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We present new calculations of the mass inflow and outflow rates around the Milky Way (MW), derived from a catalog of ultraviolet metal-line high-velocity clouds (HVCs). These calculations are conducted by transforming the HVC velocities into the Galactic standard of rest (GSR) reference frame, identifying inflowing (vGSR.<.0 km s(-1)) and outflowing (vGSR > 0 km s(-1)) populations, and using observational constraints on the distance, metallicity, dust content, covering fractions, and total silicon column density of each population. After removing HVCs associated with the Magellanic Stream and the Fermi Bubbles, we find inflow and outflow rates in cool (T similar to 10(4) K) ionized gas of dM(in)/dt greater than or similar to.(0.53 +/- 0.23)(d/12 kpc)(Z/0.2Z(circle dot))-1M(circle dot) yr(-1) and dM(out)/dt greater than or similar to (0.16 +/- 0.07)(d/12 kpc)(Z/0.5Z(circle dot))M--1(circle dot) yr(-1). The apparent excess of inflowing over outflowing gas suggests that the MW is currently in an inflow-dominated phase, but the presence of substantial mass flux in both directions supports a Galactic fountain model, in which gas is constantly recycled between the disk and the halo. We also find that the metal flux in both directions (in and out) is indistinguishable. By comparing the outflow rate to the Galactic star formation rate, we present the first estimate of the mass loading factor (eta(HVC)) of the disk-wide MW wind, finding eta(HVC) greater than or similar to (0.10 +/- 0.06)(d/12 kpc)(Z/0.5Z(circle dot))(-1). Including the contributions from low- and intermediatevelocity clouds and from hot gas would increase these inflow and outflow estimates.
Context. For the spectral analysis of high-resolution and high signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. New Kr IV-VII oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTE model-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods. We calculated Kr IV-VII oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high S/N ultraviolet (UV) observations of the hot white dwarf RE 0503-289. Results. We reanalyzed the effective temperature and surface gravity and determined T-eff = 70 000 +/- 2000 K and log (g/cm s(-2)) = 7.5 +/- 0.1. We newly identified ten Kr V lines and one Kr vi line in the spectrum of RE 0503-289. We measured a Kr abundance of 3.3 +/- 0.3 (logarithmic mass fraction). We discovered that the interstellar absorption toward RE 0503-289 has a multi-velocity structure within a radial-velocity interval of -40 km s(-1) < upsilon(rad) < +18 km s(-1). Conclusions. Reliable measurements and calculations of atomic data are a prerequisite for state-of-the-art NLTE stellar-atmosphere modeling. Observed Kr V-VII line profiles in the UV spectrum of the white dwarf RE 0503-289 were simultaneously well reproduced with our newly calculated oscillator strengths.
Contemporary methods for the modification of porphyrins are presented. In association with the Third International Conference on Porphyrins and Phthalocyanines (ICPP-3) a survey of current method developments and reactivity studies is made. The review focuses on synthetic transformations of porphyrins currently in use for various applications and on functional group transformations. A brief survey of important developments covers selectively the literature from late 2001 to early 2004. Copyright (c) 2004 Society of Porphyrins C Phthalocyanines
We present a sample of 34 weak metal line absorbers at z < 0.3 selected by the simultaneous >3σ detections of the Si iiλ1260 and C iiλ1334 absorption lines, with Wr(SiII)<0.2 Å and Wr(CII)<0.3 Å, in archival HST/COS spectra. Our sample increases the number of known low-z ‘weak absorbers’ by a factor of >5. The column densities of H i and low-ionization metal lines obtained from Voigt profile fitting are used to build simple photoionization models. The inferred densities and line-of-sight thicknesses of the absorbers are in the ranges of −3.3 < log nH/cm−3 < −2.4 and ∼1 pc–50 kpc (median ≈500 pc), respectively. Most importantly, 85 per cent (50 per cent) of these absorbers show a metallicity of [Si/H]>−1.0(0.0). The fraction of systems showing near-/supersolar metallicity in our sample is significantly higher than in the H i-selected sample of Wotta et al., and the galaxy-selected sample of Prochaska et al., of absorbers probing the circum-galactic medium at similar redshift. A search for galaxies has revealed a significant galaxy-overdensity around these weak absorbers compared to random positions with a median impact parameter of 166 kpc from the nearest galaxy. Moreover, we find the presence of multiple galaxies in ≈80 per cent of the cases, suggesting group environments. The observed dN/dz of 0.8 ± 0.2 indicates that such metal-enriched, compact, dense structures are ubiquitous in the haloes of low-z group galaxies. We suggest that these are transient structures that are related to galactic outflows and/or stripping of metal-rich gas from galaxies.
