how different patterns of multiple tipping dynamics emerge from a very simple coupling of two previously studied idealized tipping elements. In particular, we distinguish between a two phase cascade, a domino cascade and a joint cascade. A mitigation of an unfolding two phase cascade may be possible and common early warning indicators are sensitive to upcoming critical transitions to a certain degree. In contrast, a domino cascade may hardly be stopped once initiated and critical slowing down-based indicators fail to indicate tipping of the following element. These different potentials for intervention and anticipation across the distinct patterns of multiple tipping dynamics should be seen as a call to be more precise in future analyses of cascading dynamics arising from tipping element interactions in the Earth system.
The synthesis and the crystal structure of the double cluster compound [Nb6Cl14(MeCN)(4)][Nb6Cl14(pyz)(4)]middot6CH(3)CN are described. The synthesis is based on a partial ligand exchange reaction, which proceeds upon dissolving [Nb6Cl14(pyz)(4)]middot2CH(2)Cl(2) in acetonitrile. The compound is built up of two discrete neutral cluster units, which consist of octahedra of Nb-6 atoms coordinated by 12 edge-bridging chlorido and two terminal chlorido ligands, and four acetonitrile ligands on one and four pyrazine ligands on the other cluster unit. Co-crystallized acetonitrile molecules are also present. The single-crystal structure determination has revealed a cluster arrangement in which the [Nb6Cl14(pyz)(4)] units are connected by (halogen) lone-pair-(pyrazine) pi interactions. These lead to chains of [Nb6Cl14(pyz)(4)] clusters. These chains are further connected to cluster layers by (nitrile-halogen) dipole-dipole interactions, in which the [Nb6Cl14(MeCN)(4)] and co-crystallized MeCN molecules are also involved. These cluster layers are arranged parallel to the crystallographic {011} plane.
Purpose UK guidelines recommend dietary saturated fatty acids (SFAs) should not exceed 10% total energy (%TE) for cardiovascular disease prevention, with benefits observed when SFAs are replaced with unsaturated fatty acids (UFAs). This study aimed to assess the efficacy of a dietary exchange model using commercially available foods to replace SFAs with UFAs. Methods Healthy men (n = 109, age 48, SD 11 year) recruited to the Reading, Imperial, Surrey, Saturated fat Cholesterol Intervention-1 (RISSCI-1) study (ClinicalTrials.Gov n degrees NCT03270527) followed two sequential 4-week isoenergetic moderate-fat (34%TE) diets: high-SFA (18%TE SFAs, 16%TE UFAs) and low-SFA (10%TE SFAs, 24%TE UFAs). Dietary intakes were assessed using 4-day weighed diet diaries. Nutrient intakes were analysed using paired t-tests, fasting plasma phospholipid fatty acid (PL-FA) profiles and dietary patterns were analysed using orthogonal partial least square discriminant analyses. Results Participants exchanged 10.2%TE (SD 4.1) SFAs for 9.7%TE (SD 3.9) UFAs between the high and low-SFA diets, reaching target intakes with minimal effect on other nutrients or energy intakes. Analyses of dietary patterns confirmed successful incorporation of recommended foods from commercially available sources (e.g. dairy products, snacks, oils, and fats), without affecting participants' overall dietary intakes. Analyses of plasma PL-FAs indicated good compliance to the dietary intervention and foods of varying SFA content. Conclusions RISSCI-1 dietary exchange model successfully replaced dietary SFAs with UFAs in free-living healthy men using commercially available foods, and without altering their dietary patterns. Further intervention studies are required to confirm utility and feasibility of such food-based dietary fat replacement models at a population level.
This paper studies cosmic-ray (CR) transport in magnetohydrodynamic (MHD) turbulence. CR transport is strongly dependent on the properties of the magnetic turbulence.
We perform test particle simulations to study the interactions of CR with both total MHD turbulence and decomposed MHD modes.
The spatial diffusion coefficients and the pitch angle scattering diffusion coefficients are calculated from the test particle trajectories in turbulence.
Our results confirm that the fast modes dominate the CR propagation, whereas Alfven and slow modes are much less efficient and have shown similar pitch-angle scattering rates.
We investigate the cross field transport on large and small scales. On large/global scales, normal diffusion is observed and the diffusion coefficient is suppressed by M-A(zeta) compared to the parallel diffusion coefficients, with zeta closer to 4 in Alfven modes than that in total turbulence, as theoretically expected.
For the CR transport on scales smaller than the turbulence injection scale, both the local and global magnetic reference frames are adopted. Superdiffusion is observed on such small scales in all the cases. Particularly, CR transport in Alfven modes show clear Richardson diffusion in the local reference frame. The diffusion transitions smoothly from the Richardson's one with index 1.5 to normal diffusion as the particle mean free path decreases from lambda(parallel to) >> L to lambda(parallel to) << L, where L is the injection/coherence length of turbulence.
Our results have broad applications to CRs in various astrophysical environments.
Active matter broadly covers the dynamics of self-propelled particles.
While the onset of collective behavior in homogenous active systems is relatively well understood, the effect of inhomogeneities such as obstacles and traps lacks overall clarity.
Here, we study how interacting, self-propelled particles become trapped and released from a trap.
We have found that captured particles aggregate into an orbiting condensate with a crystalline structure. As more particles are added, the trapped condensates escape as a whole.
Our results shed light on the effects of confinement and quenched disorder in active matter.
Quantification of reaction fluxes of metabolic networks can help us understand how the integration of different metabolic pathways determines cellular functions. Yet, intracellular fluxes cannot be measured directly but are estimated with metabolic flux analysis (MFA), which relies on the patterns of isotope labeling of metabolites in the network. The application of MFA also requires a stoichiometric model with atom mappings that are currently not available for the majority of large-scale metabolic network models, particularly of plants. While automated approaches such as the Reaction Decoder Toolkit (RDT) can produce atom mappings for individual reactions, tracing the flow of individual atoms of the entire reactions across a metabolic model remains challenging. Here we establish an automated workflow to obtain reliable atom mappings for large-scale metabolic models by refining the outcome of RDT, and apply the workflow to metabolic models of Arabidopsis thaliana. We demonstrate the accuracy of RDT through a comparative analysis with atom mappings from a large database of biochemical reactions, MetaCyc. We further show the utility of our automated workflow by simulating N-15 isotope enrichment and identifying nitrogen (N)-containing metabolites which show enrichment patterns that are informative for flux estimation in future N-15-MFA studies of A. thaliana. The automated workflow established in this study can be readily expanded to other species for which metabolic models have been established and the resulting atom mappings will facilitate MFA and graph-theoretic structural analyses with large-scale metabolic networks.
Long- and short-term monitoring of a dam in response to seasonal changes and ground motion loading
(2021)
An experimental multi-parameter structural monitoring system has been installed on the Kurpsai dam, western Kyrgyz Republic. This system consists of equipment for seismic and strain measurements for making longer- (days, weeks, months) and shorter- (minutes, hours) term observations, dealing with, for example seasonal (longer) effects or the response of the dam to ground motion from noise or seismic events. Fibre-optic strain sensors allow the seasonal and daily opening and closing of the spaces between the dam's segments to be tracked. For the seismic data, both amplitude (in terms of using differences in amplitudes in the Fourier spectra for mapping the modes of vibration of the dam) and their time-frequency distribution for a set of small to moderate seismic events are investigated and the corresponding phase variabilities (in terms of lagged coherency) are evaluated. Even for moderate levels of seismic-induced ground motion, some influence on the structural response can be detected, which then sees the dam quickly return to its original state. A seasonal component was identified in the strain measurements, while levels of noise arising from the operation of the dam's generators and associated water flow have been provisionally identified.
Lost in Germania
(2021)
Tacitus’ Germania is notable for its absences: lacking a preface and programmatic statements, and being the only ethnographic monograph to have survived from Greco-Roman antiquity, readers have often leapt to fill in its perceived blanks. This chapter aims at redressing the effects of overdetermined readings by interpreting the text’s absences as significant in their own right.
