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Diketopyrrolopyrrole (DPP)-based donor acceptor copolymers have gained a significant amount of research interest in the organic electronics community because of their high charge carrier mobilities in organic field-effect transistors (OFETs) and their ability to harvest near-infrared (NIR) photons in solar cells. In this study, we have synthesized four DPP based donor-acceptor copolymers with variations in the donor unit and the branching point of the solubilizing alkyl chains (at the second or sixth carbon position). Grazing incidence wide-angle X-ray scattering (GIWAXS) results suggest that moving the branching point further away from the polymer backbone increases the tendency for aggregation and yields polymer phases with a higher degree of crystallinity (DoC). The polymers were blended with PC70BM and used as active layers in solar cells. A careful analysis of the energetics of the neat polymer and blend films reveals that the charge-transfer state energy (E-CT) of the blend films lies exceptionally close to the singlet energy of the donor (E-D*), indicating near zero electron transfer losses. The difference between the optical gap and open-circuit voltage (V-OC) is therefore determined to be due to rather high nonradiative 418 +/- 13 mV) and unavoidable radiative voltage losses (approximate to 255 +/- 8 mV). Even though the four materials have similar optical gaps, the short-circuit current density (J(SC)) covers a vast span from 7 to 18 mA cm(-2) for the best performing system. Using photoluminescence (PL) quenching and transient charge extraction techniques, we quantify geminate and nongeminate losses and find that fewer excitons reach the donor-acceptor interface in polymers with further away branching points due to larger aggregate sizes. In these material systems, the photogeneration is therefore mainly limited by exciton harvesting efficiency.
Zinc oxide (ZnO) is regarded as a promising alternative material for transparent conductive electrodes in optoelectronic devices. However, ZnO suffers from poor chemical stability. ZnO also has a moderate work function (WF), which results in substantial charge injection barriers into common (organic) semiconductors that constitute the active layer in a device. Controlling and tuning the ZnO WF is therefore necessary but challenging. Here, a variety of phosphonic acid based self-assembled monolayers (SAMs) deposited on ZnO surfaces are investigated. It is demonstrated that they allow the tuning the WF over a wide range of more than 1.5 eV, thus enabling the use of ZnO as both the hole-injecting and electron-injecting contact. The modified ZnO surfaces are characterized using a number of complementary techniques, demonstrating that the preparation protocol yields dense, well-defined molecular monolayers.
Inhalt: Gutachten im Auftrag des Ministeriums der Finanzen des Landes Brandenburg (beinhaltet den Text des Gutachtens - Teil a) Mischfinanzierungstatbestände -Allgemeine Probleme der Mischfinanzierung -Gemeinschaftsaufgaben -Finanzhilfen nach Art. 104a Abs. 4 GG -Geldleistungsgesetze nach Art. 104a Abs. 3 GG Lösungsmöglichkeiten -Verteilungsschlüssel und Mischfinanzierung -Umsetzungsmöglichkeiten -Neuverteilung der Mittelzuweisungen am Beispiel der Gemeinschaftsaufgabe "Verbesserung der regionalen Wirtschaftsstruktur" -Kompensationsmodelle für Mischfinanzierungstatbestände
Inhalt: Veränderungen der Bemessungsgrundlage -Besteuerung der Alterseinkommen -Sozialversicherungsbeiträge, Vorsorgeaufwendungen und Sonderausgaben -Die Behandlung der Einkünfte aus nichtselbständiger Arbeit -Behandlung der Einkünfte aus Vermietung und Verpachtung -Behandlung der Gewinneinkunftsarten und der Einkünfte aus Kapitalvermögen -Kindergeld und Kinderfreibeträge Gesamtwirkungen Der Karlsruher Reformentwurf -Die Elemente des Karlsruher Entwurfs -Karlsruher Entwurf im empirischen Vergleich Tarifanalyse unter Einschluß des Grundfreibetrags
The “HPI Future SOC Lab” is a cooperation of the Hasso Plattner Institute (HPI) and industry partners. Its mission is to enable and promote exchange and interaction between the research community and the industry partners.
The HPI Future SOC Lab provides researchers with free of charge access to a complete infrastructure of state of the art hard and software. This infrastructure includes components, which might be too expensive for an ordinary research environment, such as servers with up to 64 cores and 2 TB main memory. The offerings address researchers particularly from but not limited to the areas of computer science and business information systems. Main areas of research include cloud computing, parallelization, and In-Memory technologies.
This technical report presents results of research projects executed in 2018. Selected projects have presented their results on April 17th and November 14th 2017 at the Future SOC Lab Day events.