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Fractional crystallization of peraluminous F- and H(2)O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions. We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.
A localized dehydration zone, Sondrum stone quarry, Halmstad, SW Sweden, consists of a central, 1 m wide granitic pegmatoid dyke, on either side of which extends a 2.5-3 m wide dehydration zone (650-700 degrees C; 800 MPa; orthopyroxene-clinopyroxene-biotite-amphibole-garnet) overprinting a local migmatized granitic gneiss (amphibole-biotite- garnet). Whole-rock chemistry indicates that dehydration of the granitic gneiss was predominantly isochemical. Exceptions include [Y + heavy rare earth elements (HREE)], Ba, Sr, and F, which are markedly depleted throughout the dehydration zone. Systematic trends in the silicate and fluorapatite mineral chemistry across the dehydration zone include depletion in Fe, (Y + HREE), Na, K, F, and Cl, and enrichment in Mg, Mn, Ca, and Ti. Fluid inclusion chemistry is similar in all three zones and indicates the presence of a fluid containing CO2, NaCl, and H2O components. Water activities in the dehydration zone average 0.36, or XH2O = 0.25. All lines of evidence suggest that the formation of the dehydration zone was due to advective transport of a CO2-rich fluid with a minor NaCl brine component originating from a tectonic fracture. Fluid infiltration resulted in the localized partial breakdown of biotite and amphiboles to pyroxenes releasing Ti and Ca, which were partitioned into the remaining biotite and amphibole, as well as uniform depletion in (Y + HREE), Ba, Sr, Cl, and F. At some later stage, H2O-rich fluids (H2O activity > 0.8) gave rise to localized partial melting and the probable injection of a granitic melt into the tectonic fracture, which resulted in the biotite and amphibole recording a diffusion profile for F across the dehydration zone into the granitic gneiss as well as a diffusion profile in Fe, Mn, and Mg for all Fe-Mg silicate minerals within 100 cm of the pegmatoid dyke
"Hastite", the orthorhombic dimorph of CoSe2, formerly considered as a valid mineral species occurring in the Trogtal quarries, Harz Mountains, Germany, is discredited as being identical with ferroselite, orthorhombic FeSe2. The discreditation has been unanimously approved by the IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) (IMA No. 07-E). We also provide observations on the composition, homogeneity, and origin of trogtalite (cubic CoSe2) from its type locality.
To address one of the central questions of plate tectonics-How do large transform systems work and what are their typical features?-seismic investigations across the Dead Sea Transform (DST), the boundary between the African and Arabian plates in the Middle East, were conducted for the first time. A major component of these investigations was a combined reflection/ refraction survey across the territories of Palestine, Israel and Jordan. The main results of this study are: (1) The seismic basement is offset by 3-5 km under the DST, (2) The DST cuts through the entire crust, broadening in the lower crust, (3) Strong lower crustal reflectors are imaged only on one side of the DST, (4) The seismic velocity sections show a steady increase in the depth of the crust-mantle transition (Moho) from 26 km at the Mediterranean to 39 km under the Jordan highlands, with only a small but visible, asymmetric topography of the Moho under the DST. These observations can be linked to the left-lateral movement of 105 km of the two plates in the last 17 Myr, accompanied by strong deformation within a narrow zone cutting through the entire crust. Comparing the DST and the San Andreas Fault (SAF) system, a strong asymmetry in subhorizontal lower crustal reflectors and a deep reaching deformation zone both occur around the DST and the SAF. The fact that such lower crustal reflectors and deep deformation zones are observed in such different transform systems suggests that these structures are possibly fundamental features of large transform plate boundaries
The mildly peraluminous granite of Seiffen, in the eastern Erzgebirge of Germany, is exposed by drillcores and associated with an abandoned Sri mine. The granite is of Stefanian age, with overlapping Th-U-total Pb monazite (302 +/- 4 Ma) and K-Ar siderophyllite ages (301 +/- 5 Ma). It is among the youngest granites in the Erzgebirge, emplaced in an extensional setting. The medium-grained, equigranular granite classifies as high-F, low-P Li-mica granite of A-type affinity. It is spatially associated with a high-Si rhyolitic microgranite, documenting the shallow intrusion level of this igneous association. Zircon, monazite-(Ce), and xenotime-(Y) constitute important radioactive accessory minerals in the granite, hosting the major proportions (> 80-90%) of the bulk-rock budgets of the REE, Y, and Th. A significant percentage of U (40-50%) may reside within unidentified phases or precipitated along grain boundaries. The most uncommon accessory phase is late-magmatic ytterbian xenotime-(Y) containing up to 11.2 wt% Yb2O3, in addition to 7.3 wt% Er2O3 and 7.9 wt% Dy2O3. The Seiffen granite (epsilon(Nd(300)) = -4.6) is geochemically evolved and rich in Sri (23-63 ppm) and W (11-14 ppm). It contains elevated to high concentrations of incompatible lithophile elements such as F, Li, Ga, Rb, Y, Nb, Cs, REE, Th, and U, thus having much in common chemically with subvolcanic ongonites. The most prominent compositional feature is the strong enrichment (in ppm) in Be (51-55) and Ta (23-28). The granite exhibits flat chondrite-normalized REE patterns (La-N/Lu-N = 1.35-1.48) and a moderate negative Eu anomaly (Eu/Eu* = 0.12-0.13). Indications for alteration-induced, postmagmatic disturbances of initial elemental abundances are weak and mainly relate to the ore-forming elements Sri and U.
