Refine
Has Fulltext
- yes (153) (remove)
Year of publication
Document Type
- Doctoral Thesis (153) (remove)
Keywords
- Arktis (6)
- Arctic (5)
- Fernerkundung (4)
- Klimawandel (4)
- Nanopartikel (4)
- climate change (4)
- Anden (3)
- Andes (3)
- Atmosphäre (3)
- Holozän (3)
- Kohlenstoff (3)
- Schadensmodellierung (3)
- Systembiologie (3)
- atmosphere (3)
- carbon (3)
- molecular motors (3)
- molekulare Motoren (3)
- remote sensing (3)
- uncertainty (3)
- Antarctica (2)
- Antarktis (2)
- Antibiotikaresistenz (2)
- Argentina (2)
- Argentinien (2)
- Deformation (2)
- Energiespeicher (2)
- Erdbeben (2)
- GIS (2)
- Galaxien (2)
- Geodynamik (2)
- Grenzschicht (2)
- Hochwasserrisiko (2)
- Holocene (2)
- Kohlenstoffnitriden (2)
- Korrosion (2)
- Magnetismus (2)
- Magnetohydrodynamik (2)
- Mesokristalle (2)
- Modellierung (2)
- Nachhaltigkeit (2)
- Paläoklima (2)
- Rheologie (2)
- Rheology (2)
- Seesedimente (2)
- Spektroskopie (2)
- Subduktion (2)
- Systems Biology (2)
- Unsicherheiten (2)
- Virus (2)
- Vulnerabilität (2)
- Winderosion (2)
- air-water interface (2)
- boundary layer (2)
- carbon nitrides (2)
- corrosion (2)
- cosmic rays (2)
- damage modeling (2)
- economic impacts (2)
- energy storage (2)
- flood risk (2)
- galaxies (2)
- heterogene Photokatalyse (2)
- heterogeneous photocatalysis (2)
- high resolution (2)
- hohe Auflösung (2)
- hydraulic fracturing (2)
- kosmische Strahlung (2)
- magnetohydrodynamics (2)
- mesocrystals (2)
- nanoparticles (2)
- numerical modelling (2)
- numerische Modellierung (2)
- organic synthesis (2)
- organische Synthese (2)
- palaeoclimate (2)
- perovskite (2)
- polymerization (2)
- stable isotopes (2)
- stochastic processes (2)
- stochastische Prozesse (2)
- sustainability (2)
- virus (2)
- vulnerability (2)
- Ökologie (2)
- 2D Numerical Modelling (1)
- AC Elektrokinetik (1)
- AC Elektroosmosis (1)
- AC electrokinetics (1)
- AC electroosmosis (1)
- AGN (1)
- ALOX15B (1)
- ARMS (1)
- ASPECT (1)
- ATRP (1)
- Acetobacteraceae (1)
- Acetylcholin (1)
- Adana Basin (1)
- Adana Becken (1)
- Adsorption (1)
- Aerosole (1)
- Aerosols (1)
- Aktiven Galaxienkerne (1)
- Allgemeine Relativitätstheorie (1)
- Alliierte Militärverbindungsmissionen (1)
- Altiplano (1)
- Aluminiumlegierung (1)
- Amblystegiaceae (1)
- Aminosäuren (1)
- Analyse von Abflussganglinien (1)
- Andenplateau Puna (1)
- Andes Centrales (1)
- Anpassung (1)
- Antibiotic alternatives (1)
- Antibiotic resistance (1)
- Antibiotikaersatz (1)
- Antikörper (1)
- Antwortmengenprogrammierung (1)
- Application Server (1)
- Archetyp (1)
- Arctic tundra (1)
- Artificial Intelligence (1)
- Astronomie (1)
- Atmosphärenforschung (1)
- Atmosphärenmodellierung (1)
- Atomwaffen (1)
- Auenbereich (1)
- Aufmerksamkeit (1)
- Ausbreitung (1)
- Ausbreitung der kosmischen Strahlung (1)
- Aussterbeschuld (1)
- Bachstufen (1)
- Bakterien (1)
- Bandenenergien (1)
- Basalt-Vulkane (1)
- Bay of Bengal (1)
- Bayesian Network (1)
- Bayesianisches Netzwerk (1)
- Bayesianism (1)
- Bayesianismus (1)
- Begabung (1)
- Bemessungshochwasser (1)
- Beschichtungen (1)
- Beta-Lactoglobulin (1)
- Beta-Zelle (1)
- Beweidung (1)
- Bi2Se3 (1)
- Bi2Te3 (1)
- Big Data Analytics (1)
- Big data mining zu Hochwasserrisiken (1)
- Bindungsinteraktion (1)
- Biochemie (1)
- Biodiversität (1)
- Biofilm (1)
- Biomoleküle (1)
- Bioraffinerie (1)
- Blattverschiebung (1)
- Boden (1)
- Bodenbearbeitung (1)
- Borna Disease Virus (1)
- Borna disease virus (1)
- Botanik (1)
- Braunmoose (1)
- Bruchausbreitung (1)
- Bruchmodel (1)
- Bryophyten (1)
- Bucht von Bengalen (1)
- Bulge (1)
- Bundesländer (1)
- Bundesnachrichtendienst (1)
- Bundeswehr (1)
- Bundeswehrkommando Ost (1)
- CDF (1)
- CLSM (1)
- CaM4 (1)
- Caco-2 (1)
- Capsule (1)
- Cars (1)
- Causal structure (1)
- Central Andes (1)
- Chaco-Paraná Becken (1)
- Chaco-Paraná basin (1)
- Chalkogenide (1)
- Chaos Theory (1)
- Chaostheorie (1)
- Charnockit (1)
- Chemokinematik der Milchstraße (1)
- Cherenkov telescopes (1)
- Cherenkov-Teleskope (1)
- China (1)
- Chloroplast transformation (1)
- Chloroplastentransformation (1)
- Citrazinsäure (1)
- Climate reconstruction (1)
- Clustering (1)
- Coiled coils (1)
- Cold War (1)
- Computational Biology (1)
- Computersimulation (1)
- Continental Rifts (1)
- Core-Collapse Supernovae (1)
- Cu doped InP (1)
- Cu-dotiertes InP (1)
- DGVM (1)
- DSS-Colitis (1)
- Dark Matter (1)
- Data-Mining (1)
- Datenanalyse (1)
- Deligne Cohomology (1)
- Deligne Kohomologie (1)
- Density modelling (1)
- Deoxyfructosazin (1)
- Deutschland (1)
- Diabetes (1)
- Diamantstempelzelle (1)
- Diatomeen (1)
- Diatoms (1)
- Dichteeffekte (1)
- Dichtemodellierung (1)
- Dielektrophorese (1)
- Digital Rebound (1)
- Digitalisierung (1)
- Diskursverstehen (1)
- Dronning Maud Land (1)
- Dunkle Materie (1)
- Durchmusterung (1)
- Düngung (1)
- E. coli (1)
- EKP (1)
- ERP (1)
- ETV (1)
- Earthquake (1)
- Ecology (1)
- Ecotoxicology (1)
- Einkapselung (1)
- Einwanderungskredit (1)
- Einzelatomkatalyse (1)
- Einzelmolekülkraftspektroskopie (1)
- Einzugsgebietshydrologie (1)
- Eisbohrkern (1)
- Electron acceleration (1)
- Elektronenbeschleunigung (1)
- Emissionslinienklassifikation (1)
- Emulsion (1)
- Endophyten (1)
- Energie (1)
- Entstehung der Milchstraße (1)
- Epiphyten (1)
- Erdmantel (1)
- Ereigniskorreliertes Potenzial (1)
- Erosion (1)
- Essigsäurebakterien (1)
- Europa (1)
- Europe (1)
- Evolution (1)
- Evolution der Milchstraße (1)
- Exoplaneten (1)
- Exoplanetenatmosphären (1)
- FARIMA (1)
- FastScape (1)
- Federal Armed Forces of Germany (1)
- Federal Foreign Intelligence Service (1)
- Ferroperiklas (1)
- Figurative Sprachverarbeitung (1)
- Figurative language processing (1)
- Fiskalregeln (1)
- Flache Subduktion (1)
- Flat subduction (1)
- Flood Change (1)
- Flood Risk Big Data Mining (1)
- Fluorpolymere (1)
- Foreland (1)
- Foreland basin (1)
- Foreland basins (1)
- Forstwirtschaft (1)
- Frequenzanalyse (1)
- Frucht (1)
- Fundamental Modeling Concepts (1)
- GC-MS (1)
- GITEWS (1)
- GPS (1)
- Galaxie: allgemein (1)
- Galaxienhaufen (1)
- Gasgeochemie (1)
- Gassorption (1)
- Gebirgsbäche (1)
- Geflügelmist (1)
- Gen-Koexpression (1)
- Gene co-expression (1)
- General Relativity (1)
- Geodynamic Modelling (1)
- Geodynamics (1)
- Geodynamische Modellierung (1)
- Geomorphologie (1)
- Geothermal monitoring (1)
- Geothermisches Monitoring (1)
- Gerben (1)
- Gerbes (1)
- Gerinne-Hang-Kopplung (1)
- German reunification (1)
- Germany (1)
- Geschiebetransport (1)
- Geschmacksrezeptor (1)
- Gezeitenwechselwirkungen (1)
- Gleichaltrigenbeziehungen (1)
- Gletschervorfeld (1)
- Global Differentialgeometry (1)
- Global Value Chains (1)
- Globale Differentialgeometrie (1)
- Globale Wertschöpfungsketten (1)
- Glucolipotoxizität (1)
- Glykan-Protein-Wechselwirkung (1)
- Glykopolymere (1)
- Gold (1)
- Grabenbrüche (1)
- Graphentheorie (1)
- Gravitational Waves (1)
- Gravitationswellen (1)
- Greenhouse Gas Emissions (1)
- Greenland (1)
- Greenland Ice Sheet (1)
- Grenzflächen (1)
- Grenzflächenchemie (1)
- Grundgestein (1)
- Gruppe der Sowjetischen Streitkräfte in Deutschland (1)
- Grönland (1)
- Grönländisches Eisschild (1)
- Grüne Chemie (1)
- Grünland (1)
- Gyrochronologie (1)
- HMA (1)
- Halogenbindung (1)
- Hanghydrologie (1)
- Harnstoff-Glas-Route (1)
- Hauptfaserbündel (1)
- Hebung des Plateaus (1)
- HepG2 (1)
- Heptazine (1)
- Hochdruck (1)
- Holonomie (1)
- Holonomy (1)
- Horizontal flux (1)
- Hydrogele (1)
- Hydrograph Analysis (1)
- Hyperakkumulation (1)
- Hysterese (1)
- IBM 360 (1)
- ICP OES (1)
- ICT competencies (1)
- IRF3 (1)
- Immunoassay (1)
- Impakt (1)
- Importin (1)
- InSAR (1)
- Indian Summer Monsoon (1)
- Indischer Sommermonsun (1)
- Industrial Internet of Things (1)
- Industrie 4.0 (1)
- Industrielles Internet der Dinge (1)
- Industry 4.0 (1)
- Induzierte Seismizität (1)