Centroid moment tensor (CMT) parameters can be estimated from seismic waveforms. Since these data indirectly observe the deformation process, CMTs are inferred as solutions to inverse problems which are generally underdetermined and require significant assumptions, including assumptions about data noise. Broadly speaking, we consider noise to include both theory and measurement errors, where theory errors are due to assumptions in the inverse problem and measurement errors are caused by the measurement process. While data errors are routinely included in parameter estimation for full CMTs, less attention has been paid to theory errors related to velocity-model uncertainties and how these affect the resulting moment-tensor (MT) uncertainties. Therefore, rigorous uncertainty quantification for CMTs may require theory-error estimation which becomes a problem of specifying noise models. Various noise models have been proposed, and these rely on several assumptions. All approaches quantify theory errors by estimating the covariance matrix of data residuals. However, this estimation can be based on explicit modelling, empirical estimation and/or ignore or include covariances. We quantitatively compare several approaches by presenting parameter and uncertainty estimates in nonlinear full CMT estimation for several simulated data sets and regional field data of the M-1 4.4, 2015 June 13 Fox Creek, Canada, event. While our main focus is at regional distances, the tested approaches are general and implemented for arbitrary source model choice. These include known or unknown centroid locations, full MTs, deviatoric MTs and double-couple MTs. We demonstrate that velocity-model uncertainties can profoundly affect parameter estimation and that their inclusion leads to more realistic parameter uncertainty quantification. However, not all approaches perform equally well. Including theory errors by estimating non-stationary (non-Toeplitz) error covariance matrices via iterative schemes during Monte Carlo sampling performs best and is computationally most efficient. In general, including velocity-model uncertainties is most important in cases where velocity structure is poorly known.
Successful conservation efforts have led to recent increases of large mammals such as European bison Bison bonasus, moose Alces alces and grey wolf Canis lupus and their return to former habitats in central Europe.
While embraced by some, the recovery of these species is a controversial topic and holds potential for human-wildlife conflicts.
Involving the public has been suggested to be an effective method for monitoring wildlife and mitigating associated conflicts.
To assess two interrelated prerequisites for engaging people in Citizen Science (CS)-knowledge of returning species and respondents' readiness to participate in CS activities for monitoring and managing these species-we conducted a survey (questionnaire) in two wildlife parks located in different states of Germany.
Based on 472 complete questionnaires, we developed generalized linear models to understand how sociodemographic variables and exposure to the species affected visitors' knowledge of each species, and to investigate if sociodemographic variables and knowledge influenced the likelihood of visitors to participate in CS activities.
Almost all visitors were aware of the returning wolf population, while knowledge and awareness about bison and moose were significantly lower.
Knowledge of the two herbivores differed geographically (higher knowledge of moose in the north-eastern state), possibly indicating a positive association between exposure to the species and knowledge.
However, models generally performed poorly in predicting knowledge about wildlife, suggesting that such specific knowledge is insufficiently explained by sociodemographic variables. Our model, which explained stated willingness in CS indicated that younger participants and those with higher knowledge scores in the survey were more willing to engage in CS activities.
Overall, our analyses highlight how exposure to large mammals, knowledge about wildlife and human demographics are interrelated-insights that are helpful for effectively recruiting citizen scientists for wildlife conservation.
Read the free Plain Language Summary for this article on the Journal blog.
This study investigates the use of pulse stretching (skew-sized) inverters for monitoring the variation of count rate and linear energy transfer (LET) of energetic particles. The basic particle detector is a cascade of two pulse stretching inverters, and the required sensing area is obtained by connecting up to 12 two-inverter cells in parallel and employing the required number of parallel arrays. The incident particles are detected as single-event transients (SETs), whereby the SET count rate denotes the particle count rate, while the SET pulsewidth distribution depicts the LET variations. The advantage of the proposed solution is the possibility to sense the LET variations using fully digital processing logic. SPICE simulations conducted on IHP's 130-nm CMOS technology have shown that the SET pulsewidth varies by approximately 550 ps over the LET range from 1 to 100 MeV center dot cm(2) center dot mg(-1). The proposed detector is intended for triggering the fault-tolerant mechanisms within a self-adaptive multiprocessing system employed in space. It can be implemented as a standalone detector or integrated in the same chip with the target system.
Fatty acids are widely used to study trophic interactions in food web assemblages. Generally, it is assumed that there is a very small modification of fatty acids from one trophic step to another, making them suitable as trophic biomarkers. However, recent literature provides evidence that many fishes possess genes encoding enzymes with a role in bioconversion, thus the capability for bioconversion might be more widespread than previously assumed. Nonetheless, empirical evidence for biosynthesis occurring in natural populations remains scarce. In this study, we investigated different feeding types of perch (Perca fluviatilis) that are specialized on specific resources with different levels of highly unsaturated fatty acids (HUFAs), and analyzed the change between HUFA proportions in perch muscle tissue compared to their resources. Perch showed matching levels to their resources for EPA, but ARA and especially DHA were accumulated. Compound-specific stable isotope analyses helped us to identify the origin of HUFA carbon. Our results suggest that perch obtain a substantial amount of DHA via bioconversion when feeding on DHA-poor benthic resources. Thus, our data indicate the capability of bioconversion of HUFAs in a natural freshwater fish population.
Circular economy
(2021)
In a circular economy, the use of recycled resources in production is a key performance indicator for management. Yet, academic studies are still unable to inform managers on appropriate recycling and pricing policies. We develop an optimal control model integrating a firm's recycling rate, which can use both virgin and recycled resources in the production process. Our model accounts for recycling influence both at the supply- and demandsides. The positive effect of a firm's use of recycled resources diminishes over time but may increase through investments. Using general formulations for demand and cost, we analytically examine joint dynamic pricing and recycling investment policies in order to determine their optimal interplay over time. We provide numerical experiments to assess the existence of a steady-state and to calculate sensitivity analyses with respect to various model parameters. The analysis shows how to dynamically adapt jointly optimized controls to reach sustainability in the production process. Our results pave the way to sounder sustainable practices for firms operating within a circular economy.
Cirrus is the only cloud type capable of inducing daytime cooling or heating at the top of the atmosphere (TOA) and the sign of its radiative effect highly depends on its optical depth. However, the investigation of its geometrical and optical properties over the Arctic is limited. In this work the long-term properties of cirrus clouds are explored for the first time over an Arctic site (Ny-Alesund, Svalbard) using lidar and radiosonde measurements from 2011 to 2020. The optical properties were quality assured, taking into account the effects of specular reflections and multiple-scattering. Cirrus clouds were generally associated with colder and calmer wind conditions compared to the 2011-2020 climatology. However, the dependence of cirrus properties on temperature and wind speed was not strong. Even though the seasonal cycle was not pronounced, the winter-time cirrus appeared under lower temperatures and stronger wind conditions. Moreover, in winter, geometrically- and optically-thicker cirrus were found and their ice particles tended to be more spherical. The majority of cirrus was associated with westerly flow and westerly cirrus tended to be geometrically-thicker. Overall, optically-thinner layers tended to comprise smaller and less spherical ice crystals, most likely due to reduced water vapor deposition on the particle surface. Compared to lower latitudes, the cirrus layers over Ny-Alesund were more absorbing in the visible spectral region and they consisted of more spherical ice particles.
MALDI-TOF-MS-based identification of monoclonal murine Anti-SARS-CoV-2 antibodies within one hour
(2022)
During the SARS-CoV-2 pandemic, many virus-binding monoclonal antibodies have been developed for clinical and diagnostic purposes. This underlines the importance of antibodies as universal bioanalytical reagents. However, little attention is given to the reproducibility crisis that scientific studies are still facing to date. In a recent study, not even half of all research antibodies mentioned in publications could be identified at all. This should spark more efforts in the search for practical solutions for the traceability of antibodies. For this purpose, we used 35 monoclonal antibodies against SARS-CoV-2 to demonstrate how sequence-independent antibody identification can be achieved by simple means applied to the protein. First, we examined the intact and light chain masses of the antibodies relative to the reference material NIST-mAb 8671. Already half of the antibodies could be identified based solely on these two parameters. In addition, we developed two complementary peptide mass fingerprinting methods with MALDI-TOF-MS that can be performed in 60 min and had a combined sequence coverage of over 80%. One method is based on the partial acidic hydrolysis of the protein by 5 mM of sulfuric acid at 99 degrees C. Furthermore, we established a fast way for a tryptic digest without an alkylation step. We were able to show that the distinction of clones is possible simply by a brief visual comparison of the mass spectra. In this work, two clones originating from the same immunization gave the same fingerprints. Later, a hybridoma sequencing confirmed the sequence identity of these sister clones. In order to automate the spectral comparison for larger libraries of antibodies, we developed the online software ABID 2.0. This open-source software determines the number of matching peptides in the fingerprint spectra. We propose that publications and other documents critically relying on monoclonal antibodies with unknown amino acid sequences should include at least one antibody fingerprint. By fingerprinting an antibody in question, its identity can be confirmed by comparison with a library spectrum at any time and context.
