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Fast analysis of different species of molecules in soils is investigated by capillary electrophoresis (CE). Several CE techniques for the analysis of inorganic ions and carbohydrates have been tested. With regard to the intents of pedologists and the usually large number of soil analyses a bundle of CE systems is proposed, capable of effecting time-saving soil analyses. Adapted electrolyte systems recently published and new separation systems are described. Examples of the application of these methods to two different soil samples are presented.
The haemolymph of the adult Colorado potato beetle, Lepinotarsa decemlineata Say, contains a high molecular weight (MW > 200,000) JH-III specific binding protein. The Kd value of the protein for racemic JH-III is 1.3 ± 0.2 × 10−7 M. It has a lower affinity for racemic JH-I and it does not bind JH-III-diol or JH-III-acid. The binding protein does discriminate between the enantiomers of synthetic, racemic JH-III as was determined by stereochemical anaysis of the bound and the free JH-III. Incubation of racemic JH-III with crude haemolymph results in preferential formation of (10S)-JH-III-acid, the unnatural configuration. The JH-esterase present in L. decemlineata haemolymph is not enantioselective. It is concluded that the most important function of the binding protein is that of a specific carrier, protecting the natural hormone against degradation by esterases. The carrier does not protect JH-I as efficiently as the lower homologue.
The site of confluence of the artery and the portal vein in the liver still appears to be controversial. Anatomical studies suggested a presinusoidal or an intrasinusoidal confluence in the first, second or even final third of the sinusoids. The objective of this investigation was to study the problem with functional biochemical techniques. Rat livers were perfused through the hepatic artery and simultaneously either in the orthograde direction from the portal vein to the hepatic vein or in the retrograde direction from the hepatic vein to the portal vein. Arterial how was linearly dependent on arterial pressure between 70 cm H2O and 120 cm H2O at a constant portal or hepatovenous pressure of 18 cm H2O. An arterial pressure of 100 cm H2O was required for the maintenance of a homogeneous orthograde perfusion of the whole parenchyma and of a physiologic ratio of arterial to portal how of about 1:3. Glucagon was infused either through the artery or the portal vein and hepatic vein, respectively, to a submaximally effective ''calculated'' sinusoidal concentration after mixing of 0.1 nmol/L. During orthograde perfusions, arterial and portal glucagon caused the same increases in glucose output. Yet during retrograde perfusions, hepatovenous glucagon elicited metabolic alterations equal to those in orthograde perfusions, whereas arterial glucagon effected changes strongly reduced to between 10% and 50%. Arterially infused trypan blue was distributed homogeneously in the parenchyma during orthograde perfusions, whereas it reached clearly smaller areas of parenchyma during retrograde perfusions. Finally, arterially applied acridine orange was taken up by all periportal hepatocytes in the proximal half of the acinus during orthograde perfusions but only by a much smaller portion of periportal cells in the proximal third of the acinus during retrograde perfusions. These findings suggest that in rat liver, the hepatic artery and the portal vein mix before and within the first third of the sinusoids, rather than in the middle or even last third.
Bei N = 101 Arbeitnehmern verschiedener Berufe wurden mit der Experience Sampling Method (ESM) eine Woche lang Daten zum Flow-Erleben, zu Glück/Zufriedenheit und zur Zielausrichtung laufender Aktivitäten erhoben (N = 4603 Messungen). Die Daten wurden mit GLMM-Analysen ausgewertet. Auch bei der jetzt vollständigen Erfassung aller Flow-Komponenten mit der FKS bestätigte sich das „Paradoxon der Arbeit“, wonach während der Arbeit höhere Flow-Werte, aber niedrigere Werte für Glück/Zufriedenheit auftreten als jeweils in der Freizeit. Während der Arbeit waren Aktivitäten häufiger auf die Erreichung von Zielen ausgerichtet als während der Freizeit. Die Zielausrichtung wirkte auf Flow vs. Glück/Zufriedenheit signifikant verschieden. Während der Arbeit hat die Zielausrichtung auf Flow einen stark positiven Effekt, auf Glück/Zufriedenheit jedoch nicht. Im Freizeitbereich war der Effekt von Zielausrichtung auf Glück/Zufriedenheit sogar negativ. Das „Paradoxon der Arbeit“ lässt sich partiell als Effekt der Zielausrichtung verstehen.
Small livestock is an important resource for rural human populations in dry climates. How strongly will climate change affect the capacity of the rangeland? We used hierarchical modelling to scale quantitatively the growth of shrubs and annual plants, the main food of sheep and goats, to the landscape extent in the eastern Mediterranean region. Without grazing, productivity increased in a sigmoid way with mean annual precipitation. Grazing reduced productivity more strongly the drier the landscape. At a point just under the stocking capacity of the vegetation, productivity declined precipitously with more intense grazing due to a lack of seed production of annuals. We repeated simulations with precipitation patterns projected by two contrasting IPCC scenarios. Compared to results based on historic patterns, productivity and stocking capacity did not differ in most cases. Thus, grazing intensity remains the stronger impact on landscape productivity in this dry region even in the future.
A multitype Dawson-Watanabe process is conditioned, in subcritical and critical cases, on non-extinction in the remote future. On every finite time interval, its distribution is absolutely continuous with respect to the law of the unconditioned process. A martingale problem characterization is also given. Several results on the long time behavior of the conditioned mass process - the conditioned multitype Feller branching diffusion - are then proved. The general case is first considered, where the mutation matrix which models the interaction between the types, is irreducible. Several two-type models with decomposable mutation matrices are analyzed too .
Team diversity
(2007)
Team diversity refers to the differences between team members on any attribute that may lead each single member of the group to perceive any other member of the group as being different from the self of this particular member. These attributes and perceptions refer to all dimensions people can differ on, such as age, gender, ethnicity, religious and functional background, personality, skills, abilities, beliefs, and attitudes.
The authors used the frameworks of reciprocal determinism and occupational socialization to study the effects of work characteristics (consisting of control and complexity of work) on personal initiative (PI)--mediated by control orientation (a 2nd-order factor consisting of control aspiration, perceived opportunity for control, and self-efficacy) and the reciprocal effects of PI on changes in work characteristics. They applied structural equation modeling to a longitudinal study with 4 measurement waves (N = 268) in a transitional economy: East Germany. Results confirm the model plus 1 additional, nonhypothesized effect. Work characteristics had a synchronous effect on PI via control orientation (full mediation). There were also effects of control orientation and of PI on later changes in work characteristics: As predicted, PI functioned as partial mediator, changing work characteristics in the long term (reciprocal effect); unexpectedly, there was a 2nd reciprocal effect of an additional lagged partial mediation of control orientation on later work characteristics.
Significant seasonal variation in size at settlement has been observed in newly settled larvae of Dreissena polymorpha in Lake Constance. Diet quality, which varies temporally and spatially in freshwater habitats, has been suggested as a significant factor influencing life history and development of freshwater invertebrates. Accordingly, experiments were conducted with field-collected larvae to test the hypothesis that diet quality can determine planktonic larval growth rates, size at settlement and subsequent post-metamorphic growth rates. Larvae were fed one of two diets or starved. One diet was composed of cyanobacterial cells which are deficient in polyunsaturated fatty acids (PUFAs), and the other was a mixed diet rich in PUFAs. Freshly metamorphosed animals from the starvation treatment had a carbon content per individual 70% lower than that of larvae fed the mixed diet. This apparent exhaustion of larval internal reserves resulted in a 50% reduction of the postmetamorphic growth rates. Growth was also reduced in animals previously fed the cyanobacterial diet. Hence, low food quantity or low food quality during the larval stage of D. polymorpha lead to irreversible effects for postmetamorphic animals, and is related to inferior competitive abilities.
