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The potential increase in frequency and magnitude of extreme floods is currently discussed in terms of global warming and the intensification of the hydrological cycle. The profound knowledge of past natural variability of floods is of utmost importance in order to assess flood risk for the future. Since instrumental flood series cover only the last ~150 years, other approaches to reconstruct historical and pre-historical flood events are needed. Annually laminated (varved) lake sediments are meaningful natural geoarchives because they provide continuous records of environmental changes > 10000 years down to a seasonal resolution. Since lake basins additionally act as natural sediment traps, the riverine sediment supply, which is preserved as detrital event layers in the lake sediments, can be used as a proxy for extreme discharge events. Within my thesis I examined a ~ 8.50 m long sedimentary record from the pre-Alpine Lake Mondsee (Northeast European Alps), which covered the last 7000 years. This sediment record consists of calcite varves and intercalated detrital layers, which range in thickness from 0.05 to 32 mm. Detrital layer deposition was analysed by a combined method of microfacies analysis via thin sections, Scanning Electron Microscopy (SEM), μX-ray fluorescence (μXRF) scanning and magnetic susceptibility. This approach allows characterizing individual detrital event layers and assigning a corresponding input mechanism and catchment. Based on varve counting and controlled by 14C age dates, the main goals of this thesis are (i) to identify seasonal runoff processes, which lead to significant sediment supply from the catchment into the lake basin and (ii) to investigate flood frequency under changing climate boundary conditions. This thesis follows a line of different time slices, presenting an integrative approach linking instrumental and historical flood data from Lake Mondsee in order to evaluate the flood record inferred from Lake Mondsee sediments. The investigation of eleven short cores covering the last 100 years reveals the abundance of 12 detrital layers. Therein, two types of detrital layers are distinguished by grain size, geochemical composition and distribution pattern within the lake basin. Detrital layers, which are enriched in siliciclastic and dolomitic material, reveal sediment supply from the Flysch sediments and Northern Calcareous Alps into the lake basin. These layers are thicker in the northern lake basin (0.1-3.9 mm) and thinner in the southern lake basin (0.05-1.6 mm). Detrital layers, which are enriched in dolomitic components forming graded detrital layers (turbidites), indicate the provenance from the Northern Calcareous Alps. These layers are generally thicker (0.65-32 mm) and are solely recorded within the southern lake basin. In comparison with instrumental data, thicker graded layers result from local debris flow events in summer, whereas thin layers are deposited during regional flood events in spring/summer. Extreme summer floods as reported from flood layer deposition are principally caused by cyclonic activity from the Mediterranean Sea, e.g. July 1954, July 1997 and August 2002. During the last two millennia, Lake Mondsee sediments reveal two significant flood intervals with decadal-scale flood episodes, during the Dark Ages Cold Period (DACP) and the transition from the Medieval Climate Anomaly (MCA) into the Little Ice Age (LIA) suggesting a linkage of transition to climate cooling and summer flood recurrences in the Northeastern Alps. In contrast, intermediate or decreased flood episodes appeared during the MWP and the LIA. This indicates a non-straightforward relationship between temperature and flood recurrence, suggesting higher cyclonic activity during climate transition in the Northeast Alps. The 7000-year flood chronology reveals 47 debris flows and 269 floods, with increased flood activity shifting around 3500 and 1500 varve yr BP (varve yr BP = varve years before present, before present = AD 1950). This significant increase in flood activity shows a coincidence with millennial-scale climate cooling that is reported from main Alpine glacier advances and lower tree lines in the European Alps since about 3300 cal. yr BP (calibrated years before present). Despite relatively low flood occurrence prior to 1500 varve yr BP, floods at Lake Mondsee could have also influenced human life in early Neolithic lake dwellings (5750-4750 cal. yr BP). While the first lake dwellings were constructed on wetlands, the later lake dwellings were built on piles in the water suggesting an early flood risk adaptation of humans and/or a general change of the Late Neolithic Culture of lake-dwellers because of socio-economic reasons. However, a direct relationship between the final abandonment of the lake dwellings and higher flood frequencies is not evidenced.
In this paper, we analyse the effectiveness of flood management measures based on the concept known as "retaining water in the landscape". The investigated measures include afforestation, micro-ponds and small-reservoirs. A comparative and model-based methodological approach has been developed and applied for three meso-scale catchments located in different European hydro-climatological regions: Poyo (184 km(2)) in the Spanish Mediterranean, Upper Iller (954 km(2)) in the German Alps and Kamp (621 km(2)) in Northeast-Austria representing the Continental hydro-climate. This comparative analysis has found general similarities in spite of the particular differences among studied areas. In general terms, the flood reduction through the concept of "retaining water in the landscape" depends on the following factors: the storage capacity increase in the catchment resulting from such measures, the characteristics of the rainfall event, the antecedent soil moisture condition and the spatial distribution of such flood management measures in the catchment. In general, our study has shown that, this concept is effective for small and medium events, but almost negligible for the largest and less frequent floods: this holds true for all different hydro-climatic regions, and with different land-use, soils and morphological settings.
To provide physically based wind modelling for wind erosion research at regional scale, a 3D computational fluid dynamics (CFD) wind model was developed. The model was programmed in C language based on the Navier-Stokes equations, and it is freely available as open source. Integrated with the spatial analysis and modelling tool (SAMT), the wind model has convenient input preparation and powerful output visualization. To validate the wind model, a series of experiments was conducted in a wind tunnel. A blocking inflow experiment was designed to test the performance of the model on simulation of basic fluid processes. A round obstacle experiment was designed to check if the model could simulate the influences of the obstacle on wind field. Results show that measured and simulated wind fields have high correlations, and the wind model can simulate both the basic processes of the wind and the influences of the obstacle on the wind field. These results show the high reliability of the wind model. A digital elevation model (DEM) of an area (3800 m long and 1700 m wide) in the Xilingele grassland in Inner Mongolia (autonomous region, China) was applied to the model, and a 3D wind field has been successfully generated. The clear implementation of the model and the adequate validation by wind tunnel experiments laid a solid foundation for the prediction and assessment of wind erosion at regional scale.
Monsoon systems around the world are governed by the so-called moisture-advection feedback. Here we show that, in a minimal conceptual model, this feedback implies a critical threshold with respect to the atmospheric specific humidity q(o) over the ocean adjacent to the monsoon region. If q(o) falls short of this critical value q(o)(c), monsoon rainfall over land cannot be sustained. Such a case could occur if evaporation from the ocean was reduced, e.g. due to low sea surface temperatures. Within the restrictions of the conceptual model, we estimate q(o)(c) from present-day reanalysis data for four major monsoon systems, and demonstrate how this concept can help understand abrupt variations in monsoon strength on orbital timescales as found in proxy records.
Volcanic eruptions are often preceded by seismic activity that can be used to quantify the volcanic activity. In order to allow consistent inference of the volcanic activity state from the observed seismicity patterns, objective and time-invariant classification results achievable by automatic systems should be preferred. Most automatic classification approaches need a large preclassified data set for training the system. However, in case of a volcanic crisis, we are often confronted with a lack of training data due to insufficient prior observations. In the worst case (e. g., volcanic crisis related reconfiguration of stations), there are even no prior observations available. Finally, due to the imminent crisis there might be no time for the time-consuming process of preparing a training data set. For this reason, we have developed a novel seismic-event spotting technique in order to be less dependent on previously acquired data bases and classification schemes. We are using a learning-while-recording approach based on a minimum number of reference waveforms, thus allowing for the build-up of a classification scheme as early as interesting events have been identified. First, short-term wave-field parameters (here, polarization and spectral attributes) are extracted from a continuous seismic data stream. The sequence of multidimensional feature vectors is then used to identify a fixed number of clusters in the feature space. Based on this general description of the overall wave field by a mixture of multivariate Gaussians, we are able to learn particular event classifiers (here, hidden Markov models) from a single waveform example. To show the capabilities of this new approach we apply the algorithm to a data set recorded at Soufriere Hills volcano, Montserrat. Supported by very high classification rates, we conclude that the suggested approach provides a valuable tool for volcano monitoring systems.