Both climate change and land use regimes affect the viability of populations, but they are often studied separately. Moreover, population viability analyses (PVAs) often ignore the effects of large environmental gradients and use temporal resolutions that are too coarse to take into account that different stages of a population's life cycle may be affected differently by climate change. Here, we present the High-resolution Large Environmental Gradient (HiLEG) model and apply it in a PVA with daily resolution based on daily climate projections for Northwest Germany. We used the large marsh grasshopper (LMG) as the target species and investigated (1) the effects of climate change on the viability and spatial distribution of the species, (2) the influence of the timing of grassland mowing on the species and (3) the interaction between the effects of climate change and grassland mowing. The stageand cohort-based model was run for the spatially differentiated environmental conditions temperature and soil moisture across the whole study region. We implemented three climate change scenarios and analyzed the population dynamics for four consecutive 20-year periods. Climate change alone would lead to an expansion of the regions suitable for the LMG, as warming accelerates development and due to reduced drought stress. However, in combination with land use, the timing of mowing was crucial, as this disturbance causes a high mortality rate in the aboveground life stages. Assuming the same date of mowing throughout the region, the impact on viability varied greatly between regions due to the different climate conditions. The regional negative effects of the mowing date can be divided into five phases: (1) In early spring, the populations were largely unaffected in all the regions; (2) between late spring and early summer, they were severely affected only in warm regions; (3) in summer, all the populations were severely affected so that they could hardly survive; (4) between late summer and early autumn, they were severely affected in cold regions; and (5) in autumn, the populations were equally affected across all regions. The duration and start of each phase differed slightly depending on the climate change scenario and simulation period, but overall, they showed the same pattern. Our model can be used to identify regions of concern and devise management recommendations. The model can be adapted to the life cycle of different target species, climate projections and disturbance regimes. We show with our adaption of the HiLEG model that high-resolution PVAs and applications on large environmental gradients can be reconciled to develop conservation strategies capable of dealing with multiple stressors.
Supergenes are nonrecombining genomic regions ensuring the coinheritance of multiple, coadapted genes. Despite the importance of supergenes in adaptation, little is known on how they originate. A classic example of supergene is the S locus controlling heterostyly, a floral heteromorphism occurring in 28 angiosperm families. In Primula, heterostyly is characterized by the cooccurrence of two complementary, self-incompatible floral morphs and is controlled by five genes clustered in the hemizygous, ca. 300-kb S locus. Here, we present the first chromosome-scale genome assembly of any heterostylous species, that of Primula veris (cowslip). By leveraging the high contiguity of the P. veris assembly and comparative genomic analyses, we demonstrated that the S-locus evolved via multiple, asynchronous gene duplications and independent gene translocations. Furthermore, we discovered a new whole-genome duplication in Ericales that is specific to the Primula lineage. We also propose a mechanism for the origin of S-locus hemizygosity via nonhomologous recombination involving the newly discovered two pairs of CFB genes flanking the S locus. Finally, we detected only weak signatures of degeneration in the S locus, as predicted for hemizygous supergenes. The present study provides a useful resource for future research addressing key questions on the evolution of supergenes in general and the S locus in particular: How do supergenes arise? What is the role of genome architecture in the evolution of complex adaptations? Is the molecular architecture of heterostyly supergenes across angiosperms similar to that of Primula?
Ancient genome provides insights into the history of Eurasian lynx in Iberia and Western Europe
(2022)
The Eurasian lynx (Lynx lynx) is one of the most widely distributed felids in the world. However, most of its populations started to decline a few millennia ago. Historical declines have been especially severe in Europe, and particularly in Western Europe, from where the species disappeared in the last few centuries. Here, we analyze the genome of an Eurasian lynx inhabiting the Iberian Peninsula 2500 ya, to gain insights into the phylogeographic position and genetic status of this extinct population. Also, we contextualize previous ancient data in the light of new phylogeographic studies of the species. Our results suggest that the Iberian population is part of an extinct European lineage closely related to the current Carpathian-Baltic lineages. Also, this sample holds the lowest diversity reported for the species so far, and similar to that of the highly endangered Iberian lynx. A combination of historical factors, such as a founder effect while colonizing the peninsula, together with intensified human impacts during the Holocene in the Cantabrian strip, could have led to a genetic impoverishment of the population and precipitated its extinction. Mitogenomic lineages distribution in space and time support the long-term coexistence of several lineages of Eurasian lynx in Western Europe with fluctuating ranges. While mitochondrial sequences related to the lineages currently found in Balkans and Caucasus were predominant during the Pleistocene, those more closely related to the lineage currently distributed in Central Europe prevailed during the Holocene. The use of ancient genomics has proven to be a useful tool to understand the biogeographic pattern of the Eurasian lynx in the past.
The water vapor-induced swelling, as well as subsequent phase-transition kinetics, of thin films of a diblock copolymer (DBC) loaded with different amounts of the salt NaBr, is investigated in situ. In dilute aqueous solution, the DBC features an orthogonally thermoresponsive behavior. It consists of a zwitterionic poly(sulfobetaine) block, namely, poly(4-(N-(3'-methacrylamidopropyl)-N, N-dimethylammonio) butane-1-sulfonate) (PSBP), showing an upper critical solution temperature, and a nonionic block, namely, poly(N-isopropylmethacrylamide) (PNIPMAM), exhibiting a lower critical solution temperature. The swelling kinetics in D2O vapor at 15 degrees C and the phase transition kinetics upon heating the swollen film to 60 degrees C and cooling back to 15 degrees C are followed with simultaneous time-of-flight neutron reflectometry and spectral reflectance measurements. These are complemented by Fourier transform infrared spectroscopy. The collapse temperature of PNIPMAM and the swelling temperature of PSBP are found at lower temperatures than in aqueous solution, which is attributed to the high polymer concentration in the thin-film geometry. Upon inclusion of sub-stoichiometric amounts (relative to the monomer units) of NaBr in the films, the water incorporation is significantly increased. This increase is mainly attributed to a salting-in effect on the zwitterionic PSBP block. Whereas the addition of NaBr notably shifts the swelling temperature of PSBP to lower temperatures, the collapse temperature of PNIPMAM remains unaffected by the presence of salt in the films.
Complex networks are abundant in nature and many share an important structural property: they contain a few nodes that are abnormally highly connected (hubs). Some of these hubs are called influencers because they couple strongly to the network and play fundamental dynamical and structural roles. Strikingly, despite the abundance of networks with influencers, little is known about their response to stochastic forcing. Here, for oscillatory dynamics on influencer networks, we show that subjecting influencers to an optimal intensity of noise can result in enhanced network synchronization. This new network dynamical effect, which we call coherence resonance in influencer networks, emerges from a synergy between network structure and stochasticity and is highly nonlinear, vanishing when the noise is too weak or too strong. Our results reveal that the influencer backbone can sharply increase the dynamical response in complex systems of coupled oscillators. Influencer networks include a small set of highly-connected nodes and can reach synchrony only via strong node interaction. Tonjes et al. show that introducing an optimal amount of noise enhances synchronization of such networks, which may be relevant for neuroscience or opinion dynamics applications.
The mean free path of ionizing photons, lambda(mfp), is a key factor in the photoionization of the intergalactic medium (IGM). At z greater than or similar to 5, however, lambda(mfp) may be short enough that measurements towards QSOs are biased by the QSO proximity effect. We present new direct measurements of lambda(mfp) that address this bias and extend up to z similar to 6 for the first time. Our measurements at z similar to 5 are based on data from the Giant Gemini GMOS survey and new Keck LRIS observations of low-luminosity QSOs. At z similar to 6 we use QSO spectra from Keck ESI and VLT X-Shooter. We measure lambda(mfp) = 9.09(-1.28)(+1.62) proper Mpc and 0.75(-0.45)(+0.65) proper Mpc (68 percent confidence) at z = 5.1 and 6.0, respectively. The results at z = 5.1 are consistent with existing measurements, suggesting that bias from the proximity effect is minor at this redshift. At z = 6.0, however, we find that neglecting the proximity effect biases the result high by a factor of two or more. Our measurement at z = 6.0 falls well below extrapolations from lower redshifts, indicating rapid evolution in lambda(mfp) over 5 < z < 6. This evolution disfavours models in which reionization ended early enough that the IGM had time to fully relax hydrodynamically by z = 6, but is qualitatively consistent with models wherein reionization completed at z = 6 or even significantly later. Our mean free path results are most consistent with late reionization models wherein the IGM is still 20 percent neutral at z = 6, although our measurement at z = 6.0 is even lower than these models prefer.
