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Aims. We performed a spatially resolved spectral X-ray study of the pulsar wind nebula ( PWN) in the supernova remnant G0.9+ 0.1. Furthermore, we modeled its nonthermal emission in the X-ray and very high-energy (VHE, E > 100 GeV) gamma-ray regime. Methods. Using Chandra ACIS-S3 data, we investigated the east-west dependence of the spectral properties of G0.9+ 0.1 by calculating hardness ratios. We analyzed the EPIC-MOS and EPIC-pn data of two on-axis observations of the XMM-Newton telescope and extracted spectra of four annulus-shaped regions, centered on the region of brightest emission of the source. A radially symmetric leptonic model was applied in order to reproduce the observed X-ray emission of the inner part of the PWN. Using the optimized model parameter values obtained from the X-ray analysis, we then compared the modeled inverse Compton (IC) radiation with the published H.E.S.S. gamma-ray data. Results. The spectral index within the four annuli increases with growing distance to the pulsar, whereas the surface brightness drops. With the adopted model we are able to reproduce the characteristics of the X-ray spectra. The model results for the VHE. radiation, however, strongly deviate from the H.E.S.S. data.
This study provides a detailed analysis of the mid-Holocene to present-day precipitation change in the Asian monsoon region. We compare for the first time results of high resolution climate model simulations with a standardised set of mid-Holocene moisture reconstructions. Changes in the simulated summer monsoon characteristics (onset, withdrawal, length and associated rainfall) and the mechanisms causing the Holocene precipitation changes are investigated. According to the model, most parts of the Indian subcontinent received more precipitation (up to 5 mm/day) at mid-Holocene than at present-day. This is related to a stronger Indian summer monsoon accompanied by an intensified vertically integrated moisture flux convergence. The East Asian monsoon region exhibits local inhomogeneities in the simulated annual precipitation signal. The sign of this signal depends on the balance of decreased pre-monsoon and increased monsoon precipitation at mid-Holocene compared to present-day. Hence, rainfall changes in the East Asian monsoon domain are not solely associated with modifications in the summer monsoon circulation but also depend on changes in the mid-latitudinal westerly wind system that dominates the circulation during the pre-monsoon season. The proxy-based climate reconstructions confirm the regional dissimilarities in the annual precipitation signal and agree well with the model results. Our results highlight the importance of including the pre-monsoon season in climate studies of the Asian monsoon system and point out the complex response of this system to the Holocene insolation forcing. The comparison with a coarse climate model simulation reveals that this complex response can only be resolved in high resolution simulations.
Direction of gaze (eye angle + head angle) has been shown to be important for representing space for action, implying a crucial role of vision for spatial updating. However, blind people have no access to vision yet are able to perform goal-directed actions successfully. Here, we investigated the role of visual experience for localizing and updating targets as a function of intervening gaze shifts in humans. People who differed in visual experience (late blind, congenitally blind, or sighted) were briefly presented with a proprioceptive reach target while facing it. Before they reached to the target's remembered location, they turned their head toward an eccentric direction that also induced corresponding eye movements in sighted and late blind individuals. We found that reaching errors varied systematically as a function of shift in gaze direction only in participants with early visual experience (sighted and late blind). In the late blind, this effect was solely present in people with moveable eyes but not in people with at least one glass eye. Our results suggest that the effect of gaze shifts on spatial updating develops on the basis of visual experience early in life and remains even after loss of vision as long as feedback from the eyes and head is available.
The spatial magnetic properties, through-space NMR shieldings (TSNMRS), of benzenoid and quinoid tautomeric structures such as benzodifurantrione and phenazine-type molecules have been calculated using the GIAO perturbation method employing the nucleus independent chemical shift (NICS) concept of Paul von Rague Schleyer and visualized as iso-chemical-shielding surfaces (ICSS) of various size and direction. The TSNMRS values were employed to quantify and visualize the partial aromaticity of the studied compounds. In the case of the surprisingly more stable quinoid tautomers, the aromaticity-synonymous with stability due to the conjugation of p electrons and lone pairs-was not found to be particularly reduced.
The spatial magnetic properties, through-space NMR shieldings (TSNMRS), of benzenoid and quinoid tautomeric structures such as benzodifurantrione and phenazine-type molecules have been calculated using the GIAO perturbation method employing the nucleus independent chemical shift (NICS) concept of Paul von Rague Schleyer and visualized as iso- chemical-shielding surfaces (ICSS) of various size and direction. The TSNMRS values were employed to quantify and visualize the partial aromaticity of the studied compounds. In the case of the surprisingly more stable quinoid tautomers, the aromaticity-synonymous with stability due to the conjugation of p electrons and lone pairs-was not found to be particularly reduced.