The factors that determine the efficiency of energy transfer in aquatic food webs have been investigated for many decades. The plant-animal interface is the most variable and least predictable of all levels in the food web. In order to study determinants of food quality in a large lake and to test the recently proposed central importance of the long-chained eicosapentaenoic acid (EPA) at the pelagic producer-grazer interface, we tested the importance of polyunsaturated fatty acids (PUFAs) at the pelagic producerconsumer interface by correlating sestonic food parameters with somatic growth rates of a clone of Daphnia galeata. Daphnia growth rates were obtained from standardized laboratory experiments spanning one season with Daphnia feeding on natural seston from Lake Constance, a large pre-alpine lake. Somatic growth rates were fitted to sestonic parameters by using a saturation function. A moderate amount of variation was explained when the model included the elemental parameters carbon (r2 = 0.6) and nitrogen (r2 = 0.71). A tighter fit was obtained when sestonic phosphorus was incorporated (r2 = 0.86). The nonlinear regression with EPA was relatively weak (r2 = 0.77), whereas the highest degree of variance was explained by three C18-PUFAs. The best (r2 = 0.95), and only significant, correlation of Daphnia's growth was found with the C18-PUFA α-linolenic acid (α-LA; C18:3n-3). This correlation was weakest in late August when C:P values increased to 300, suggesting that mineral and PUFA-limitation of Daphnia's growth changed seasonally. Sestonic phosphorus and some PUFAs showed not only tight correlations with growth, but also with sestonic α-LA content. We computed Monte Carlo simulations to test whether the observed effects of α-LA on growth could be accounted for by EPA, phosphorus, or one of the two C18-PUFAs, stearidonic acid (C18:4n-3) and linoleic acid (C18:2n-6). With >99 % probability, the correlation of growth with α-LA could not be explained by any of these parameters. In order to test for EPA limitation of Daphnia's growth, in parallel with experiments on pure seston, growth was determined on seston supplemented with chemostat-grown, P-limited Stephanodiscus hantzschii, which is rich in EPA. Although supplementation increased the EPA content 80-800x, no significant changes in the nonlinear regression of the growth rates with α-LA were found, indicating that growth of Daphnia on pure seston was not EPA limited. This indicates that the two fatty acids, EPA and α-LA, were not mutually substitutable biochemical resources and points to different physiological functions of these two PUFAs. These results support the PUFA-limitation hypothesis for sestonic C:P < 300 but are contrary to the hypothesis of a general importance of EPA, since no evidence for EPA limitation was found. It is suggested that the resource ratios of EPA and α-LA rather than the absolute concentrations determine which of the two resources is limiting growth.
4-Phenylphenoxazinones were isolated after biomimetic oxidation, using diphenoloxidases of insect cuticle, mushroom tyrosinase, or after autoxidation of N-acetyldopamine (Image ) in the presence of β-alanine, β-alanine methyl ester or N-acetyl-L-lysine. They are formed presumably by addition of 2-aminoalkyl-5-alkylphenols to the o-quinone of biphenyltetrol which, in turn, arises from oxidative coupling of. The structures of present the first examples for the assembly of reasonably stable intermediates in the rather complex process of chemical modifications of aliphatic amino acid residues by o-quinones.
Amphiphilic derivatives of octadiene and docosadiene were investigated in monolayers and Langmuir-Blodgett multilayers, with respect to their self-organization and their polymerization behavior. All amphiphiles investigated form monolayers. However, only acid and alcohol derivatives were able to build up multilayers. Those multilayers are rapidly photopolymerized in the layers via a two-step process: Irradiation with long-wavelength UV light yields soluble polymers, whereas additional irradiation with sfiort-wavelength UV light produces insoluble and presumably cross-linked polymers. The reaction meclianism is discussed according to the polymer characterization by UV spectroscopy, small-angle X-ray scattering, NMR spectroscopy, and gel permeation chromatography. All multilayers undergo structural changes during the polymerization; substantial changes result in defects in the polymerized layers as observed by scanning electron microscopy. In contrast to the acids and alcohols, the deposition of monolayers of the aldehyde derivatives did not yield well-ordered multilayers, but rather amorphous films. In this different film structure, the photopolymerization process differs from the one observed in multilayers.
Aus dem Inhalt: Die Juvenilhormone 1a-c werden im Blut von Insekten enzymatisch zu den biologisch inaktiven Sluren hydrolysiert. Bei der Hydrolyse von racemischem 1c im Blut der Wanderheuschrecke Locusta migratoria wird ein Umsatz von 40-60% erreicht. Das unumgesetzte Edukt enthällt einen Überschuß an natürlich konfiguriertem (10R)-1c (e.e. 47.2%). Wir konnten zeigen, daß das in der Hämolymphe vorhandene Hormon-Bindungsprotein bevorzugt mit (10R)- 1c assoziiert.
The topography of first-order catchments in a region of western Amazonia was found to exhibit distinctive, recurrent features: a steep, straight lower side slope, a flat or nearly flat terrace at an intermediate elevation between valley floor and interfluve, and an upper side slope connecting interfluve and intermediate terrace. A detailed survey of soil-saturated hydraulic conductivity (K sat)-depth relationships, involving 740 undisturbed soil cores, was conducted in a 0.75-ha first-order catchment. The sampling approach was stratified with respect to the above slope units. Exploratory data analysis suggested fourth-root transformation of batches from the 0–0.1 m depth interval, log transformation of batches from the subsequent 0.1 m depth increments, and the use of robust estimators of location and scale. The K sat of the steep lower side slope decreased from 46 to 0.1 mm/h over the overall sampling depth of 0.4 m. The corresponding decrease was from 46 to 0.1 mm/h on the intermediate terrace, from 335 to 0.01 mm/h on the upper side slope, and from 550 to 0.015 mm/h on the interfluve. A depthwise comparison of these slope units led to the formulation of several hypotheses concerning the link between K sat and topography.
Rainfall erosivities as defined by the R factor from the universal soil loss equation were determined for all events during a two-year period at the station La Cuenca in western Amazonia. Three methods based on a power relationship between rainfall amount and erosivity were then applied to estimate event and daily rainfall erosivities from the respective rainfall amounts. A test of the resulting regression equations against an independent data set proved all three methods equally adequate in predicting rainfall erosivity from daily rainfall amount. We recommend the Richardson model for testing in the Amazon Basin, and its use with the coefficient from La Cuenca in western Amazonia.
Previous hydrometric studies demonstrated the prevalence of overland flow as a hydrological pathway in the tropical rain forest catchment of South Creek, northeast Queensland. The purpose of this study was to consider this information in a mixing analysis with the aim of identifying sources of, and of estimating their contribution to, storm flow during two events in February 1993. K and acid-neutralizing capacity (ANC) were used as tracers because they provided the best separation of the potential sources, saturation overland flow, soil water from depths of 0.3, 0.6, and 1.2 m, and hillslope groundwater in a two-dimensional mixing plot. It was necessary to distinguish between saturation overland flow, generated at the soil surface and following unchanneled pathways, and overland flow in incised pathways. This latter type of overland flow was a mixture of saturation overland flow (event water) with high concentrations of K and a low ANC, soil water (preevent water) with low concentrations of K and a low ANC, and groundwater (preevent water) with low concentrations of K and a high ANC. The same sources explained the streamwater chemistry during the two events with strongly differing rainfall and antecedent moisture conditions. The contribution of saturation overland flow dominated the storm flow during the first, high-intensity, 178-mm event, while the contribution of soil water reached 50% during peak flow of the second, low-intensity, 44-mm event 5 days later. This latter result is remarkably similar to soil water contributions to storm flow in mountainous forested catchments of the southeastern United States. In terms of event and preevent water the storm flow hydrograph of the high-intensity event is dominated by event water and that of the low-intensity event by preevent water. This study highlights the problems of applying mixing analyses to overland flow-dominated catchments and soil environments with a poorly developed vertical chemical zonation and emphasizes the need for independent hydrometric information for a complete characterization of watershed hydrology and chemistry.
Chemical fingerprints of hydrological compartments and flow paths at La Cuenca, western Amazonia
(1995)
A forested first-order catchment in western Amazonia was monitored for 2 years to determine the chemical fingerprints of precipitation, throughfall, overland flow, pipe flow, soil water, groundwater, and streamflow. We used five tracers (hydrogen, calcium, magnesium, potassium, and silica) to distinguish “fast” flow paths mainly influenced by the biological subsystem from “slow” flow paths in the geochemical subsystem. The former comprise throughfall, overland flow, and pipe flow and are characterized by a high potassium/silica ratio; the latter are represented by soil water and groundwater, which have a low potassium/silica ratio. Soil water and groundwater differ with respect to calcium and magnesium. The groundwater-controlled streamflow chemistry is strongly modified by contributions from fast flow paths during precipitation events. The high potassium/silica ratio of these flow paths suggests that the storm flow response at La Cuenca is dominated by event water.
Earlier investigations at South Creek in northeastern Queensland established the importance of overland flow as a hydrologic pathway in this tropical rainforest environment. Since this pathway is ‘fast’, transmitting presumably ‘new’ water, its importance should be reflected in the stormflow chemistry of South Creek: the greater the volumentric contribution to the stormflow hydrograph, the more similarity between the chemical composition of streamwater and of overland flow is to be expected. Water samples were taken during two storm events in an ephemeral gully (gully A), an intermittent gully (gully B) and at the South Creek catchment outlet; additional spot checks were made in several poorly defined rills. The chemical composition of ‘old’ water was determined from 45 baseflow samples collected throughout February. The two events differed considerably in their magnitudes, intensities and antecedent moisture conditions. In both events, the stormflow chemistry in South Creek was characterized by a sharp decrease in Ca, Mg, Na, Si, Cl, EC, ANC, alkalinity and total inorganic carbon. pH remained nearly constant with discharge, whereas K increased sharply, as did sulfate in an ill-defined manner. In event 1, this South Creek stormflow pattern was closely matched by the pattern in gully A, implying a dominant contribution of ‘new’ water. This match was confirmed by the spot samples from rills. Gully B behaved like South Creek itself, but with a dampened ‘new’ water signal, indicating less overland flow generation in its subcatchment. In event 2, which occurred five days later, the initial ‘new’ water signal in gully A was rapidly overwhelmed by a different signal which is attributed to rapid drainage from a perched water table. This study shows that stormflow in this rainforest catchment consists predominantly of ‘new’ water which reaches the stream channel via ‘fast’ pathways. Where the ephemeral gullies delivering overland flow are incised deeply enough to intersect a perched water table, a delayed, ‘old’ water-like signal may be transmitted.