Ice-rich permafrost has been subject to abrupt thaw and thermokarst formation in the past and is vulnerable to current global warming. The ice-rich permafrost domain includes Yedoma sediments that have never thawed since deposition during the late Pleistocene and Alas sediments that were formed by previous thermokarst processes during the Lateglacial and Holocene warming. Permafrost thaw unlocks organic carbon (OC) and minerals from these deposits and exposes OC to mineralization. A portion of the OC can be associated with iron (Fe), a redox-sensitive element acting as a trap for OC. Post-depositional thaw processes may have induced changes in redox conditions in these deposits and thereby affected Fe distribution and interactions between OC and Fe, with knock-on effects on the role that Fe plays in mediating present day OC mineralization. To test this hypothesis, we measured Fe concentrations and proportion of Fe oxides and Fe complexed with OC in unthawed Yedoma and previously thawed Alas deposits. Total Fe concentrations were determined on 1,292 sediment samples from the Yedoma domain using portable X-ray fluorescence; these concentrations were corrected for trueness using a calibration based on a subset of 144 samples measured by inductively coupled plasma optical emission spectrometry after alkaline fusion (R (2) = 0.95). The total Fe concentration is stable with depth in Yedoma deposits, but we observe a depletion or accumulation of total Fe in Alas deposits, which experienced previous thaw and/or flooding events. Selective Fe extractions targeting reactive forms of Fe on unthawed and previously thawed deposits highlight that about 25% of the total Fe is present as reactive species, either as crystalline or amorphous oxides, or complexed with OC, with no significant difference in proportions of reactive Fe between Yedoma and Alas deposits. These results suggest that redox driven processes during past thermokarst formation impact the present-day distribution of total Fe, and thereby the total amount of reactive Fe in Alas versus Yedoma deposits. This study highlights that ongoing thermokarst lake formation and drainage dynamics in the Arctic influences reactive Fe distribution and thereby interactions between Fe and OC, OC mineralization rates, and greenhouse gas emissions.
How biased are our models?
(2021)
Geophysical process simulations play a crucial role in the understanding of the subsurface. This understanding is required to provide, for instance, clean energy sources such as geothermal energy. However, the calibration and validation of the physical models heavily rely on state measurements such as temperature. In this work, we demonstrate that focusing analyses purely on measurements introduces a high bias. This is illustrated through global sensitivity studies. The extensive exploration of the parameter space becomes feasible through the construction of suitable surrogate models via the reduced basis method, where the bias is found to result from very unequal data distribution. We propose schemes to compensate for parts of this bias. However, the bias cannot be entirely compensated. Therefore, we demonstrate the consequences of this bias with the example of a model calibration.
Urban air pollution is a substantial threat to human health. Traffic emissions remain a large contributor to air pollution in urban areas. The mobility restrictions put in place in response to the COVID-19 pandemic provided a large-scale real-world experiment that allows for the evaluation of changes in traffic emissions and the corresponding changes in air quality. Here we use observational data, as well as modelling, to analyse changes in nitrogen dioxide, ozone, and particulate matter resulting from the COVID-19 restrictions at the height of the lockdown period in Spring of 2020. Accounting for the influence of meteorology on air quality, we found that reduction of ca. 30-50 % in traffic counts, dominated by changes in passenger cars, corresponded to reductions in median observed nitrogen dioxide concentrations of ca. 40 % (traffic and urban background locations) and a ca. 22 % increase in ozone (urban background locations) during weekdays. Lesser reductions in nitrogen dioxide concentrations were observed at urban background stations at weekends, and no change in ozone was observed. The modelled reductions in median nitrogen dioxide at urban background locations were smaller than the observed reductions and the change was not significant. The model results showed no significant change in ozone on weekdays or weekends. The lack of a simulated weekday/weekend effect is consistent with previous work suggesting that NOx emissions from traffic could be significantly underestimated in European cities by models. These results indicate the potential for improvements in air quality due to policies for reducing traffic, along with the scale of reductions that would be needed to result in meaningful changes in air quality if a transition to sustainable mobility is to be seriously considered. They also confirm once more the highly relevant role of traffic for air quality in urban areas.
The understanding of bidimensional materials dynamics and its electrolyte interface equilibrium, such as graphene oxide (GO), is critical for the development of a capacitive biosensing platform. The interfacial capacitance (C-i) of graphene-based materials may be tuned by experimental conditions such as pH optimization and cation size playing key roles at the enhancement of their capacitive properties allowing their application as novel capacitive biosensors. Here we reported a systematic study of C-i of multilayer GO films in different aqueous electrolytes employing electrochemical impedance spectroscopy for the application in a capacitive detection system. We demonstrated that the presence of ionizable oxygen-containing functional groups within multilayer GO film favors the interactions and the accumulation of cations in the structure of the electrodes enhancing the GO C-i in aqueous solutions, where at pH 7.0 (the best condition) the C-i was 340 mu F mg(-1) at -0.01 V vs Ag/AgCl. We also established that the hydrated cation radius affects the mobility and interaction with GO functional groups and it plays a critical role in the Ci, as demonstrated in the presence of different cations Na+=640 mu F mg(-1), Li+=575 mu F mg(-1) and TMA(+)=477 mu F mg(-1). As a proof-of-concept, the capacitive behaviour of GO was explored as biosensing platform for standard streptavidin-biotin systems. For this system, the C-i varied linearly with the log of the concentration of the targeting analyte in the range from 10 pg mL(-1) to 100 ng mL(-1), showing the promising applicability of capacitive GO based sensors for label-free biosensing.
Design thinking is a well-established practical and educational approach to fostering high-level creativity and innovation, which has been refined since the 1950s with the participation of experts like Joy Paul Guilford and Abraham Maslow. Through real-world projects, trainees learn to optimize their creative outcomes by developing and practicing creative cognition and metacognition. This paper provides a holistic perspective on creativity, enabling the formulation of a comprehensive theoretical framework of creative metacognition. It focuses on the design thinking approach to creativity and explores the role of metacognition in four areas of creativity expertise: Products, Processes, People, and Places. The analysis includes task-outcome relationships (product metacognition), the monitoring of strategy effectiveness (process metacognition), an understanding of individual or group strengths and weaknesses (people metacognition), and an examination of the mutual impact between environments and creativity (place metacognition). It also reviews measures taken in design thinking education, including a distribution of cognition and metacognition, to support students in their development of creative mastery. On these grounds, we propose extended methods for measuring creative metacognition with the goal of enhancing comprehensive assessments of the phenomenon. Proposed methodological advancements include accuracy sub-scales, experimental tasks where examinees explore problem and solution spaces, combinations of naturalistic observations with capability testing, as well as physiological assessments as indirect measures of creative metacognition.
Case report
(2023)
The increasing prevalence of Long COVID is an imminent public health disaster, and established approaches have not provided adequate diagnostics or treatments. Recently, anesthetic blockade of the stellate ganglion was reported to improve Long COVID symptoms in a small case series, purportedly by "rebooting" the autonomic nervous system. Here, we present a novel diagnostic approach based on the Adaptive Force (AF), and report sustained positive outcome for one severely affected Long COVID patient using individualized pulsed electromagnetic field (PEMF) at the area C7/T1. AF reflects the capacity of the neuromuscular system to adapt adequately to external forces in an isometric holding manner. In case, maximal isometric AF (AFiso(max)) is exceeded, the muscle merges into eccentric muscle action. Thereby, the force usually increases further until maximal AF (AFmax) is reached. In case adaptation is optimal, AFiso(max) is similar to 99-100% of AFmax. This holding capacity (AFiso(max)) was found to be vulnerable to disruption by unpleasant stimulus and, hence, was regarded as functional parameter. AF was assessed by an objectified manual muscle test using a handheld device. Prior to treatment, AFiso(max) was considerably lower than AFmax for hip flexors (62 N = similar to 28% AFmax) and elbow flexors (71 N = similar to 44% AFmax); i.e., maximal holding capacity was significantly reduced, indicating dysfunctional motor control. We tested PEMF at C7/T1, identified a frequency that improved neuromuscular function, and applied it for similar to 15 min. Immediately post-treatment, AFiso(max) increased to similar to 210 N (similar to 100% AFmax) at hip and 184 N (similar to 100% AFmax) at elbow. Subjective Long COVID symptoms resolved the following day. At 4 weeks post-treatment, maximal holding capacity was still on a similarly high level as for immediately post-treatment (similar to 100% AFmax) and patient was symptom-free. At 6 months the patient's Long COVID symptoms have not returned. This case report suggests (1) AF could be a promising diagnostic for post-infectious illness, (2) AF can be used to test effective treatments for post-infectious illness, and (3) individualized PEMF may resolve post-infectious symptoms.