High-pressure is a key feature of deep subsurface environments. High partial pressure of dissolved gasses plays an important role in microbial metabolism, because thermodynamic feasibility of many reactions depends on the concentration of reactants. For gases, this is controlled by their partial pressure, which can exceed 1 MPa at in situ conditions. Therefore, high hydrostatic pressure alone is not sufficient to recreate true deep subsurface in situ conditions, but the partial pressure of dissolved gasses has to be controlled as well. We developed an incubation system that allows for incubations at hydrostatic pressure up to 60 MPa, temperatures up to 120 degrees C, and at high gas partial pressure. The composition and partial pressure of gasses can be manipulated during the experiment. To keep costs low, the system is mainly made from off-the-shelf components with only very few custommade parts. A flexible and inert PVDF (polyvinylidene fluoride) incubator sleeve, which is almost impermeable for gases, holds the sample and separates it from the pressure fluid. The flexibility of the incubator sleeve allows for sub-sampling of the medium without loss of pressure. Experiments can be run in both static and flow-through mode. The incubation system described here is usable for versatile purposes, not only the incubation of microorganisms and determination of growth rates, but also for chemical degradation or extraction experiments under high gas saturation, e.g., fluid-gas-rock-interactions in relation to carbon dioxide sequestration. As an application of the system we extracted organic compounds from sub-bituminous coal using H2O as well as a H2O-CO2 mixture at elevated temperature (90 degrees C) and pressure (5 MPa). Subsamples were taken at different time points during the incubation and analyzed by ion chromatography. Furthermore we demonstrated the applicability of the system for studies of microbial activity, using samples from the Isis mud volcano. We could detect an increase in sulfate reduction rate upon the addition of methane to the sample.
The first 1400-year floating varve chronology for north-eastern Germany covering the late Allered to the early Holocene has been established by microscopic varve counts from the Rehwiese palaeolake sediment record. The Laacher See Tephra (LST), at the base of the studied interval, forms the tephrochronological anchor point. The fine laminations were examined using a combination of micro-facies and mu XRF analyses and are typical of calcite varves, which in this case provide mainly a warm season signal. Two varve types with different sub-layer structures have been distinguished: (I) complex varves consisting of up to four seasonal sub-layers formed during the Allered and early Holocene periods, and, (II) simple two sub-layer type varves only occurring during the Younger Dryas. The precision of the chronology has been improved by varve-to-varve comparison of two independently analyzed sediment profiles based on well-defined micro-marker layers. This has enabled both (1) the precise location of single missing varies in one of the sediment profiles, and, (2) the verification of varve interpolation in disturbed varve intervals in the parallel core. Inter-annual and decadal-scale variability in sediment deposition processes were traced by multi-proxy data series including seasonal layer thickness, high-resolution element scans and total organic and inorganic carbon data at a five-varve resolution. These data support the idea of a two-phase Younger Dryas, with the first interval (12,675-12,275 varve years BP) characterised by a still significant but gradually decreasing warm-season calcite precipitation and a second phase (12,275-11,690 varve years BP) with only weak calcite precipitation. Detailed correlation of these two phases with the Meerfelder Maar record based on the LST isochrone and independent varve counts provides clues about regional differences and seasonal aspects of YD climate change along a transect from a location proximal to the North Atlantic in the west to a more continental site in the east
Terrestrial mud volcanoes (TMVs) represent geochemically diverse habitats with varying sulfur sources and yet sulfur cycling in these environments remains largely unexplored. Here we characterized the sulfur-metabolizing microorganisms and activity in four TMVs in Azerbaijan. A combination of geochemical analyses, biological rate measurements and molecular diversity surveys (targeting metabolic genes aprA and dsrA and SSU ribosomal RNA) supported the presence of active sulfur-oxidizing and sulfate-reducing guilds in all four TMVs across a range of physiochemical conditions, with diversity of these guilds being unique to each TMV. The TMVs varied in potential sulfate reduction rates (SRR) by up to four orders of magnitude with highest SRR observed in sediments where in situ sulfate concentrations were highest. Maximum temperatures at which SRR were measured was 60 degrees C in two TMVs. Corresponding with these trends in SRR, members of the potentially thermophilic, spore-forming, Desulfotomaculum were detected in these TMVs by targeted 16S rRNA analysis. Additional sulfate-reducing bacterial lineages included members of the Desulfobacteraceae and Desulfobulbaceae detected by aprA and dsrA analyses and likely contributing to the mesophilic SRR measured. Phylotypes affiliated with sulfide-oxidizing Gamma- and Betaproteobacteria were abundant in aprA libraries from low sulfate TMVs, while the highest sulfate TMV harboured 16S rRNA phylotypes associated with sulfur-oxidizing Epsilonproteobacteria. Altogether, the biogeochemical and microbiological data indicate these unique terrestrial habitats support diverse active sulfur-cycling microorganisms reflecting the in situ geochemical environment.
Microbial communities can subsist at depth in marine sediments without fresh supply of organic matter for millions of years. At threshold sedimentation rates of 1 millimeter per 1000 years, the low rates of microbial community metabolism in the North Pacific Gyre allow sediments to remain oxygenated tens of meters below the sea floor. We found that the oxygen respiration rates dropped from 10 micromoles of O-2 liter(-1) year(-1) near the sediment-water interface to 0.001 micromoles of O-2 liter(-1) year(-1) at 30-meter depth within 86 million-year-old sediment. The cell-specific respiration rate decreased with depth but stabilized at around 10(-3) femtomoles of O-2 cell(-1) day(-1) 10 meters below the seafloor. This result indicated that the community size is controlled by the rate of carbon oxidation and thereby by the low available energy flux.
Orbitolinids are larger foraminifera widespread in Lower Cretaceous shallow-water carbonates of the Tethyan realm. They are among the most important fossil groups used for Biostratigraphy. Despite this and although the structural features of the group have been described in detail, very little is known about the composition of their agglutinated test and the process by which they selected foreign grains. In this study, the test of Orbitolina d'Orbigny, 1850 (subgenus Mesorbitolina Schroeder, 1962) from Aptian shallow-water carbonate deposits of southern Italy has been studied in detail. We combine petrographic techniques (optical microscope and SEM) with energy-dispersive x-ray spectrometry (EDS), electron probe microanalyzer (EPMA), X-ray diffraction and Raman spectroscopy analyses.
The results show that the test of Mesorbitolina is composed of carbonate and non-carbonate agglutinated grains with the latter distributed across the test with a specific pattern, moving from the marginal to the central zone. In the marginal zone, non-carbonate grains are found only in the epidermis and along the septa which are composed of quartz, with smaller amounts of illite/muscovite and K-feldspar grains. In the central zone of the test, non-carbonate grains are distributed in two ways. Coarse grains of quartz and K-feldspar are abundant and randomly placed in the endoskeleton embedded in a mosaic of minute carbonate grains. Flat grains, mainly of illite/muscovite constitute the external part of the septa. Our observations indicate that Mesorbitolina did select and place agglutinated grains across its test, mainly according to their shape, whereas it did not select particles according to grain size. The distribution of agglutinated particles according to their mineralogical composition shows some contradictory evidence and therefore, at the moment, grain selection in function of mineralogy cannot be completely confirmed or ruled out. Analogies in the test composition of Mesorbitolina specimens from coeval deposits from different areas of southern Italy indicate that the features of their agglutinated test are typical characters of the genus Mesorbitolina. However, it is still unclear what advantage was obtained by the foraminifer by the described test features.