Just and Carpenter (1980) presented a theory of reading based on eye fixations wherein their "psycholinguistic" variables accounted for 72% of the variance in word gaze durations. This comment raises some statistical and theoretical problems with their use of simultaneous regression analysis of gaze duration measures and with the resulting theory of reading. A major problem was the confounding of perceptual with psycholinguistic factors. New eye fixation data are presented to support these criticisms. Analysis of fixations within words revealed that most gaze duration variance was contributed by number of fixations rather than by fixation duration.
The synthesis of galactose clusters that are linked to a steroid moiety by a peptide-like spacer unit is described. The galactose cluster is obtained by Koenigs-Knorr glycosylation of TRIS-Gly-Fmoc (2b) under Helferich conditions. Peptide and ester bonds are formed after activation of carboxylic acids as diphenylthiophene dioxide (TDO) esters. 6a is synthesized in a convergent way by coupling of (Ac4Gal)3-TRIS-Gly (3e) with cholesteryl TDO succinate (5b). Coupling of (Ac4Gal)3-TRIS-Gly hydrogen succinate (3f) with Gly-O-Chol (5d) by means of EEDQ yields 6d. Reaction of (Ac4Gal)3-TRIS-Gly-SUCC-O-TDO (3g) with 25-hydroxycholesterol leads in a linear sequence to the oxysterol derivative 6f. Selective cleavage of the acetyl groups from galactose units yields the known compound 6b and the new derivatives 6e and 6g.
The complement fragments C3a and C5a were purified from zymosan-activated human serum by column chromatographic procedures after the bulk of the proteins had been removed by acidic polyethylene glycol precipitation. In the isolated in situ perfused rat liver C3a increased glucose and lactate output and reduced flow. Its effects were enhanced in the presence of the carboxypeptidase inhibitor DL-mercaptomethyl-3-guanidinoethylthio-propanoic acid (MERGETPA) and abolished by preincubation of the anaphylatoxin with carboxypeptidase B or with Fab fragments of an anti-C3a monoclonal antibody. The C3a effects were partially inhibited by the thromboxane antagonist BM13505. C5a had no effect. It is concluded that locally but not systemically produced C3a may play an important role in the regulation of local metabolism and hemodynamics during inflammatory processes in the liver.
In the isolated rat liver perfused in situ stimulation of the nerve bundles around the portal vein and the hepatic artery caused an increase of urate formation that was inhibited by the α1-blocker prazosine and the xanthine oxidase inhibitor allopurinol. Moreover, nerve stimulation increased glucose and lactate output and decreased perfusion flow. Infusion of noradrenaline had similar effects. Compared to nerve stimulation infusion of glucagon led to a less pronounced increase of urate formation and a twice as large increase in glucose output but a decrease in lactate release without affecting the flow rate. Insulin had no effect on any of the parameters studied.
Increase in prostanoid formation in rat liver macrophages (Kupffer cells) by human anaphylatoxin C3a
(1993)
Human anaphylatoxin C3a increases glycogenolysis in perfused rat liver. This action is inhibited by prostanoid synthesis inhibitors and prostanoid antagonists. Because prostanoids but not anaphylatoxin C3a can increase glycogenolysis in hepatocytes, it has been proposed that prostanoid formation in nonparenchymal cells represents an important step in the C3a-dependent increase in hepatic glycogenolysis. This study shows that (a) human anaphylatoxin C3a (0.1 to 10 mug/ml) dose-dependently increased prostaglandin D2, thromboxane B, and prostaglandin F2alpha formation in rat liver macrophages (Kupffer cells); (b) the C3a-mediated increase in prostanoid formation was maximal after 2 min and showed tachyphylaxis; and (c) the C3a-elicited prostanoid formation could be inhibited specifically by preincubation of C3a with carboxypeptidase B to remove the essential C-terminal arginine or by preincubation of C3a with Fab fragments of a neutralizing monoclonal antibody. These data support the hypothesis that the C3a-dependent activation of hepatic glycogenolysis is mediated by way of a C3a-induced prostanoid production in Kupffer cells.
"Considerons une particule mobile se mouvant aleatoirement sur la droite (ou sur un segment de droite). Supposons qu'il existe une probabilite F(x,y;s,t) bien definie pour que la particule se trouvant a l'instant s dans la position x se trouve a l'instant t (> s) a gauche de y, probabilite independante du mouvement anterieur de la particule...." Mit diesen Worten beginnt eines der berühmtesten mathematischen Manuskripte des letzten Jahrhunderts. Es stammt vom Soldaten Wolfgang Döblin, Sohn des deutschen Schriftstellers Alfred Döblin, und trägt den Titel "Sur l'equation de Kolmogoroff". Seine Veröffentlichung verbindet sich mit einer unglaublichen Geschichte. Wolfgang Döblin, stationiert mit seiner Einheit in den Ardennen im Winter 1939/1940, arbeitete an diesem Manuskript. Er entschloss sich, es als versiegeltes Manuskript an die Academie des Sciences in Paris zu schicken. Aber er kehrte nie aus diesem Krieg zurück. Sein Manuskript blieb 60 Jahre unter Verschluss im Archiv, und wurde erst im Jahre 2000 geöffnet. Wie weit Döblin damit seiner Zeit voraus war, wurde erkannt, nachdem es von Bernard Bru und Marc Yor ausgewertet worden war. Im ersten Satz umschreibt W. Döblin gleichzeitig das Programm des Manuskripts: "Wir betrachten ein bewegliches Teilchen, das sich zufällig auf der Geraden (oder einem Teil davon) bewegt." Er widmet sich damit der Aufgabe, die Fundamente eines Gebiets zu legen, das wir heute als stochastische Analysis bezeichnen.
The effect of moderate rates of nitrogen deposition on ground floor vegetation is poorly predicted by uncontrolled surveys or fertilization experiments using high rates of nitrogen (N) addition. We compared the temporal trends of ground floor vegetation in permanent plots with moderate (7–13 kg ha−1 year−1) and lower bulk N deposition (4–6 kg ha−1 year−1) in southern Sweden during 1982–1998. We examined whether trends differed between growth forms (vascular plants and bryophytes) and vegetation types (three types of coniferous forest, deciduous forest, and bog). Trends of site-standardized cover and richness varied among growth forms, vegetation types, and deposition regions. Cover in spruce forests decreased at the same rate with both moderate and low deposition. In pine forests cover decreased faster with moderate deposition and in bogs cover decreased faster with low deposition. Cover of bryophytes in spruce forests increased at the same rate with both moderate and low deposition. In pine forests cover decreased faster with moderate deposition and in bogs and deciduous forests there was a strong non-linear increase with moderate deposition. The trend of number of vascular plants was constant with moderate and decreased with low deposition. We found no trend in the number of bryophyte species. We propose that the decrease of cover and number with low deposition was related to normal ecosystem development (increased shading), suggesting that N deposition maintained or increased the competitiveness of some species in the moderate-deposition region. Deposition had no consistent negative effect on vegetation suggesting that it is less important than normal successional processes.
Recent research has shown that the early lexical representations children establish in their second year of life already seem to be phonologically detailed enough to allow differentiation from very similar forms. In contrast to these findings children with specific language impairment show problems in discriminating phonologically similar word forms up to school age. In our study we investigated the question whether there would be differences in the processing of phonological details in normally developing and in children with low language performance in the second year of life. This was done by a retrospective study in which in the processing of phonological details was tested by a preferential looking experiment when the children were 19 months old. At the age of 30 months children were tested with a standardized German test of language comprehension and production (SETK2). The preferential looking data at 19 months revealed an opposite reaction pattern for the two groups: while the children scoring normally in the SETK2 increase their fixations of a pictured object only when it was named with the correct word, children with later low language performance did so only when presented with a phonologically slightly deviant mispronunciation. We suggest that this pattern does not point to a specific deficit in processing phonological information in these children but might be related to an instability of early phonological representations, and/or a generalized problem of information processing as compared to typically developing children.
Recent work has shown that English-learning 18-month-olds can detect the relationship between discontinuous morphemes such as is and -ing in Grandma is always running (Gomez, 2002; Santelmann & Jusczyk, 1998) but only at a maximum of 3 intervening syllables. In this article we examine the tracking of discontinuous dependencies in children acquiring German. Due to freer word order, German allows for greater distances between dependent elements and a greater syntactic variety of the intervening elements than English does. The aim of this study was to investigate whether factors other than distance may influence the child’s capacity to recognize discontinuous elements. Our findings provide evidence that children’s recognition capacities are affected not only by distance but also by their ability to linguistically analyze the material intervening between the dependent elements. We speculate that this result supports the existence of processing mechanisms that reduce a discontinuous relation to a local one based on subcategorization relations.