Alcohol intoxication is known to affect many aspects of human behavior and cognition; one of such affected systems is articulation during speech production. Although much research has revealed that alcohol negatively impacts pronunciation in a first language (L1), there is only initial evidence suggesting a potential beneficial effect of inebriation on articulation in a non-native language (L2). The aim of this study was thus to compare the effect of alcohol consumption on pronunciation in an L1 and an L2. Participants who had ingested different amounts of alcohol provided speech samples in their L1 (Dutch) and L2 (English), and native speakers of each language subsequently rated the pronunciation of these samples on their intelligibility (for the L1) and accent nativelikeness (for the L2). These data were analyzed with generalized additive mixed modeling. Participants' blood alcohol concentration indeed negatively affected pronunciation in L1, but it produced no significant effect on the L2 accent ratings. The expected negative impact of alcohol on L1 articulation can be explained by reduction in fine motor control. We present two hypotheses to account for the absence of any effects of intoxication on L2 pronunciation: (1) there may be a reduction in L1 interference on L2 speech due to decreased motor control or (2) alcohol may produce a differential effect on each of the two linguistic subsystems.
Objective:
Depression and coronary heart disease (CHD) are highly comorbid conditions. Brain-derived neurotrophic factor (BDNF) plays an important role in cardiovascular processes. Depressed patients typically show decreased BDNF concentrations. We analysed the relationship between BDNF and depression in a sample of patients with CHD and additionally distinguished between cognitive-affective and somatic depression symptoms. We also investigated whether BDNF was associated with somatic comorbidity burden, acute coronary syndrome (ACS) or congestive heart failure (CHF).
Methods:
The following variables were assessed for 225 hospitalised patients with CHD: BDNF concentrations, depression [Patient Health Questionnaire-9 (PHQ-9)], somatic comorbidity (Charlson Comorbidity Index), CHF, ACS, platelet count, smoking status and antidepressant treatment.
Results:
Regression models revealed that BDNF was not associated with severity of depression. Although depressed patients (PHQ-9 score >7) had significantly lower BDNF concentrations compared to non-depressed patients (p = 0.04), this was not statistically significant after controlling for confounders (p = 0.15). Cognitive-affective symptoms and somatic comorbidity burden each closely missed a statistically significant association with BDNF concentrations (p = 0.08, p = 0.06, respectively). BDNF was reduced in patients with CHF (p = 0.02). There was no covariate-adjusted, significant association between BDNF and ACS.
Conclusion:
Serum BDNF concentrations are associated with cardiovascular dysfunction. Somatic comorbidities should be considered when investigating the relationship between depression and BDNF.
Der vorliegende Beitrag informiert über 14 deutschsprachige Programme zur Prävention und Intervention bei Hatespeech unter Kindern und Jugendlichen (Jahrgangsstufen 5–12). Inhalte und Durchführungsmodalitäten der Programme sowie Ergebnisse einer kriteriengeleiteten Qualitätseinschätzung anhand von fünf Kriterien werden im Hinblick auf deren Anwendung in der schulischen Praxis beschrieben und erörtert. Der Überblick über Schwerpunkte, Stärken und Entwicklungspotentiale schulbezogener Hatespeech-Programme ermöglicht Leser*innen eine informierte Entscheidung über den Einsatz der Programme in der Schule sowie in der offenen Kinder- und Jugendarbeit.
With the surging reliance on videoconferencing tools, users may find themselves staring at their reflections for hours a day. We refer to this phenomenon as self-referential information (SRI) consumption and examine its consequences and the mechanism behind them. Building on self-awareness research and the strength model of self-control, we argue that SRI consumption heightens the state of self-awareness and thereby depletes participants’ mental resources, eventually undermining virtual meeting (VM) outcomes. Our findings from a European employee sample revealed contrary effects of SRI consumption across speaker vs listener roles. Engagement with self-view is positively associated with self-awareness, which, in turn, is negatively related to satisfaction with VM process, perceived productivity, and enjoyment. Looking at the self while listening to others exhibits adverse direct and indirect (via self-awareness) effects on VM outcomes. However, looking at the self when speaking exhibits positive direct effects on satisfaction with VM process and enjoyment.
Raub mit Luftpumpe
(2023)
Strafbares Heldentum?
(2022)
Heldentum ist kein Straftatbestand. Dennoch kann ein Verhalten, das man ethisch als „heldenhaft“ bewerten würde, straftatbestandsmäßig sein. Leonidas und seine Mitstreiter waren Helden, obwohl sie vorsätzlich viele Perser getötet haben. Strafbar allerdings ist solches Heldentum nicht, sofern es gerechtfertigt oder wenigstens entschuldigt ist. Eine Tat, die nicht gerechtfertigt oder entschuldigt ist, würde man wahrscheinlich auch nicht „heldenhaft“ nennen. Diese Auszeichnung verdienen vor allem Menschen, die ohne Rücksicht auf eigene Sicherheit viel riskieren, sich selbst in Gefahr begeben oder sogar darin „umkommen“, weil sie jemanden, der in Gefahr ist, retten wollen. Dass ein zusätzliches Risiko einer solchen Aktion die Begründung eigener Strafbarkeit sein könnte, überrascht vielleicht. Jedoch besteht das Risiko des Bestraftwerdens, wenn das Strafrecht falsch angewendet wird. Abstrakt gibt es dieses Risiko immer. Strafrechtsanwendende sind nicht unfehlbar, Strafgesetzgebende auch nicht. Aber das Risiko ist verringerbar. Wo der Gesetzgeber keine oder ausfüllungsbedürftige Normen geschaffen hat, sollte die Strafrechtslehre falschen Strafentscheidungen entgegenwirken, indem sie den Gerichten klare Handlungsanweisungen gibt. Die richtige konkrete Einzelfallentscheidung muss sich idealerweise abstrakt bereits in den strafrechtlichen Regeln abzeichnen. Der Held in spe sollte schon anhand des Gesetzes und seiner Erläuterungen durch die wissenschaftliche Literatur erkennen können, wo seine mutige Selbstaufopferung de lege lata in strafbaren Aktionismus umzuschlagen droht. Das kann ihm gegenwärtig noch nicht garantiert werden. Denn bei den Themen, die Gegenstand dieser Abhandlung sind, existiert noch erheblicher Normsetzungs- und Normerläuterungsbedarf.
Der Fall thematisiert klassische und neuartige Probleme der Rechtfertigungsdogmatik im Strafrecht. Neben dem Fehlen eines subjektiven Rechtfertigungselements sind Probleme des § 32 StGB zu bewältigen, die darauf beruhen, dass (scheinbar) weder auf der Seite des Angreifers noch auf der Seite des Angegriffenen ein Mensch unmittelbar am Konflikt beteiligt ist.
Rspr. und Strafrechtswissenschaft tun sich schwer mit der Behandlung von Taten, deren Akteure als „Lebensmittelerpresser“ bezeichnet werden. Das hat der Fall gezeigt, über den der 1. Strafsenat des BGH am BGH 5.6.2019 nach Revision des Angekl. gegen die Verurteilung durch das LG Ravensburg entschieden hat. Sowohl das Gericht als auch die Kommentatoren der BGH-Entscheidung beschäftigen sich ausführlich mit den Problemen des Rücktritts vom Versuch (§ STGB § 24 StGB). Die Tatbestandsmerkmale der (versuchten) qualifizierten räuberischen Erpressung werden hingegen fast gänzlich außer Acht gelassen. Bei genauerem Hinsehen erkennt man, dass schon die Erfüllung des Grundtatbestandes „versuchte Erpressung“ (§§ STGB § 253, STGB § 22 StGB) zweifelhaft ist und einer nicht ganz unkomplizierten Begründung bedarf. Erst recht problematisch sind sodann sämtliche Qualifikationsstufen, also §§ STGB § 255, STGB § 250 und STGB § 251 StGB. Der BGH und die Literatur – so hat es den Anschein − erachten dies als weitgehend unproblematisch. Am Beispiel des Friedrichshafener Falles soll aufgezeigt werden, was gegen eine Strafbarkeit des Täters aus §§ STGB § 253, STGB § 255, STGB § 250, STGB § 251, STGB § 22 StGB sprechen könnte und wie sich die Bedenken – teilweise − überwinden lassen.