In the earliest emplaced granite subintrusion of the multiphase peraluminous Satzung pluton, Erzgebirge, Germany, a mineral aggregate was observed consisting of sekaninaite (X-Fe = 0.74-0.94), Zn-rich hercynite (X-Zn = 0.03- 0.11), tri- and dioctahedral layer silicates of different composition and color, and minor quartz. Geological, textural, and compositional criteria argue that the sekaninaite, hercynite, quartz, and the brown biotite are not primary or secondary granite minerals, but are of metamorphic origin representing a xenolith uptaken from the granite melt near its level of emplacement. The metamorphic origin is supported by the occurrence of this mineral assemblage in metamorphic rocks exposed locally in the Erzgebirge basement. Reaction of the polymineralic metamorphic aggregate with the surrounding melt and subsequent interaction with alkali-, F- and LILE-rich residual fluids account for the widespread decomposition of the sekaninaite and formation of several layer silicates including green biotite, muscovite, berthierine/Fe chlorite, and sericite. The observed enrichment of the relic sekaninaite and its replacement products in elements such as Na, Li, Be, Rb, Cs, and F is result of interaction of the metamorphic fragment with the surrounding melt/fluid, in accordance with the evolved nature of the Satzung magmatic-hydrothermal system
Thermobarometrical and mineral-chemical investigations by electron microprobe and LA-ICP-MS on a sillimanite- bearing pegmatoid from the Reinbolt Hills provide important constraints on the P-T-X-age relations of part of East Antarctica during Pan-African tectonism. U-Th-total Pb ages of monazite imply that the pegmatoid of originally Grenvillan age (zircon U-Pb age of ca. 900 Ma) underwent a major, late Pan-African (Cambrian) regional, granulite-facies metamorphism between 500 and 550 Ma. Most of the monazite formed during this event, as result of apatite metasomatism owing to infiltration of high-grade metamorphic fluids. Apatite-biotite and other mineral thermobarometers define the peak metamorphic temperatures and pressures with 850-950 degrees C and 0.8-1.0 GPa. The F-Cl-OH relations in apatite, and biotite, the chemistry of fluid inclusions and the presence of K-feldspar microveins suggest that the metasomatising fluid was a CO2-bearing, diluted KCl brine. The pegmatoid is the first record of monazite-(Ce) formed from fluorapatite that is rich in U (up to 2.6 Wt% UO2) and possesses Th/U ratios <1 (0.09 on average). These chemical signatures are direct reflection of the U and Th concentration patterns in the parental fluorapatite
In a sample from the Niederschlema-Alberoda U-Se-polymetallic deposit, western Erzgebirge, Germany, the entire PbSe-PbS solid-solution series was observed associated with uraninite, coffinite, hematite, acanthite, sphalerite, chalcopyrite, pyrite, and lollingite. Early deposited, Se-rich members of the Pb(Se, S) series occur as fracture fillings inside spherical uraninite or on its surface or form anhedral to subhedral grains precipitated in the immediate neighbourhood of the U minerals. Later crystallized, S-rich members of the series are affiliated with the sulfide minerals. The solid-solution series covers the range PbS1.00-Pb(S0.04Se0.96)(&USigma; 1.00) virtually free of gaps, consistent with a temperature of formation of &GE; 100° C. The PbSe-PbS solid solutions were likely deposited from hydrothermal fluids that became successively depleted in Se and enriched in S. The fugacities of selenium and sulfur covered the range -17 < logfSe(2) < -26 and -17 < logfS(2) < -22, respectively, implying fSe(2)/fS(2) &LE; 1. The spherical texture of the uraninite, as well as its U-Th-total Pb age (192 ± 21 Ma), imply deposition of the Pb(Se, S) series during the Jurassic, contemporaneous with the formation of the bulk of the other selenium minerals. The electron-microprobe data from this study confirm earlier inferences on complete miscibility between clausthalite and galena deduced from X-ray patterns of PbSe-PbS solid solutions from different uranium-vanadium deposits of the Colorado Plateau (COLEMAN 1959). In Niederschlema-Alberoda, the entire clausthalite-galena series occurs in a single section