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BACKROUND: Few studies have been carried out to connect nutrients recovery from wastewater and heavy metals immobilization in contaminated soil. To achieve the goal, ammonia nitrogen (AN) and phosphorus (P) were recovered from rare-earth wastewater by using the formation of struvite, which was used as the amendment with plant ash for copper, lead and chromium immobilization. RESULTS: AN removal efficiency and residual P reached 95.32 +/- 0.73% and 6.14 +/- 1.72mgL(-1) under optimal conditions: pH= 9.0, n(Mg): n(N): n(P)= 1.2: 1: 1.1, which were obtained using response surface methodology (RSM). The minimum available concentrations of Cu, Pb and Cr (CPC) separately reduced to 320.82 mg kg(-1), 190.77 mg kg(-1) and 121.46 mg kg(-1) with increasing immobilization time at the mass ratio of phosphate precipitate (PP)/plant ash (PA) of 1: 3. Humic acid (HA) and fulvic acid (FA) were beneficial to immobilize Cu, both of which showed no effect or even a negative effect on Pb and Cr immobilization.
The northern part of the Pamir orogen is the preeminent example of an active intracontinental subduction zone in the early stages of continent-continent collision. Such zones are the least understood type of plate boundaries because modern examples are few and of limited access, and ancient analogs have been extensively overprinted by subsequent tectonic and erosion processes. In the Pamir, it has been assumed that most of the plate convergence was accommodated by overthrusting along the plate-bounding Main Pamir Thrust (MPT), which forms the principal northern mountain and deformation front of the Pamir. However, the synopsis of our new and previously published thermochronologic data from this region shows that the hanging wall of the MPT experienced relatively minor amounts of late Cenozoic exhumation. The Pamir orogen as a whole is an integral part of the overriding plate in a subduction system, while the remnant basin to the north constitutes the downgoing plate, with the bulk of the convergence accommodated by underthrusting. Herein, we demonstrate that the observed deformation of the upper and lower plates within the Pamir-Alai convergence zone resembles highly arcuate oceanic subduction systems characterized by slab rollback, subduction erosion, subduction accretion, and marginal slab-tear faults. We suggest that the curvature of the North Pamir is genetically linked to the short width and rollback of the south-dipping Alai slab; northward motion (indentation) of the Pamir is accommodated by crustal processes related to this rollback. The onset of south-dipping subduction is tentatively linked to intense Pamir contraction following break-off of the north-dipping Indian slab beneath the Karakoram.
Yedoma-extremely ice-rich permafrost with massive ice wedges formed during the Late Pleistocene-is vulnerable to thawing and degradation under climate warming. Thawing of ice-rich Yedoma results in lowering of surface elevations. Quantitative knowledge about surface elevation changes helps us to understand the freeze-thaw processes of the active layer and the potential degradation of Yedoma deposits. In this study, we use C-band Sentinel-1 InSAR measurements to map the elevation changes over ice-rich Yedoma uplands on Sobo-Sise Island, Lena Delta with frequent revisit observations (as short as six or 12 days). We observe significant seasonal thaw subsidence during summer months and heterogeneous inter-annual elevation changes from 2016-17. We also observe interesting patterns of stronger seasonal thaw subsidence on elevated flat Yedoma uplands by comparing to the surrounding Yedoma slopes. Inter-annual analyses from 2016-17 suggest that our observed positive surface elevation changes are likely caused by the delayed progression of the thaw season in 2017, associated with mean annual air temperature fluctuations.
Yedoma-extremely ice-rich permafrost with massive ice wedges formed during the Late Pleistocene-is vulnerable to thawing and degradation under climate warming. Thawing of ice-rich Yedoma results in lowering of surface elevations. Quantitative knowledge about surface elevation changes helps us to understand the freeze-thaw processes of the active layer and the potential degradation of Yedoma deposits. In this study, we use C-band Sentinel-1 InSAR measurements to map the elevation changes over ice-rich Yedoma uplands on Sobo-Sise Island, Lena Delta with frequent revisit observations (as short as six or 12 days). We observe significant seasonal thaw subsidence during summer months and heterogeneous inter-annual elevation changes from 2016-17. We also observe interesting patterns of stronger seasonal thaw subsidence on elevated flat Yedoma uplands by comparing to the surrounding Yedoma slopes. Inter-annual analyses from 2016-17 suggest that our observed positive surface elevation changes are likely caused by the delayed progression of the thaw season in 2017, associated with mean annual air temperature fluctuations.
Understanding the evolution of continental deformation zones relies on quantifying spatial and temporal changes in deformation rates of tectonic structures. Along the eastern boundary of the Pamir-Tian Shan collision zone, we constrain secular variations of rock uplift rates for a series of five Quaternary detachment- and fault-related folds from their initiation to the modern day. When combined with GPS data, decomposition of interferometric synthetic aperture radar time series constrains the spatial pattern of surface and rock uplift on the folds deforming at decadal rates of 1-5mm/yr. These data confirm the previously proposed basinward propagation of structures during the Quaternary. By fitting our geodetic rates and previously published geologic uplift rates with piecewise linear functions, we find that gradual rate changes over >100kyr can explain the interferometric synthetic aperture radar observations where changes in average uplift rates are greater than similar to 1 mm/yr among different time intervals (similar to 10(1), 10(4-5), and 10(5-6) years).
Fluvial planation surfaces, such as straths, commonly serve as recorders of climatic and tectonic changes and are formed by the lateral erosion of rivers, a process that remains poorly understood. Here we present a study of kilometer-wide, fluvially eroded, low-relief surfaces on rapidly uplifting folds in the foreland of the southwestern Tian Shan. A combination of field work, digital elevation model analysis, and dating of fluvial deposits reveals that despite an arid climate and rapid average rock-uplift rates of 1-3mm/yr, rivers cut extensive (>1-2km wide) surfaces with typical height variations of <6m over periods of >2-6kyr. The extent of this beveling varies in space and time, such that different beveling episodes affect individual structures. Between times of planation, beveled surfaces are abandoned, incised, and deformed across the folds. In a challenge to models that link strath cutting and abandonment primarily to changes in river incision rates, we demonstrate that lateral erosion rates of antecedent streams crossing the folds have to vary by more than 1 order of magnitude to explain the creation of beveled platforms in the past and their incision at the present day. These variations do not appear to covary with climate variability and might be caused by relatively small (much less than an order of magnitude) changes in sediment or water fluxes. It remains uncertain in which settings variations in lateral bedrock erosion rates predominate over changes in vertical erosion rates. Therefore, when studying fluvial planation and strath terraces, variability of both lateral and vertical erosion rates should be considered.