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The Central Asian Pamir Mountains (Pamirs) are a high-altitude region sensitive to climatic change, with only few paleoclimatic records available. To examine the glacial-interglacial hydrological changes in the region, we analyzed the geochemical parameters of a 31-kyr record from Lake Karakul and performed a set of experiments with climate models to interpret the results. delta D values of terrestrial biomarkers showed insolation-driven trends reflecting major shifts of water vapor sources. For aquatic biomarkers, positive delta D shifts driven by changes in precipitation seasonality were observed at ca. 31-30, 28-26, and 17-14 kyr BP. Multiproxy paleoecological data and modelling results suggest that increased water availability, induced by decreased summer evaporation, triggered higher lake levels during those episodes, possibly synchronous to northern hemispheric rapid climate events. We conclude that seasonal changes in precipitation-evaporation balance significantly influenced the hydrological state of a large waterbody such as Lake Karakul, while annual precipitation amount and inflows remained fairly constant.
In this study transmission X-ray microscopy (TXM) was tested as a method to investigate the chemistry and structure of corroded silicate glasses at the nanometer scale. Three different silicate glasses were altered in static corrosion experiments for 1-336 hours at temperatures between 60 degrees C and 85 degrees C using a 25% HCl solution. Thin lamellas were cut perpendicular to the surface of corroded glass monoliths and were analysed with conventional TEM as well as with TXM. By recording optical density profiles at photon energies around the Na and O K-edges, the shape of the corrosion rim/pristine glass interfaces and the thickness of the corrosion rims has been determined. Na and O near-edge X-ray absorption fine-structure spectra (NEXAFS) were obtained without inducing irradiation damage and have been used to detect chemical changes in the corrosion rims. Spatially resolved NEXAFS spectra at the O K-edge provided insight to structural changes in the corrosion layer on the atomic scale. By comparison to O K-edge spectra of silicate minerals and (hydrous) albite glass as well as to O K-edge NEXAFS of model structures simulated with ab initio calculations, evidence is provided that changes of the fine structure at the O K-edge are assigned to the formation of siloxane groups in the corrosion rim.
Aus dem Inhalt dieser Ausgabe: BEITRÄGE: Elmar Henrich: Die Luccheser Bergmilizen: Bauernmobilisierung und Bauernmilitanz in einer Renaissancerepublik des späten 16. und frühen 17. Jahrhunderts, Jutta Nowosadtko: Der „Vampyrus Serviensis“ und sein Habitat: Impressionen von der österreichischen Militärgrenze, PROJEKTE: Thomas Fuchs, Ulrich Kandolf: Die Wehrbereichsbibliothek II (Hannover) in der Niedersächsischen Landesbibliothek, Sascha Möbius: „... Der blutdürstige Degen drung ihnen die Feder so gar aus der Hand.“ : Unruhe und Krieg in der Chronik des Lübecker Schreiners Heinrich Christian Schulze (1728-1734) (Dissertationsprojekt), Ernst Riegg: Die Erinnerungskultur der Stadt vom Spätmittelalter bis zum 18. Jahrhundert : ihre Erforschung anhand der städtischen Chronistik (DFG-Projekt, Potsdam), BERICHTE: Gregor Maier: „Krieg und Umbruch um 1800“ (12. bis 13. März 2004 Tübingen), Olaf Jessen: „Zur Geschichte des militärischen Denkens vom späten Mittelalter bis zum 20. Jahrhundert“ (29. bis 30. April 2004 Stuttgart), Cornel Zwierlein: „Militär und Gesellschaft im Europa der Neuzeit“ (13. bis 17. September 2004 Trient), Sonja Neubauer: „Christentum und Krieg in der Moderne“ (26. bis 29. September 2004 Weingarten), Protokoll der Mitgliederversammlung vom 29.10.2004, REZENSIONEN: Elke Anna Werner: Peter Burke, Augenzeugenschaft : Bilder als historische Quellen, Berlin 2003, Andrea Pühringer: Steffen Martus, Marina Münkler, Werner Röcke (Hrsg.), Schlachtfelder : Codierung von Gewalt im medialen Wandel, Berlin 2003, Arbeitskreis Historische Bildforschung (Hrsg.): Der Krieg im Bild – Bilder vom Krieg : Hamburger Beiträge zur Historischen Bildforschung, Frankfurt/Main 2003, Maren Lorenz: Johann Carl Wilhelm Moehsen, Betrachtungen über die Berlinischen Selbstmörder unter den Soldaten : nach dem Manuskript aus den Materialien der Berliner Mittwochsgesellschaft, hrsg. von Hans-Uwe Lammel, Hannover 