We report on a new series of isoreticular frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate (IFP-14, IFP=imidazolate framework Potsdam) that form one-dimensional, microporous hexagonal channels. Varying R in the 2-substitued linker (R=Me (IFP-1), Cl (IFP-2), Br (IFP-3), Et (IFP-4)) allowed the channel diameter (4.01.7 angstrom), the polarisability and functionality of the channel walls to be tuned. Frameworks IFP-2, IFP-3 and IFP-4 are isostructural to previously reported IFP-1. The structures of IFP-2 and IFP-3 were solved by X-ray crystallographic analyses. The structure of IFP-4 was determined by a combination of PXRD and structure modelling and was confirmed by IR spectroscopy and 1H MAS and 13C CP-MAS NMR spectroscopy. All IFPs showed high thermal stability (345400?degrees C); IFP-1 and IFP-4 were stable in boiling water for 7 d. A detailed porosity analysis was performed on the basis of adsorption measurements by using various gases. The potential of the materials to undergo specific interactions with CO2 was investigated by measuring the isosteric heats of adsorption. The capacity to adsorb CH4 (at 298 K), CO2 (at 298 K) and H2 (at 77 K) at high pressure were also investigated. In situ IR spectroscopy showed that CO2 is physisorbed on IFP-14 under dry conditions and that both CO2 and H2O are physisorbed on IFP-1 under moist conditions.
One of the major problems for the implementation of water resources planning and management in arid and semi-arid environments is the scarcity of hydrological data and, consequently, research studies. In this thesis, the hydrology of dryland river systems was analyzed and a semi-distributed hydrological model and a forecasting approach were developed for flow transmission processes in river-systems with a focus on semi-arid conditions. Three different sources of hydrological data (streamflow series, groundwater level series and multi-temporal satellite data) were combined in order to analyze the channel transmission losses of a large reach of the Jaguaribe River in NE Brazil. A perceptual model of this reach was derived suggesting that the application of models, which were developed for sub-humid and temperate regions, may be more suitable for this reach than classical models, which were developed for arid and semi-arid regions. Summarily, it was shown that this river reach is hydraulically connected with groundwater and shifts from being a losing river at the dry and beginning of rainy seasons to become a losing/gaining (mostly losing) river at the middle and end of rainy seasons. A new semi-distributed channel transmission losses model was developed, which was based primarily on the capability of simulation in very different dryland environments and flexible model structures for testing hypotheses on the dominant hydrological processes of rivers. This model was successfully tested in a large reach of the Jaguaribe River in NE Brazil and a small stream in the Walnut Gulch Experimental Watershed in the SW USA. Hypotheses on the dominant processes of the channel transmission losses (different model structures) in the Jaguaribe river were evaluated, showing that both lateral (stream-)aquifer water fluxes and ground-water flow in the underlying alluvium parallel to the river course are necessary to predict streamflow and channel transmission losses, the former process being more relevant than the latter. This procedure not only reduced model structure uncertainties, but also reported modelling failures rejecting model structure hypotheses, namely streamflow without river-aquifer interaction and stream-aquifer flow without groundwater flow parallel to the river course. The application of the model to different dryland environments enabled learning about the model itself from differences in channel reach responses. For example, the parameters related to the unsaturated part of the model, which were active for the small reach in the USA, presented a much greater variation in the sensitivity coefficients than those which drove the saturated part of the model, which were active for the large reach in Brazil. Moreover, a nonparametric approach, which dealt with both deterministic evolution and inherent fluctuations in river discharge data, was developed based on a qualitative dynamical system-based criterion, which involved a learning process about the structure of the time series, instead of a fitting procedure only. This approach, which was based only on the discharge time series itself, was applied to a headwater catchment in Germany, in which runoff are induced by either convective rainfall during the summer or snow melt in the spring. The application showed the following important features: • the differences between runoff measurements were more suitable than the actual runoff measurements when using regression models; • the catchment runoff system shifted from being a possible dynamical system contaminated with noise to a linear random process when the interval time of the discharge time series increased; • and runoff underestimation can be expected for rising limbs and overestimation for falling limbs. This nonparametric approach was compared with a distributed hydrological model designed for real-time flood forecasting, with both presenting similar results on average. Finally, a benchmark for hydrological research using semi-distributed modelling was proposed, based on the aforementioned analysis, modelling and forecasting of flow transmission processes. The aim of this benchmark was not to describe a blue-print for hydrological modelling design, but rather to propose a scientific method to improve hydrological knowledge using semi-distributed hydrological modelling. Following the application of the proposed benchmark to a case study, the actual state of its hydrological knowledge and its predictive uncertainty can be determined, primarily through rejected hypotheses on the dominant hydrological processes and differences in catchment/variables responses.
Away from active plate boundaries the relationships between spatiotemporal variations in density and geothermal gradient are important for understanding the evolution of topography in continental interiors. In this context the classic concept of the continental lithosphere as comprising three static layers of different densities (upper crust, lower crust, and upper mantle) is not adequate to assess long-term changes in topography and relief in regions associated with pronounced thermal anomalies in the mantle. We have therefore developed a one-dimensional model, which is based on thermodynamic equilibrium assemblage computations and deliberately excludes the effects of melting processes like intrusion or extrusions. Our model calculates the "metamorphic density" of rocks as a function of pressure, temperature, and chemical composition. It not only provides a useful tool for quantifying the influence of petrologic characteristics on density, but also allows the modeled "metamorphic" density to be adjusted to variable geothermal gradients and applied to different geodynamic environments. We have used this model to simulate a scenario in which the lithosphere-asthenosphere boundary is subjected to continuous heating over a long period of time (130 Ma), and demonstrate how an anorogenic plateau with an elevation of 1400 m can be formed solely as a result of heat transfer within the continental lithosphere. Our results show that, beside dynamic topography (of asthenospheric origin), density changes within the lithosphere have an important impact on the evolution of anorogenic plateaus.
Apatite fission track and apatite and zircon (U-Th)/He ages were obtained from high- and ultra high-pressure rocks from the Kaghan Valley, Pakistan. Four samples from the high altitude northern parts of the valley yielded apatite fission track ages between 24.5 +/- 3.7 and 15.6 +/- 2.1 Ma and apatite (U-Th)/He ages between 21.0 +/- 0.6 and 5.3 +/- 0.2 Ma. These data record cooling of the formerly deeply-subducted high-grade metamorphic rocks induced by denudation and exhumation consistent with extension and back sliding along the reactivated, normal-acting Main Mantle Thrust. Overlap at around 10 Ma between fission track and (U-Th)/He ages is recognised at one location (Besal) showing that fast cooling occurred due to brittle reactivation of a former thrust fault. Widespread Miocene cooling is also evident in adjacent areas to the west (Deosai Plateau, Tso Moran), most likely related to uplift and unroofing linked to continued underplating of the Indian lower crust beneath Ladakh and Kohistan in the Late Eocene to Oligocene. In the southernmost part of the study area, near Naran, two significantly younger Late Miocene to Pliocene apatite fission track ages of 7.6 +/- 2.1 to 4.0 +/- 0.5 Ma suggest a spatial and temporal separation of exhumation processes. These younger ages are best explained by enhanced Late Miocene uplift and erosion driven by thrusting along the Main Boundary Thrust.
Intensive grazing leads to land degradation and desertification of grassland ecosystems followed by serious environmental and social problems. The Xilingol steppe grassland in Inner Mongolia, China, which has been a sink area for dust for centuries, is strongly affected by the negative effects of overgrazing and wind erosion. The aim of this study is the provision of a wind erosion risk map with a spatial high resolution of 25 m to identify actual source and sink areas. In an integrative approach, field measurements of vegetation features and surface roughness length z0 were combined with Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) image data for a land use classification. To determine the characteristics of the different land use classes, a field observation (ground truth) was performed in April 2009. The correlation of vegetation height and z0 (R2 = 0.8, n = 55) provided the basis for a separation of three main classes, grassland, non-vegetation and other. The integration of the soil-adjusted vegetation index (SAVI) and the spectral information from the atmospheric corrected ASTER bands 1, 2 and 3 (visible to near-infrared) led to a classification of the overall accuracy (OA) of 0.79 with a kappa () statistic of 0.74, respectively. Additionally, a digital elevation model (DEM) was used to identify topographical effects in relation to the main wind direction, which enabled a qualitative estimation of potential dust deposition areas. The generated maps result in a significantly higher description of the spatial variability in the Xilingol steppe grassland reflecting the different land use intensities on the current state of the grassland less, moderately and highly degraded. The wind erosion risk map enables the identification of characteristic mineral dust sources, sinks and transition zones.
