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Taking the visit of Erich Honecker to China as an example, the author analyses the bilateral GDR-Chinese relations in the 1980s. Based on extensive original research, the objectives as well as disappointed hopes are presented. The author reveals that not Honecker played the "Chinese Card", but he himself became part of Chinese politics. At the same time, the contradictory reaction to that visit in Moscow are documented when, with the election of Gorbachev, first signs of a change in Soviet policy toward China were indicated. Jahresabo: 40,00 € (ermäßigt: 25,00 €)
The knowledge of transformation pathways and identification of transformation products (TPs) of veterinary drugs is important for animal health, food, and environmental matters. The active agent Monensin (MON) belongs to the ionophore antibiotics and is widely used as a veterinary drug against coccidiosis in broiler farming. However, no electrochemically (EC) generated TPs of MON have been described so far. In this study, the online coupling of EC and mass spectrometry (MS) was used for the generation of oxidative TPs. EC-conditions were optimized with respect to working electrode material, solvent, modifier, and potential polarity. Subsequent LC/HRMS (liquid+ chromatography/high resolution mass spectrometry) and MS/MS experiments were performed to identify the structures of derived TPs by a suspected target analysis. The obtained EC-results were compared to TPs observed in metabolism tests with microsomes and hydrolysis experiments of MON. Five previously undescribed TPs of MON were identified in our EC/MS based study and one TP, which was already known from literature and found by a microsomal assay, could be confirmed. Two and three further TPs were found as products in microsomal tests and following hydrolysis, respectively. We found decarboxylation, O-demethylation and acid-catalyzed ring-opening reactions to be the major mechanisms of MON transformation
In this issue, we continue and complete the debate on the future of the transatlantic relationship and of world order after the Iraq war. The debate was initiated by an article by Thomas Risse (Freie Universität Berlin) in WeltTrends 39, which has provoked a remarkable reaction within the German academic community, as documented in WeltTrends 40. This issue features additional comments and the rebuttal by Thomas Risse. Most authors believe that the transatlantic partnership is in a serious crisis, but claim that it remains without an alternative for both sides of the Atlantic.
Lithuania and Poland had cooperated for centuries and even created a political union. The pacts had been very useful for both sides and consequently, the peoples and especially the Lithuanian elite was ready to absorb parts of the Polish culture. Lithuania broke with this tradition dating back to the Middle Ages only after the first division of Poland. During 1944- 1990, the so-called "Soviet period in Lithuania", two different processes could be observed: Russification and Lithuanification. Although dependent on Moscow, the leading Lithuanian politicians never forgot Lithuanian interests and supported the national conscience. After Lithuania gained independence in 1990, a huge wave of national enthusiasm swapped over the country. In the meantime, politicians came back to reality: The independence of Lithuania seems consolidated and the old tradition to re-establish the Polish-Lithuanian cooperation seems to be on the run since Aleksander Kwasniewski had visited Lithuania in January 1996.
Since the end of the year 1989 Liberia has been ravaged by a bloody civil war. It has almost completely destroyed the state structure of Liberian society which was manipulated by military ruler Samuel Doe and a small elite with the ends of amassing wealth and retaining power during the decade of 1980 to 1989. The state and almost all political institutions were stripped of credibility and legitimacy. During the war it was easy for the warlords of the various factions and their mostly young supporters to seize power and the remaining resources of the country. They established a radical free market system with the help of internationally operating companies and banks, protecting it by terror. Nearly two thirds of the population have left their homes and now live as refugees abroad, in the capital Monrovia or in Buchanan, where remnants of state structure and a weak civil society survive under the protection of a regional intervention army (Ecomog). By discussing different sociological explanations, the author traces the origins of the civil war and of its extreme brutality.
The haemolymph of the adult Colorado potato beetle, Lepinotarsa decemlineata Say, contains a high molecular weight (MW > 200,000) JH-III specific binding protein. The Kd value of the protein for racemic JH-III is 1.3 ± 0.2 × 10−7 M. It has a lower affinity for racemic JH-I and it does not bind JH-III-diol or JH-III-acid. The binding protein does discriminate between the enantiomers of synthetic, racemic JH-III as was determined by stereochemical anaysis of the bound and the free JH-III. Incubation of racemic JH-III with crude haemolymph results in preferential formation of (10S)-JH-III-acid, the unnatural configuration. The JH-esterase present in L. decemlineata haemolymph is not enantioselective. It is concluded that the most important function of the binding protein is that of a specific carrier, protecting the natural hormone against degradation by esterases. The carrier does not protect JH-I as efficiently as the lower homologue.
Cinnamic acid moieties were incorporated into amphiphilic compounds containing one and two alkyl chains. These lipid-like compounds with photoreactive units undergo self-organization to form monolayers at the gas-water interface and bilayer structures (vesicles) in aqueous solutions. The photoreaction of the cinnamic acid moiety induced by 254 nm UV light was investigated in the crystalline state, in monolayers, in vesicles and in solution in organic solvents. The single-chain amphiphiles undergo dimerization to yield photoproducts with twice the molecular weight of the corresponding monomers in organized systems. The photoreaction of amphiphiles containing two cinnamic acid groups occurs via two mechanisms: The intramolecular dimerization produces bicycles, with retention of the molecular weight of the corresponding monomer. The intermolecular reaction leads to oligomeric and polymeric photoproducts. In contrast to the single-chain amphiphiles, photodimerization processes of lipoids containing two cinnamic acid moieties also occur in solution in organic solvents.
At the beginning of the 21st century the welfare state is under pressure from two sides. On the one hand, there is "globalisation", on the other hand seems to be some sort of normative crisis of the welfare state’s moral foundations. The welfare state is said to curtail individual freedom and autonomy. This article rejects this assumption by exploring the philosophical and moral foundations of the welfare state, thereby demonstrating that it is essentially necessary for individual freedom and autonomy. Furthermore, it is shown that individual freedom is also the core principle of liberal democracy and that the welfare state is therefore an indispensable prerequisite for democracy itself.
According to the author, chairman of the Foreign Policy Committee in the German parliament (Bundestag), German foreign policy is based on a strong parliamentary consensus: continuing as a Western European country, co-operating with our partners in the European Union and the NATO, acting as a responsible member of UN and OSCE. Germany firmly stands up to these basic decisions, also today in a changed world, concentrating on reaching two major goals: building up a new security architecture for Europe as a whole and reuniting Europe by enlarging the European Union. Moderate and co-operate in style, Germany will continue to be a reliable partner, willing and ready to accept even more responsibilities in Europe and beyond Europe.
Flight and expulsion are and will remain important international problems. The existence of refugees is a result of unsolved domestic tasks. Thus, effective solutions require comprehensive and long-term strategies. So far the efforts to reduce the causes of escape have not been sufficient. In the current refugee crises millions of people can survive only with the help of an efficient international system (for example the UNHCR) that guarantees humanitarian aid and protection. However, this system has turned out to be inadequate although the potential of preventive action is sufficient to reach a major progress in diminishing the refugee problem.