2004, Thomas Wollschläger: Michael Römling, Ein Heer ist ein großes gefräßiges Tier : Soldaten in spanischen und kaiserlichen Diensten und die Bevölkerung der vom Krieg betroffenen Gebiete in Italien zwischen 1509 und 1530, Göttingen 2002, Jörg Muth: Jürgen Kloosterhuis (Bearb.), Legendäre „lange Kerls“. Quellen zur Regimentskultur der Königsgrenadiere Friedrich Wilhelms I., 1713-1740, Berlin 2003, Martin Winter: Alfred Messerli, Adolf Muschg (Hrsg.), Schreibsucht. Autobiographische Schriften des Pietisten Ulrich Bräker (1735-1798), Göttingen 2004, Michael Kleinen, Sascha Möbius: Stig Förster, Markus Pöhlmann, Dierk Walter (Hrsg.), Schlachten der Weltgeschichte : von Salamis bis Sinai, München 2001, ANKÜNDIGUNGEN: 11. Forschungskolloquium: Neuere Forschungen zur Militärgeschichte, Universität Potsdam, Winersemester 2004/05, AMG-Tagung: „Krieg, Militär und Migration in der Frühen Neuzeit“ (17. bis 19. November 2005 Tübingen), Aufruf: Werner-Hahlweg-Preis 2006 für Militärgeschichte und Wehrwissenschaften, Michael Hochedlinger: Aufruf: Habsburgs Generale. Die kaiserliche und kaiserlich-königliche Generalität 1618-1815 : ein biographisches Lexikon
From the roots of the African plant Bulbine frutescens (Asphodelaceae), two unprecedented novel dimeric phenylanthraquinones, named joziknipholones A and B, possessing axial and centrochirality, were isolated, together with six known compounds. Structural elucidation of the new metabolites was achieved by spectroscopic and chiroptical methods, by reductive cleavage of the central bond between the monomeric phenylanthraquinone and -anthrone portions with sodium dithionite, and by quantum chemical CD calculations. Based on the recently revised absolute axial configuration of the parent phenylanthraquinones, knipholone and knipholone anthrone, the new dimers were attributed to possess the P-configuration (i.e., with the acetyl portions below the anthraquinone plane) at both axes in the case of joziknipholone A, whereas in joziknipholone B, the knipholone part was found to be M-configured. Joziknipholones A and B are active against the chloroquine resistant strain K1 of the malaria pathogen, Plasmodium falciparum, and show moderate activity against murine leukemic lymphoma L5178y cells.
Intensive land use is a major cause of biodiversity loss, but most studies comparing the response of multiple taxa rely on simple diversity measures while analyses of other community attributes are only recently gaining attention. Species-abundance distributions (SADs) are a community attribute that can be used to study changes in the overall abundance structure of species groups, and whether these changes are driven by abundant or rare species. We evaluated the effect of grassland management intensity for three land-use modes (fertilization, mowing, grazing) and their combination on species richness and SADs for three belowground (arbuscular mycorrhizal fungi, prokaryotes and insect larvae) and seven aboveground groups (vascular plants, bryophytes and lichens; arthropod herbivores; arthropod pollinators; bats and birds). Three descriptors of SADs were evaluated: general shape (abundance decay rate), proportion of rare species (rarity) and proportional abundance of the commonest species (dominance). Across groups, taxonomic richness was largely unaffected by land-use intensity and only decreased with increasing mowing intensity. Of the three SAD descriptors, abundance decay rate became steeper with increasing combined land-use intensity across groups. This reflected a decrease in rarity among plants, herbivores and vertebrates. Effects of fertilization on the three descriptors were similar to the combined land-use intensity effects. Mowing intensity only affected the SAD descriptors of insect larvae and vertebrates, while grazing intensity produced a range of effects on different descriptors in distinct groups. Overall, belowground groups had more even abundance distribtitions than aboveground groups. Strong differences among aboveground groups and between above- and belowground groups indicate that no single taxonomic group can serve as an indicator for effects in other groups. In the past, the use of SADs has been hampered by concerns over theoretical models underlying specific forms of SADs. Our study shows that SAD descriptors that are not connected to a particular model are suitable to assess the effect of land use on community structure.