Questions remain about the exact ultrasonic energy level that is required to effectively disperse soil aggregates and to what extent this is accompanied by physical damage to individual soil particles. We found maximum aggregate dispersion at energy levels of 1500 J?cm3 and no evidence for the disintegration of particles < 20 mu m even at that energy level. Our findings suggest that sonication at energies much greater than those applied conventionally can disperse aggregates of high mechanical stability.
Analyzing insurance-loss data we derive stochastic storm-damage functions for residential buildings. On district level we fit power-law relations between daily loss and maximum wind speed, typically spanning more than 4 orders of magnitude. The estimated exponents for 439 German districts roughly range from 8 to 12. In addition, we find correlations among the parameters and socio-demographic data, which we employ in a simplified parametrization of the damage function with just 3 independent parameters for each district. A Monte Carlo method is used to generate loss estimates and confidence bounds of daily and annual storm damages in Germany. Our approach reproduces the annual progression of winter storm losses and enables to estimate daily losses over a wide range of magnitudes. Citation: Prahl, B. F., D. Rybski, J. P. Kropp, O. Burghoff, and H. Held (2012), Applying stochastic small-scale damage functions to German winter storms, Geophys. Res. Lett., 39, L06806, doi: 10.1029/2012GL050961.
The seasonal succession of plankton is an annually repeated process of community assembly during which all major external factors and internal interactions shaping communities can be studied. A quarter of a century ago, the state of this understanding was described by the verbal plankton ecology group (PEG) model. It emphasized the role of physical factors, grazing and nutrient limitation for phytoplankton, and the role of food limitation and fish predation for zooplankton. Although originally targeted at lake ecosystems, it was also adopted by marine plankton ecologists. Since then, a suite of ecological interactions previously underestimated in importance have become research foci: overwintering of key organisms, the microbial food web, parasitism, and food quality as a limiting factor and an extended role of higher order predators. A review of the impact of these novel interactions on plankton seasonal succession reveals limited effects on gross seasonal biomass patterns, but strong effects on species replacements.
Low biostratigraphic resolution and lack of chronostratigraphic calibration hinder precise correlations between platform carbonates and coeval deep-water successions. These are the main obstacle when studying the record of Mesozoic oceanic anoxic events in carbonate platforms. In this paper carbon and strontium isotope stratigraphy are used to produce the first chronostratigraphic calibration of the Barremian-Aptian biostratigraphy of the Apenninic carbonate platform of southern Italy. According to this calibration, the segment of decreasing delta C-13 values, leading to the negative peak that is generally taken as the onset of the Selli event, starts a few metres above the last occurrence of Palorbitolina lenticularis and Voloshinoides murgensis. The following rise of delta C-13 values, corresponding to the interval of enhanced accumulation of organic matter in deep-water sections, ends just below the first acme of Salpingoporella dinarica, which roughly corresponds to the segment of peak delta C-13 values. The whole carbon isotope excursion associated with the oceanic anoxic event 1a is bracketed in the Apenninic carbonate platform between the last occurrence of Voloshinoides murgensis and the "Orbitolina level", characterized by the association of Mesorbitolina parva and Mesorbitolina texana. Since these bioevents have been widely recognized beyond the Apenninic platform, the calibration presented in this paper can be used to pinpoint the interval corresponding to the Early Aptian oceanic anoxic event in other carbonate platforms of central and southern Tethys. This calibration will be particularly useful to interpret the record of the Selli event in carbonate platform sections for which a reliable carbon isotope stratigraphy is not available.
We investigate the crust, upper mantle and mantle transition zone of the Cape Verde hotspot by using seismic P and S receiver functions from several tens of local seismograph stations. We find a strong discontinuity at a depth of similar to 10 km underlain by a similar to 15-km thick layer with a high (similar to 1.9) Vp/Vs velocity ratio. We interpret this discontinuity and the underlying layer as the fossil Moho, inherited from the pre-hotspot era, and the plume-related magmatic underplate. Our uppermost-mantle models are very different from those previously obtained for this region: our S velocity is much lower and there are no indications of low densities. Contrary to previously published arguments for the standard transition zone thickness our data indicate that this thickness under the Cape Verde islands is up to similar to 30 km less than in the ambient mantle. This reduction is a combined effect of a depression of the 410-km discontinuity and an uplift of the 660-km discontinuity. The uplift is in contrast to laboratory data and some seismic data on a negligible dependence of depth of the 660-km discontinuity on temperature in hotspots. A large negative pressure-temperature slope which is suggested by our data implies that the 660-km discontinuity may resist passage of the plume.
Our data reveal beneath the islands a reduction of S velocity of a few percent between 470-km and 510-km depths. The low velocity layer in the upper transition zone under the Cape Verde archipelago is very similar to that previously found under the Azores and a few other hotspots. In the literature there are reports on a regional 520-km discontinuity, the impedance of which is too large to be explained by the known phase transitions. Our observations suggest that the 520-km discontinuity may present the base of the low-velocity layer in the transition zone.
Deposits of submarine debris flows can build up substantial topography on the sea floor. The resulting sea floor morphology can strongly influence the pathways of and deposition from subsequent turbidity currents. Map views of sea floor morphology are available for parts of the modern sea floor and from high-resolution seismic-reflection data. However, these data sets usually lack lithological information. In contrast, outcrops provide cross-sectional and lateral stratigraphic details of deep-water strata with superb lithological control but provide little information on sea floor morphology. Here, a methodology is presented that extracts fundamental lithological information from sediment core and well logs with a novel calibration between core, well-logs and seismic attributes within a large submarine axial channel belt in the Tertiary Molasse foreland basin, Austria. This channel belt was the course of multiple debris-flow and turbidity current events, and the fill consists of interbedded layers deposited by both of these processes. Using the core-well-seismic calibration, three-dimensional lithofacies proportion volumes were created. These volumes enable the interpretation of the three-dimensional distribution of the important lithofacies and thus the investigation of sea floor morphology produced by debris-flow events and its impact on succeeding turbidite deposition. These results show that the distribution of debris-flow deposits follows a relatively regular pattern of levees and lobes. When subsequent high-density turbidity currents encountered this mounded debris-flow topography, they slowed and deposited a portion of their sandy high-density loads just upstream of morphological highs. Understanding the depositional patterns of debris flows is key to understanding and predicting the location and character of associated sandstone accumulations. This detailed model of the filling style and the resulting stratigraphic architecture of a debris-flow dominated deep-marine depositional system can be used as an analogue for similar modern and ancient systems.
Discontinuity surfaces are widely recognized but often poorly understood features of epeiric carbonate settings. In sedimentary systems, these features often represent hiatus surfaces below biostratigraphic resolution and may represent a considerable portion of the time contained in the sediment record. From an applied perspective, discontinuities may represent horizontal flow barriers and result in reservoir compartmentalization. Here, a total of 80 condensed surfaces (S1), firmgrounds (S2) and hardgrounds (S3) from a Jurassic (Middle and Upper Bajocian Assoul Formation) ramp setting of the High Atlas in Morocco are carefully documented with respect to their morphology, their secondary impregnation by Fe and Mn oxides and phosphates and their palaeoecological record. A statistical frequency distribution of two surfaces of the S1 type, 1.1 surfaces of the S2 type and 0.4 surfaces of the S3 type per 10 section metres is observed along a 220 m long carbonate succession. Based on two stratigraphically and spatially separated study windows and correlative sections, the stratigraphic frequency distribution, the lateral extent and the nature of facies change across discontinuities are documented in a quantitative manner. Specific features of the study site include the considerable stratigraphic thickness of the Assoul Formation and the conspicuous absence of subaerial-exposure-related features. Based on the data presented here, firmground and hardground surfaces are best interpreted as maximum-regression-related features. Relative sea-level lowstand results in a lowered wave base, and wave orbitals and currents result in sea floor omission and lithification. Care must be taken to avoid overly simplistic interpretations, as differences in bathymetry and carbonate facies result in marked changes in discontinuity characteristics in proximal-distal transects. The data shown here are of significance for those concerned with the interpretation of shoal water carbonate environments and are instrumental in the building of more realistic carbonate reservoir flow models.