Detailed knowledge on the spatial distribution of soils is crucial for environmental monitoring, management, and modeling. However soil maps with a finite number of discrete soil map units are often the only available information about soils. Depending on the map scale or the detailing of the map legend this information could be too imprecise. We present a method for the spatial disaggregation of map units, namely the refinement of complex soil map units in which two or more soil types are aggregated. Our aim is to draw new boundaries inside the map polygons to represent a single soil type and no longer a mixture of several soil types. The basic idea for our method is the functional relationship between soil types and topographic position as formulated in the concept of the catena. We use a comprehensive soil profile database and topographic attributes derived from a 10 m digital elevation model as input data for the classification of soil types with random forest models. We grouped all complex map units which have the same combination of soil types. Each group of map units is modeled separately. For prediction of the soil types we stratified the soil map into these groups and apply a specific random forest model only to the associated map units. In order to get reliable results we define a threshold for the predicted probabilities at 0.7 to assign a specific soil type. In areas where the probability is below 0.7 for every possible soil type we assign a new class "indifferent" because the model only makes unspecific classification there. Our results show a significant spatial refinement of the original soil polygons. Validation of our predictions was estimated on 1812 independent soil profiles which were collected subsequent to prediction in the field. Field validation gave an overall accuracy of 70%. Map units, in which shallow soils were grouped together with deep soils could be separated best. Also histosols could be predicted successful. Highest error rate were found in map units, in which Gleysoils were grouped together with deep soils or Anthrosols. To check for validity of our results we open the black box random forest model by calculating the variable importance for each predictor variable and plotting response surfaces. We found good confirmations of our hypotheses, that topography has a significant influence on the spatial arrangement of soil types and that these relationships can be used for disaggregation.
The goal of behavioral neuroscience is to map psychological concepts onto physiological and anatomical concepts and vice versa. The present paper reflects on some of the hidden obstacles that have to be overcome in order to find unique psychophysiological relationships. These are, among others: (1) the different status of concepts which are defined in the two domains (ontological subjectivity in psychology and ontological objectivity in physiology); (2) the distinct hierarchical levels to which concepts from the two domains may belong; (3) ambiguity of concepts, because-due to limited measurement resolution or definitional shortcomings-they sometimes do not cover unique states or processes; (4) ignored context dependencies. Moreover, it is argued that due to the gigantic number of states and state changes, which are possible in a nervous system, it seems unlikely that neuroscience can provide exact causal explanations and predictions of behavior. Rather, as in statistical thermodynamics the transition from the microlevel of explanations to the macrolevel is only possible with probabilistic uncertainty.
The following article is concerned with the problem of language diversity within the framework of Radical Minimalism (Krivochen 2011, 2012). How can the diversity and variation of languages be explained? For Noam Chomsky, language faculty in the narrow sense (FLN) is nothing but an "organ of the body,' along with other cognitive systems. Our analysis of human language builds on Chomsky's (1995, 2005, 2010) minimalist assumption that the design of language is grounded in conceptual necessity. Adopting this idea, we expect to find three factors that interact to determine (I-) languages attained: genetic endowment (the topic of Universal Grammar), experience, and principles that are language- or even organism-independent." (Chomsky 2005:1). In the present article we provide some ideas about how generative research based on Radical Minimalism can contribute on a par with the typology of languages to a more profound and sound exploration of language variation. The scope of the paper is to compare the distribution of adverbs within the three domains of the clause in Czech and German. The aim of this paper is to show that the feature-based theory of adverb licensing is not able to handle the problem of adverb order variation. Instead, a more parsimonious approach based on the Theory of Radical Minimalism will be chosen. The paper is organized as follows: After some remarks on the role of Universal Grammar, Variation and Typology in section 1, section 2 introduces the theoretical background by introducing the principles and the core of Radical Minimalism, e.g. free unbounded merge, asymmetric c-command and the restrictions within the clause structure composition. In section 3, the distribution of adverbs in the middle field is discussed for Czech and German. In the last part, we introduce the so-called Late Adjunction Hypothesis that results in similar effects to the Early Spell-Out model argued for in our paper.
A linear differential operator L is called weakly hypoelliptic if any local solution u of Lu = 0 is smooth. We allow for systems, i.e. the coefficients may be matrices, not necessarily of square size. This is a huge class of important operators which covers all elliptic, overdetermined elliptic, subelliptic and parabolic equations. We extend several classical theorems from complex analysis to solutions of any weakly hypoelliptic equation: the Montel theorem providing convergent subsequences, the Vitali theorem ensuring convergence of a given sequence, and Riemann's first removable singularity theorem. In the case of constant coefficients we show that Liouville's theorem holds, any bounded solution must be constant and any L^p solution must vanish.
The self-assembly of double-hydrophilic poly(ethylene oxide)-poly(2-methyl-2-oxazoline) diblock copolymers in water has been studied. Isothermal titration calorimetry, small-angle X-ray scattering, and analytical ultracentrifugation suggest that only single polymer chains are present in solution. In contrast, light scattering and transmission electron microscopy detect aggregates with radii of ca. 100 nm. Pulsed field gradient NMR spectroscopy confirms the presence of aggregates, although only 2% of the polymer chains undergo aggregation. Water uptake experiments indicate differences in the hydrophilicity of the two blocks, which is believed to be the origin of the unexpected aggregation behavior (in accordance with an earlier study by Ke et al. [Macromolecules 2009, 42, 5339-5344]). The data therefore suggest that even in double-hydrophilic block copolymers, differences in hydrophilicity are sufficient to drive polymer aggregation, a phenomenon that has largely been overlooked or ignored so far.