How do children determine the syntactic category of novel words? In this article we present the results of 2 experiments that investigated whether German children between 12 and 16 months of age can use distributional knowledge that determiners precede nouns and subject pronouns precede verbs to syntactically categorize adjacent novel words. Evidence from the head-turn preference paradigm shows that, although 12- to 13-month-olds cannot do this, 14- to 16-month-olds are able to use a determiner to categorize a following novel word as a noun. In contrast, no categorization effect was found for a novel word following a subject pronoun. To understand this difference we analyzed adult child-directed speech. This analysis showed that there are in fact stronger co-occurrence relations between determiners and nouns than between subject pronouns and verbs. Thus, in German determiners may be more reliable cues to the syntactic category of an adjacent novel word than are subject pronouns. We propose that the capacity to syntactically categorize novel words, demonstrated here for the first time in children this young, mediates between the recognition of the specific morphosyntactic frame in which a novel word appears and the word-to-world mapping that is needed to build up a semantic representation for the novel word.
Many methods have been proposed for the simulation of constrained mechanical systems. The most obvious of these have mild instabilities and drift problems. Consequently, stabilization techniques have been proposed A popular stabilization method is Baumgarte's technique, but the choice of parameters to make it robust has been unclear in practice. Some of the simulation methods that have been proposed and used in computations are reviewed here, from a stability point of view. This involves concepts of differential-algebraic equation (DAE) and ordinary differential equation (ODE) invariants. An explanation of the difficulties that may be encountered using Baumgarte's method is given, and a discussion of why a further quest for better parameter values for this method will always remain frustrating is presented. It is then shown how Baumgarte's method can be improved. An efficient stabilization technique is proposed, which may employ explicit ODE solvers in case of nonstiff or highly oscillatory problems and which relates to coordinate projection methods. Examples of a two-link planar robotic arm and a squeezing mechanism illustrate the effectiveness of this new stabilization method.
A Hamiltonian system in potential form (formula in the original abstract) subject to smooth constraints on q can be viewed as a Hamiltonian system on a manifold, but numerical computations must be performed in Rn. In this paper methods which reduce "Hamiltonian differential algebraic equations" to ODEs in Euclidean space are examined. The authors study the construction of canonical parameterizations or local charts as well as methods based on the construction of ODE systems in the space in which the constraint manifold is embedded which preserve the constraint manifold as an invariant manifold. In each case, a Hamiltonian system of ordinary differential equations is produced. The stability of the constraint invariants and the behavior of the original Hamiltonian along solutions are investigated both numerically and analytically.
Many methods have been proposed for the stabilization of higher index differential-algebraic equations (DAEs). Such methods often involve constraint differentiation and problem stabilization, thus obtaining a stabilized index reduction. A popular method is Baumgarte stabilization, but the choice of parameters to make it robust is unclear in practice. Here we explain why the Baumgarte method may run into trouble. We then show how to improve it. We further develop a unifying theory for stabilization methods which includes many of the various techniques proposed in the literature. Our approach is to (i) consider stabilization of ODEs with invariants, (ii) discretize the stabilizing term in a simple way, generally different from the ODE discretization, and (iii) use orthogonal projections whenever possible. The best methods thus obtained are related to methods of coordinate projection. We discuss them and make concrete algorithmic suggestions.
Es gibt aus unserer Sicht eine Reihe von Gründen, sich in der gewerkschaftlichen Bildungsarbeit von der Dominanz des Lehrplans abzuwenden und sich an Stelle dessen dem Lernenden in einer Weise zuzuwenden, die seine Deutungen, seine Handlungsmotive und seine Lerninteressen in den Vordergrund stellt. Für den Bildungspraktiker ergeben sich Gründe vor allem aus der wiederholten Erfahrung von Diskrepanzen. Erstens die Diskrepanzen, die zwischen der Definition von Lehrzielen und ihrem Erreichen in der Erwachsenenbildung bestehen. Zweitens die Diskrepanzen, die zwischen dem tatsächlich erlernten Wissen und seiner Umsetzung und Anwendung in der Praxis sich auftun. (aus dem Inhalt)
Im vorliegenden Beitrag wird an Hand dreier Beispiele der Einsatz von optischer Sensorik zur Produktcharakterisierung dargestellt, nämlich Untersuchungen zum O2-Gehalt in Fruchtsäften, zur Isotopiesignatur von CO2 in Mineralwässern und zu Lichtstreueigenschaften eines Sonnenschutzmittels. Inhalt: Bestimmung von O2 mit Lumineszenzsonden Isotopenselektive Bestimmung von CO2 mit TDLAS Optische Charakterisierung stark streuender Materialien mit Photonendichtewellen
An approach to the development of fluorescent probes to follow polymerizations in situ using fluorinated cross-conjugated enediynes (Y-enynes) is reported. Different substitution patterns in the Y-enynes result in distinct solvatochromic behavior. β,β-Bis(phenylethynyl)pentafluorostyrene 7, which bears no donor substituents and only fluorine at the styrene moiety, shows no solvatochromism. Donor substituted β,β-bis(3,4,5-trimethoxyphenylethynyl) pentafluorostyrene 8 and β,β-bis(4-butyl-2,3,5,6-tetrafluorophenylethynyl)-3,4,5-trimethoxystyrene 9 exhibit solvatochromism upon change of solvent polarity. Y-enyne 8 showed the largest solvatochromic shift (94 nm bathochromic shift) upon changing solvent from cyclohexane to acetonitrile. A smaller solvatochromic response (44 nm bathochromic shift) was observed for 9. Lippert–Mataga treatment of 8 and 9 yields slopes of -10,800 and -6,400 cm -1, respectively. This corresponds to a change in dipole moment of 9.6 and 6.9 D, respectively. The solvatochromic behavior in 8 and 9 supports the formation of an intramolecular charge transfer (ICT) state. The low fluorescence quantum yields are caused by competitive double bond rotation. The fluorescence decay time of 9 decreases in methyltetrahydrofuran from 2.1 ns at 77 K to 0.11 ns at 200 K. Efficient single bond rotation in 9 was frozen at -50 °C in a configuration in which the trimethoxyphenyl ring is perpendicular to the fluorinated rings. 7–9 are photostable compounds. The X-ray structure of 7 shows it is not planar and that its conjugation is distorted. Y-enyne 7 stacks in the solid state showing coulombic, actetylene–arene, and fluorine–π interactions.
Investigations with frequency domain photon density waves allow elucidation of absorption and scattering properties of turbid media. The temporal and spatial propagation of intensity modulated light with frequencies up to more than 1 GHz can be described by the P1 approximation to the Boltzmann transport equation. In this study, we establish requirements for the appropriate choice of turbid model media and characterize mixtures of isosulfan blue as absorber and polystyrene beads as scatterer. For these model media, the independent determination of absorption and reduced scattering coefficients over large absorber and scatterer concentration ranges is demonstrated with a frequency domain photon density wave spectrometer employing intensity and phase measurements at various modulation frequencies.
Die Anwendung von optischen Parametern zur Stoffcharakterisierung wird diskutiert. Dabei ist der Schwerpunkt der Diskussion auf absorptions- und fluoreszenzspektroskopische Methoden gesetzt. Beide Methoden können schnell und zuverlässig – auch im on-line Betrieb – eingesetzt werden. Der Beitrag soll einen Überblick über die grundlegenden Möglichkeiten der Anwendung beider Methoden geben.
China ist auf dem Weg zu einer offeneren Gesellschaft mit zunehmender Partizipation, größerer rechtlicher Sicherheit und individueller Autonomie. Der Staat zog sich aus vielen Bereichen zurück, ökonomische Ziele bestimmen seine Prioritäten. Die Entwicklungserfolge brachten jedoch eine Legitimationskrise des Staates mit sich. Vier Dilemmata, die China heute konfrontieren, werden aufgezeigt und Hypothesen zur Charakterisierung des chinesischen party state diskutiert.
Chinas Wandel und die Welt
(2006)
Wie stellt sich das Verhältnis zwischen China und der Welt im 21. Jahrhundert dar? Die Autorin, Politikwissenschaftlerin aus Peking, verweist auf die aktuelle Debatte in China, in der das Primat der Innenpolitik, regionaler Multilateralismus und harmonische Weltordnung intensiv diskutiert werden. China habe nicht vor, das internationale System herauszufordern oder zu zerstören. Vielmehr sei es um stärkere Einbindung bemüht.