Multibeam bathymetry revealed the occurrence of numerous craterlike depressions, so-called pockmarks, on the sea floor of the Hammerfest Basin and the Loppa High, south-western Barents Sea. To investigate whether these pockmarks are related to ongoing gas seepage, microbial processes associated with methane metabolism were analyzed using geochemical, biogeochemical and microbiological techniques. Gravity cores were collected along transects crossing individual pockmarks, allowing a direct comparison between different locations inside (assumed activity center), on the rim, and outside of a pockmark (reference sites). Concentrations of hydrocarbons in the sediment, particularly methane, were measured as headspace (free) gas, and in the occluded and adsorbed gas fraction. Down to a depth of 2.6 m below sea floor (mbsf) sulfate reduction rates were quantified by radiotracer incubations. Concentrations of dissolved sulfate in the porewater were determined as well. Neither the sulfate profiles nor the gas measurements show any evidence of microbial activity or active fluid venting. Methane concentrations and sulfate reduction rates were extremely low or even below the detection limit. The results show that the observed sediment structures are most likely paleo-pockmarks, their formation probably occurred during the last deglaciation.
Sedimentological, provenance, and detrital thermochronological results for basin fill at the modern deformation front of the northern Andes (6 degrees N latitude) provide a long-term, Eocene to Pliocene record of foreland-basin sedimentation along the Eastern Cordillera !Janos basin boundary in Colombia. Lithofacies assemblages and paleocurrent orientations in the upward-coarsening, 5-km-thick succession of the Nunchia syncline reveal a systematic shift from craton-derived, shallow-marine distal foreland (back-bulge) accumulation in the Mirador Formation, to orogen-sourced, deltaic, and coastalinfluenced sedimentation of the distal to medial foreland (foredeep) in the Carbonera and Leon Formations, to anastomosing fluvial and distributive braided fluvial megafan systems of the proximal foreland (foredeep to wedge-top) basin in the lower and upper Guayabo Formation. These changes in depositional processes and sediment dispersal are supported by up-section variations in detrital zircon U-Pb and (U-Th)/He ages that record exhumation of evolving, compartmentalized sediment source areas in the Eastern Cordillera. The data are interpreted in terms of a progressive eastward advance in foldand-thrust deformation, with late Eocene Oligocene deformation in the axial zone of the Eastern Cordillera along the western edge of Floresta basin (Soapaga thrust), early Miocene reactivation (inversion) of the eastern margin of the Mesozoic rift system (Pajarito and Guaicaramo thrusts), and middle late Miocene propagation of a footwall shortcut fault (Vopal thrust) that created the Nunchia syncline in a wedge-top (piggyback) setting of the eastern foothills along the transition from the Eastern Cordillera to Harms foreland basin. Collectively, the data presented here for the frontal Eastern Cordillera define a general in-sequence pattern of eastwardadvancing fold-and-thrust deformation during Cenozoic east-west shortening in the Colombian Andes.
Agriculture is one of the most important human activities providing food and more agricultural goods for seven billion people around the world and is of special importance in sub-Saharan Africa. The majority of people depends on the agricultural sector for their livelihoods and will suffer from negative climate change impacts on agriculture until the middle and end of the 21st century, even more if weak governments, economic crises or violent conflicts endanger the countries’ food security. The impact of temperature increases and changing precipitation patterns on agricultural vegetation motivated this thesis in the first place. Analyzing the potentials of reducing negative climate change impacts by adapting crop management to changing climate is a second objective of the thesis. As a precondition for simulating climate change impacts on agricultural crops with a global crop model first the timing of sowing in the tropics was improved and validated as this is an important factor determining the length and timing of the crops´ development phases, the occurrence of water stress and final crop yield. Crop yields are projected to decline in most regions which is evident from the results of this thesis, but the uncertainties that exist in climate projections and in the efficiency of adaptation options because of political, economical or institutional obstacles have to be considered. The effect of temperature increases and changing precipitation patterns on crop yields can be analyzed separately and varies in space across the continent. Southern Africa is clearly the region most susceptible to climate change, especially to precipitation changes. The Sahel north of 13° N and parts of Eastern Africa with short growing seasons below 120 days and limited wet season precipitation of less than 500 mm are also vulnerable to precipitation changes while in most other part of East and Central Africa, in contrast, the effect of temperature increase on crops overbalances the precipitation effect and is most pronounced in a band stretching from Angola to Ethiopia in the 2060s. The results of this thesis confirm the findings from previous studies on the magnitude of climate change impact on crops in sub-Saharan Africa but beyond that helps to understand the drivers of these changes and the potential of certain management strategies for adaptation in more detail. Crop yield changes depend on the initial growing conditions, on the magnitude of climate change, and on the crop, cropping system and adaptive capacity of African farmers which is only now evident from this comprehensive study for sub-Saharan Africa. Furthermore this study improves the representation of tropical cropping systems in a global crop model and considers the major food crops cultivated in sub-Saharan Africa and climate change impacts throughout the continent.
Many agriculture-based economies are increasingly under stress from climate change and socio-economic pressures. The excessive exploitation of natural resources still represents the standard procedure to achieve socio-economic development. In the area of the Moulouya river basin, Morocco, natural water availability represents a key resource for all economic activities. Agriculture represents the most important sector, and frequently occurring water deficits are aggravated by climate change. On the basis of historical trends taken from CRU TS 2.1, this paper analyses the impact of climate change on the per capita water availability under inclusion of population trends. The Climatic Water Balance (CWB) shows a significant decrease for the winter period, causing adverse effects for the main agricultural season. Further, moisture losses due to increasing evapotranspiration rates indicate problems for the annual water budget and groundwater recharge. The per capita blue water availability falls below a minimum threshold of 500 m(3) per year, denoting a high regional vulnerability to increasing water scarcity assuming a no-response scenario. Regional development focusing on the water-intense sectors of agriculture and tourism appears to be at risk. Institutional capacities and policies need to address the problem, and the prompt implementation of innovative water production and efficiency measures is recommended.
The sediment flux through Himalayan rivers directly impacts water quality and is important for sustaining agriculture as well as maintaining drinking-water and hydropower generation. Despite the recent increase in demand for these resources, little is known about the triggers and sources of extreme sediment flux events, which lower water quality and account for extensive hydropower reservoir filling and turbine abrasion. Here, we present a comprehensive analysis of the spatiotemporal trends in suspended sediment flux based on daily data during the past decade (2001-2009) from four sites along the Sutlej River and from four of its main tributaries. In conjunction with satellite data depicting rainfall and snow cover, air temperature and earthquake records, and field observations, we infer climatic and geologic controls of peak suspended sediment concentration (SSC) events. Our study identifies three key findings: First, peak SSC events (a parts per thousand yen 99th SSC percentile) coincide frequently (57-80%) with heavy rainstorms and account for about 30% of the suspended sediment flux in the semi-arid to arid interior of the orogen. Second, we observe an increase of suspended sediment flux from the Tibetan Plateau to the Himalayan Front at mean annual timescales. This sediment-flux gradient suggests that averaged, modern erosion in the western Himalaya is most pronounced at frontal regions, which are characterized by high monsoonal rainfall and thick soil cover. Third, in seven of eight catchments, we find an anticlockwise hysteresis loop of annual sediment flux variations with respect to river discharge, which appears to be related to enhanced glacial sediment evacuation during late summer. Our analysis emphasizes the importance of unconsolidated sediments in the high-elevation sector that can easily be mobilized by hydrometeorological events and higher glacial-meltwater contributions. In future climate change scenarios, including continuous glacial retreat and more frequent monsoonal rainstorms across the Himalaya, we expect an increase in peak SSC events, which will decrease the water quality and impact hydropower generation.
