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The application of nanoscale zero-valent iron (nZVI) for subsurface remediation of groundwater contaminants is a promising new technology, which can be understood as alternative to the permeable reactive barrier technique using granular iron. Dechlorination of organic contaminants by zero-valent iron seems promising. Currently, one limitation to widespread deployment is the fast agglomeration and sedimentation of nZVI in colloidal suspensions, even more so when in soils and sediments, which limits the applicability for the treatment of sources and plumes of contamination. Colloid-supported nZVI shows promising characteristics to overcome these limitations. Mobility of Carbo-Iron Colloids (CIC) - a newly developed composite material based on finely ground activated carbon as a carrier for nZVI - was tested in a field application: In this study, a horizontal dipole flow field was established between two wells separated by 53 m in a confined, natural aquifer. The injection/extraction rate was 500 L/h. Approximately 12 kg of CIC was suspended with the polyanionic stabilizer carboxymethyl cellulose. The suspension was introduced into the aquifer at the injection well. Breakthrough of CIC was observed visually and based on total particle and iron concentrations detected in samples from the extraction well. Filtration of water samples revealed a particle breakthrough of about 12% of the amount introduced. This demonstrates high mobility of CIC particles and we suggest that nZVI carried on CIC can be used for contaminant plume remediation by in-situ formation of reactive barriers. (C) 2015 Elsevier B.V. All rights reserved.
Near-surface seismic traveltime tomography using a direct-push source and surface-planted geophones
(2009)
Information about seismic velocity distribution in heterogeneous near-surface sedimentary deposits is essential for a variety of environmental and engineering geophysical applications. We have evaluated the suitability of the minimally invasive direct-push technology for near-surface seismic traveltime tomography. Geophones placed at the surface and a seismic source installed temporarily in the subsurface by direct-push technology quickly acquire reversed multioffset vertical seismic profiles (VSPs). The first-arrival traveltimes of these data were used to reconstruct the 2D seismic velocity distribution tomographically. After testing this approach on synthetic data, we applied it to field data collected over alluvial deposits in a former river floodplain. The resulting velocity model contains information about high- and low-velocity anomalies and offers a significantly deeper penetration depth than conventional refraction tomography using surface-planted sources and receivers at the investigated site. A combination of refraction seismic and direct-push data increases resolution capabilities in the unsaturated zone and enables reliable reconstruction of velocity variations in near-surface unconsolidated sediments. The final velocity model structurally matches the results of cone-penetration tests and natural gamma-radiation data acquired along the profile. The suitability of multiple rapidly acquired reverse VSP surveys for 2D tomographic velocity imaging of near-surface unconsolidated sediments was explored.