First studies of electron transfer in [N]phenylenes were performed in bimolecular quenching reactions of angular [3]- and triangular [4]phenylene with various electron acceptors. The relation between the quenching rate constants kq and the free energy change of the electron transfer (ΔG0CS ) could be described by the Rehm-Weller equation. From the experimental results, a reorganization energy λ of 0.7 eV was derived. Intramolecular electron transfer reactions were studied in an [N]phenylene bichomophore and a corresponding reference compound. Fluorescence lifetime and quantum yield of the bichromophor display a characteristic dependence on the solvent polarity, whereas the corresponding values of the reference compound remain constant. From the results, a nearly isoenergonic ΔG0CS can be determined. As the triplet quantum yield is nearly independent of the polarity, charge recombination leads to the population of the triplet state.
According to the author, chairman of the Foreign Policy Committee in the German parliament (Bundestag), German foreign policy is based on a strong parliamentary consensus: continuing as a Western European country, co-operating with our partners in the European Union and the NATO, acting as a responsible member of UN and OSCE. Germany firmly stands up to these basic decisions, also today in a changed world, concentrating on reaching two major goals: building up a new security architecture for Europe as a whole and reuniting Europe by enlarging the European Union. Moderate and co-operate in style, Germany will continue to be a reliable partner, willing and ready to accept even more responsibilities in Europe and beyond Europe.
The ten-years presidency of Alberto Fujimori in Peru is a classic example of the sort of hybrid democracy that emerged in various Latin American countries in the 1990s, combining a mixture of democratic and clearly non-democratic elements. Fujimori was one of the more autocratic Latin American leaders of the 1990s, he is being the only regime formally to break with pre-existing constitutional rules. Closely tied to the military and intelligence apparatus, his government involved a concentration of political power that reduced the scope and autonomy of other branches of the state. But, unlike previous Latin American military dictatorships, Fujimori’s government enjoyed a considerable popularity, born out of disaffection for representative institutions. The article argues, however, that these characteristics of apparent strength carried within them the seeds of their own destruction. Far from establishing lasting political stability, the regime was weakly based. Within six weeks of his inauguration for a third term in July 2000, Fujimori was obliged to announce his intention to withdraw from politics. Two months later, he was ousted altogether.
After the democratic euphoria of the early 1990s, today the "third wave of democratization" seems to be less a triumph of political liberalism and much more a success story of a "defective" form of democracy. The authors argue that none of the strategies which can be found in contemporary democratization studies is satisfactory. They offer an alternative two-step-strategy of (1) specifying the root concept of democracy and (2) building subtypes of democracy which are based on this specified root concept. In doing so, the authors conceptualize the model of embedded democracy, from which they generate the concept of "defective democracy" and present a typology of these "defective democracies".
While at the time of Goethe, Turkey and other parts of the world seemed to be far away. Today’s Germany is confronted with the pressure of globalization. With regard to environmental issues or the threat of terrorism, international co-operation and combined efforts are strongly demanded. Unfortunately, the German higher education system is not prepared to face these challenges. The article calls for the education of an elite at German universities, which is fit to work in national as well in international institutions. The author presents the Master’s of International Relations coursework at the Technical University of Dresden.
Confronted with new dimensions of international problems, Germany needs a new foreign policy elite that is able to deal with the pending challenges in world politics. Therefore, the author points out, it is necessary to reorganize the German way to recruit personal for international tasks and the manner of its education at German universities. Furthermore, the German society should revise its general hostile attitude towards the elite and recognize it as an important driving force in politics.
The author detects some of the causes for the less than satisfactory representation of the German foreign policy elite on the international level within the German university structure. The article also reflects upon the issue of the 'content' of a possible and desirable German 'Weltpolitik' which is seen in Global Public Policy - an example of which is provided and reasons given for the ability of the German elite to be proactively engaged in the promotion and management of Global Public Policy Networks.
The security policy of Pakistan is aimed at a reduction of nuclear threats in the South Asian region. It is only natural, that a state, whose national security is endangered by a mighty neighbor, will have to strengthen its defense capacities. Unfortunately, the effective collective measures to prevent and to remove threats to peace and international security as laid down in the Charter of the United Nations prove to be an unreliable promise. Ever since India carried out its first nuclear tests in 1974, Pakistan has been forced into a race to catch up with the capabilities if its neighbor. Nevertheless, Pakistan chose a minimalist approach and refrained from converting its nuclear capabilities into weapon systems. Pakistan is against an arms race in the South Asian region, and opposes the concept of first use of nuclear weapons. To ensure lasting peace, a common vision on disarmament is necessary.
The comprehensive transformation after the breakdown of communist rule was also reflected in a profound change in national policies. The dominating approach in the days of the old regime were grounded in the concept of a single nation state. The years since 1989 witnessed a rise of new democratic attitudes towards national and ethnic minorities. National minorities make up 3 to 4% of the population. Their total number is estimated to be approximately 1.0 to 1.3 Million people. Contemporary national policy rejects the principle of assimilation (polonization) of national and ethnic minorities while supporting their integration.
The Bush Administration supported, earlier than some West European NATO partners, the reunification of the two German states. When the crisis of the political system in East Germany escalated in 1989, the US-government tried to link the support for far-reaching democratic reforms with a rapid involvement of all NATO members in the unification strategy of the Bonn government. For the Bush administration, the most complicated task was to convince the Moscow leadership that a loss of the GDR as a strategic domain in the Central Europe, and NATO membership of a united Germany, would not undermine security interests of the Soviet Union. At the End of the East-West-Conflict, German unification was in full accordance with the global strategic interests of the United States.
The end of the Cold War opened a window for a new era in world security. Instead of rising to this extraordinary occasion, the United States has adopted a regressive Great Power approach to military security. Rather than promote 'win-win' solutions for peace, security, disarmament, and democracy, it treats international security as a 'zero-sum' game. This article discusses examples in the areas of military spending, military research and development, and arms production and export. It also looks at US policy regarding the use of force, including the role of the United Nations, military intervention in other nations, military alliances, and multilateral military action. In conclusion, the article comments on whether we can expect more constructive action under a new administration and congress.
Ghana’s local government system has been subject to various reform attempts which all involved some sort of decentralisation. This article tries to link decentralisation to changing national policy frames and the various governments’ need to maintain political control. Consequently, decentralisation becomes a dependent variable of the so called bureaucratic development state. After a brief discussion of the colonial and post-colonial local government system in Ghana, emphasis is placed on the crisis of the post colonial state and the emergence of a new local government system in 1988 - which was successfully transformed into the administrative system of Ghana’s 4th republic after 1992. Local participation has been substantially improved an sustained by the introduction of the District Assemblies Common Fund in 1993 which transfers 5% of the national tax income to the districts.
During the 1990s the relations between Russia and China developed intensivly. At the highest level, between 1992 and 1998, six summits took place. Both countries declared a "strategic cooperative partnership", designed to contribute to a "multipolar world" and a "well-balanced international political order". Both Russia and China endaveour to use their alliance to raise the importance of their respective places compared against the USA, EU and Japan. Policy changes in Russia have been especially instrumental in solving former conflicts between the two countries, and in developing a new quality to the bilateral relationship. Both countries have shown a strong interest in political and territorial integrity, both expect much from the markets, they need each other as partners in developing new weapon systems and both expect many advantages by normalising the situation along their joint borderline. Though future prospects of a Russian-Chinese partnership are reasonably foreseeable, it is clear that differences will remain. A complete balance of interests may not be seen.
Considering the problems of retirement security systems leads one to look beyond the border in order to get a glimpse of the way things work in other societies. Contrary to formal public pension schemes in South American and East European industrial countries, the predominant pension system in Asia is of an informal nature, based upon the extended family structure. The rise of the city-state of Singapore has been accompanied by the development of a comprehensive social security system within the framework of the Central Provident Fund (CPF). The CPF is based on a symbiosis of Western social concepts and Eastern pragmatism. The article gives an insight into the development of this system, and the way it works underpresent political and economic conditions.
The border between Germany and Poland today is undisputed and definite, and thought to promote great co-operation and a culture of good-neighbourliness. Relations between the two governments are progressing nicely. But public opinion and behaviour are still lagging behind. The author describes how thought and emotions on the Polish side are still influenced by memories of the past, especially of the German occupation during the Second World War, and the slow pace of progress in overcoming that memory. He shows that the "shadows of history" have strongly influenced Polish politics in the context of German reunification. Special emphasis is given to the role of the Catholic Church in the controversial debate on the relations towards Germany in the 1950s and 1960s.
The end of the cold war division of the Baltic Sea in 1989, and the three Baltic states’ return to independence in 1991 created new opportunities for the decision-makers of the area, as well as new possibilities for fashioning security in the region. This article will examine the security debate affecting the Baltic Sea region in the post-cold war period, and in particular, the relevance of the European Union to that debate. The following section will examine various concepts of security relevant to the Baltic region; the third section looks at the EU and the Baltic area; and the last part deals with the implications that EU membership by the Baltic Sea states may have for the security of the Baltic Sea zone.