Moving arms
(2018)
Embodied cognition postulates a bi-directional link between the human body and its cognitive functions. Whether this holds for higher cognitive functions such as problem solving is unknown. We predicted that arm movement manipulations performed by the participants could affect the problem-solving solutions. We tested this prediction in quantitative reasoning tasks that allowed two solutions to each problem (addition or subtraction). In two studies with healthy adults (N=53 and N=50), we found an effect of problem-congruent movements on problem solutions. Consistent with embodied cognition, sensorimotor information gained via right or left arm movements affects the solution in different types of problem-solving tasks.
Most epiphytic bromeliads, especially those in the genus Tillandsia, lack functional roots and rely on the absorption of water and nutrients by large, multicellular trichomes on the epidermal surfaces of leaves and stems. Another important function of these structures is the spread of water over the epidermal surface by capillary action between trichome "wings" and epidermal surface. Although critical for the ultimate absorption by these plants, understanding of this function of trichomes is primarily based on light microscope observations. To better understand this phenomenon, the distribution of water was followed by its attenuation of cold neutrons following application of H2O to the cut end of Tillandsia usneoides shoots. Experiments confirmed the spread of added water on the external surfaces of this "atmospheric" epiphyte. In a morphologically and physiologically similar plant lacking epidermal trichomes, water added to the cut end of a shoot clearly moved via its internal xylem and not on its epidermis. Thus, in T. usneoides, water moves primarily by capillarity among the overlapping trichomes forming a dense indumentum on shoot surfaces, while internal vascular water movement is less likely. T. usneoides, occupying xeric microhabitats, benefits from reduction of water losses by low-shoot xylem hydraulic conductivities.
Topsoil conditions in temperate forests are influenced by several soil-forming factors, such as canopy composition (e.g. through litter quality), land-use history, atmospheric deposition, and the parent material. Many studies have evaluated the effects of single factors on physicochemical topsoil conditions, but few have assessed the simultaneous effects of multiple drivers. Here, we evaluate the combined effects of litter quality, land-use history (past land cover as well as past forest management), and atmospheric deposition on several physicochemical topsoil conditions of European temperate deciduous forest soils: bulk density, proportion of exchangeable base cations, carbon/nitrogen-ratio (C/N), litter mass, bio-available and total phosphorus, pH(KCI)and soil organic matter. We collected mineral soil and litter layer samples, and measured site characteristics for 190 20 x 20 m European mixed forest plots across gradients of litter quality (derived from the canopy species composition) and atmospheric deposition, and for different categories of past land cover and past forest management. We accounted for the effects of parent material on topsoil conditions by clustering our plots into three soil type groups based on texture and carbonate concentration. We found that litter quality was a stronger driver of topsoil conditions compared to land-use history or atmospheric deposition, while the soil type also affected several topsoil conditions here. Plots with higher litter quality had soils with a higher proportion of exchangeable base cations, and total phosphorus, and lower C/N-ratios and litter mass. Furthermore, the observed litter quality effects on the topsoil were independent from the regional nitrogen deposition or the soil type, although the soil type likely (co)-determined canopy composition and thus litter quality to some extent in the investigated plots. Litter quality effects on topsoil phosphorus concentrations did interact with past land cover, highlighting the need to consider land-use history when evaluating canopy effects on soil conditions. We conclude that forest managers can use the canopy composition as an important tool for influencing topsoil conditions, although soil type remains an important factor to consider.
From the roots of the African plant Bulbine frutescens (Asphodelaceae), two unprecedented novel dimeric phenylanthraquinones, named joziknipholones A and B, possessing axial and centrochirality, were isolated, together with six known compounds. Structural elucidation of the new metabolites was achieved by spectroscopic and chiroptical methods, by reductive cleavage of the central bond between the monomeric phenylanthraquinone and -anthrone portions with sodium dithionite, and by quantum chemical CD calculations. Based on the recently revised absolute axial configuration of the parent phenylanthraquinones, knipholone and knipholone anthrone, the new dimers were attributed to possess the P- configuration (i.e., with the acetyl portions below the anthraquinone plane) at both axes in the case of joziknipholone A, whereas in joziknipholone B, the knipholone part was found to be M-configured. Joziknipholones A and B are active against the chloroquine resistant strain K1 of the malaria pathogen, Plasmodium falciparum, and show moderate activity against murine leukemic lymphoma L5178y cells.