- Influenza (1)
- Informatikdidaktik (1)
- Informations- und Kommunikationstechnologien (1)
- Informatische Kompetenzen (1)
- Injektion (1)
- Injektionsschema (1)
- Inlandeis (1)
- Innovationen in den Städten (1)
- Instrumente: Polarimeter (1)
- Instrumente: Spektrographen (1)
- Integration (1)
- Intelligence history (1)
- Interactors (1)
- Interaktoren (1)
- Interface-Engineering (1)
- Interferon <beta-> (1)
- Introgression (1)
- Inversion (1)
- Ionenmobilitätspektrometrie (1)
- JUB1 (1)
- Java 2 Enterprise Edition (1)
- Java Virtual Machine (1)
- Jets (1)
- Kalter Krieg (1)
- Karbonnitrid Ionothermalsynthese (1)
- Kathode (1)
- Kausalstruktur (1)
- Kern-Kollaps-Supernovae (1)
- Kernlokalisierungssignal (1)
- Kleinwinkelröntgenstreuung (1)
- Klimafolgenforschung (1)
- Klimaphysik (1)
- Klimarekonstruktion (1)
- Klimavariabilität (1)
- Knochen (1)
- Knock in Mäuse (1)
- Kognition (1)
- Kohlenstoffdioxid (1)
- Kohlenstoffhaushalt (1)
- Kohlenstoffkreislauf (1)
- Kohlenstoffmaterialien (1)
- Kohlenstoffmodell (1)
- Kohnen (1)
- Kompetenzen (1)
- Kontaktschichten (1)
- Koordinationskomplexe (1)
- Kultivierung (1)
- Künstliche Intelligenz (1)
- LAEs (1)
- LOC (1)
- LPJ (1)
- Lab-on-a-chip (1)
- Lake sediments (1)
- Lakunen (1)
- Landnutzung (1)
- Landnutzungshistorie (1)
- Laser ablation (1)
- Lateglacial (1)
- Lavafontänen (1)
- Leistungsentwicklung (1)
- Lektine (1)
- Li-Batterien (1)
- Li-Ionen-Akkus (1)
- Li-Ionen-Kondensator (1)
- Li-batteries (1)
- Li-ion batteries (1)
- Li-ion capacitor (1)
- LiFePO4 (1)
- Lidar (1)
- Lignin (1)
- Lipoxygenase (1)
- Lithosphäre (1)
- Lokalisierung von Deformation (1)
- Luftverschmutzung (1)
- Lyman Kontinuum (1)
- Lyman alpha (1)
- Lyman continuum (1)
- Lyman-Alpha-Emitter (1)
- Lyman-alpha emitters (1)
- Lysimeter (1)
- MTP (1)
- MTP1 (1)
- MTP2 (1)
- MTP3 (1)
- Macht (1)
- Magnetfelder (1)
- Magnetoelastizität (1)
- Markov chains (1)
- Markov-Prozesse (1)
- Markovketten (1)
- Massenspektrometrie (1)
- Mechanobiologie (1)
- Meereis (1)
- Meeresspiegelanstieg (1)
- Mehrschichtsysteme (1)
- Mesoporosity (1)
- Mesoporosität (1)
- Metabolic Modeling (1)
- Metabolism (1)
- Metabolit (1)
- Metabolome (1)
- Meteorologie (1)
- Methan (1)
- Microschwimmer (1)
- Mikroheizung (1)
- Mikrokapsel (1)
- Mikroplatte (1)
- Mikrostrukturierung (1)
- Mikrowellensynthese (1)
- Militärgeschichte (1)
- Milky Way chemo-kinematics (1)
- Milky Way evolution (1)
- Milky Way formation (1)
- Mineralisierung (1)
- Mineralverwitterungsreaktionen (1)
- Mistausbringung (1)
- Mitochondrien (1)
- Mobilität (1)
- Model-Daten Integration (1)
- Modeling (1)
- Modelle (1)
- Modellkalibrierung (1)
- Modellvalidierung (1)
- Moden Stabilität (1)
- Mondsee (1)
- Moorsukzession (1)
- Moos-Mikroben-Interaktion (1)
- Moos-assoziierte Methanoxidation (1)
- Moos-assoziierte Methanproduktion (1)
- Morphologie von Kapseln (1)
- Multilayers (1)
- Muttergalaxien (1)
- NZO (1)
- Nachrichtendienstgeschichte (1)
- Nano (1)
- Nanoelektroden (1)
- Natrium-Ionen-Akkumulator (1)
- Naturgefahren (1)
- Neuritenwachstum (1)
- Neutronensterne (1)
- Nichtlineare Spektroskopie (1)
- Nichtlineare Wellen (1)
- Nicotin (1)
- Nitrat (1)
- Nitride (1)
- Nitrides (1)
- Non-linear Geoscience (1)
- Non-stationary Flood Risk (1)
- Nonlinear waves (1)
- Nuklearwaffen (1)
- Numerische 2D Modellierung (1)
- Oberflächenbeschichtung (1)
- Oberflächenchemie (1)
- Oberflächenprozesse (1)
- Oberflächentemperatur (1)
- Oberflächenzustände (1)
- Open Access (1)
- Open Source (1)
- OpenStreetMap (1)
- Operationalisierung (1)
- Orogen (1)
- Oscillating Bubble (1)
- Oxinitride (1)
- Oxo-Kohlenstoff (1)
- Oxynitrides (1)
- P-Typ ATPase (1)
- PAVM (1)
- PBCEC (1)
- PHREEQC (1)
- PM10 (1)
- PM10, PM2, PM1 (1)
- POC (1)
- PVA (population viability analysis) (1)
- Paleofloods (1)
- Paläohochwasser (1)
- Paläolimnologie (1)
- Patent (1)
- Peptid (1)
- Peptide (1)
- Permafrost (1)
- Permafrostdegradation (1)
- Permafrostsedimente (1)
- Perowskit (1)
- Perowskit Solarzellen (1)
- Perowskite (1)
- Pflanzenwissenschaften (1)
- Pfotenödem Mausmodell (1)
- Phage lysins (1)
- Phagenlysine (1)
- Phasenraum des Time Delay Embedding (1)
- Phosphatidylethanolamin (1)
- Phosphatidylserin (1)
- Phosphatidylserin Decarboxylase (1)
- Phospholipide (1)
- Photochemische Reaktionen (1)
- Photovoltaik (1)
- Physik (1)
- Pkw (1)
- Politik (1)
- Pollen (1)
- Polyelectrolyte (1)
- Polyelektrolyt (1)
- Polymerisation (1)
- Polyneuropathie (1)
- Popularity (1)
- Populationsdynamik (1)
- Populationsgefährdungsanalyse (1)
- Power (1)
- Pragmatik (1)
- Prinicipal Fibre Bundles (1)
- Privathaushalte (1)
- Procrustes rotation analysis (1)
- Prokrustes Analyse (1)
- Propeller (1)
- Proteom (1)
- Proteomics (1)
- Protonenleitfähigkeit (1)
- Proxyunsicherheit (1)
- Proxyverständnis (1)
- Pseudodatensätze (1)
- Puna (1)
- Puna plateau (1)
- QD device (1)
- QD stability (1)
- QD-Gerät (1)
- QD-Stabilität (1)
- QtClassify (1)
- Quadratsäure (1)
- RAFT (1)
- RAVE Beobachtungskampagne (1)
- RAVE survey (1)
- Rare and Unseasonal Flood (1)
- Recurrence Plots (1)
- Reionisierung (1)
- Rekurrenzanalyse (1)
- Rekurrenzplot (1)
- Relativistische Astrophysik (1)
- Remote Sensing (1)
- Rezeptor (1)
- Rhodamin B (1)
- Rhodamine B (1)
- Rift (1)
- Roboter (1)
- Rotation (1)
- Russian Arctic (1)
- Röntgenbeugung (1)
- Röntgenkleinwinkelstreuung (1)
- SAR (1)
- SAXS (1)
- SEGUE Beobachtungskampagne (1)
- SEGUE survey (1)
- Salzgestein (1)
- Salzschmelze (1)
- Salzschmelze-Templating (1)
- Saprolit (1)
- Schallemissionen (1)
- Schatten eines Schwarzen Lochs (1)
- Schaum (1)
- Scheibe (1)
- Schlüsselkompetenzen (1)
- Schuldenbremse (1)
- Schwarzes Loch (1)
- Sedimentenabfolge (1)
- Segmentierung (1)
- Seismologie (1)
- Selbstheilende Beschichtungen (1)
- Selbstähnlichkeit (1)
- Selen (1)
- Selenonein (1)
- Seneszenz (1)
- Shock waves (1)
- Shortening (1)
- Sierras Pampeanas (1)
- Silika (1)
- Silizium (1)
- Simulationen (1)
- Simulationsframework (1)
- Skalierung (1)
- Social Status (1)
- Sociometry (1)
- Sol-Gel (1)
- Solar corona (1)
- Sonne: Oszillationen (1)
- Sonne: Sonnenflecken (1)
- Sonnenkorona (1)
- Soziale Ungleichheit (1)
- Sozialer Status (1)
- Soziometrie (1)
- Spalteneruption (1)
- Spannungsfeld (1)
- Spannungsfeld des späten Känozoikums (1)
- Spannungsmessung (1)
- Sphagnum (1)
- Spinpolarisation (1)
- Spionage (1)
- Split Ubiquitin (1)
- Spätglazial (1)
- Sri Lanka (1)
- Staatsverschuldung (1)
- Stabile Isotope (1)
- Stabilität (1)
- Stadtwachstumsraten (1)
- Stakeholder-based Science (1)
- Stakeholder-basierte Forschung (1)
- Stalagmiten (1)
- Starkregen (1)
- Statistik (1)
- Staubemission (1)
- Stern-Brauner Zwerg Systeme (1)
- Stern-Planet Systeme (1)
- Stern-Planeten-Wechselwirkung (1)
- Sterne: Entfernungen (1)
- Sternentwicklung (1)
- Sternphysik (1)
- Stethophyma grossum (1)
- Stickstoff (1)
- Stimuli (1)
- Stoffwechsel (1)
- Stoßwellen (1)
- Strain Localisation (1)
- Strukturgeologie (1)
- Styrol (1)
- Städte (1)
- Subduction (1)
- Subsidenzgeschichte (1)
- Sumpfschrecke (1)
- Sun: oszillations (1)
- Sun: sunspots (1)
- Superconducting gravimetry (1)
- Supernovaüberreste (1)
- Supraleit-Gravimetrie (1)
- Synchrotronstrahlung (1)
- Synthese (1)
- Synthesis (1)
- Systeme interagierender Partikel (1)
- Süd-Türkei (1)
- TBK1 (1)
- TRPV1 (1)
- Tabak (1)
- Tandem-Solarzelle (1)
- Tas1r1 (1)
- Tauziehen (1)
- Tektonik (1)
- Temperaturproxy (1)
- Templatphase (1)
- Tensid (1)
- Teukolsky Gleichung (1)
- Teukolsky master equation (1)
- Thermoelektrizität (1)
- Thermokarstprozesse (1)
- Thermometrie (1)
- Thioester (1)
- Tibet Plateau (1)
- Tibetan Plateau (1)
- Time Embedded Phase Space (1)
- Time series analysis (1)
- Tomate (1)
- Tomato (1)
- Torfmoose (1)
- Torsion Experiments (1)
- Torsionsexperimente (1)
- Transdisziplinarität (1)
- Transkriptionsfaktor (1)