The article mobilises the concept of strategic culture in order to identify the impact of history upon contemporary security policy. The article will first look at the "wholesale construction" of a strategic culture after the Second World War in West Germany before exploring its impact upon security policy since the end of the Cold War in two areas: the Bundeswehr's out-of-area role and conscription. The central argument presented here is that the strategic culture of the former Federal Republic now writ large on to the new united Germany sets the context within which security policies are designed. This strategic culture, as will be argued, acts as both a facilitating and a restraining variable on behaviour, making certain policy options possible and others impossible.
The author shows the strong relation between political developments, frontiers and their graphical representation on maps. Human rights, economic globalisation and the European integration process do change national policy and erode classical border lines. Still today, maps with lines and colours as their main graphic elements represent the world of the 19th century with separate national states in atlases, schoolbooks and electronic media. The main argument of the article insists on stressing the political character of maps and showing the contradiction between the cartographic picture of the world and the recent international transformations. The author concludes with the question of whether maps can reproduce these new developments at all.
The fiscal reform of 1994 was introduced to strengthen the redistributive function of central government. In the aftermath of the reform it turned out, however, that the dominating cleavage is not necessarily the rivalry between "centre" and "regions", mainly because of the very complex relationships within the provinces. Though taxation itself is highly centralized there is a growing tendency of expensation of "extra-budget revenues". That is why the share of the central government concerning all revenues fell to 27%, falling considerably short of the purpose of the fiscal reform to increase the rate of central redistribution to 60% of the national fiscal ressources. Local communities have turned out to be rather successful in collecting non-tax revenues, concentrating on the non-state sectors of the economy. The problem is not so much the threat of fiscal decentralization but the definition of rules and procedures in the relationship between centre, provinces and local administrations.
In 1988, the Government of the People’s Republic of China established the island of Hainan as a province and made it a Special Economic Zone. While the hope for a spectecular economic take off was the main driving force behind this decision, it provided China with an area where far reaching trial-and-error politics could be. Hence the new provincial government was granted the privilege of setting its own legal framework for administering the special economic policies and establishing a governmental structure guided by the principle of "Small government, big society". Although some of the efforts to reduce the administration in terms of scope and resources, to develop and strengthen non-governmental organizations and provide economic actors with a minimum of freedom and reliability proved successful, the overall results are mixed: While well-being and opportunities for self-fulfillment clearly grew, political participation is still confined to areas defined by the Communist Party.
Auf der Suche nach einem neuen Ideal : zu Theorie, Norm und Praxis des Rechtsstaats in der VR China
(1998)
Besides establishing a legal system for the needs of economic construction, legal theory and legislation in China are extending their concern from an instrumental concept of law to a more value based notion, thus supplementing "rule by laws" by elements of the "Rechtsstaat" (rule of law). Whereas legal and constitutional theory take more and more bold views concerning integrating structures of checks and balances and division of powers into the legal system, urging for statutory control of the ruling party, for reforming the National People’s Congress into a responsible legislative body based on real representation of the people, providing for constitutionality of legal norms by a system of judicial review etc., legislation has started to deal with certain aspects of the Rechtsstaat in fields as administrative, criminal and criminal procedure law. In view of grave problems of implementation, this legislation may partly be regarded more to be an expression of intention to develop gradually a new ideal and a new legitimation for the political system than well established actual practice.
In August 1997 the Australian Government released the first White Paper ever issued on its foreign policy. As one important element, this essay tries to delineate the pro Asia-Pacific shift of Australia’s international economic and security orientations, particularly since the early 1970s - a foreign policy which could rest upon an certain bipartisan basis. The recently launched White Paper represents a new reflection upon Australia’s national interests and a soft relativisation of the strong emphasis on regional and multilateral foreign policy performances of former governments. According to a least the author’s judgement, the fundamental legacy of Australia’s international relations remain: a certain (a definite?) contradiction between the country’s predominant cultural and ethnic (!) heritage on the one hand and its geographical location on the other.
Since 1989 the German-Czech relationship has been burdened by the problem of a just assessment of World War II and the following forced transfer of the Sudeten Germans. Why are democrats on both sides who acknowledge the same values and principles unable to reach an agreement about crucial events in the past? The political and legal differences imply a moral dissent which is not being discussed systematically. The article tries to investigate the deficits of the moral arguments on both sides.
The economic reforms in the German Democratic Republic during the 60s, known as "New Economic System" (NES) or "Economic System of Socialism" (ESS) have been characterised by historians as truly technocratic. What is often not known is the fact, that during the first debate on economic reform in Eastern Germany in 1954-1958 the idea of democratic reform was prominent thanks to the role and writing of the outstanding GAR economist Fritz Behrens, who favoured a diminished role of the state in the economy and the self-rule of the workers in the factories. Behrens and his followers were denounced by party leader Walter Ulbricht as "revisionist". Together with his economic advisor, Wolfgang Berger, originally a scholar of Behrens’, he started the NES and ESS in the 60s. Behrens remained barred from the management of the reform, in which Berger plaid a prominent role. When Behrens began again to publish his demands for a democratic reform in 1967, thus intervening in the progress of the reform, he was forced to leave his academic job into retirement. In 1971, Erich Honekker succeeded Ulbricht. The economic reform was stopped. And Berger lost his job, too.
Nowadays the term "technocracy", which means the elimination of politics by the rule of scientific reasoning, is most often used with a quite negative overtone. Technocrats are described as experts without morals, able to function in any kind of political system. Nevertheless one should remember that the technocratic idea contained from the very beginning a strong ethic element: conventional political power as an instrument of repression should be replaced by the rule of sciences as an instrument to improve human life. Although the idea of eliminating politics by "science-based" decisions of an autocratic leadership has been widely used to legitimate totalitarian rule, it is obvious, that clear technocratic reasoning and decision making do not go conform with the functioning of a totalitarian system. On the contrary, technic and technologic innovation accelerated the breakdown of totalitarianism. The complex character of modern societies calls for regulation by markets and pluralistic political systems. The evolution of our technical civilization improved the conditions for democratic selforganisation.
After overcoming the divergence from the general features of Western and international urban development caused by Germany's division, Berlin is catching up with and imitating almost all features of post-modern city formation constituted and demonstrated in the last two decades. Berlin is trying to make good its backwardness and to keep abreast of the metropolis in Europe and the world through a strategy aimed at a cultural re-evaluation of urban structure and architecture. The so-called Prussian style based on the Classicist tradition of the beginning of the 19th century is the historical and asthetic horizon. A small administrative and architectural elite pushing the redefinition of the social, political and asthetic meaning of public space ignores consciously the architectural reality in the Eastern and Western parts of the city. Crucial objectives are the cultural, political and economic recapturing of the traditional centre of Berlin profoundly marked by its socialist past and the protection of middle class interests.
In the rapidly growing literature on globalization, many authors have emphasized the apparent disembedding of social relations from their local-territorial preconditions. Such arguments neglect the relatively fixed and immobile forms of territorial organization upon which the current round of globalization is premised, such as urban-regional agglomerations and territorial states. Drawing on the work of David Harvey and Henri Lefebvre, this article argues that processes of reterritorialization - the reconfiguration of forms of terrritorial organization such as cities and states - must be viewed as an intrinsic moment of the current round of globalization. Globalization is conceived here as a reterritorialization of both socio-economic and political-institutional spaces that unfolds simultaneously upon multiple, superimposed geographical scales. The ongoing restructuring of contemporary urban spaces and state institutional-territorial structures must be viewed at once as presupposition, a medium and an outcome of this highly contested dynamic of global spatial restructuring. New theories and representations of the scaling of spatial practices are needed to grasp the rapidly changing territorial organization of world capitalism in the late 20th century.
J. Kiaupiene, a severe critic of Kosman’s ideas, presents a different view on Lithuanian history. Kosman's description of Lithuania's past is neither exact nor new. Scholars in Russia, Poland and Belorussia have interpreted Lithuania's history in very different ways. The reason for this variety is the difference of national interests. Kosman's view reflects Polish messianism and cultural hybris. But even among Lithuanian scholars there are conflicting views on this nation's history and cultural identity.
Lithuania and Poland had cooperated for centuries and even created a political union. The pacts had been very useful for both sides and consequently, the peoples and especially the Lithuanian elite was ready to absorb parts of the Polish culture. Lithuania broke with this tradition dating back to the Middle Ages only after the first division of Poland. During 1944- 1990, the so-called "Soviet period in Lithuania", two different processes could be observed: Russification and Lithuanification. Although dependent on Moscow, the leading Lithuanian politicians never forgot Lithuanian interests and supported the national conscience. After Lithuania gained independence in 1990, a huge wave of national enthusiasm swapped over the country. In the meantime, politicians came back to reality: The independence of Lithuania seems consolidated and the old tradition to re-establish the Polish-Lithuanian cooperation seems to be on the run since Aleksander Kwasniewski had visited Lithuania in January 1996.