East African paleoenvironments are highly variable, marked by extreme fluctuations in moisture availability, which has far-reaching implications for the origin, evolution and dispersal of Homo sapiens in and beyond the region. This paper presents results from a pilot core from the Chew Bahir basin in southern Ethiopia that records the climatic history of the past 45 ka, with emphasis on the African Humid Period (AHP, similar to 15-5 ka calBP). Geochemical, physical and biological indicators show that Chew Bahir responded to climatic fluctuations on millennial to centennial timescales, and to the precessional cycle, since the Last Glacial Maximum. Potassium content of the sediment appears to be a reliable proxy for aridity, showing that Chew Bahir reacted to the insolation-controlled humidity increase of the AHP with a remarkably abrupt onset and a gradual termination, framing a sharply defined arid phase (similar to 12.8-11.6 ka calBP) corresponding to the Younger Dryas chronozone. The Chew Bahir record correlates well with low- and high-latitude paleoclimate records, demonstrating that the site responded to regional and global climate changes.
Understanding the dynamics of sediment fluxes is a key issue to constrain modern erosion rates in mountain belts and determine the still debated level of control exerted by precipitation, topography and tectonics. The well defined monsoon seasonality in the Himalayas, together with active tectonics and strong relief provide an ideal environment to assess these possible interactions. For this purpose, we present a new compilation of daily suspended sediment data for 12 stations of the major rivers of the Nepal Himalayas. We analyze the relationships of sediment transport with daily river discharge and precipitation data as well as with morphometric parameters. We show that suspended sediment concentrations vary systematically through the seasons and asynchronously to river discharge displaying a hysteresis effect. This clockwise hysteresis effect disappears when suspended sediment fluxes are directly compared with direct storm discharge. Therefore we attribute the hysteresis effect to groundwater dilution rather than a sediment supply limitation. We infer a rating model to calculate erosion rates directly from long river discharge chronicles. We show that, when normalized by drainage area and mean sediment flux, all rivers exhibit the same trend. This similarity implies that all river basins have the same erosion behavior, independent of location, size and catchment characteristics. Erosion rates calculated from suspended sediment fluxes range between 0.1 and 2.8 mm/yr. The erosion rates of the three main basins of Nepal are in the range 0.9-1.5 mm/yr. Erosion rates in the Higher Himalayas are relatively low ( <0.5 mm/yr, except for Kali Gandaki), while in the Lesser Himalayas they range from 0.2 to 2 mm/yr. We propose that material transport in the rivers depends on hillslope sediment supply, which is, in turn, controlled by those rainfalls producing direct runoff. In other words, the rivers in the Nepal Himalayas are supply-limited and the hillsopes as a contributing source are transport-limited. We also show that erosion processes are not as much controlled by infrequently occurring extreme precipitation events, than by moderate ones with a high recurrence interval.
Constructing a hidden Markov Model based earthquake detector: application to induced seismicity
(2012)
The triggering or detection of seismic events out of a continuous seismic data stream is one of the key issues of an automatic or semi-automatic seismic monitoring system. In the case of dense networks, either local or global, most of the implemented trigger algorithms are based on a large number of active stations. However, in the case of only few available stations or small events, for example, like in monitoring volcanoes or hydrothermal power plants, common triggers often show high false alarms. In such cases detection algorithms are of interest, which show reasonable performance when operating even on a single station. In this context, we apply Hidden Markov Models (HMM) which are algorithms borrowed from speech recognition. However, many pitfalls need to be avoided to apply speech recognition technology directly to earthquake detection. We show the fit of the model parameters in an innovative way. State clustering is introduced to refine the intrinsically assumed time dependency of the HMMs and we explain the effect coda has on the recognition results. The methodology is then used for the detection of anthropogenicly induced earthquakes for which we demonstrate for a period of 3.9 months of continuous data that the single station HMM earthquake detector can achieve similar detection rates as a common trigger in combination with coincidence sums over two stations. To show the general applicability of state clustering we apply the proposed method also to earthquake classification at Mt. Merapi volcano, Indonesia.
Reliable age models are fundamental for any palaeoclimate reconstruction. Available interpolation procedures between age control points are often inadequately reported, and very few translate age uncertainties to proxy uncertainties. Most available modeling algorithms do not allow incorporation of layer counted intervals to improve the confidence limits of the age model in question.
We present a framework that allows detection and interactive handling of age reversals and hiatuses, depth-age modeling, and proxy-record reconstruction. Monte Carlo simulation and a translation procedure are used to assign a precise time scale to climate proxies and to translate dating uncertainties to uncertainties in the proxy values. The presented framework allows integration of incremental relative dating information to improve the final age model. The free software package COPRA1.0 facilitates easy interactive usage.
Within the field of species distribution modelling an apparent dichotomy exists between process-based and correlative approaches, where the processes are explicit in the former and implicit in the latter. However, these intuitive distinctions can become blurred when comparing species distribution modelling approaches in more detail. In this review article, we contrast the extremes of the correlativeprocess spectrum of species distribution models with respect to core assumptions, model building and selection strategies, validation, uncertainties, common errors and the questions they are most suited to answer. The extremes of such approaches differ clearly in many aspects, such as model building approaches, parameter estimation strategies and transferability. However, they also share strengths and weaknesses. We show that claims of one approach being intrinsically superior to the other are misguided and that they ignore the processcorrelation continuum as well as the domains of questions that each approach is addressing. Nonetheless, the application of process-based approaches to species distribution modelling lags far behind more correlative (process-implicit) methods and more research is required to explore their potential benefits. Critical issues for the employment of species distribution modelling approaches are given, together with a guideline for appropriate usage. We close with challenges for future development of process-explicit species distribution models and how they may complement current approaches to study species distributions.
Developments of future scenarios of Antarctic ecosystems are still in their infancy, whilst predictions of the physical environment are recognized as being of global relevance and corresponding models are under continuous development. However, in the context of environmental change simulations of the future of the Antarctic biosphere are increasingly demanded by decision makers and the public, and are of fundamental scientific interest. This paper briefly reviews existing predictive models applied to Antarctic ecosystems before providing a conceptual framework for the further development of spatially and temporally explicit ecosystem models. The concept suggests how to improve approaches to relating species' habitat description to the physical environment, for which a case study on sea urchins is presented. In addition, the concept integrates existing and new ideas to consider dynamic components, particularly information on the natural history of key species, from physiological experiments and biomolecular analyses. Thereby, we identify and critically discuss gaps in knowledge and methodological limitations. These refer to process understanding of biological complexity, the need for high spatial resolution oceanographic data from the entire water column, and the use of data from biomolecular analyses in support of such ecological approaches. Our goal is to motivate the research community to contribute data and knowledge to a holistic, Antarctic-specific, macroecological framework. Such a framework will facilitate the integration of theoretical and empirical work in Antarctica, improving our mechanistic understanding of this globally influential ecoregion, and supporting actions to secure this biodiversity hotspot and its ecosystem services.
CpG-oligonucleotides modulate sphingosine-1-phosphate metabolism in normal human keratinocytes
(2012)
Spatially explicit multi-year crop information is required for many environmental applications. The study presented here proposes a hierarchical classification approach for per-plot crop type identification that is based on spectral-temporal profiles and accounts for deviations from the average growth stage timings by incorporating agro-meteorological information in the classification process. It is based on the fact that each crop type has a distinct seasonal spectral behavior and that the weather may accelerate or delay crop development. The classification approach was applied to map 12 crop types in a 14,000 km(2) catchment area in Northeast Germany for several consecutive years. An accuracy assessment was performed and compared to those of a maximum likelihood classification. The 7.1% lower overall classification accuracy of the spectral-temporal profiles approach may be justified by its independence of ground truth data. The results suggest that the number and timing of image acquisition is crucial to distinguish crop types. The increasing availability of optical imagery offering a high temporal coverage and a spatial resolution suitable for per-plot crop type mapping will facilitate the continuous refining of the spectral-temporal profiles for common crop types and different agro-regions and is expected to improve the classification accuracy of crop type maps using these profiles.