- Treibhausgase (1)
- Treibhausgasemissionen (1)
- Triazin (1)
- Trockenstress (1)
- Truppenabzug (1)
- Tsunami (1)
- Tupaia belangeri (1)
- Turbulenz (1)
- Turbulenzparametrisierungen (1)
- Unsicherheit (1)
- Unsicherheitsanalyse (1)
- Urea-Glas-Route (1)
- VLT/MUSE (1)
- VM (1)
- VM Integration (1)
- VOC (1)
- Variationen terrestrischer Wasserspeicher (1)
- Vegetation (1)
- Vegetationsmodell (1)
- Verkürzung (1)
- Vernetzer (1)
- Vertical flux (1)
- Vertreibung (1)
- Verwitterungsfeedback (1)
- Videoanalyse (1)
- Virtuelle Maschine (1)
- Vorland (1)
- Vorlandbecken (1)
- Vulkan Verformung (1)
- Vulkanologie (1)
- Warven (1)
- Warves (1)
- Wasser-Gesteins-Wechselwirkungen (1)
- Wasser/Luft Grenzflächen (1)
- Wasserhaushalt (1)
- Weitwinkelröntgenstreuung (1)
- Westgruppe der Truppen (1)
- Wiedervereinigung (1)
- Windböen (1)
- Wirtsspezifität (1)
- Wärmefluss (1)
- Wärmekapazität (1)
- Wärmeleitfähigkeit von Schnee (1)
- X-ray diffraction (1)
- Zeitpunkt von Störungen (1)
- Zeitreihenanalyse (1)
- Zelladhäsionskontrolle (1)
- Zentralanden (1)
- Zink (1)
- Zirkulardichroismus (1)
- Zyklone (1)
- Züchtung (1)
- abrupte Übergänge (1)
- achievement trajectory (1)
- acoustic emissions (1)
- acoustically levitated droplets (1)
- active galactic nuclei (1)
- actylcholine (1)
- adaptation (1)
- adsorption (1)
- agricultural (1)
- air pollution (1)
- airborne bacteria (1)
- aktive Galaxienkerne (1)
- akustisch schwebende Tropfen (1)
- allied military liaison missions (1)
- aluminum alloy (1)
- amino acids (1)
- anaerobe Inkubationensexperimente (1)
- anaerobic incubation experiments (1)
- angle resolved photoelectron spectroscopy (1)
- anisotrop (1)
- anisotropic (1)
- answer set programming (1)
- antibiotic resistance (1)
- antibody (1)
- archetype (1)
- arctic (1)
- arktische Tundra (1)
- astronomy (1)
- atmospheric modelling (1)
- atmospheric science (1)
- attention (1)
- bacteria (1)
- basaltic volcanoes (1)
- basement rock (1)
- bedload transport (1)
- beta-cell (1)
- bidirectional intracellular transport (1)
- bidirektionaler intrazellulärer Transport (1)
- bild (1)
- binding interactions (1)
- biochemistry (1)
- biofilm (1)
- biohybrid molecules (1)
- biomolecule (1)
- biorefinery (1)
- black hole (1)
- black hole shadows (1)
- black holes (1)
- bone (1)
- breeding (1)
- brown mosses (1)
- bryophytes (1)
- bulge (1)
- calmodulin (1)
- campo de esfuerzo del Cenozoico tardío (1)
- capsule morphology (1)
- carbon cycle (1)
- carbon cycling (1)
- carbon dioxide (1)
- carbon materials (1)
- carbon nitride (1)
- catchment hydrology (1)
- cathode (1)
- cell adhesion control (1)
- central Andes (1)
- central-eastern Beringia (1)
- chalcogenide (1)
- channel steps (1)
- channel-hillslope coupling (1)
- charnockite (1)
- chemical weathering (1)
- chemische Verwitterung (1)
- chlorbenzol (1)
- chronic pain (1)
- chronischer Schmerz (1)
- circular dichroism (1)
- citrazinic acid (1)
- climate impact research (1)
- climate physics (1)
- closed chamber method (1)
- clustering (1)
- coating (1)
- cognition (1)
- coiled coils (1)
- colloidal quantum dot (1)
- colonization credit (1)
- competencies (1)
- complex emulsion (1)
- complex systems (1)
- computer science education (CSE) (1)
- computergestützte Biologie (1)
- consolidation (1)
- contact layers (1)
- cooperative phenomena (1)
- cooperative transport (1)
- coordination complexes (1)
- cosmic ray propagation (1)
- covalent frameworks (1)
- critical collapse (1)
- critical zone (1)
- crops (1)
- crosslinker (1)
- cultivation (1)
- cyclones (1)
- damage modelling (1)
- data analysis (1)
- data-mining (1)
- debt brake (1)
- deep eutectic solvents (1)
- deformation (1)
- density effects (1)
- density-driven flow (1)
- deoxyfructosazine (1)
- diabetes (1)
- diamond anvil cell (1)
- dichlorbenzol (1)
- dichlorobenzene (1)
- dichtegetriebene Strömung (1)
- dielectrophoresis (1)
- digitalization (1)
- disc (1)
- discourse comprehension (1)
- dispersal (1)
- displacement (1)
- disturbance timing (1)
- drought stress (1)
- dust emission (1)
- dwarf spheroidal galaxies (1)
- dünne Filme (1)
- earth mantle (1)
- earthquakes (1)
- ecology (1)
- elastic coupling (1)
- elastische Kopplung (1)
- emission line classification (1)
- employment precariousness (1)
- emulsion (1)
- encapsulation (1)
- endophytes (1)
- energy (1)
- energy levels (1)
- enhanced geothermal system (1)
- enhanced geothermal systems (EGS) (1)
- environmental upgrading (1)
- enzymatic conjugation (1)
- enzymatische Reaktionsspezifität (1)
- epiphytes (1)
- erosion (1)
- espionage, Intelligence (1)
- event-related potentials (1)
- exoplanet atmospheres (1)
- exoplanets (1)
- extinction debt (1)
- family (1)
- fecal contamination (1)
- ferropericlase (1)
- fertilization (1)
- firn (1)
- fiscal rules (1)
- fissure eruption (1)
- flooding (1)
- fluorinated polymers (1)
- foam (1)
- forestry (1)
- fracture growth (1)
- frequency analysis (1)
- fruit (1)
- fundamental parameters (1)
- fundamentale Parameter (1)
- fäkale Kontamination (1)
- galactic astronomy (1)
- galactic magnetic fields (1)
- galaktische Astronomie (1)
- galaktische Magnetfelder (1)
- galaxy clusters (1)
- galaxy: general (1)
- gas geochemistry (1)
- gas sorption (1)
- gefangene lichtartige Kurven (1)
- gender (1)
- general education in computer science (1)
- geodynamics (1)
- geographische Großstudie (1)
- geomorphology (1)
- geothermal exploration (1)
- geothermal monitoring (1)
- geothermische Exploration (1)
- geothermische Überwachung (1)
- geschlossene Haubenmessmethode (1)
- giftedness (1)
- glacier forefield (1)
- global change (1)
- global flood model (1)
- global hydrological modeling (1)
- globale hydrologische Modellierung (1)
- globales Überschwemmungsmodell (1)
- glucolipotoxicity (1)
- glycan-protein interaction (1)
- glycopolymers (1)
- gold (1)
- governance (1)
- grafting-from (1)
- graph theory (1)
- grassland (1)
- grazing (1)
- green chemistry (1)
- greenhouse gases (1)
- group of Soviet forces in Germany (1)
- großräumige Struktur des Universums (1)
- gyrochronology (1)
- halogen bonding (1)
- heat capacity (1)
- heat flux (1)
- heptazine (1)
- heteroatom-doped carbons (1)
- heteroatom-dotierte Kohlenstoffe (1)
- heterogene Katalyse (1)
- heterogeneous catalysis (1)
- hierarchical porosity (1)
- hierarchische Porosität (1)
- high pressure (1)
- high-achieving students; high-performing students; high-achievers (1)
- high-redshift (1)
- hillslope hydrology (1)
- hoher Rotverschiebung (1)
- horizontaler Fluss (1)
- host galaxies (1)
- host-specificity (1)
- hydraulische Risserzeugung (1)
- hydraulisches Aufbrechen (1)
- hydro-meteorological risk (1)
- hydro-meteorologische Risiken (1)
- hydrogels (1)
- hyperaccumulation (1)
- hyperspectral remote sensing (1)
- hyperspektral Fernerkundung (1)
- hyporheic zone (1)
- hyporheische Zone (1)
- hysteresis (1)
- ice core (1)
- ice sheet (1)
- ice-flow modeling (1)
- image (1)
- imaging spectroscopy (1)
- immunoassay (1)
- impact (1)
- importin (1)
- induced seismicity (1)
- influenza (1)
- information and communication technologies (1)
- informatische Allgemeinbildung (1)
- injection (1)
- injection scheme (1)
- innovations in the city (1)
- instrumentation: polarimeters (1)
- instrumentation: spectrographs (1)
- integration (1)
- interacting particle systems (1)
- interface engineering (1)
- interfaces (1)
- intracellular transport (1)
- intracluster medium (1)
- intrazellulärer Transport (1)
- inversion (1)
- ion mobility spectrometry (1)
- ionothermal synthesis (1)
- isotope variations (1)
- key competencies (1)
- kolloidaler Quantenpunkt (1)
- komplexe Emulsion (1)
- komplexe Systeme (1)
- konfokales Laser-Scanning-Mikroskop (1)
- kooperative Phänomene (1)
- kooperativer Transport (1)
- kovalente Rahmenbedingungen (1)
- kritische Zone (1)
- kritischer Kollaps (1)