Germany gained its unity, but the restoration of virtual national cohesion presents itself as a lasting problem. The rebuilding of common national identity forms one complex aspect. Particular West and East German political, social and cultural features still exist. The East Germans brought elements of a peculiar identity into the unity; as a repercussion of some setbacks in their position and of some actual inter-German distinctions, their peculiarities are not yet in retreat. They prolong their role as conventional feelings, in temporary behaviours as an answer to their actual stance, and to a certain extent also with traits staged and suggested by entrenched media interpretations about the presently hampered inter-German evolution.
The self-awareness of the subject is always dependent on interaction with others. Thus, self-awareness and social awareness are two sides of the same coin. The Self is not only to be won through social ties with others, but at the same time through distance from them. So long as this does not lead to isolation, there is a possibility of working out common values and identities. The construction of common identities is a process of social definition and construction. Materials for this are space-time, social, cultural, economic, and administrative-legal attributes which are transformed into identity-building attributes. Ethnic movements are often portrayed as social dramas. The processes of institution-building and nation-building never stop. Their supporters relate identity management to the central nation-state and consensus, possible minorities count on a strategy of differentiation and conflict instead.
The attitude of the East Germans to the Polish is burdened with the heritage of the past. After 1945 the composition of the population on both sides of the new border along the Oder and Neisse rivers changed drastically. On the eastern side the Germans were expelled and Polish people were settled. On the western side many expelled Germans found a new home. Despite the fact that the GDR signed the Oder-Neisse border treaty, the ruling communist party (SED) did not encourage contacts between the people living on both sides of Oder and Neisse in the following years. The policy of the SED towards the Polish communists during the whole period between 1946-1989 was characterised by arrogance and suspicion, at times falling back on old anti-Polish stereotypes. Especially in the 1980s, the GDR tried to prevent the influence of Solidarnosc and dissident ideas from entering the country. Despite this policy, substantial personal contacts developed, particularly in the 1970s when the border was fully opened. The authors argue that current German-Polish relations should make use of these experiences.
Since the end of the year 1989 Liberia has been ravaged by a bloody civil war. It has almost completely destroyed the state structure of Liberian society which was manipulated by military ruler Samuel Doe and a small elite with the ends of amassing wealth and retaining power during the decade of 1980 to 1989. The state and almost all political institutions were stripped of credibility and legitimacy. During the war it was easy for the warlords of the various factions and their mostly young supporters to seize power and the remaining resources of the country. They established a radical free market system with the help of internationally operating companies and banks, protecting it by terror. Nearly two thirds of the population have left their homes and now live as refugees abroad, in the capital Monrovia or in Buchanan, where remnants of state structure and a weak civil society survive under the protection of a regional intervention army (Ecomog). By discussing different sociological explanations, the author traces the origins of the civil war and of its extreme brutality.
Gomułka’s harsh criticism of the Stalinist past and the introduction of liberal elements into the public life of Poland was not welcomed by the East German leadership. Ulbricht demanded full support for the sovereignty of the GDR and tried to prevent any independent Polish moves to come to terms with the Federal Republic. The Polish leadership strived towards a closer economic integration with the GDR and Czechoslovakia to foster industrial development in Poland and to bind the East German state more closely into the "socialist camp". These ideas were flatly rejected by the GDR. The level of economic interdependence between the two German states and the advantages of the GDR resulting from the "intra-German" status of trade and transfer of technologies provoked Gomułka’s distrust. Relations worsened even more when, towards the end of his time in power, Ulbricht moved towards a rapprochement with the FRG and showed some readiness to question the Görlitz treaty on the German-Polish border line.
The transition and transformation within the three countries dealt with are still in process. In her essay, the author analyses whether there is a need for Poland to re-define its relationship to Germany and Russia, whilst searching for a new identity and a new place within Europe. She argues that there is a set of historical and geopolitical reasons for doing so. But whilst the Polish aim is to normalise its relationship to its neighbours, the perception of Russians and Germans in Poland is rather different. On the one hand, in the Polish people opinion, Germany is the main promoter of their European institutional integration wishes. On the other, relatively aggressive attitude towards Russia can also be identified. The essay is a strong plea for mutual responsibility and co-operation in favour of peace and security in Europe. Additionally Russia is to be regarded as part of European history, and should thus be involved in the European political process.
The fatal "eye disease" that afflicts Realists and Neorealists, and even infects some self-styled Institutionalists and Constructivists, has several causes. In his polemical essay, the author defines these as historicism, the legalistic bias, the underestimation of non-state actors and the overestimation of the state as such. Discussing the linkage between loyality, ethnicy, and politics, he strongly argues for recognition of the fact that the world is groping for new political arrangements for which we simply do not have the appropriate ideas or words to describe. In the future, the range of political identities and loyalities in the global culture of "fragmegration" will extend beyond traditional multiculturalism.
The post cold war world order is popularly discussed in terms of what Samuel Huntington has called the "clash of civilizations". The authors hold that Huntington is just a prominent example of the trend which constructs geopolitical identities based on ethnic definitions of world regions, where ethnicitiy is understood to be a primordial, transhistorical and static understanding of cultural identities. In their paper, they extensively deconstruct this concept of ethnicity, drawing parallels with the history of nationalism and nation-building, and analyze its functions for legitimizing projects of building exclusive economic blocs in Europe, America and Pacific Asia. At present, ethnic concepts of world regions are competing with liberal, non-ethnic identities of the three world regions. Finally, the dangerous potentials of ethnic regionalization are discussed. From a peace research perspective, support for a common global identity of "mankind" is strongly advocated.
Observers of international politics have been conscious of the growing international involvement of non-central governments (NCGs), particularly in federal systems. These have been supplemented by the internationalisation of subnational actors in quasi-federal and even unitary states. One of the difficulties is that analysis has often been locked into the dominant paradigm debate in International Relations concerning who and who are not significant actors. Having briefly explored the nature of this changing environment, marked by a growing emphasis on access rather than control as a policy objective and the emergence of what is termed a 'catalytic diplomacy', the discussion focuses on the need for linkage between the levels of government in the pursuit of international as well as domestic policy goals. The nature of linkage mechanisms are discussed.
Are we witnessing a decline of war, the spread of violence or both? The growing number of wars and genocids conveys the impression of uncontrolled violence. Is there any possibility to overcome belligerent conflicts between states? Do imply social, technological, cultural or even anthropological changes moments which could shift the ground of state’s rivalry towards non-belligerent relationships? Peace trough interdependence and democracy seems possible. The priorities of modern states cannot be thought on the basis of attributes like sovereignty and territoriality. The peaceful 'bourgeois islands' not only bring about prosperity but increasing social exclusion as well. New phenomenon of ethnicism and religiosity often originate from, around and in their midst. Threats arising from terrorism and racial or religious riots are the consequences. There are two options, the author considers as possible: an "embourgeoisement" of the "barbarians" or a "barbarisation of the bourgeois". Or is there a new political form emerging?
The failure of politics is closely connected with deeply rooted misconceptions about the term politics. The author argues that a re-reading of Immanuel Kant's work "The Perpetual Peace" written 200 years ago offers a challenging possibility for a new conceptualization of politics, morality and peace. Morality is seen by Kant as an essential dimension of politics and the implementation and acknowledgement of laws by moral demands is defined as a precondition for a community of free citizens. In its public discourse politics does require law and morality. Deriving future rights from existing laws is one of the most favored argumentation used by politicians in the public. If the needs of law and justice are interpretated by politicians in their own interest, i.e. above all guarantees for the realization of political selfdetermination, then a real chance will exist for improving peace in the future.
The article argues that the concept of statehood is not functioning any longer. It exists a crisis for the international legal order which is represented by the failure of state to maintain order within its borders. The problem of violence in international relations are connected to the implosion of a considerable number of the state entities in the contemporary international society. The federalist institutional approach in international law and international theory could not contribute in an appropriate way to the solution of the "problem of violence", because it supposes a willingness on the part of states to do so. Only the concept of "national interest", in a sociological sense, connected to the development of a discource of solidarity and mutual responsibility between the "West" and the "rest of the world" offers the possibility to create a common consciousness which could make it easier to overcome the contemporary crises for the international legal order.
The Chinese coastal cities play an increasing economic role in the Yellow Sea region. The inclusion of these cities into the intra Asian economic cooperation is accomplished not only in the conventional sphere of trade but also by a growing involvement in telecommunication networks, technological exchange and the circulation of human resources. That is why these cities emerge as autonomous actors in the East Asian integration process. In this context national states face deep structural change, especially in the field of sovereignty and territory. Concerning the internal situation of China, this change could also cause a turn over of the relationship between the central government and the regions.
There is sufficient evidence of integration processes in the Asia-Pacific rim. But these processes differ profoundly from the European case. On the other hand integration theory up to the present day has been based mainly on the European evidence. Does this mean, that conventional integration theory is irrelevant in the case of the Asia-Pacific development? This contributuion tries to re-examine the theoretical capacity of various approaches (institionalism, functionalism, regionalism, flying geese pattern, regime-theory) when applied to the realities of transnational interaction and international organization in the Asia-Pacific rim.