We present a detailed analysis of the absorption properties of one of the tidal gas streams around the "Whale" galaxy NGC 4631 in the direction of the quasar 2MASS J12421031+3214268. Our study is based on ultraviolet spectral data obtained with the Cosmic Origins Spectrograph (COS) on board the Hubble Space Telescope (HST) and 21cm-data from the HALOGAS project and the Green Bank Telescope (GBT). We detect strong H I Ly alpha absorption in the velocity range +550 to +800 km s(-1) related to gas from a NGC 4631 tidal stream known as Spur 2. We measure a column density of log (N(H I/cm(-2))) = 18.68 +/- 0.15, indicating that the quasar sightline traces the outer boundary of Spur 2 as seen in the 21 cm data. Metal absorption in Spur 2 is detected in the lines of O I, C II, Si II, and Si III in a complex absorption pattern that reflects the multiphase nature of the gas. We find that the average neutral gas fraction in Spur 2 toward 2MASS J12421031+3214268 is only 14%. This implies that ionized gas dominates the total mass of Spur 2, which then may comprise more than 10(9)M(circle dot). No significant depletion of Si is observed, showing that Spur 2 does not contain significant amounts of dust. From the measured O I/H I column density ratio, we determine an alpha abundance in Spur 2 of 0.131(-0.05)(+0.07) solar ([alpha/H] = -0.90 +/- 0.16), which is substantially lower than what is observed in the NGC 4631 disk. The low metallicity and low dust content suggest that Spur 2 represents metal-deficient gas stripped off a gas-rich satellite galaxy during a recent encounter with NGC 4631.
We report on the detection of strongly varying intergalactic He II absorption in HST/COS spectra of two z(em) similar or equal to 3 quasars. From our homogeneous analysis of the He II absorption in these and three archival sightlines, we find a marked increase in the mean He II effective optical depth from <tau(eff, He II)> similar or equal to 1 at z similar or equal to 2.3 to <tau(eff, He II)> greater than or similar to 5 at z similar or equal to 3.2, but with a large scatter of 2 less than or similar to tau(eff, He II) less than or similar to 5 at 2.7 < z < 3 on scales of similar to 10 proper Mpc. This scatter is primarily due to fluctuations in the He II fraction and the He II-ionizing background, rather than density variations that are probed by the coeval Hi forest. Semianalytic models of He II absorption require a strong decrease in the He II-ionizing background to explain the strong increase of the absorption at z greater than or similar to 2.7, probably indicating He II reionization was incomplete at z(reion) greater than or similar to 2.7. Likewise, recent three-dimensional numerical simulations of He II reionization qualitatively agree with the observed trend only if He II reionization completes at z(reion) similar or equal to 2.7 or even below, as suggested by a large tau(eff, He II) greater than or similar to 3 in two of our five sightlines at z < 2.8. By doubling the sample size at 2.7 less than or similar to z less than or similar to 3, our newly discovered He II sightlines for the first time probe the diversity of the second epoch of reionization when helium became fully ionized.