- lab-on-a-chip (1)
- lab-on-chip (1)
- lacunae (1)
- lacuno-canalicular network (1)
- lake sediments (1)
- lakuno-kanaliculäres Netzwerk (1)
- land use (1)
- land use history (1)
- landwirtschaftlich (1)
- langreichweitige Korrelationen (1)
- large marsh grasshopper (1)
- large-scale structure (1)
- large-scale study (1)
- late cenozoic stress field (1)
- lava fountains (1)
- layered compounds (1)
- lebende Materialien (1)
- lectins (1)
- leistungsstarke Schüler (1)
- light-programmable viscosity (1)
- lignin (1)
- lithosphere (1)
- living materials (1)
- logical signaling networks (1)
- logische Signalnetzwerke (1)
- long-memory (1)
- long-range dependence (1)
- low-cost sensor (1)
- lubricant (1)
- luftgetragene Bakterien (1)
- lysimeter (1)
- ländliche Entwicklung (1)
- lösungsmittelfreie Synthese (1)
- machine learning (1)
- magnetic fields (1)
- magnetism (1)
- magnetoelasticity (1)
- mammalian ALOX15 orthologs (1)
- manure application (1)
- markov processes (1)
- maschinelles Lernen (1)
- mass spectrometry (1)
- mechanics (1)
- mechanische Stabilität (1)
- mechanobiology (1)
- medical (1)
- medizinisch (1)
- mehrfache Stressfaktoren (1)
- mehrschichtige Verbindungen (1)
- mesoporous (1)
- mesoporös (1)
- metabolic genomics (1)
- metabolische Modellierung (1)
- metabolite breeding (1)
- metabolite profiling (1)
- metabolome (1)
- meteorology (1)
- methane (1)
- methanogenic archaea (1)
- methanotrophic bacteria (1)
- methanoxidierende Bakterien (1)
- methanproduzierende Archaeen (1)
- miRNA (1)
- microbial communities (1)
- microheating (1)
- microplate (1)
- microstructures (1)
- microswimmers (1)
- microwave synthesis (1)
- mikrobielle Gemeinschaften (1)
- mikrobielle Moor-Kerngemeinschaft (1)
- military history (1)
- mineral weathering reactions (1)
- mineralization (1)
- mitochondria (1)
- mobility (1)
- mock data catalogues (1)
- mode stability (1)
- model calibration (1)
- model validation (1)
- model-data integration (1)
- modelling (1)
- models (1)
- molecular biomarkers (1)
- molekulare Biomarker (1)
- monochlorobenzene (1)
- moss-associated archaea (1)
- moss-associated bacteria (1)
- moss-associated methanogenesis (1)
- moss-associated methanotrophy (1)
- moss-microbe-interactions (1)
- mountain rivers (1)
- multiple stress factors (1)
- multiresponsiv (1)
- multiresponsive (1)
- nachhaltige Energiespeichermaterialien (1)
- nachhaltige Stadtentwicklung (1)
- nachhaltige industrielle Entwicklung (1)
- nachhaltiges Lieferkettenmanagement (1)
- nanoelectrodes (1)
- nanoparticle (1)
- nanoporous carbon particles (1)
- nanoporöser Kohlenstoffpartikel (1)
- natural hazards (1)
- neurite outgrowth (1)
- neuronal networks (1)
- neuronale Netzwerke (1)
- neutron stars (1)
- nicht-thermische Strahlung (1)
- nichtgenestete Modellselektion (1)
- nichtlineare Geowissenschaften (1)
- nichtlineare Zeitreihenanalyse (1)
- nichtstationäres Hochwasserrisiko (1)
- nicotine (1)
- nitrate (1)
- nitrogen (1)
- noise (1)
- non-nested model selection (1)
- non-thermal radiation (1)
- nonlinear optics (1)
- nonlinear time series analysis (1)
- northern peatlands (1)
- nuclear localization signal (1)
- nuclear weapons (1)
- numerical astrophysics (1)
- numerical relativity (1)
- numerische Astrophysik (1)
- numerische Relativitätstheorie (1)
- nördliche Moore (1)
- ob/ob (1)
- offene Daten (1)
- open data (1)
- operationalisation; operationalization (1)
- optical properties (1)
- optische Eigenschaften (1)
- organic matter (1)
- organic-inorganic hybrids (1)
- organisch-anorganische Hybride (1)
- organische Bodensubstanz (1)
- organisches Material (1)
- oscillating bubble (1)
- oxocarbon (1)
- p-type ATPase (1)
- paleolimnology (1)
- patent (1)
- peatland core microbiome (1)
- peatland development (1)
- peer relations (1)
- peptide (1)
- peptide synthesis (1)
- peptides (1)
- periglacial landscape evolution (1)
- periglacial landscapes (1)
- periglaziale Landschaften (1)
- periglaziale Landschaftsentwicklung (1)
- permafrost (1)
- permafrost degradation (1)
- permafrost sediments (1)
- perovskite solar cells (1)
- petrothermales System (EGS) (1)
- phosphatidylethanolamine (1)
- phosphatidylserine (1)
- phosphatidylserine decarboxylase (1)
- phospholipids (1)
- photochemical reactions (1)
- photovoltaic (1)
- physics (1)
- plant science (1)
- plant secondary metabolites (1)
- plateau uplift (1)
- pluvial flooding (1)
- point-of-care (1)
- policy (1)
- polyneuropathy (1)
- population dynamics (1)
- porous materials (1)
- porous polymers (1)
- poröse Materialien (1)
- poröse Polymere (1)
- post-depositional (1)
- poultry manure (1)
- pragmatics (1)
- private households (1)
- probabilistic (1)
- probabilistic approach (1)
- probabilistischer Ansatz (1)
- programmable friction (1)
- propellers (1)
- protein (1)
- proteome (1)
- proton conductivity (1)
- proxy uncertainty (1)
- proxy understanding (1)
- public finance (1)
- quasiparticle interactions (1)
- rational choice (1)
- reactive transport (1)
- reaktiver Transport (1)
- receptor (1)
- recurrence analysis (1)
- regime shifts (1)
- reionization (1)
- relativistic hydrodynamics (1)
- relativistische Hydrodynamik (1)
- return level estimation (1)
- rift (1)
- riparian zone (1)
- rising bubble (1)
- robot (1)
- rotation (1)
- rural development (1)
- russische Arktis (1)
- räumlich explizit (1)
- räumlich explizites Modell (1)
- räumliche Analyse (1)
- salt melt (1)
- salt melt templating (1)
- salt rock (1)
- sandige Böden (1)
- sandy soils (1)
- saprolite (1)
- scaling (1)
- schwarze Löcher (1)
- sea ice (1)
- sea-level rise (1)
- seasonality (1)
- sedimentary record (1)
- segmentation (1)
- seismology (1)
- sekundäre Pflanzenstoffe (1)
- selenium (1)
- selenoneine (1)
- self-healing coatings (1)
- self-rated health (1)
- self-similarity (1)
- seltenes und saisonunübliches Hochwasser (1)
- senescence (1)
- silica nanoparticles (1)
- silicon (1)
- simulation (1)
- simulation framework (1)
- single-atom catalysis (1)
- single-molecule force spectroscopy (1)
- small-angle x-ray scattering (1)
- snow thermal conductivity (1)
- sodium-ion batteries (1)
- soft and hard templating (1)
- soil (1)
- soil organic matter (1)
- sol-gel (1)
- solvent-free reactions (1)
- sortagging (1)
- sortaseA (1)
- source model (1)
- southern Turkey (1)
- spatial analyses (1)
- spatially explicit (1)
- spatially explicit model (1)
- species richness (1)
- spectroscopy (1)
- sphäroidische Zwerggalaxien (1)
- spin resolved photoelectron spectroscopy (1)
- spin-orbit coupling (1)
- spinaufgelöste Photoelektronenspektroskopie (1)
- spindown (1)
- spiropyran copolymer (1)
- squaric acid (1)
- stabile Isotope (1)
- stabile Schichtung (1)
- stability (1)
- stable stratification (1)
- stalagmites (1)
- star-brown dwarf systems (1)
- star-planet interaction (1)
- star-planet systems (1)
- stark eutektisches Lösungsmittel (1)
- stars: distances (1)
- statistical physics (1)
- statistics (1)
- statistische Physik (1)
- steigende Blasen (1)
- stellar content (1)
- stellar evolution (1)
- stellar physics (1)
- stellarer Inhalt (1)
- stimuli (1)
- stress field (1)
- stress measurement (1)
- strike-slip (1)
- structural geology (1)
- styrene (1)
- subduction (1)
- subsidence history (1)
- supercritical carbon dioxide (scCO₂) (1)
- supernova remnants (1)
- surface chemistry (1)
- surface modification (1)
- surface processes (1)
- surface rheology (1)
- surface states (1)
- surface temperature (1)
- surfactants (1)
- survey (1)
- sustainable development (1)
- sustainable energy storage materials (1)
- sustainable industrial development (1)
- sustainable supply chain management (1)
- switchSENSE (1)
- switchSENSE Technologie (1)
- synchrotron radiation (1)
- systems biology (1)
- tandem solar cell (1)
- taste receptor (1)
- tectonics (1)
- temperature proxy (1)
