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In this study, an in situ application for identifying neodymium (Nd) enriched surface materials that uses multitemporal hyperspectral images is presented (HySpex sensor). Because of the narrow shape and shallow absorption depth of the neodymium absorption feature, a method was developed for enhancing and extracting the necessary information for neodymium from image spectra, even under illumination conditions that are not optimal. For this purpose, the two following approaches were developed: (1) reducing noise and analyzing changing illumination conditions by averaging multitemporal image scenes and (2) enhancing the depth of the desired absorption band by deconvolving every image spectrum with a Gaussian curve while the rest of the spectrum remains unchanged (Richardson-Lucy deconvolution). To evaluate these findings, nine field samples from the Fen complex in Norway were analyzed using handheld X-ray fluorescence devices and by conducting detailed laboratory-based geochemical rare earth element determinations. The result is a qualitative outcrop map that highlights zones that are enriched in neodymium. To reduce the influences of non-optimal illumination, particularly at the studied site, a minimum of seven single acquisitions is required. Sharpening the neodymium absorption band allows for robust mapping, even at the outer zones of enrichment. From the geochemical investigations, we found that iron oxides decrease the applicability of the method. However, iron-related absorption bands can be used as secondary indicators for sulfidic ore zones that are mainly enriched with rare earth elements. In summary, we found that hyperspectral spectroscopy is a noninvasive, fast and cost-saving method for determining neodymium at outcrop surfaces
The 933 km(2) Bengue catchment in northeastern Brazil is characterized by distinct rainy and dry seasons. Precipitation is stored in variously sized reservoirs, which is essential for the local population. In this study, we used TerraSAR-X SM(HH) data for an one-year monitoring of seasonal changes in the reservoir areas from July 2011 to July 2012. The monitoring was based on acquisitions in the ascending pass direction, complemented by occasional descending-pass images. To detect water surface areas, a histogram analysis followed by a global threshold classification was performed, and the results were validated using in situ GPS data. Distinguishing between small reservoirs and similar looking dark areas was difficult. Therefore, we tested several approaches for identifying misclassified areas. An analysis of the surface area dynamics of the reservoirs indicated high spatial and temporal heterogeneities and a large decrease in the total water surface area of the reservoirs in the catchment by approximately 30% within one year.