Using Milky Way data of the new Effelsberg-Bonn HI Survey (EBHIS) and the Galactic All-Sky Survey (GASS), we present a revised picture of the high-velocity cloud (HVC) complex Galactic center negative (GCN). Owing to the higher angular resolution of these surveys compared to previous studies (e.g., the Leiden Dwingeloo Survey), we resolve complex GCN into lots of individual tiny clumps, that mostly have relatively broad line widths of more than 15 km s(-1). We do not detect a diffuse extended counterpart, which is unusual for an HVC complex. In total 243 clumps were identified and parameterized which allows us to statistically analyze the data. Cold-line components (i.e.,Delta upsilon(fwhm) < 7.5 km s(-1)) are found in about 5% only of the identified cloudlets. Our analysis reveals that complex GCN is likely built up of several subpopulations that do not share a common origin. Furthermore, complex GCN might be a prime example for warm-gas accretion onto the Milky Way, where neutral HI clouds are not stable against interaction with the Milky Way gas halo and become ionized prior to accretion.
Aims. We aim at analysing systematically the distribution and physical properties of neutral and mildly ionised gas in the Milky Way halo, based on a large absorption-selected data set.
Methods. Multi-wavelength studies were performed combining optical absorption line data of Ca II and Na I with follow-up H I 21-cm emission line observations along 408 sight lines towards low-and high-redshift QSOs. We made use of archival optical spectra obtained with UVES/VLT. H I data were extracted from the Effelsberg-Bonn H I survey and the Galactic All-Sky survey. For selected sight lines we obtained deeper follow-up observations using the Effelsberg 100-m telescope.
Results. Ca II (Na I) halo absorbers at intermediate and high radial velocities are present in 40-55% (20-35%) of the sightlines, depending on the column density threshold chosen. Many halo absorbers show multi-component absorption lines, indicating the presence of sub-structure. In 65% of the cases, absorption is associated with H I 21-cm emission. The Ca II (Na I) column density distribution function follows a power-law with a slope of beta approximate to -2.2 (-1.4).
Conclusions. Our absorption-selected survey confirms our previous results that the Milky Way halo is filled with a large number of neutral gas structures whose high column density tail represents the population of common H I high-and intermediate-velocity clouds seen in 21-cm observations. We find that Na I/Ca II column density ratios in the halo absorbers are typically smaller than those in the Milky Way disc, in the gas in the Magellanic Clouds, and in damped Lyman a systems. The small ratios (prominent in particular in high-velocity components) indicate a lower level of Ca depletion onto dust grains in Milky Way halo absorbers compared to gas in discs and inner regions of galaxies.
We use a background quasar to detect the presence of circumgalactic gas around a z = 0.91 low-mass star-forming galaxy. Data from the new Multi Unit Spectroscopic Explorer (MUSE) on the Very Large Telescope show that the galaxy has a dust-corrected star formation rate (SFR) of 4.7 +/- 2.0. M-circle dot yr(-1), with no companion down to 0.22 M-circle dot yr(-1) (5 sigma) within 240 h(-1) kpc ("30"). Using a high-resolution spectrum of the background quasar, which is fortuitously aligned with the galaxy major axis (with an azimuth angle alpha of only 15 degrees), we find, in the gas kinematics traced by low-ionization lines, distinct signatures consistent with those expected for a "cold-flow disk" extending at least 12 kpc (3 x R-1/2). We estimate the mass accretion rate M-in to be at least two to three times larger than the SFR, using the geometric constraints from the IFU data and the H (I) column density of log N-H (I)/cm(-2) similar or equal to 20.4 obtained from a Hubble Space Telescope/COS near-UV spectrum. From a detailed analysis of the low-ionization lines (e.g., Zn II, Cr II, Ti II, MnII, Si II), the accreting material appears to be enriched to about 0.4 Z(circle dot) (albeit with large uncertainties: log Z/Z(circle dot) = -0.4 +/- 0.4), which is comparable to the galaxy metallicity (12 + log O/H = 8.7 +/- 0.2), implying a large recycling fraction from past outflows. Blueshifted Mg II and Fe II absorptions in the galaxy spectrum from the MUSE data reveal the presence of an outflow. The Mg II and Fe II absorption line ratios indicate emission infilling due to scattering processes, but the MUSE data do not show any signs of fluorescent Fe II* emission.