- temperature variability (1)
- template phase (1)
- terrestrial water storage variation (1)
- thermoelectricity (1)
- thermokarst processes (1)
- thermometry (1)
- thermoresponsive Polymere (1)
- thermoresponsive polymers (1)
- thin films (1)
- thioester (1)
- tidal interactions (1)
- tillage (1)
- time reversal symmetry (1)
- tobacco (1)
- topological insulators (1)
- topologische Isolatoren (1)
- transcription factor (1)
- transdisciplinary (1)
- transition metals (1)
- trapping (1)
- triazine (1)
- tug-of-war (1)
- turbulence (1)
- turbulence parameterizations (1)
- two-dimensional (1)
- ultra-high energy cosmic rays (1)
- ultrafast (1)
- ultrahochenergetische kosmische Strahlung (1)
- ultraschnell (1)
- umami (1)
- uncertainty analysis (1)
- unemployment (1)
- urban (1)
- urban growth (1)
- vegetation (1)
- vegetation model (1)
- verbal irony (1)
- verbale Ironie (1)
- verbesserte geothermische Systeme (1)
- vertikaler Fluss (1)
- video analysis (1)
- volcano deformation (1)
- volcanology (1)
- water balance (1)
- water rock interactions (1)
- weathering feedback (1)
- weiche und harte Templatierung (1)
- welfare and gender regimes (1)
- western group of forces (1)
- wide-angle x-ray scattering (1)
- wind erosion (1)
- wind gusts (1)
- winderosion (1)
- winkelaufgelöste Photoelektronenspektroskopie (1)
- withdrawal of troops (1)
- zentral-östliches Beringia (1)
- zentralen Anden (1)
- zinc (1)
- µCT (1)
- Änderungen des Hochwassers (1)
- Ökotoxikologie (1)
- Übergangsmetalle (1)
- Überschwemmungen (1)
- Þeistareykir Iceland (1)
- Þeistareykir Island (1)
- ökologisches Upgrading (1)
- ökonomische Auswirkungen (1)
- überkritisches Kohlendioxid (scCO₂) (1)
Institute
- Extern (153) (remove)
Biofilms are complex living materials that form as bacteria get embedded in a matrix of self-produced protein and polysaccharide fibres. The formation of a network of extracellular biopolymer fibres contributes to the cohesion of the biofilm by promoting cell-cell attachment and by mediating biofilm-substrate interactions. This sessile mode of bacteria growth has been well studied by microbiologists to prevent the detrimental effects of biofilms in medical and industrial settings. Indeed, biofilms are associated with increased antibiotic resistance in bacterial infections, and they can also cause clogging of pipelines or promote bio-corrosion. However, biofilms also gained interest from biophysics due to their ability to form complex morphological patterns during growth. Recently, the emerging field of engineered living materials investigates biofilm mechanical properties at multiple length scales and leverages the tools of synthetic biology to tune the functions of their constitutive biopolymers.
This doctoral thesis aims at clarifying how the morphogenesis of Escherichia coli (E. coli) biofilms is influenced by their growth dynamics and mechanical properties. To address this question, I used methods from cell mechanics and materials science. I first studied how biological activity in biofilms gives rise to non-uniform growth patterns. In a second study, I investigated how E. coli biofilm morphogenesis and its mechanical properties adapt to an environmental stimulus, namely the water content of their substrate. Finally, I estimated how the mechanical properties of E. coli biofilms are altered when the bacteria express different extracellular biopolymers.
On nutritive hydrogels, micron-sized E. coli cells can build centimetre-large biofilms. During this process, bacterial proliferation and matrix production introduce mechanical stresses in the biofilm, which release through the formation of macroscopic wrinkles and delaminated buckles. To relate these biological and mechanical phenomena, I used time-lapse fluorescence imaging to track cell and matrix surface densities through the early and late stages of E. coli biofilm growth. Colocalization of high cell and matrix densities at the periphery precede the onset of mechanical instabilities at this annular region. Early growth is detected at this outer annulus, which was analysed by adding fluorescent microspheres to the bacterial inoculum. But only when high rates of matrix production are present in the biofilm centre, does overall biofilm spreading initiate along the solid-air interface. By tracking larger fluorescent particles for a long time, I could distinguish several kinematic stages of E. coli biofilm expansion and observed a transition from non-linear to linear velocity profiles, which precedes the emergence of wrinkles at the biofilm periphery. Decomposing particle velocities to their radial and circumferential components revealed a last kinematic stage, where biofilm movement is mostly directed towards the radial delaminated buckles, which verticalize. The resulting compressive strains computed in these regions were observed to substantially deform the underlying agar substrates. The co-localization of higher cell and matrix densities towards an annular region and the succession of several kinematic stages are thus expected to promote the emergence of mechanical instabilities at the biofilm periphery. These experimental findings are predicted to advance future modelling approaches of biofilm morphogenesis.
E. coli biofilm morphogenesis is further anticipated to depend on external stimuli from the environment. To clarify how the water could be used to tune biofilm material properties, we quantified E. coli biofilm growth, wrinkling dynamics and rigidity as a function of the water content of the nutritive substrates. Time-lapse microscopy and computational image analysis revealed that substrates with high water content promote biofilm spreading kinetics, while substrates with low water content promote biofilm wrinkling. The wrinkles observed on biofilm cross-sections appeared more bent on substrates with high water content, while they tended to be more vertical on substrates with low water content. Both wet and dry biomass, accumulated over 4 days of culture, were larger in biofilms cultured on substrates with high water content, despite extra porosity within the matrix layer. Finally, the micro-indentation analysis revealed that substrates with low water content supported the formation of stiffer biofilms. This study shows that E. coli biofilms respond to the water content of their substrate, which might be used for tuning their material properties in view of further applications.
Biofilm material properties further depend on the composition and structure of the matrix of extracellular proteins and polysaccharides. In particular, E. coli biofilms were suggested to present tissue-like elasticity due to a dense fibre network consisting of amyloid curli and phosphoethanolamine-modified cellulose. To understand the contribution of these components to the emergent mechanical properties of E. coli biofilms, we performed micro-indentation on biofilms grown from bacteria of several strains. Besides showing higher dry masses, larger spreading diameters and slightly reduced water contents, biofilms expressing both main matrix components also presented high rigidities in the range of several hundred kPa, similar to biofilms containing only curli fibres. In contrast, a lack of amyloid curli fibres provides much higher adhesive energies and more viscoelastic fluid-like material behaviour. Therefore, the combination of amyloid curli and phosphoethanolamine-modified cellulose fibres implies the formation of a composite material whereby the amyloid curli fibres provide rigidity to E. coli biofilms, whereas the phosphoethanolamine-modified cellulose rather acts as a glue. These findings motivate further studies involving purified versions of these protein and polysaccharide components to better understand how their interactions benefit biofilm functions.
