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Fjords and old-growth forests store large amounts of organic carbon. Yet the role of episodic disturbances, particularly volcanic eruptions, in mobilizing organic carbon in fjord landscapes covered by temperate rainforests remains poorly quantified. To this end, we estimated how much wood and soils were flushed to nearby fjords following the 2008 eruption of Chaiten volcano in south-central Chile, where pyroclastic sediments covered >12km(2) of pristine temperate rainforest. Field-based surveys of forest biomass, soil organic content, and dead wood transport reveal that the reworking of pyroclastic sediments delivered similar to 66,500+14,600/-14,500tC of large wood to two rivers entering the nearby Patagonian fjords in less than a decade. A similar volume of wood remains in dead tree stands and buried beneath pyroclastic deposits (similar to 79,900+21,100/-16,900tC) or stored in active river channels (5,900-10,600tC). We estimate that bank erosion mobilized similar to 132,300(+21,700)/(-30,600)tC of floodplain forest soil. Eroded and reworked forest soils have been accreting on coastal river deltas at >5mmyr(-1) since the eruption. While much of the large wood is transported out of the fjord by long-shore drift, the finer fraction from eroded forest soils is likely to be buried in the fjords. We conclude that the organic carbon fluxes boosted by rivers adjusting to high pyroclastic sediment loads may remain elevated for up to a decade and that Patagonian temperate rainforests disturbed by excessive loads of pyroclastic debris can be episodic short-lived carbon sources. Plain Language Summary Fjords and old-growth forests are important sinks of organic carbon. However, the role of volcanic eruptions in flushing organic carbon in fjord landscapes remains unexplored. Here we estimated how much forest vegetation and soils were lost to fjords following the 2008 eruption ofunknownChaiten volcano in south-central Chile. Pyroclastic sediments obliterated near-pristine temperateunknownrainforest, and the subsequent reworking of these sediments delivered in less than a decade similar to 66,000 tC of large wood to the mountain rivers, draining into the nearby Patagonian fjords. A similar volume of wood remains in dead tree stands and buried beneath pyroclastic deposits or stored in active riverunknownchannels. We estimate that similar to 130,000 tC of organic carbon-rich soil was lost to erosion, thus adding to the carbon loads. While much of the wood enters the long-shore drift in the fjord heads, the finerunknownfraction from eroded forest soils is likely to be buried in the fjords at rates that exceed regional estimates by an order of magnitude. We anticipate that these eruption-driven fluxes will remain elevated forunknownthe coming years and that Patagonian temperate rainforests episodically switch from carbon sinks to hitherto undocumented carbon sources if disturbed by explosive volcanic eruptions.
Lignin valorization
(2017)
The topic of this project is the use of lignin as alternative source of aromatic building blocks and oligomers to fossil feedstocks. Lignin is known as the most abundant aromatic polymer in nature and is isolated from the lignocellulosic component of plants by different possible extraction treatments. Both the biomass source and the extraction method affect the structure of the isolated lignin, therefore influencing its further application. Lignin was extracted from beech wood by two different hydrothermal alkaline treatments, which use NaOH and Ba(OH)2 as base and by an acid-catalyzed organosolv process. Moreover, lignin was isolated from bamboo, beech wood and coconut by soda treatment of the biomasses. A comparison of the structural features of such isolated lignins was performed through the use of a wide range of analytical methods. Alkaline lignins resulted in a better candidate as carbon precursor and macromonomers for the synthesis of polymer than organosolv lignin. In fact, alkaline lignins showed higher residual mass after carbonization and higher content of the reactive hydroxy functionalities. In contrast, the lignin source turned out to slightly affect the lignin hydroxyl content.
One of the most common lignin modifications is its deconstruction to obtain aromatic molecules, which can be used as starting materials for the synthesis of fine chemicals. Lignin deconstruction leads to a complex mixture of aromatic molecules. A gas chromatographic analytical method was developed to characterize the mixture of products obtained by lignin deconstruction via heterogeneous catalytic hydrogenolysis. The analytical protocol allowed the quantification of three main groups of molecules by means of calibration curves, internal standard and a preliminary silylation step of the sample. The analytical method was used to study the influence of the hydrogenolysis catalyst, temperature and system (flow and batch reactor) on the yield and selectivity of the aromatic compounds.
Lignin extracted from beech wood by a hydrothermal process using Ba(OH)2 as base, was functionalized by aromatic nitration in order to add nitrogen functionalities. The final goal was the synthesis of a nitrogen doped carbon. Nitrated lignin was reduced to the amino form in order to compare the influence of different nitrogen functionalities on the porosity of the final carbon. The carbons were obtained by ionothermal treatment of the precursors in the presence of the eutectic salt mixture KCl/ZnCl2 Such synthesized carbons showed micro-, macro- and mesoporosity and were tested for their electrocatalytic activity towards the oxygen reduction reaction. Mesoporous carbon derived from nitro lignin displayed the highest electrocatalytic activity.
Lignins isolated from coconut, beech wood and bamboo were used as macromonomers for the synthesis of biobased polyesters. A condensation reaction was performed between lignin and a hyper branched poly(ester-amine), previously obtained by condensation of triethanolamine and adipic acid. The influence of the lignin source and content on the thermochemical and mechanical properties of the final material was investigated. The prepolymer showed adhesive properties towards aluminum and its shear strength was therefore measured. The gluing properties of such synthesized glues turned out to be independent from the lignin source but affected by the amount of lignin in the final material.
This work shows that, although still at a laboratory scale, the valorization of lignin can overcome the critical issues of lignin´s structure variability and complexity.
The sustainability of agro-bioenergy systems is dependent on many factors, some local or regional in implementation, some others global in nature. This study assessed the effects of often ignored local and regional factors (e.g. alternative agronomic factor options, alternative agricultural production systems, alternative biomass flows, alternative conversion technologies etc. The results from this study suggests that key to enhancing the energy efficiency (and by extension the sustainability) of agro-bioenergy systems is paying attention to local and regional factors such as biomass conversion technology, alternative agronomic factor options, alternative agricultural production systems and available biomass flows.