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We develop a model of stochastic radiation pressure for rotating non-spherical particles and apply the model to circumplanetary dynamics of dust grains. The stochastic properties of the radiation pressure are related to the ensemble-averaged characteristics of the rotating particles, which are given in terms of the rotational time-correlation function of a grain. We investigate the model analytically and show that an ensemble of particle trajectories demonstrates a diffusion-like behaviour. The analytical results are compared with numerical simulations, performed for the motion of the dusty ejecta from Deimos in orbit around Mars. We find that the theoretical predictions are in a good agreement with the simulation results. The agreement however deteriorates at later time, when the impact of non-linear terms, neglected in the analytic approach, becomes significant. Our results indicate that the stochastic modulation of the radiation pressure can play an important role in the circumplanetary dynamics of dust and may in case of some dusty systems noticeably alter an optical depth. (c) 2006 Elsevier Ltd. All rights reserved.
Questions of identity and provenance of minerals that are parts of masterpieces in museums have become increasingly important in mineralogical and historical studies. Detailed investigations of valuable and unique objects require on-site, nondestructive and noninvasive methods because touching or removing them may cause irreparable damage. A mobile Raman-microprobe has been used to meet these demands for truly in situ mineralogical studies of the large collection of minerals and rocks of the Prussian kings in the Grotto Hall (Grottensaal) of the New Palace (Neues Palais), Park Sanssouci in Potsdam. Minerals on the walls of the Grotto Hall were analyzed to identify them and thereby to complete the data bank of the collection. Fluid and solid inclusions in the interior of a large quartz crystal have been studied to provide evidence of the provenance of the crystal. The fluid inclusions contain aqueous saline solutions, whereas the solid inclusions are needles of anhydrite with a length of about 1.5 mm. The quartz probably originated from an area in the eastern Alps, from the surroundings of Bad Gastein, Austria. This is the first on-site and in situ study of inclusions below the surface of a mineral with a mobile Raman-microprobe outside a laboratory.
Fractional crystallization of peraluminous F- and H(2)O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions. We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.
The velocity distribution function of granular gases in the homogeneous cooling state as well as some heated granular gases decays for large velocities as f proportional to exp(-const x nu). That is, its high-energy tail is overpopulated as compared with the Maxwell distribution. At the present time, there is no theory to describe the influence of the tail on the kinetic characteristics of granular gases. We develop an approach to quantify the overpopulated tail and analyze its impact on granular gas properties, in particular on the cooling coefficient. We observe and explain anomalously slow relaxation of the velocity distribution function to its steady state.
The influence of branched poly(ethyleneimine) on the phase behavior of the system sodium dodecylsulfate/toluene-pentanol (1:1)/water has been studied. The isotropic microemulsions still exist when water is replaced with aqueous solutions of PEI (up to 30% in weight), but their stability is significantly influenced. From a polymer concentration of 20 wt%, the polymer enhances the solubilization of water in oil, changes the sign of the spontaneous curvature of the surfactant film, and induces an inversion of the microemulsion type from water-in-oil (L-2) to oil-in-water (L-1), by the formation of a bicontinuous channel. Further investigations show that the addition of polymer in the L-2 phase changes the droplet-droplet interactions as the conductivity drops and the percolation disappears. In the bicontinuous channel, higher viscosities can be detected, as well as a weak percolation followed by a steep increase of the conductivity, which can be related to evident structural changes in the system. DSC measurements allow then to follow the changes of the water properties in the system, from interfacial-water in the L-2 phase to free-water in the sponge-like phase. Finally, all the measurements performed permit to characterize the structural transitions in the system and to understand the role of the added polymer.
The nanostructuring of ORMOCER (R) to form inverse opals is described. For this purpose a polymer opal is used as a template and infiltrated with liquid ORMOCER (R). After photopolymerization of the resin the host opal is dissolved in tetrahydrofuran and an ORMOCER (R) inverse opal is obtained. It shows excellent periodicity (by SEM) and optical properties to reveal a high degree of face centered cubic order. This replication process leads to a nanostructured photonic crystal with the outstanding mechanical properties of ORMOCER (R) and high temperature stability up to 350 degrees C.
Lago Laja is a late Quaternary volcanic‐dammed lake located near the drainage divide of the south central Andes. Field observations, lake reflection seismic profiles, bathymetry, and remote sensing data reveal an active fault system that runs parallel to the volcanic arc along the axis of the Main Cordillera, the Lago Laja fault system (LLFS). Normal faults of this extensional system cut late Pleistocene volcanics, <7.1 ka still water lacustrine sediments, 6.3 ka pyroclastic deposits, and Holocene alluvial fans. We divide the LLFS in three segments on the basis of fault geometry, width, and slip magnitude. The underwater faults of the central segment in the lake's deepest part have the maximum Holocene vertical slip rate of >2.7 mm/yr. Since 7.1 ka, the LLFS accounts for ∼0.7% of arc‐normal extension at an average minimum rate of 1.2 mm/yr and strain rate of ∼10−14 s−1. Seismites and surface ruptures evidence M>6 paleoearthquakes. The Main Cordillera at ∼37°S is a large‐scale pop‐up structure uplifted by thrusting along its foothills. In this light, we interpret extension in the axial and highest part of the Andes as incipient synorogenic gravitational collapse in response to uplift and crustal thickening. Thermal weakening due to elevated heat flow and postglacial lithospheric rebound and unbending have probably contributed to the arc‐limited collapse and Holocene acceleration of deformation rates. The lack of significant strike‐slip offsets along the LLFS as well as along both foothills‐thrust systems at 37°S contrasts with the intra‐arc dextral fault zone south of 38°S. Regional structural data indicates that north of 38°S, diffusely distributed strain reflects low partitioning of oblique subduction, while to the south deformation is localized in a discrete strike‐slip fault zone along the volcanic arc, reflecting a higher degree of partitioning. We relate this strain partitioning gradient to favorable fault orientations in the fore arc north of the Arauco Peninsula, a major seismotectonic boundary.
Great apes are the closest living relatives of humans. Physiological similarities between great apes and humans provide clues to identify which biological features in humans are primitive or derived from great apes. Vitamin A (VA) and carotenoid metabolism have been only partially studied in great apes, and comparisons between great apes and humans are not available. We aimed to investigate VA and carotenoid intake and plasma concentrations in great apes living in captivity, and to compare them to healthy humans. Dietary intakes of humans (n = 20) and, among the great apes, chimpanzees (n = 15) and orangutans (n = 5) were calculated. Plasma retinol (ROH), retinol-binding protein (RBP), retinyl esters, and major carotenoids were analyzed. The great ape diet was higher in VA than in humans, due to high intake of provitamin A carotenoids. Plasma ROH concentrations in great apes were similar to those in humans, but retinyl esters were higher in great apes than in humans. Differences in plasma carotenoid concentrations were observed between great apes and humans. Lutein was the main carotenoid in great apes, while P-carotene was the main carotenoid for humans. RBP concentrations did not differ between great apes and humans. The molar ratio of ROH to RBP was close to 1.0 in both great apes and humans. In conclusion, great apes show homeostatic ROH regulation, with high but physiological retinyl esters circulating in plasma. Furthermore, great apes show great selectivity in their plasmatic carotenoid concentration, which is not explained by dietary intake.