We use the prolonged Greek crisis as a case study to understand how a lasting economic shock affects the innovation strategies of firms in economies with moderate innovation activities. Adopting the 3-stage CDM model, we explore the link between R&D, innovation, and productivity for different size groups of Greek manufacturing firms during the prolonged crisis. At the first stage, we find that the continuation of the crisis is harmful for the R&D engagement of smaller firms while it increased the willingness for R&D activities among the larger ones. At the second stage, among smaller firms the knowledge production remains unaffected by R&D investments, while among larger firms the R&D decision is positively correlated with the probability of producing innovation, albeit the relationship is weakened as the crisis continues. At the third stage, innovation output benefits only larger firms in terms of labor productivity, while the innovation-productivity nexus is insignificant for smaller firms during the lasting crisis.
Paid parental leave schemes have been shown to increase women’s employment rates but to decrease their wages in case of extended leave duration. In view of these potential trade-offs, many countries are discussing the optimal design of parental leave policies. We analyze the impact of a major parental leave reform on mothers’ long-term earnings. The 2007 German parental leave reform replaced a means-tested benefit with a more generous earnings-related benefit that is granted for a shorter period of time. Additionally, a ”daddy quota” of two months was introduced. To identify the causal effect of this policy mix on long-run earnings of mothers, we use a difference-in-differences approach that compares labor market outcomes of mothers who gave birth just before and right after the reform and nets out seasonal effects by including the year before. Using administrative social security data, we confirm previous findings and show that the average duration of employment interruptions increased for mothers with high pre-birth earnings. Nevertheless, we find a positive long-run effect on earnings for mothers in this group. This effect cannot be explained by changes in the selection of working mothers, working hours or changes in employer stability. Descriptive evidence suggests that the stronger involvement of fathers, incentivized by the ”daddy months”, could have facilitated mothers’ re-entry into the labor market and thereby increased earnings. For mothers with low pre-birth earnings, however, we do not find beneficial long-run effects of this parental leave reform.
Gender stereotypes influence subjective beliefs about the world, and this is reflected in our use of language. But do gender biases in language transparently reflect subjective beliefs? Or is the process of translating thought to language itself biased? During the 2016 United States (N = 24,863) and 2017 United Kingdom (N = 2,609) electoral campaigns, we compared participants' beliefs about the gender of the next head of government with their use and interpretation of pronouns referring to the next head of government. In the United States, even when the female candidate was expected to win, she pronouns were rarely produced and induced substantial comprehension disruption. In the United Kingdom, where the incumbent female candidate was heavily favored, she pronouns were preferred in production but yielded no comprehension advantage. These and other findings suggest that the language system itself is a source of implicit biases above and beyond previously known biases, such as those measured by the Implicit Association Test.
Due to their ability to capture attention, emotional stimuli tend to benefit from enhanced perceptual processing, which can be helpful when such stimuli are task-relevant but hindering when they are task-irrelevant. Altered emotion-attention interactions have been associated with symptoms of affective disturbances, and emerging research focuses on improving emotion-attention interactions to prevent or treat affective disorders. In line with the Human Affectome Project's emphasis on linguistic components, we also analyzed the language used to describe attention-related aspects of emotion, and highlighted terms related to domains such as conscious awareness, motivational effects of attention, social attention, and emotion regulation. These terms were discussed within a broader review of available evidence regarding the neural correlates of (1) Emotion-Attention Interactions in Perception, (2) Emotion-Attention Interactions in Learning and Memory, (3) Individual Differences in Emotion-Attention Interactions, and (4) Training and Interventions to Optimize Emotion-Attention Interactions. This comprehensive approach enabled an integrative overview of the current knowledge regarding the mechanisms of emotion-attention interactions at multiple levels of analysis, and identification of emerging directions for future investigations.
In contrast to the common conception that the interfacial energy-level alignment is affixed once the interface is formed, we demonstrate that heterojunctions between organic semiconductors and metal-halide perovskites exhibit huge energy-level realignment during photoexcitation. Importantly, the photoinduced level shifts occur in the organic component, including the first molecular layer in direct contact with the perovskite. This is caused by charge-carrier accumulation within the organic semiconductor under illumination and the weak electronic coupling between the junction components.
This study is trying to understand the pre-eruptive magma storage and crystallization conditions of the Middle Miocene aged, silica-saturated trachytic rocks of the Afyon Volcanic Complex (AVC) in Western Anatolia, Turkey. Those rocks can be divided by their high K2O, K2O/Na2O ratio and Mg# into two groups, namely the intermediate-potassic (IPG) and the ultrapotassic (UPG). Here we are comparing calculated pressure (P) - temperature (T) conditions derived from geothermobarometric calculations of natural samples with results of high-pressure, high-temperature phase equilibria experiments. IPG samples are richer in silica (57-64 wt% SiO2), whereas UPG samples show intermediate SiO2 contents of 56-58 wt%. UPG are having high K2O contents ((>)9 wt %), K2O/Na2O ratios ((>)10 wt%) and Mg# values (75-77). IPG phenocrysts comprise plagioclase + biotite + amphibole + clinopyroxene +/- orthopyroxene +/- sanidine +/- phlogopite and oxides, while UPG mineralogical assemblage consists of amphibole + phlogopite + clinopyroxene + olivine + sanidine and oxides. IPG and UPG are enriched in Large-Ion Lithophile Elements (LILE), and both have negative anomalies in Nb, Sr, Zr and Ti elements. Additionally, IPG shows positive anomalies in Pb. Both IPG and UPG display enrichment in Light Rare Earth Elements (LREE), while IPG shows a more significant negative anomaly in Eu when compared to UPG. Plagioclase fractionation may play a role in magma generation. In IPG samples Ni and Cr values range between (3.3-18.8 ppm) and (2.6-27.8 ppm), respectively; whereas UPG samples have (119.1-120.7 ppm) Ni and (212.1-219.9 ppm) Cr. Dy/Yb ratios of IPG and UPG are higher than 2 and may indicate that garnet was present in the source. Geothermobarometric calculations for natural IPG clinopyroxene-melt pairs imply higher PT conditions (Dogan-Kulahci et al., 2015), while in this study high-pressure/high-temperature (HP/HT) phase equilibria experiments recreated the natural mineral assemblage at 2-4 kbar, 6-9 km and c. 900 degrees C. New plagioclase-melt calculations have confirmed lower mean magma storage temperatures, which are closer to the experimental results but still slightly elevated. Thus, trace element results of the natural rocks and experimental data may imply that a deep garnet-bearing magma source mixed with shallower magmas (IPG) was feeding the volcanic eruption.
We traced diatom composition and diversity through time using diatom-derived sedimentary ancient DNA (sedaDNA) from eastern continental slope sediments off Kamchatka (North Pacific) by applying a short, diatom-specific marker on 63 samples in a DNA metabarcoding approach. The sequences were assigned to diatoms that are common in the area and characteristic of cold water. SedaDNA allowed us to observe shifts of potential lineages from species of the genus Chaetoceros that can be related to different climatic phases, suggesting that pre-adapted ecotypes might have played a role in the long-term success of species in areas of changing environmental conditions. These sedaDNA results complement our understanding of the long-term history of diatom assemblages and their general relationship to environmental conditions of the past. Sea-ice diatoms (Pauliella taeniata [Grunow] Round & Basson, Attheya septentrionalis [ostrup] R. M. Crawford and Nitzschia frigida [Grunow]) detected during the late glacial and Younger Dryas are in agreement with previous sea-ice reconstructions. A positive correlation between pennate diatom richness and the sea-ice proxy IP25 suggests that sea ice fosters pennate diatom richness, whereas a negative correlation with June insolation and temperature points to unfavorable conditions during the Holocene. A sharp increase in proportions of freshwater diatoms at similar to 11.1 cal kyr BP implies the influence of terrestrial runoff and coincides with the loss of 42% of diatom sequence variants. We assume that reduced salinity at this time stabilized vertical stratification which limited the replenishment of nutrients in the euphotic zone.