Crosshole traveltime tomography using particle swarm optimization a near-surface field example
(2012)
Particle swarm optimization (PSO) is a relatively new global optimization approach inspired by the social behavior of bird flocking and fish schooling. Although this approach has proven to provide excellent convergence rates in different optimization problems, it has seldom been applied to inverse geophysical problems. Until today, published geophysical applications mainly focus on finding an optimum solution for simple, 1D inverse problems. We have applied PSO-based optimization strategies to reconstruct 2D P-wave velocity fields from crosshole traveltime data sets. Our inversion strategy also includes generating and analyzing a representative ensemble of acceptable models, which allows us to appraise uncertainty and nonuniqueness issues. The potential of our strategy was tested on field data collected at a well-constrained test site in Horstwalde, Germany. At this field site, the shallow subsurface mainly consists of sand- and gravel-dominated glaciofluvial sediments, which, as known from several boreholes and other geophysical experiments, exhibit some well-defined layering at the scale of our crosshole seismic data. Thus, we have implemented a flexible, layer-based model parameterization, which, compared with standard cell-based parameterizations, allows for significantly reducing the number of unknown model parameters and for efficiently implementing a priori model constraints. Comparing the 2D velocity fields resulting from our PSO strategy to independent borehole and direct-push data illustrated the benefits of choosing an efficient global optimization approach. These include a straightforward and understandable appraisal of nonuniqueness issues as well as the possibility of an improved and also more objective interpretation.
The Maule earthquake (Mw 8.8) that affected south-central Chile on February 27, 2010 was preceded by the 1835 event documented by FitzRoy and Darwin. The relation between both events has been controversial. Fault slip in 2010 estimated by Lorito et al. (2011) is less than expected from 175 years of strain accumulation, leading them to conclude only limited overlap between the 2010 and 1835 events, and that a Mw 7.5-8 event could still strike the Concepcion region. However, Lorito et al.'s model was based on displacements obtained from only 6 GPS stations and underpredicts observations from recent studies. Here we show that an alternative model based on 169 GPS displacements reproduces the data better, suggesting Lorito et al.'s main conclusion is not correct. Based on a slip deficit map, we suggest the seismic gap opened in 1835 was most likely closed in 2010.
Metamorphic studies in the cover sequences of the Bitlis complex allow the thermal evolution of the massif to be constrained using metamorphic index minerals. Regionally distributed metamorphic index minerals such as glaucophane, carpholite, relics of carpholite in chloritoid-bearing schists and pseudomorphs after aragonite in marbles record a LT-HP evolution:This demonstrates that the Bitlis complex was subducted and stacked to form a nappe complex during the closure of the Neo-Tethys. During late Cretaceous to Cenozoic evolution the Bitlis complex experienced peak metamorphism of 1.0-1.1 GPa at 350-400 degrees C. During the retrograde evolution temperatures remained below 460 degrees C. Ar-39/Ar-40 dating of white mica in different parageneses from the Bitlis complex reveals a 74-79 Ma (Campanian) date of peak metamorphism and rapid exhumation to an almost isothermal greenschist stage at 67-70 Ma (Maastrichtian). The HP Eocene flysch escaped the greenschist facies stage and were exhumed under very cold conditions. These single stage evolutions contrast with the multistage evolution reported further north from the Amassia-Stepanavan Suture in Armenia. Petrological investigations and isotopic dating show that the collision of Arabia with Eurasia resulted in an assemblage of different blocks derived from the northern as well as from the southern plate and a set of subduction zones producing HP rocks with diverse exhumation histories.
In the framework of the Dead Sea Integrated Research project (DESIRE), 59 seismological stations were deployed in the region of the Dead Sea Basin. Twenty of these stations recorded data of sufficiently high quality between May and September 2007 to be used for ambient seismic noise analysis. Empirical Green's functions are extracted from cross-correlations of long term recordings. These functions are dominated by Rayleigh waves, whose group velocities can be measured in the frequency range from 0.1 to 0.5 Hz. Analysis of positive and negative correlation lags of the Green's functions makes it possible to identify the direction of the source of the incoming energy. Signals with frequencies higher than 0.2 Hz originate from the Mediterranean Sea, while low frequencies arrive from the direction of the Red Sea. Travel times of the extracted Rayleigh waves were measured between station pairs for different frequencies, and tomographically inverted to provide independent velocity models. Four such 2D models were computed for a set of frequencies, all corresponding to different sampling depths, and thus together giving an indication of the velocity variations in 3D extending to a depth of 10 km. The results show low velocities in the Dead Sea Basin, consistent with previous studies suggesting up to 8 km of recent sedimentary infill in the Basin. The complex structure of the western margin of the Basin is also observed, with sedimentary infill present to depths not exceeding 5 km west of the southern part of the Dead Sea. The high velocities associated with the Lisan salt diapir are also observed down to a depth of similar to 5 km. The reliability of the results is confirmed by checkerboard recovery tests.
Determination of the source rocks for the diatexites from the Edough Massif, Annaba, NE Algeria
(2012)
The crystalline Edough Massif is located in the oriental part of the Algerian coastline. It consists of two tectonically superposed units of gneisses, augen-gneisses and migmatitic gneisses in the lower unit and micaschists in the upper unit. The crystalline rocks underwent a low to moderate degree of metamorphism; the gneisses suffered partial melting. They display migmatitic features such as nebulitic structures with contorted leucosome layers and K-feldspar porphyroblasts and thus can be classified as diatexites. The mineralogical composition of these rocks is very homogenous and consists of K-feldspar, micas and quartz. The feldspar-rich, arkosic nature of the outcrop implies a granitic source rock. High K2O/Na2O ratios and high A/CNK > 1.1 indicate an S-type granite source and a peraluminous composition of the protolith respectively. Chondrite normalized REE distribution patterns of the Edough diatexites show gently inclined patterns with a minor negative Eu anomaly (Eu/Eu* = 0.36-0.49), which points to a very slightly differentiated granitic source. The REE pattern and trace element data of the diatexites are similar to those of average Proterozoic upper continental crust, which suggests that they are derived mainly from upper continental crust and were deposited in continental margins.
The expansion of soybean cultivation into the Amazon in Brazil has potential hydrological effects at local to regional scales. To determine the impacts of soybean agriculture on hydrology, a comparison of net precipitation (throughfall, stemflow) in undisturbed tropical forest and soybean fields on the southern edge of the Amazon Basin in the state of Mato Grosso is needed. This study measured throughfall with troughs and stemflow with collar collectors during two rainy seasons. The results showed that in forest 91.6% of rainfall was collected as throughfall and 0.3% as stemflow, while in soybean fields with two-month old plants, 46.2% of rainfall was collected as throughfall and 9.0% as stemflow. Hence, interception of precipitation in soybean fields was far greater than in intact forests. Differences in throughfall, stemflow and net precipitation were found to be mainly associated with differences in plant structure and stem density in transitional forest and soybean cropland. Because rainfall interception in soybean fields is higher than previously believed and because both the area of cropland and the frequency of crop cycles (double cropping) are increasing rapidly, interception needs to be reconsidered in regional water balance models when consequences of land cover changes are analyzed in the Amazon soybean frontier region. Based on the continued expansion of soybean fields across the landscape and the finding that net precipitation is lower in soy agriculture, a reduction in water availability in the long term can be assumed.