All three studies depict different aspects of biofilm morphogenesis, which are interrelated. The first work reveals the correlation between non-uniform biological activities and the emergence of mechanical instabilities in the biofilm. The second work acknowledges the adaptive nature of E. coli biofilm morphogenesis and its mechanical properties to an environmental stimulus, namely water. Finally, the last study reveals the complementary role of the individual matrix components in the formation of a stable biofilm material, which not only forms complex morphologies but also functions as a protective shield for the bacteria it contains. Our experimental findings on E. coli biofilm morphogenesis and their mechanical properties can have further implications for fundamental and applied biofilm research fields.
In the present thesis I investigate the lattice dynamics of thin film hetero structures of magnetically ordered materials upon femtosecond laser excitation as a probing and manipulation scheme for the spin system. The quantitative assessment of laser induced thermal dynamics as well as generated picosecond acoustic pulses and their respective impact on the magnetization dynamics of thin films is a challenging endeavor. All the more, the development and implementation of effective experimental tools and comprehensive models are paramount to propel future academic and technological progress.
In all experiments in the scope of this cumulative dissertation, I examine the crystal lattice of nanoscale thin films upon the excitation with femtosecond laser pulses. The relative change of the lattice constant due to thermal expansion or picosecond strain pulses is directly monitored by an ultrafast X-ray diffraction (UXRD) setup with a femtosecond laser-driven plasma X-ray source (PXS). Phonons and spins alike exert stress on the lattice, which responds according to the elastic properties of the material, rendering the lattice a versatile sensor for all sorts of ultrafast interactions. On the one hand, I investigate materials with strong magneto-elastic properties; The highly magnetostrictive rare-earth compound TbFe2, elemental Dysprosium or the technological relevant Invar material FePt. On the other hand I conduct a comprehensive study on the lattice dynamics of Bi1Y2Fe5O12 (Bi:YIG), which exhibits high-frequency coherent spin dynamics upon femtosecond laser excitation according to the literature. Higher order standing spinwaves (SSWs) are triggered by coherent and incoherent motion of atoms, in other words phonons, which I quantified with UXRD. We are able to unite the experimental observations of the lattice and magnetization dynamics qualitatively and quantitatively. This is done with a combination of multi-temperature, elastic, magneto-elastic, anisotropy and micro-magnetic modeling.
The collective data from UXRD, to probe the lattice, and time-resolved magneto-optical Kerr effect (tr-MOKE) measurements, to monitor the magnetization, were previously collected at different experimental setups. To improve the precision of the quantitative assessment of lattice and magnetization dynamics alike, our group implemented a combination of UXRD and tr-MOKE in a singular experimental setup, which is to my knowledge, the first of its kind. I helped with the conception and commissioning of this novel experimental station, which allows the simultaneous observation of lattice and magnetization dynamics on an ultrafast timescale under identical excitation conditions. Furthermore, I developed a new X-ray diffraction measurement routine which significantly reduces the measurement time of UXRD experiments by up to an order of magnitude. It is called reciprocal space slicing (RSS) and utilizes an area detector to monitor the angular motion of X-ray diffraction peaks, which is associated with lattice constant changes, without a time-consuming scan of the diffraction angles with the goniometer. RSS is particularly useful for ultrafast diffraction experiments, since measurement time at large scale facilities like synchrotrons and free electron lasers is a scarce and expensive resource. However, RSS is not limited to ultrafast experiments and can even be extended to other diffraction techniques with neutrons or electrons.
The Greenland Ice Sheet is the second-largest mass of ice on Earth. Being almost 2000 km long, more than 700 km wide, and more than 3 km thick at the summit, it holds enough ice to raise global sea levels by 7m if melted completely. Despite its massive size, it is particularly vulnerable to anthropogenic climate change: temperatures over the Greenland Ice Sheet have increased by more than 2.7◦C in the past 30 years, twice as much as the global mean temperature. Consequently, the ice sheet has been significantly losing mass since the 1980s and the rate of loss has increased sixfold since then. Moreover, it is one of the potential tipping elements of the Earth System, which might undergo irreversible change once a warming threshold is exceeded. This thesis aims at extending the understanding of the resilience of the Greenland Ice Sheet against global warming by analyzing processes and feedbacks relevant to its centennial to multi-millennial stability using ice sheet modeling.
One of these feedbacks, the melt-elevation-feedback is driven by the temperature rise with decreasing altitudes: As the ice sheet melts, its thickness and surface elevation decrease, exposing the ice surface to warmer air and thus increasing the melt rates even further. The glacial isostatic adjustment (GIA) can partly mitigate this melt-elevation feedback as the bedrock lifts in response to an ice load decrease, forming the negative GIA feedback. In my thesis, I show that the interaction between these two competing feedbacks can lead to qualitatively different dynamical responses of the Greenland Ice Sheet to warming – from permanent loss to incomplete recovery, depending on the feedback parameters. My research shows that the interaction of those feedbacks can initiate self-sustained oscillations of the ice volume while the climate forcing remains constant.
Furthermore, the increased surface melt changes the optical properties of the snow or ice surface, e.g. by lowering their albedo, which in turn enhances melt rates – a process known as the melt-albedo feedback. Process-based ice sheet models often neglect this melt-albedo feedback. To close this gap, I implemented a simplified version of the diurnal Energy Balance Model, a computationally efficient approach that can capture the first-order effects of the melt-albedo feedback, into the Parallel Ice Sheet Model (PISM). Using the coupled model, I show in warming experiments that the melt-albedo feedback almost doubles the ice loss until the year 2300 under the low greenhouse gas emission scenario RCP2.6, compared to simulations where the melt-albedo feedback is neglected,
and adds up to 58% additional ice loss under the high emission scenario RCP8.5. Moreover, I find that the melt-albedo feedback dominates the ice loss until 2300, compared to the melt-elevation feedback.
Another process that could influence the resilience of the Greenland Ice Sheet is the warming induced softening of the ice and the resulting increase in flow. In my thesis, I show with PISM how the uncertainty in Glen’s flow law impacts the simulated response to warming. In a flow line setup at fixed climatic mass balance, the uncertainty in flow parameters leads to a range of ice loss comparable to the range caused by different warming levels.
While I focus on fundamental processes, feedbacks, and their interactions in the first three projects of my thesis, I also explore the impact of specific climate scenarios on the sea level rise contribution of the Greenland Ice Sheet. To increase the carbon budget flexibility, some warming scenarios – while still staying within the limits of the Paris Agreement – include a temporal overshoot of global warming. I show that an overshoot by 0.4◦C increases the short-term and long-term ice loss from Greenland by several centimeters. The long-term increase is driven by the warming at high latitudes, which persists even when global warming is reversed. This leads to a substantial long-term commitment of the sea level rise contribution from the Greenland Ice Sheet.
Overall, in my thesis I show that the melt-albedo feedback is most relevant for the ice loss of the Greenland Ice Sheet on centennial timescales. In contrast, the melt-elevation feedback and its interplay with the GIA feedback become increasingly relevant on millennial timescales. All of these influence the resilience of the Greenland Ice Sheet against global warming, in the near future and on the long term.
Basaltic fissure eruptions, such as on Hawai'i or on Iceland, are thought to be driven by the lateral propagation of feeder dikes and graben subsidence. Associated solid earth processes, such as deformation and structural development, are well studied by means of geophysical and geodetic technologies. The eruptions themselves, lava fountaining and venting dynamics, in turn, have been much less investigated due to hazardous access, local dimension, fast processes, and resulting poor data availability.
This thesis provides a detailed quantitative understanding of the shape and dynamics of lava fountains and the morphological changes at their respective eruption sites. For this purpose, I apply image processing techniques, including drones and fixed installed cameras, to the sequence of frames of video records from two well-known fissure eruptions in Hawai'i and Iceland. This way I extract the dimensions of multiple lava fountains, visible in all frames. By putting these results together and considering the acquisition times of the frames I quantify the variations in height, width and eruption velocity of the lava fountains. Then I analyse these time-series in both time and frequency domains and investigate the similarities and correlations between adjacent lava fountains. Following this procedure, I am able to link the dynamics of the individual lava fountains to physical parameters of the magma transport in the feeder dyke of the fountains.
The first case study in this thesis focuses on the March 2011 Pu'u'O'o eruption, Hawai'i, where a continuous pulsating behaviour at all eight lava fountains has been observed. The lava fountains, even those from different parts of the fissure that are closely connected, show a similar frequency content and eruption behaviour. The regular pattern in the heights of lava fountain suggests a controlling process within the magma feeder system like a hydraulic connection in the underlying dyke, affecting or even controlling the pulsating behaviour.
The second case study addresses the 2014-2015 Holuhraun fissure eruption, Iceland. In this case, the feeder dyke is highlighted by the surface expressions of graben-like structures and fault systems. At the eruption site, the activity decreases from a continuous line of fire of ~60 vents to a limited number of lava fountains. This can be explained by preferred upwards magma movements through vertical structures of the pre-eruptive morphology. Seismic tremors during the eruption reveal vent opening at the surface and/or pressure changes in the feeder dyke. The evolving topography of the cinder cones during the eruption interacts with the lava fountain behaviour. Local variations in the lava fountain height and width are controlled by the conduit diameter, the depth of the lava pond and the shape of the crater. Modelling of the fountain heights shows that long-term eruption behaviour is controlled mainly by pressure changes in the feeder dyke.
