Refine
Year of publication
- 2014 (13) (remove)
Language
- English (13)
Is part of the Bibliography
- yes (13) (remove)
Keywords
- chromoionophore (2)
- green (2)
- indicators (2)
- ion optodes (2)
- ionophore (2)
- membrane (2)
- samples (2)
- sensors (2)
- switches (2)
- systems (2)
Institute
In situ imidazolate-4,5-diamide-2-olate linker generation leads to the formation of a [Zn-14(L2)(12)(O)-(OH)(2)(H2O)(4)] molecular building block (MBB) with a Zn-6 octahedron inscribed in a Zn-8 cube. The MBBs connect by amide-amide hydrogen bonds to a 3D robust supramolecular network which can be activated for N-2, CO2, CH4, and H-2 gas sorption.
A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N-2, CO2, CH4 and H-2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.