Prior research suggests that teachers with higher levels of empathy are more willing to intervene in bullying among students. However, these findings are based on hypothetical bullying situations and teachers' self-reports. In this study with 2,071 German students and their 556 teachers, we analysed reactions to hypothetical relational bullying situations as well as retrospectively reported bullying situations both from the teachers' as well as the students' perspectives. Results showed that teachers with higher levels of empathy reported stronger intentions to intervene in hypothetical relational bullying situations but were not more likely to intervene in retrospectively reported bullying situations. From the students' perspective, teachers' empathy was neither connected to the teachers' intention to intervene nor to the likelihood of intervention in the retrospectively reported situations. These different results could be taken as an opportunity to investigate whether existing findings could be influenced by methodological aspects such as teachers' self-reports. Implications for future research are discussed.
Cyanobacteria are important primary producers in temperate freshwater ecosystems. However, studies on the seasonal and spatial distribution of cyanobacteria in deep lakes based on high-throughput DNA sequencing are still rare. In this study, we combined monthly water sampling and monitoring in 2019, amplicon sequence variants analysis (ASVs; a proxy for different species) and quantitative PCR targeting overall cyanobacteria abundance to describe the seasonal and spatial dynamics of cyanobacteria in the deep hard-water oligo-mesotrophic Lake Tiefer See, NE Germany. We observed significant seasonal variation in the cyanobacterial community composition (p < 0.05) in the epi- and metalimnion layers, but not in the hypolimnion. In winter-when the water column is mixed-picocyanobacteria (Synechococcus and Cyanobium) were dominant. With the onset of stratification in late spring, we observed potential niche specialization and coexistence among the cyanobacteria taxa driven mainly by light and nutrient dynamics. Specifically, ASVs assigned to picocyanobacteria and the genus Planktothrix were the main contributors to the formation of deep chlorophyll maxima along a light gradient. While Synechococcus and different Cyanobium ASVs were abundant in the epilimnion up to the base of the euphotic zone from spring to fall, Planktothrix mainly occurred in the metalimnetic layer below the euphotic zone where also overall cyanobacteria abundance was highest in summer. Our data revealed two potentially psychrotolerant (cold-adapted) Cyanobium species that appear to cope well under conditions of lower hypolimnetic water temperature and light as well as increasing sediment-released phosphate in the deeper waters in summer. The potential cold-adapted Cyanobium species were also dominant throughout the water column in fall and winter. Furthermore, Snowella and Microcystis-related ASVs were abundant in the water column during the onset of fall turnover. Altogether, these findings suggest previously unascertained and considerable spatiotemporal changes in the community of cyanobacteria on the species level especially within the genus Cyanobium in deep hard-water temperate lakes.
Many animals form aggregations with individuals of the same species (single-species aggregations, SSA). Less frequently, individuals may also aggregate with individuals of other species (mixed-species aggregations, MSA). Although the benefits and costs of SSA have been intensively studied, the same is not true for MSA. Here, we first review the cases of MSA in harvestmen, an arachnid order in which the records of MSA are more frequent than other arthropod orders. We then propose several benefits and costs of MSA in harvestmen, and contrast them with those of SSA. Second, using field-gathered data we describe gregariousness in seven species of Prionostemma harvestmen from Costa Rica. These species form MSA, but individuals are also found solitarily or in SSA. We tested one possible benefit and one possible cost of gregariousness in Prionostemma harvestmen. Regarding the benefit, we hypothesized that individuals missing legs would be more exposed to predation than eight-legged individuals and thus they should be found preferentially in aggregations, where they would be more protected from predators. Our data, however, do not support this hypothesis. Regarding the cost, we hypothesized that gregariousness increases the chances of parasitism. We found no support for this hypothesis either because both mite prevalence and infestation intensity did not differ between solitary or aggregated individuals. Additionally, the type of aggregation (SSA or MSA) was not associated with the benefit or the cost we explored. This lack of effect may be explained by the fluid membership of the aggregations, as we found high turnover over time in the number of individuals and species composition of the aggregations. In conclusion, we hope our review and empirical data stimulate further studies on MSA, which remains one of the most elusive forms of group living in animals.
The purpose of this study was to examine the longitudinal relationship between problematic online gaming and subjective health complaints and depressive symptoms, and the moderation of console-gaming aggression (i.e. verbal aggression, camping, trolling) in this relationship. Participants were 202 adolescents (86% boys; M age = 12.99 years) in the 7(th) or 8(th) grade who played first-person shooter games. They completed questionnaires on problematic online gaming, console-gaming aggression, subjective health complaints, and depressive symptoms. Six months later (Time 2), they completed questionnaires on subjective health complaints and depressive symptoms again. Findings revealed that problematic online gaming and console-gaming aggression were positive predictors of Time 2 subjective health complaints and depressive symptoms, while controlling for Time 1 levels and gender. Moderating effects were found as well, indicating that high levels of console-gaming aggression increased the positive relationship between problematic online gaming and depressive symptoms. These effects were also replicated for verbal aggression, problematic online gaming, and subjective health complaints. These findings suggest the importance of considering the implications of console-gaming aggression and problematic online gaming for the physical and mental health of adolescents.
IMPACT SUMMARY
Prior State of Knowledge. Problematic online gaming and aggressive behaviors are linked to negative outcomes, including depression and subjective health complaints. Longitudinal research further supports this connection for depression, but not for subjective health complaints or various types of aggression via console games.
Novel Contributions. Few studies have focused on various types of aggression and the longitudinal associations among problematic online gaming, depression, and subjective health complaints, while controlling for previous levels of depression and subjective health complaints. The present research addresses these gaps.
Practical Implications. Findings of the present research has implications for clinicians and researchers concerned with identifying adolescents who might be at risk for negative outcomes.
Hidden semi-Markov models generalise hidden Markov models by explicitly modelling the time spent in a given state, the so-called dwell time, using some distribution defined on the natural numbers. While the (shifted) Poisson and negative binomial distribution provide natural choices for such distributions, in practice, parametric distributions can lack the flexibility to adequately model the dwell times. To overcome this problem, a penalised maximum likelihood approach is proposed that allows for a flexible and data-driven estimation of the dwell-time distributions without the need to make any distributional assumption. This approach is suitable for direct modelling purposes or as an exploratory tool to investigate the latent state dynamics. The feasibility and potential of the suggested approach is illustrated in a simulation study and by modelling muskox movements in northeast Greenland using GPS tracking data. The proposed method is implemented in the R-package PHSMM which is available on CRAN.
Predicting entrepreneurial development based on individual and business-related characteristics is a key objective of entrepreneurship research. In this context, we investigate whether the motives of becoming an entrepreneur influence the subsequent entrepreneurial development. In our analysis, we examine a broad range of business outcomes including survival and income, as well as job creation, and expansion and innovation activities for up to 40 months after business formation. Using the self-determination theory as conceptual background, we aggregate the start-up motives into a continuous motivational index. We show – based on a unique dataset of German start-ups from unemployment and non-unemployment – that the later business performance is better, the higher they score on this index. Effects are particularly strong for growth-oriented outcomes like innovation and expansion activities. In a next step, we examine three underlying motivational categories that we term opportunity, career ambition, and necessity. We show that individuals driven by opportunity motives perform better in terms of innovation and business expansion activities, while career ambition is positively associated with survival, income, and the probability of hiring employees. All effects are robust to the inclusion of a large battery of covariates that are proven to be important determinants of entrepreneurial performance.
Seed dispersal plays an important role in population dynamics in agricultural ecosystems, but the effects of surrounding vegetation height on seed dispersal and population connectivity on the landscape scale have rarely been studied. Understanding the effects of surrounding vegetation height on seed dispersal will provide important information for land-use management in agricultural landscapes to prevent the spread of undesired weeds or enhance functional connectivity. We used two model species, Phragmites australis and Typha latifolia, growing in small natural ponds known as kettle holes, in an agricultural landscape to evaluate the effects of surrounding vegetation height on wind dispersal and population connectivity between kettle holes. Seed dispersal distance and the probability of long-distance dispersal (LDD) were simulated with the mechanistic WALD model under three scenarios of "low", "dynamic" and "high" surrounding vegetation height. Connectivity between the origin and target kettle holes was quantified with a connectivity index adapted from Hanski and Thomas (1994). Our results show that mean seed dispersal distance decreases with the height of surrounding matrix vegetation, but the probability of long-distance dispersal (LDD) increases with vegetation height. This indicates an important vegetation-based trade-off between mean dispersal distance and LDD, which has an impact on connectivity. Matrix vegetation height has a negative effect on mean seed dispersal distance but a positive effect on the probability of LDD. This positive effect and its impact on connectivity provide novel insights into landscape level (meta-)population and community dynamics - a change in matrix vegetation height by land-use or climatic changes could strongly affect the spread and connectivity of wind-dispersed plants. The opposite effect of vegetation height on mean seed dispersal distance and the probability of LDD should therefore be considered in management and analyses of future land-use and climate change effects.
