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Nowadays, working in an office environment is ubiquitous. At the same time, progressively more people suffer from occupational musculoskeletal disorders. Therefore, the aim of this pilot study was to analyse the influence of back pain on sitting behaviour in the office environment. A textile pressure mat (64-sensor-matrix) placed on the seat pan was used to identify the adopted sitting positions of 20 office workers by means of random forest classification. Additionally, two standardised questionnaires (Korff, BPI) were used to assess short and long-term back pain in order to divide the subjects into two groups (with and without back pain). Independent t-test indicated that subjects who registered back pain within the last 24 h showed a clear trend towards a more static sitting behaviour. Therefore, the developed sensor system has successfully been introduced to characterise and compare sitting behaviour of subjects with and without back pain. (C) 2016 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licensesiby-nc-nd/4.0/).
Groundwater influx can significantly contribute to nutrient and carbon budgets of lakes, and its influence is the strongest in littoral areas dominated by macrophytes and periphyton. We have reviewed the effects of groundwater-borne nitrogen and phosphorus and dissolved inorganic and organic carbon (DIC, DOC) on these benthic primary producers in lakes. We develop a hypothesis for groundwater effects including the less studied impacts of periphyton shading on macrophytes. Groundwater-borne nutrients and DIC promote both macrophytes and periphyton. Direct studies on groundwater-borne DOC effects are lacking, but coloured DOC contributes to light attenuation and thus can restrict the growth of benthic primary producers. We predict that above certain threshold levels of nutrient influx by groundwater, periphyton and macrophyte biomass should decline owing to shading by phytoplankton and periphyton, respectively. However, because of their higher light requirements, those thresholds should be lower for macrophytes. For macrophytes, a threshold level is also predicted for a shift from DIC limitation to light limitation. Differences in light requirements are expected to result in lower thresholds of DOC loading for declines of macrophytes than periphyton.
We study operators on singular manifolds, here of conical or edge type, and develop a new general approach of representing asymptotics of solutions to elliptic equations close to the singularities. We introduce asymptotic parametrices, using tools from cone and edge pseudo-differential algebras. Our structures are motivated by models of many-particle physics with singular Coulomb potentials that contribute higher order singularities in Euclidean space, determined by the number of particles.
Deciphering the response of sediment routing systems to climatic forcing is fundamental for understanding the impacts of climate change on landscape evolution. In the Kangra Basin (northwest Sub-Himalaya, India), upper Pleistocene to Holocene alluvial fills and fluvial terraces record periodic fluctuations of sediment supply and transport capacity on timescales of 10(3) to 10(5) yr. To evaluate the potential influence of climate change on these fluctuations, we compare the timing of aggradation and incision phases recorded within remnant alluvial fans and terraces with climate archives. New surface-exposure dating of six terrace levels with in-situ cosmogenic Be-10 indicates the onset of incision phases. Two terrace surfaces from the highest level (T1) sculpted into the oldest preserved alluvial fan (AF1) date back to 53.4 +/- 3.2 ka and 43.0 +/- 2.7 ka (1 sigma). T2 surfaces sculpted into the remnants of AF1 have exposure ages of 18.6 +/- 1.2 ka and 15.3 +/- 0.9 ka, while terraces sculpted into the upper Pleistocene-Holocene fan (AF2) provide ages of 9.3 +/- 0.4 ka (T3), 7.1 +/- 0.4 ka (T4), 5.2 +/- 0.4 ka (T5) and 3.6 +/- 0.2 ka (T6). Together with previously published OSL ages yielding the timing of aggradation, we find a correlation between variations in sediment transport with oxygen-isotope records from regions affected by the Indian Summer Monsoon. During periods of increased monsoon intensity and post-Last Glacial Maximum glacial retreat, aggradation occurred in the Kangra Basin, likely due to high sediment flux, whereas periods of weakened monsoon intensity or lower sediment supply coincide with incision. (C) 2016 Elsevier B.V. All rights reserved.
The Greater and Lesser Caucasus mountains and their associated foreland basins contain similar rock types, experience a similar two-fold, along-strike variation in mean annual precipitation, and were affected by extreme base-level drops of the neighboring Caspian Sea. However, the two Caucasus ranges are characterized by decidedly different tectonic regimes and rates of deformation that are subject to moderate (less than an order of magnitude) gradients in climate, and thus allow for a unique opportunity to isolate the effects of climate and tectonics in the evolution of topography within active orogens. There is an apparent disconnect between modern climate, shortening rates, and topography of both the Greater Caucasus and Lesser Caucasus which exhibit remarkably similar topography along-strike despite the gradients in forcing. By combining multiple datasets, we examine plausible causes for this disconnect by presenting a detailed analysis of the topography of both ranges utilizing established relationships between catchment-mean erosion rates and topography (local relief, hillslope gradients, and channel steepness) and combining it with a synthesis of previously published low-temperature thermochronologic data. Modern climate of the Caucasus region is assessed through an analysis of remotely-sensed data (TRMM and MODIS) and historical streamflow data. Because along-strike variation in either erosional efficiency or thickness of accreted material fail to explain our observations, we suggest that the topography of both the western Lesser and Greater Caucasus are partially supported by different geodynamic forces. In the western Lesser Caucasus, high relief portions of the landscape likely reflect uplift related to ongoing mantle lithosphere delamination beneath the neighboring East Anatolian Plateau. In the Greater Caucasus, maintenance of high topography in the western portion of the range despite extremely low (<2-4 mm/y) modern convergence rates may be related to dynamic topography from detachment of the north-directed Greater Caucasus slab or to a recent slowing of convergence rates. Large-scale spatial gradients in climate are not reflected in the topography of the Caucasus and do not seem to exert any significant control on the tectonics or structure of either range. (C) 2016 Elsevier B.V. All rights reserved.