Declining groundwater levels in some forested regions in Northeast Germany indicate a reduction in groundwater recharge. Various interlinked aspects, such as changes in climate conditions and changes in forest structure, have been considered as the main factors affecting the regional level of groundwater recharge.
For this study, the water balance model WaSiM-ETH was used to calculate groundwater recharge in a 104 km(2) area between 1958 and 2007. Climate impact analysis was driven by observed data from neighbouring meteorological stations. Changes in forest stands were reconstructed from the current status and literature studies.
The model-based analysis showed that the average groundwater recharge under forest areas decreased from 1958 to 2007, with a trend of 2.3 mm/yr(2). The most important effect was changing climatic boundary conditions, which made up 53% of the decrease. Declining precipitation is identified as the main factor. Changes in tree age distribution caused 18% of the decrease, and the change of ground vegetation under pines (Pinus sylvestris) accounts for 29%.
In respect of the complexity and the interconnectivity of the processes of groundwater recharge, the necessity of using process-oriented distributed models such as WaSiM-ETH is discussed.
We conclude that changes in forest stands affecting groundwater recharge could play a significant role in the water balance, especially in regions with a priori low total runoff, this has up to now often remained unquantified.
Disproportionate single-species contribution to canopy-soil nutrient flux in an Amazonian rainforest
(2012)
Rainfall, throughfall and stemflow were monitored on an event basis in an undisturbed open tropical rainforest with a large number of palm trees located in the southwestern Amazon basin of Brazil. Stemflow samples were collected from 24 trees with a diameter at breast height (DBH) > 5 cm, as well as eight young and four full-grown babassu palms (Attalea speciosa Mart.) for 5 weeks during the peak of the wet season. We calculated rainfall, throughfall and stemflow concentrations and fluxes of Na+, K+, Ca2+, Mg2+,, Cl-, SO42-, NO3- and H+ and stemflow volume-weighted mean concentrations and fluxes for three size classes of broadleaf trees and three size classes of palms. The concentrations of most solutes were higher in stemflow than in rainfall and increased with increasing tree and palm size. Concentration enrichments from rainfall to stemflow and throughfall were particularly high (81-fold) for NO3-. Stemflow fluxes of NO3- and H+ exceeded throughfall fluxes but stemflow fluxes of other solutes were less than throughfall fluxes. Stemflow solute fluxes to the forest soil were dominated by fluxes on babassu palms, which represented only 4% of total stem number and 10% of total basal area. For NO3-, stemflow contributed 51% of the total mass of nitrogen delivered to the forest floor (stemflow + throughfall) and represented more than a 2000-fold increase in NO3- flux compared what would have been delivered by rainfall alone on the equivalent area. Because these highly localized fluxes of both water and NO3- persist in time and space, they have the potential to affect patterns of soil moisture, microbial populations and other features of soil biogeochemistry conducive to the creation of hotspots for nitrogen leaching and denitrification, which could amount to an important fraction of total ecosystem fluxes. Because these hotspots occur over very small areas, they have likely gone undetected in previous studies and need to be considered as an important feature of the biogeochemistry of palm-rich tropical forest.
The rooted zone of a soil, more precisely the rhizosphere, is a very dynamic system. Some of the key processes are water uptake and root respiration. We have developed a novel method for measuring the real-time distribution of water and oxygen concentration in the rhizosphere as a biogeochemical interface in soil. This enables understanding where and when roots are active in respect to root respiration and water uptake and how the soil responds to it.
We used glass containers (15 x 15 x 1 cm), which were filled with a quartz sand mixture. Sensor foils for fluorescence dye imaging of O-2 were installed on the inner side of the containers. A lupine plant was grown in each container for 2 weeks under controlled conditions. Then we took time series of fluorescence images for time-lapsed visualization of oxygen depletion caused by root respiration. Changing water content was mapped in parallel by non-invasive neutron radiography, which yields water content distributions in high spatial resolution. Also it can detect the root system of the lupine plants. By this combined imaging of the samples, a range of water contents and different oxygen concentration levels, both induced by root activities, could be assessed.
We monitored the dynamics of these vital parameters induced by roots during a period of several hours. We observed that for high water saturation, the oxygen concentration decreased in parts of the container. The accompanying neutron radiographies gave us the information that these locations are spatially correlated to roots. Therefore, it can be concluded that the observed oxygen deficits close to the roots result from root respiration and show up while re-aeration from atmosphere by gas phase transport is restricted by the high water saturation.
Our coupled imaging setup was able to monitor the spatial distribution and temporal dynamics of oxygen and water content in a night and day cycle. This reflects complex plant activities such as photosynthesis, transpiration, and metabolic activities impacting the root-soil interface. Our experimental setup provides the possibility to non-invasively visualize these parameters with high resolution. The particular oxygen imaging method as well as the combination with simultaneously mapping the water content by neutron radiography is a novelty.
Afyon Zone, which was derived from the Anatolide-Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic basement and unconformably overlying Triassic-Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated from the underlying Silurian-Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (similar to 250 Ma) ages, which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys.
Quantitative estimates of sediment flux and the global cycling of sediments from hillslopes to rivers, estuaries, deltas, continental shelves, and deep-sea basins have a long research tradition. In this context, extremely large and commensurately rare sediment transport events have so far eluded a systematic analysis. To start filling this knowledge gap I review some of the highest reported sediment yields in mountain rivers impacted by volcanic eruptions, earthquake- and storm-triggered landslide episodes, and catastrophic dam breaks. Extreme specific yields, defined here as those exceeding the 95th percentile of compiled data, are similar to 10(4) t km(-2) yr(-1) if averaged over 1 yr. These extreme yields vary by eight orders of magnitude, but systematically decay with reference intervals from minutes to millennia such that yields vary by three orders of magnitude for a given reference interval. Sediment delivery from natural dam breaks and pyroclastic eruptions dominate these yields for a given reference interval. Even if averaged over 10(2)-10(3) yr, the contribution of individual disturbances may remain elevated above corresponding catchment denudation rates. I further estimate rates of sediment (re-)mobilisation by individual giant terrestrial and submarine mass movements. Less than 50 postglacial submarine mass movements have involved an equivalent of similar to 10% of the contemporary annual global flux of fluvial sediment to Earth's oceans, while mobilisation rates by individual events rival the decadal-scale sediment discharge from tectonically active orogens such as Taiwan or New Zealand. Sediment flushing associated with catastrophic natural dam breaks is non-stationary and shows a distinct kink at the last glacial-interglacial transition, owing to the drainage of very large late Pleistocene ice-marginal lakes. Besides emphasising the contribution of high-magnitude and low-frequency events to the global sediment cascade, these findings stress the importance of sediment storage for fuelling rather than buffering high sediment transport rates.
The 'wet' early to mid-Holocene of tropical Africa, with its enhanced monsoon, ended with an abrupt shift toward drier conditions and was ultimately replaced by a drier climate that has persisted until the present day. The forcing mechanisms, the timing, and the spatial extent of this major climatic transition are not well understood and remain the subject of ongoing research. We have used a detailed palaeo-shoreline record from Lake Turkana (Kenya) to decipher and characterise this marked climatic transition in East Africa. We present a high-precision survey of well-preserved palaeo-shorelines, new radiocarbon ages from shoreline deposits, and oxygen-isotope measurements on freshwater mollusk shells to elucidate the Holocene moisture history from former lake water-levels in this climatically sensitive region. In combination with previously published data our study shows that during the early Holocene the water-level in Lake Turkana was high and the lake overflowed temporarily into the White Nile drainage system. During the mid-Holocene (similar to 5270 +/- 300 cal. yr BP), however, the lake water-level fell by similar to 50 m, coeval with major episodes of aridity on the African continent. A comparison between palaeo-hydrological and archaeological data from the Turkana Basin suggests that the mid-Holocene climatic transition was associated with fundamental changes in prehistoric cultures, highlighting the significance of natural climate variability and associated periods of protracted drought as major environmental stress factors affecting human occupation in the East African Rift System. (