Ranking local climate policy
(2021)
Climate mitigation and climate adaptation are crucial tasks for urban areas and can involve synergies as well as trade-offs. However, few studies have examined how mitigation and adaptation efforts relate to each other in a large number of differently sized cities, and therefore we know little about whether forerunners in mitigation are also leading in adaptation or if cities tend to focus on just one policy field. This article develops an internationally applicable approach to rank cities on climate policy that incorporates multiple indicators related to (1) local commitments on mitigation and adaptation, (2) urban mitigation and adaptation plans and (3) climate adaptation and mitigation ambitions. We apply this method to rank 104 differently sized German cities and identify six clusters: climate policy leaders, climate adaptation leaders, climate mitigation leaders, climate policy followers, climate policy latecomers and climate policy laggards. The article seeks explanations for particular cities' positions and shows that coping with climate change in a balanced way on a high level depends on structural factors, in particular city size, the pathways of local climate policies since the 1990s and funding programmes for both climate mitigation and adaptation.
Objective:
Following a life course perspective, this study examines the link between partnership trajectories and three dimensions of psychological well-being: psychological health, overall sense of self-worth and quality of life.
Background:
Assuming that life outcomes are the result of prior decisions, experiences and events, partnership histories can be seen as a resource for psychological well-being. Furthermore, advantages or disadvantages from living with or without a partner should accumulate over time. While previous cross-sectional research has mainly focused on the influence of partnership status or a status change on well-being, prior longitudinal studies could not control for reverse causality of well-being and partnership trajectories. This research addresses the question of how different patterns of partnership biographies are related to a person's well-being in middle adulthood. Selection effects of pre-trajectory well-being as well as current life conditions are also taken into account.
Method:
Using data from the German LifE Study, the partnership trajectories between ages of 16 and 45 are classified by sequence and cluster analysis. OLS regression is then used to examine the link between types of partnership trajectories and depression, self-esteem and overall life satisfaction at age 45.
Results:
For women, well-being declined when experiencing unstable non-cohabitational union trajectories or divorce followed by unpartnered post-marital trajectories. Men suffered most from being long-term single. The results could not be explained by selection effects of pre-trajectory well-being.
Conclusion:
While women seem to 'recover' from most of the negative effects of unstable partnership trajectories through a new partnership, for men it was shown that being mainly unpartnered has long-lasting effects on their psychological well-being.
This eye-tracking study establishes basic benchmarks of eye movements during reading in heritage language (HL) by Russian-speaking adults and adolescents of high (n = 21) and low proficiency (n = 27). Heritage speakers (HSs) read sentences in Cyrillic, and their eye movements were compared to those of Russian monolingual skilled adult readers, 8-year-old children and L2 learners. Reading patterns of HSs revealed longer mean fixation durations, lower skipping probabilities, and higher regressive saccade rates than in monolingual adults. High-proficient HSs were more similar to monolingual children, while low-proficient HSs performed on par with L2 learners. Low-proficient HSs differed from high-proficient HSs in exhibiting lower skipping probabilities, higher fixation counts, and larger frequency effects. Taken together, our findings are consistent with the weaker links account of bilingual language processing as well as the divergent attainment theory of HL.
This study examined the effect of 6 weeks of progressed and nonprogressed volume-based overload plyometric training (PT) on components of physical fitness and body composition measures in young male basketball players, compared with an active control group. Subjects were randomly assigned to a progressed PT (PPT, n = 7; age = 14.6 +/- 1.1 years), a non-PPT (NPPT, n = 8, age = 13.8 +/- 2.0 years), or a control group (CG, n = 7, age = 14.0 +/- 2.0 years). Before and after training, body composition measures (muscle mass and fat mass), countermovement jump with arms (CMJA) and countermovement jump without arms (CMJ), horizontal bilateral (HCMJ) and unilateral jump with right leg (RJ) and left leg (LJ), 20-cm drop jump (DJ20), sprint speed (10 m sprint), and change of direction speed (CODS [i.e., T-test]) were tested. Significant effects of time were observed for muscle and fat mass, all jump measures, and CODS (all p < 0.01; d = 0.37-0.83). Significant training group x time interactions were observed for all jump measures (all p < 0.05; d = 0.24-0.41). Post hoc analyses revealed significant pre-post performance improvements for the PPT (RJ and LJ: increment 18.6%, d = 0.8 and increment 22.7%, d = 0.9, respectively; HCMJ: increment 16.4%, d = 0.8; CMJ: increment 22.4%, d = 0.7; CMJA: increment 23.3%, d = 0.7; and DJ20: increment 39.7%, d = 1.1) and for the NPPT group (LJ: increment 14.1%, d = 0.4; DJ20: increment 32.9%, d = 0.8) with greater changes after PPT compared with NPPT for all jump measures (all p < 0.05; d = 0.21-0.81). The training efficiency was greater (p < 0.05; d = 0.22) after PPT (0.015% per jump) compared with NPPT (0.0053% per-jump). The PPT induced larger performance improvements on measures of physical fitness as compared to NPPT. Therefore, in-season progressive volume-based overload PT in young male basketball players is recommended.
Do stereotypes strike twice?
(2019)
Stereotypes influence teachers' perception of and behaviour towards students, thus shaping students' learning opportunities. The present study investigated how 315 Australian pre-service teachers' stereotypes about giftedness and gender are related to their perception of students' intellectual ability, adjustment, and social-emotional ability, using an experimental vignette approach and controlling for social desirability in pre-service teachers' responses. Repeated-measures ANOVA showed that pre-service teachers associated giftedness with higher intellectual ability, but with less adjustment compared to average-ability students. Furthermore, pre-service teachers perceived male students as less socially and emotionally competent and less adjusted than female students. Additionally, pre-service teachers seemed to perceive female average-ability students' adjustment as most favourable compared to male average-ability students and gifted students. Findings point to discrepancies between actual characteristics of gifted female and male students and stereotypes in teachers' beliefs. Consequences of stereotyping and implications for teacher education are discussed.
Making sense of the world
(2020)
For human infants, the first years after birth are a period of intense exploration-getting to understand their own competencies in interaction with a complex physical and social environment. In contemporary neuroscience, the predictive-processing framework has been proposed as a general working principle of the human brain, the optimization of predictions about the consequences of one's own actions, and sensory inputs from the environment. However, the predictive-processing framework has rarely been applied to infancy research. We argue that a predictive-processing framework may provide a unifying perspective on several phenomena of infant development and learning that may seem unrelated at first sight. These phenomena include statistical learning principles, infants' motor and proprioceptive learning, and infants' basic understanding of their physical and social environment. We discuss how a predictive-processing perspective can advance the understanding of infants' early learning processes in theory, research, and application.
We are glad to introduce the Second Journal Club of Volume Five, Second Issue. This edition is focused on relevant studies published in the last few years in the field of resistance training, chosen by our Editorial Board members and their colleagues. We hope to stimulate your curiosity in this field and to share with you the passion for the sport, seen also from the scientific point of view. The Editorial Board members wish you an inspiring lecture.
The Kohat fold and thrust belt in Pakistan shows a significantly different structural style due to the structural evolution on the double décollement compared to the rest of the Subhimalaya. In order to better understand the spatio-temporal structural evolution of the Kohat fold and thrust belt, we combine balanced cross sections with apatite (U?Th-Sm)/He (AHe) and apatite fission track (AFT) dating. The AHe and AFT ages appear to be totally reset, allowing us to date exhumation above structural ramps. The results suggest that deformation began on the frontal Surghar thrust at-15 Ma, predating or coeval with the development of the Main Boundary thrust at-12 Ma. Deformation propagated southward from the Main Boundary thrust on double de?collements between 10 Ma and 2 Ma, resulting in a disharmonic structural style inside the Kohat fold and thrust belt. Thermal modeling of the thermochronologic data suggest that samples inside Kohat fold and thrust belt experienced cooling due to formation of the duplexes; this deformation facilitated tectonic thickening of the wedge and erosion of the Miocene to Pliocene foreland strata. The spatial distribution of AHe and AFT ages in combination with the structural forward model suggest that, in the Kohat fold and thrust belt, the wedge deformed in-sequence as a supercritical wedge (-15-12 Ma), then readjusted by out-sequence deformation (-12-0 Ma) within the Kohat fold and thrust belt into a sub-critical wedge.