This research consists of six chapters with four papers, including two first author and two co-author papers. It establishes a new method to analyse lava fountain dynamics by video monitoring. The comparison with the seismicity, geomorphologic and structural expressions of fissure eruptions shows a complex relationship between focussed flow through dykes, the morphology of the cinder cones, and the lava fountain dynamics at the vents of a fissure eruption.
Spatial and temporal temperature and moisture patterns across the Tibetan Plateau are very complex. The onset and magnitude of the Holocene climate optimum in the Asian monsoon realm, in particular, is a subject of considerable debate as this time period is often used as an analogue for recent global warming. In the light of contradictory inferences regarding past climate and environmental change on the Tibetan Plateau, I have attempted to explain mismatches in the timing and magnitude of change. Therefore, I analysed the temporal variation of fossil pollen and diatom spectra and the geochemical record from palaeo-ecological records covering different time scales (late Quaternary and the last 200 years) from two core regions in the NE and SE Tibetan Plateau. For interpretation purposes I combined my data with other available palaeo-ecological data to set up corresponding aquatic and terrestrial proxy data sets of two lake pairs and two sets of sites. I focused on the direct comparison of proxies representing lacustrine response to climate signals (e.g., diatoms, ostracods, geochemical record) and proxies representing changes in the terrestrial environment (i.e., terrestrial pollen), in order to asses whether the lake and its catchments respond at similar times and magnitudes to environmental changes. Therefore, I introduced the established numerical technique procrustes rotation as a new approach in palaeoecology to quantitatively compare raw data of any two sedimentary records of interest in order to assess their degree of concordance. Focusing on the late Quaternary, sediment cores from two lakes (Kuhai Lake 35.3°N; 99.2°E; 4150 m asl; and Koucha Lake 34.0°N; 97.2°E; 4540 m asl) on the semi-arid northeastern Tibetan Plateau were analysed to identify post-glacial vegetation and environmental changes, and to investigate the responses of lake ecosystems to such changes. Based on the pollen record, five major vegetation and climate changes could be identified: (1) A shift from alpine desert to alpine steppe indicates a change from cold, dry conditions to warmer and more moist conditions at 14.8 cal. ka BP, (2) alpine steppe with tundra elements points to conditions of higher effective moisture and a stepwise warming climate at 13.6 cal. ka BP, (3) the appearance of high-alpine meadow vegetation indicates a further change towards increased moisture, but with colder temperatures, at 7.0 cal. ka BP, (4) the reoccurrence of alpine steppe with desert elements suggests a return to a significantly colder and drier phase at 6.3 cal. ka BP, and (5) the establishment of alpine steppe-meadow vegetation indicates a change back to relatively moist conditions at 2.2 cal. ka BP. To place the reconstructed climate inferences from the NE Tibetan Plateau into the context of Holocene moisture evolution across the Tibetan Plateau, I applied a five-scale moisture index and average link clustering to all available continuous pollen and non-pollen palaeoclimate records from the Tibetan Plateau, in an attempt to detect coherent regional and temporal patterns of moisture evolution on the Plateau. However, no common temporal or spatial pattern of moisture evolution during the Holocene could be detected, which can be assigned to the complex responses of different proxies to environmental changes in an already very heterogeneous mountain landscape, where minor differences in elevation can result in marked variations in microenvironments. Focusing on the past 200 years, I analysed the sedimentary records (LC6 Lake 29.5°N, 94.3°E, 4132 m asl; and Wuxu Lake 29.9°N, 101.1°E, 3705 m asl) from the southeastern Tibetan Plateau. I found that despite presumed significant temperature increases over that period, pollen and diatom records from the SE Tibetan Plateau reveal only very subtle changes throughout their profiles. The compositional species turnover investigated over the last 200 years appears relatively low in comparison to the species reorganisations during the Holocene. The results indicate that climatically induced ecological thresholds are not yet crossed, but that human activity has an increasing influence, particularly on the terrestrial ecosystem. Forest clearances and reforestation have not caused forest decline in our study area, but a conversion of natural forests to semi-natural secondary forests. The results from the numerical proxy comparison of the two sets of two pairs of Tibetan lakes indicate that the use of different proxies and the work with palaeo-ecological records from different lake types can cause deviant stories of inferred change. Irrespective of the timescale (Holocene or last 200 years) or region (SE or NE Tibetan Plateau) analysed, the agreement in terms of the direction, timing, and magnitude of change between the corresponding terrestrial data sets is generally better than the match between the corresponding lacustrine data sets, suggesting that lacustrine proxies may partly be influenced by in-lake or local catchment processes whereas the terrestrial proxy reflects a more regional climatic signal. The current disaccord on coherent temporal and spatial climate patterns on the Tibetan Plateau can partly be ascribed to the complexity of proxy response and lake systems on the Tibetan Plateau. Therefore, a multi-proxy, multi-site approach is important in order to gain a reliable climate interpretation for the complex mountain landscape of the Tibetan Plateau.
With Arctic ground as a huge and temperature-sensitive carbon reservoir, maintaining low ground temperatures and frozen conditions to prevent further carbon emissions that contrib-ute to global climate warming is a key element in humankind’s fight to maintain habitable con-ditions on earth. Former studies showed that during the late Pleistocene, Arctic ground condi-tions were generally colder and more stable as the result of an ecosystem dominated by large herbivorous mammals and vast extents of graminoid vegetation – the mammoth steppe. Characterised by high plant productivity (grassland) and low ground insulation due to animal-caused compression and removal of snow, this ecosystem enabled deep permafrost aggrad-ation. Now, with tundra and shrub vegetation common in the terrestrial Arctic, these effects are not in place anymore. However, it appears to be possible to recreate this ecosystem local-ly by artificially increasing animal numbers, and hence keep Arctic ground cold to reduce or-ganic matter decomposition and carbon release into the atmosphere.
By measuring thaw depth, total organic carbon and total nitrogen content, stable carbon iso-tope ratio, radiocarbon age, n-alkane and alcohol characteristics and assessing dominant vegetation types along grazing intensity transects in two contrasting Arctic areas, it was found that recreating conditions locally, similar to the mammoth steppe, seems to be possible. For permafrost-affected soil, it was shown that intensive grazing in direct comparison to non-grazed areas reduces active layer depth and leads to higher TOC contents in the active layer soil. For soil only frozen on top in winter, an increase of TOC with grazing intensity could not be found, most likely because of confounding factors such as vertical water and carbon movement, which is not possible with an impermeable layer in permafrost. In both areas, high animal activity led to a vegetation transformation towards species-poor graminoid-dominated landscapes with less shrubs. Lipid biomarker analysis revealed that, even though the available organic material is different between the study areas, in both permafrost-affected and sea-sonally frozen soils the organic material in sites affected by high animal activity was less de-composed than under less intensive grazing pressure. In conclusion, high animal activity af-fects decomposition processes in Arctic soils and the ground thermal regime, visible from reduced active layer depth in permafrost areas. Therefore, grazing management might be utilised to locally stabilise permafrost and reduce Arctic carbon emissions in the future, but is likely not scalable to the entire permafrost region.
Cosmic rays (CRs) constitute an important component of the interstellar medium (ISM) of galaxies and are thought to play an essential role in governing their evolution. In particular, they are able to impact the dynamics of a galaxy by driving galactic outflows or heating the ISM and thereby affecting the efficiency of star-formation. Hence, in order to understand galaxy formation and evolution, we need to accurately model this non-thermal constituent of the ISM. But except in our local environment within the Milky Way, we do not have the ability to measure CRs directly in other galaxies. However, there are many ways to indirectly observe CRs via the radiation they emit due to their interaction with magnetic and interstellar radiation fields as well as with the ISM.
In this work, I develop a numerical framework to calculate the spectral distribution of CRs in simulations of isolated galaxies where a steady-state between injection and cooling is assumed. Furthermore, I calculate the non-thermal emission processes arising from the modelled CR proton and electron spectra ranging from radio wavelengths up to the very high-energy gamma-ray regime.
I apply this code to a number of high-resolution magneto-hydrodynamical (MHD) simulations of isolated galaxies, where CRs are included. This allows me to study their CR spectra and compare them to observations of the CR proton and electron spectra by the Voyager-1 satellite and the AMS-02 instrument in order to reveal the origin of the measured spectral features.
Furthermore, I provide detailed emission maps, luminosities and spectra of the non-thermal emission from our simulated galaxies that range from dwarfs to Milk-Way analogues to starburst galaxies at different evolutionary stages. I successfully reproduce the observed relations between the radio and gamma-ray luminosities with the far-infrared (FIR) emission of star-forming (SF) galaxies, respectively, where the latter is a good tracer of the star-formation rate. I find that highly SF galaxies are close to the limit where their CR population would lose all of their energy due to the emission of radiation, whereas CRs tend to escape low SF galaxies more quickly. On top of that, I investigate the properties of CR transport that are needed in order to match the observed gamma-ray spectra.
Furthermore, I uncover the underlying processes that enable the FIR-radio correlation (FRC) to be maintained even in starburst galaxies and find that thermal free-free-emission naturally explains the observed radio spectra in SF galaxies like M82 and NGC 253 thus solving the riddle of flat radio spectra that have been proposed to contradict the observed tight FRC.