Based on the discussion on Germany´s new 'central location', the author tries to sketch Germany´s geopolitical position in view of the constellation of powers in Europe from a national point of view. This favourable position offers a great chance for the country to play an active role in Europe’s integration. However, German historical heritage as well as the delicate relationship of Germany´s political elite to the use of power are reasons for the country´s hesitation to fulfill her neighbours’ and her allies’ expectations. Anyhow, Summaries 192 rooted in the West-European and transatlantic integration is Germany the natural dooropener for its Eastern, South-Eastern and Baltic neighbours to become 'members of the club'. )</a> Jahresabo: 40,00 € (ermäßigt: 25,00 €)
Flight and expulsion are and will remain important international problems. The existence of refugees is a result of unsolved domestic tasks. Thus, effective solutions require comprehensive and long-term strategies. So far the efforts to reduce the causes of escape have not been sufficient. In the current refugee crises millions of people can survive only with the help of an efficient international system (for example the UNHCR) that guarantees humanitarian aid and protection. However, this system has turned out to be inadequate although the potential of preventive action is sufficient to reach a major progress in diminishing the refugee problem.
Although without providing a systematical comparison, it has become clear that the sects or party-factions of Japan’s New Left movement are by no means merely copies of their counterparts in the West. On the other hand their conduct may not be judged as to be a unique Japanese phenomenon. What they embody is, on the whole, a complex symbiosis of universal and particularly Japanese features, which can be observed in the fields of social behavior, organizational structure, and group dynamics. The particularity of the New Left factions is mostly revealed through the higher intensity of specific features rather than through pecularities found only in Japan.
Underlying the importance of revenue the author discusses the future of the international order from the perspective of political economy. The international system will not be a capitalist one. Political conflicts will not be removed by nonviolent market regulations. Weakness of labour force and a dominant role of revenue will further more result in political interventions by nation states. The struggle for revenue to maintain comparative advantages in high-tech-development strengthens state intervention in order to protect domestic market. The failure of the "development state" in the third world and the rising of fundamentalistic tendencies supported by a market-oriented middle class will increase conflicts in those regions.
There has never been a theory of transition from really existing Socialism to a democratic and market-oriented system. Different theoretical approaches are taken into consideration by the author. Experiences of other transitional processes are practicable on Eastern Europe in a limited way. The missing of socio-structural differentiation, the socio-cultural consequences of the really existing Socialism and the international conditions did not promote the transition. It seems that the transition in Eastern Europe is obviously not a change from one political system to another one, but for the time being an open process.
Taking the visit of Erich Honecker to China as an example, the author analyses the bilateral GDR-Chinese relations in the 1980s. Based on extensive original research, the objectives as well as disappointed hopes are presented. The author reveals that not Honecker played the "Chinese Card", but he himself became part of Chinese politics. At the same time, the contradictory reaction to that visit in Moscow are documented when, with the election of Gorbachev, first signs of a change in Soviet policy toward China were indicated. Jahresabo: 40,00 € (ermäßigt: 25,00 €)
The dramatic changes in international relations characterized by the terms "Complex Interdependence" and "Segmentary Globalization" call for new explanation. The author considers the post-modern approaches, a critical analysis of which he presents, to be one possibility to do that. In studies of international policy, these post-modern influences are gaining ground in disputes with realistic and neo-realistic approaches, and they can also clearly be felt in Latin America. Tomassini, based on the historic experiences of Latin America, forcefully calls for an active and constructive incorporation of the region into international developments. For that, Latin-American societies have to establish modern, and open political as well as economic systems which are able to meet those challenges.
Improvement of a fluorescence immunoassay with a compact diode-pumped solid state laser at 315 nm
(2006)
We demonstrate the improvement of fluorescence immunoassay (FIA) diagnostics in deploying a newly developed compact diode-pumped solid state (DPSS) laser with emission at 315 nm. The laser is based on the quasi-three-level transition in Nd:YAG at 946 nm. The pulsed operation is either realized by an active Q-switch using an electro-optical device or by introduction of a Cr<SUP>4+</SUP>:YAG saturable absorber as passive Q-switch element. By extra-cavity second harmonic generation in different nonlinear crystal media we obtained blue light at 473 nm. Subsequent mixing of the fundamental and the second harmonic in a β-barium-borate crystal provided pulsed emission at 315 nm with up to 20 μJ maximum pulse energy and 17 ns pulse duration. Substitution of a nitrogen laser in a FIA diagnostics system by the DPSS laser succeeded in considerable improvement of the detection limit. Despite significantly lower pulse energies (7 μJ DPSS laser versus 150 μJ nitrogen laser), in preliminary investigations the limit of detection was reduced by a factor of three for a typical FIA.
Two examples of our biophotonic research utilizing nanoparticles are presented, namely laser-based fluoroimmuno analysis and in-vivo optical oxygen monitoring. Results of the work include significantly enhanced sensitivity of a homogeneous fluorescence immunoassay and markedly improved spatial resolution of oxygen gradients in root nodules of a legume species.
Mit diesem Heft wird die Diskussion über eine neue deutsche Ostpolitik fortgesetzt und abgeschlossen. Diese hatte im Heft Nr. 49 mit Thesen von Jochen Franzke begonnen, im nächsten Heft wurden erste Beiträge publiziert. Insgesamt haben sich Wissenschaftler und Politiker aus Deutschland, Österreich, Polen, Finnland und Tschechien beteiligt. Die Debatte schließt mit Schlussbemerkungen des Initiators. Ulrich Best, Katrin Böttger, Vladimir Handl, Heinz Timmermann, Christian Wipperfürth, Sabina Wölkner, Gesine Schwan, Dieter Segert, Beata Wilga, Markus Löning und Ole Diehl, Angelica Schwall-Düren, Wolfgang Gehrcke und Jochen Franzke
Politische Loyalität und Sprachwahl : eine Fallstudie aus dem Flandern des frühen 19. Jahrhunderts
(2005)
"Small wars" will play an increasing role in the conflict scenarios of the 21st century, at the expense of inter-state wars. One of the key features of future war is the difficult differentiation between civilian and military targets, between combatants and noncombatants. It is argued that the parallel (and competing) structures of both states and non-state actors using force openly and equally will be a permanent feature of international security policy in the 21st century. This development is tantamount to the dissolution of the monopoly on the legitimate use of force by the states. The state-centered system of international relations has been a distinctive hallmark of the modern period. It is bound to give way, however, to the parallel and competing structures of state actors and non-state actors which was a central attribute of the Middle Ages. Jahresabo: 40,00 € (ermäßigt: 25,00 €)
In den theoretischen Grundlagen moderner Verfassungsstaaten wird Angst als zentrale politische Größe ausgewiesen. In der Hobbesschen Ursprungsmythologie moderner Staatlichkeit spielt sie eine entscheidende Rolle für die Staatskonstituierung. Aufgrund ihrer Staatszentriertheit bietet die Vertragstheorie allerdings kein hinreichendes Erklärungspotential für die transnationale terroristische Strategie der Angst. Der Angstpolitik des Terrorismus steht aber auch eine Nutzbarmachung der Angst durch Regierungen bedrohter Staaten gegenüber.
Geheimdienste in Demokratien
(2006)
Geheimdienste sind für den modernen Staat zur Gewährleistung seiner inneren und äußeren Sicherheit wesentlich und stehen ständig vor neuen Herausforderungen. Die Dienste der Bundesrepublik sind aus der Frontstaatlage im Kalten Krieg gewachsen, und ihr Wert als geheimes Regierungsinstrument ist durch eine Vielzahl systemischer Probleme erheblich eingeschränkt. Zudem gibt es weder eine klare Standortbestimmung der Dienste im politischen System, noch eine moralische Grenzziehung ihrer Aktivitäten.
In the spring issue of WeltTrends, Gunther Hellmann (Johann-Wolfgang-Goethe- Universität Frankfurt a. M.) sparked a debate on Germany's foreign policy. He argued that Germany’s international behaviour is dominated by a Realpolitik policy generally referred to as "normalization". For Hellmann this transformation indicates "the deepest crisis of German foreign policy" ever. Hellmann proposes a rehabilitation of the tradition of the Bonner Republik and an active Idealpolitik. This summer issue of WeltTrends features eleven articles written in response to Hellmann by International Relations scholars. The debate focuses on analytical as well as normative aspects of current German foreign policy. The authors discuss the context of the European Common Foreign and Security Policy, the international system and the United Nations, historical aspects of German foreign policy and the German foreign policy discourse. While some contributors share Hellmann's idealist position, most challenge his plea from a more realist perspective. In the upcoming fall issue, this debate will be continued with contributions by German foreign policy makers. A final reply by Hellmann will complete the debate in the winter issue of WeltTrends. Contributions by: Franz Ansprenger, Stephan Böckenförde, Wilfried von Bredow, Sabine Busse, Edwina S. Campbell, Hartmut Elsenhans, Hans J. Gießmann, Werner Link, Carlo Masala, Hanns W. Maull, and Siegfried Schwarz.