Biomimetic binders and catalysts have been generated in order to substitute the biological pendants in separation techniques and bioanalysis. The two major approaches use either "evolution in the test tube" of nucleotides for the preparation of aptamers or total chemical synthesis for molecularly imprinted polymers (MIPs). The reproducible production of aptamers is a clear advantage, whilst the preparation of MIPs typically leads to a population of polymers with different binding sites. The realization of binding sites in the total bulk of the MIPs results in a higher binding capacity, however, on the expense of the accessibility and exchange rate. Furthermore, the readout of the bound analyte is easier for aptamers since the integration of signal generating labels is well established. On the other hand, the overall negative charge of the nucleotides makes aptamers prone to non-specific adsorption of positively charged constituents of the sample and the "biological" degradation of non-modified aptamers and ionic strength-dependent changes of conformation may be challenging in some application.
Hydrologic regionalization deals with the investigation of homogeneity in watersheds and provides a classification of watersheds for regional analysis. The classification thus obtained can be used as a basis for mapping data from gauged to ungauged sites and can improve extreme event prediction. This paper proposes a wavelet power spectrum (WPS) coupled with the self-organizing map method for clustering hydrologic catchments. The application of this technique is implemented for gauged catchments. As a test case study, monthly streamflow records observed at 117 selected catchments throughout the western United States from 1951 through 2002. Further, based on WPS of each station, catchments are classified into homogeneous clusters, which provides a representative WPS pattern for the streamflow stations in each cluster.
The enzymatic degradation of oligo(epsilon-caprolactone) (OCL) based films at the air-water interface is investigated by Langmuir monolayer degradation (LMD) experiments to elucidate the influence of the molecular architecture and of the chemical structure on the chain scission process. For that purpose, the interactions of 2D monolayers of two star-shaped poly(epsilon-caprolactone)s (PCLs) and three linear OCL based copolyesterurethanes (P(OCL-U)) with the lipase from Pseudomonas cepacia are evaluated in comparison to linear OCL. While the architecture of star-shaped PCL Langmuir layers slightly influences their degradability compared to OCL films, significantly retarded degradations are observed for P(OCL-U) films containing urethane junction units derived from 2, 2 (4), 4-trimethyl hexamethylene diisocyanate (TMDI), hexamethylene diisocyanate (HDI) or lysine ethyl ester diisocyanate (LDI). The enzymatic degradation of the OCL based 2D structures is related to the presence of hydrophilic groups within the macromolecules rather than to the packing density of the film or to the molecular weight. The results reveal that the LMD technique allows the parallel analysis of both the film/enzyme interactions and the degradation process on the molecular level. (C) 2016 Elsevier Ltd. All rights reserved.
In recent simulations of femtosecond laser induced desorption of molecular oxygen from the Ag(110) surface, it has been shown that depending on the properties (depth and electronic environment) of the well in which 02 is adsorbed, the desorption can be either induced dominantly by hot electrons or via excitations of phonons. In this work we explore whether the ratios between the desorption yields from different adsorption wells can be tuned by changing initial surface temperature and laser pulse properties. We show that the initial surface temperature is an important parameter, and that by using low initial surface temperatures the electronically mediated process can be favored. In contrast, laser properties seem to have only a modest influence on the results. (C) 2016 Elsevier B.V. All rights reserved.
We introduce extensions of stability selection, a method to stabilise variable selection methods introduced by Meinshausen and Buhlmann (J R Stat Soc 72:417-473, 2010). We propose to apply a base selection method repeatedly to random subsamples of observations and subsets of covariates under scrutiny, and to select covariates based on their selection frequency. We analyse the effects and benefits of these extensions. Our analysis generalizes the theoretical results of Meinshausen and Buhlmann (J R Stat Soc 72:417-473, 2010) from the case of half-samples to subsamples of arbitrary size. We study, in a theoretical manner, the effect of taking random covariate subsets using a simplified score model. Finally we validate these extensions on numerical experiments on both synthetic and real datasets, and compare the obtained results in detail to the original stability selection method.