Lastly, I scrutinise the steady-state modelling of the CR proton component by investigating for the first time the influence of spectrally resolved CR transport in MHD simulations on the hadronic gamma-ray emission of SF galaxies revealing new insights into the observational signatures of CR transport both spectrally and spatially.
This paper introduces a novel measure to assess similarity between event hydrographs. It is based on Cross Recurrence Plots and Recurrence Quantification Analysis which have recently gained attention in a range of disciplines when dealing with complex systems. The method attempts to quantify the event runoff dynamics and is based on the time delay embedded phase space representation of discharge hydrographs. A phase space trajectory is reconstructed from the event hydrograph, and pairs of hydrographs are compared to each other based on the distance of their phase space trajectories. Time delay embedding allows considering the multi-dimensional relationships between different points in time within the event. Hence, the temporal succession of discharge values is taken into account, such as the impact of the initial conditions on the runoff event. We provide an introduction to Cross Recurrence Plots and discuss their parameterization. An application example based on flood time series demonstrates how the method can be used to measure the similarity or dissimilarity of events, and how it can be used to detect events with rare runoff dynamics. It is argued that this methods provides a more comprehensive approach to quantify hydrograph similarity compared to conventional hydrological signatures.
The NAC transcription factor (TF) JUNGBRUNNEN1 (JUB1) is an important negative regulator of plant senescence, as well as of gibberellic acid (GA) and brassinosteroid (BR) biosynthesis in Arabidopsis thaliana. Overexpression of JUB1 promotes longevity and enhances tolerance to drought and other abiotic stresses. A similar role of JUB1 has been observed in other plant species, including tomato and banana. Our data show that JUB1 overexpressors (JUB1-OXs) accumulate higher levels of proline than WT plants under control conditions, during the onset of drought stress, and thereafter. We identified that overexpression of JUB1 induces key proline biosynthesis and suppresses key proline degradation genes. Furthermore, bZIP63, the transcription factor involved in proline metabolism, was identified as a novel downstream target of JUB1 by Yeast One-Hybrid (Y1H) analysis and Chromatin immunoprecipitation (ChIP). However, based on Electrophoretic Mobility Shift Assay (EMSA), direct binding of JUB1 to bZIP63 could not be confirmed. Our data indicate that JUB1-OX plants exhibit reduced stomatal conductance under control conditions. However, selective overexpression of JUB1 in guard cells did not improve drought stress tolerance in Arabidopsis. Moreover, the drought-tolerant phenotype of JUB1 overexpressors does not solely depend on the transcriptional control of the DREB2A gene. Thus, our data suggest that JUB1 confers tolerance to drought stress by regulating multiple components. Until today, none of the previous studies on JUB1´s regulatory network focused on identifying protein-protein interactions. We, therefore, performed a yeast two-hybrid screen (Y2H) which identified several protein interactors of JUB1, two of which are the calcium-binding proteins CaM1 and CaM4. Both proteins interact with JUB1 in the nucleus of Arabidopsis protoplasts. Moreover, JUB1 is expressed with CaM1 and CaM4 under the same conditions. Since CaM1.1 and CaM4.1 encode proteins with identical amino acid sequences, all further experiments were performed with constructs involving the CaM4 coding sequence. Our data show that JUB1 harbors multiple CaM-binding sites, which are localized in both the N-terminal and C-terminal regions of the protein. One of the CaM-binding sites, localized in the DNA-binding domain of JUB1, was identified as a functional CaM-binding site since its mutation strongly reduced the binding of CaM4 to JUB1. Furthermore, JUB1 transactivates expression of the stress-related gene DREB2A in mesophyll cells; this effect is significantly reduced when the calcium-binding protein CaM4 is expressed as well. Overexpression of both genes in Arabidopsis results in early senescence observed through lower chlorophyll content and an enhanced expression of senescence-associated genes (SAGs) when compared with single JUB1 overexpressors. Our data also show that JUB1 and CaM4 proteins interact in senescent leaves, which have increased Ca2+ levels when compared to young leaves. Collectively, our data indicate that JUB1 activity towards its downstream targets is fine-tuned by calcium-binding proteins during leaf senescence.
Die Arbeit beschreibt die Synthese, Charakterisierung und Anwendung von meso- und mikroporösen Hochleistungspolymeren. Im ersten Teil wird die Synthese von mesoporösen Polybenzimidazol (PBI) auf der Basis einer Templatierungsmethode vorgestellt. Auf der Grundlage kommerzieller Monomere und Silikatnanopartikel sowie eines neuen Vernetzers wurde ein Polymer-Silikat-Hybridmaterial aufgebaut. Das Herauslösen des Silikats mit Ammoniumhydrogendifluorid führt zu mesoporösen Polybenzimidazolen mit spherischen Poren von 9 bis 11 nm Durchmesser. Die Abhängigkeit der beobachteten Porosität vom Massenverhältnis Silikat zu Polymer wurde ebenso untersucht wie die Abhängigkeit der Porosität vom Vernetzergehalt. Die Porosität vollvernetzter Proben zeigt eine lineare Abhängigkeit vom Verhältnis Silikat zu Polymer bis zu einem Grenzwert von 1. Wird der Grenzwert überschritten, ist teilweiser Porenkollaps zu beobachten. Die Abhängigkeit der Porosität vom Vernetzergehalt bei festem Silikatgehalt ist nichtlinear. Oberhalb einer kritischen Vernetzerkonzentration wird eine komplette Replikation der Nanopartikel gefunden. Ist die Vernetzerkonzentration dagegen kleiner als der kritische Wert, so ist der völlige Kollaps einiger Poren bei Stabilität der verbleibenden Poren zu beobachten. Ein komplett unporöses PBI resultiert bei Abwesenheit des Vernetzers. Die mesoporösen PBI-Netzwerke konnten kontrolliert mit Phosphorsäure beladen werden. Die erhaltenen Addukte wurden auf ihre Protonenleitfähigkeit untersucht. Es kann gezeigt werden, dass die Nutzung der vordefinierten Morphologie im Vergleich zu einem unstrukturierten PBI in höheren Leitfähigkeiten resultiert. Durch die vernetzte Struktur war des Weiteren genügend mechanische Stabilität gegeben, um die Addukte reversibel und bei sehr guten Leitfähigkeiten bis zu Temperaturen von 190°C bei 0% relativer Feuchtigkeit zu untersuchen. Dies ist für unstrukturierte Phosphorsäure/PBI - Addukte aus linearem PBI nicht möglich. Im zweiten Teil der Arbeit wird die Synthese intrinsisch mikroporöser Polyamide und Polyimide vorgestellt. Das Konzept intrinsisch mikroporöser Polymere konnte damit auf weitere Polymerklassen ausgeweitet werden. Als zentrales, strukturinduzierendes Motiv wurde 9,9'-Spirobifluoren gewählt. Dieses Molekül ist leicht und vielfältig zu di- bzw. tetrafunktionellen Monomeren modifizierbar. Dabei wurden bestehende Synthesevorschriften modifiziert bzw. neue Vorschriften entwickelt. Ein erster Schwerpunkt innerhalb des Kapitels lag in der Synthese und Charakterisierung von löslichen, intrinsisch mikroporösen, aromatischen Polyamid und Polyimid. Es konnte gezeigt werden, dass das Beobachten von Mikroporosität stark von der molekularen Architektur und der Verarbeitung der Polymere abhängig ist. Die Charakterisierung der Porosität erfolgte unter Nutzung von Stickstoffsorption, Kleinwinkelröntgenstreuung und Molecular Modeling. Es konnte gezeigt werden, dass die Proben stark vom Umgebungsdruck abhängigen Deformationen unterliegen. Die starke Quellung der Proben während des Sorptionsvorgangs konnte durch Anwendung des "dual sorption" Modells, also dem Auftreten von Porenfüllung und dadurch induzierter Henry-Sorption, erklärt werden. Der zweite Schwerpunkt des Kapitels beschreibt die Synthese und Charakterisierung mikroporöser Polyamid- und Polyimidnetzwerke. Während Polyimidnetzwerke auf Spirobifluorenbasis ausgeprägte Mikroporosität und spezifische Oberflächen von ca. 1100 m²/g aufwiesen, war die Situation für entsprechende Polyamidnetzwerke abweichend. Mittels Stickstoffsorption konnte keine Mikroporosität nachgewiesen werden, jedoch konnte mittels SAXS eine innere Grenzfläche von ca. 300 m²/g nachgewiesen werden. Durch die in dieser Arbeit gezeigten Experimente kann die Grenze zwischen Polymeren mit hohem freien Volumen und mikroporösen Polymeren somit etwas genauer gezogen werden. ausgeprägte Mikroporosität kann nur in extrem steifen Strukturen nachgewiesen werden. Die Kombination der Konzepte "Mesoporosität durch Templatierung" und "Mikroporosität durch strukturierte Monomere" hatte ein hierarchisch strukturiertes Polybenzimidazol zum Ergebnis. Die Präsenz einer Strukturierung im molekularen Maßstab konnte SAXS bewiesen werden. Das so strukturierte Polybenzimidazol zeichnete sich durch eine höhere Protonenleitfähigkeit im Vergleich zu einem rein mesoporösen PBI aus. Der letzte Teil der Arbeit beschäftigte sich mit der Entwicklung einer neuen Synthesemethode zur Herstellung von Polybenzimidazol. Es konnte gezeigt werden, dass lineares PBI in einer eutektischen Salzschmelze aus Lithium- und Kaliumchlorid synthetisiert werden kann. Die Umsetzung der spirobifluorenbasierten Monomere zu löslichem oder vernetztem PBI ist in der Salzschmelze möglich.