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Early Ilerdian (Early Eocene, Shallow Benthic Zones 5 and 6) carbonate systems of the Pyrenees shelf were deposited after a time of severe climatic ('Paleocene-Eocene Thermal Maximum, PETM') and phylogenetic ('Larger Foraminifer Turnover') changes. They reflect the radiation of nummulitid, alveolinid, and orbitolitid larger foraminifera after remarkable biotic changes at the end of the Paleocene, and announce their subsequent flourishing in the Middle Eocene. A paleoenvironmental model for tropical carbonate environments of this particular time interval is provided herein. During the Early Ilerdian, the inner and middle ramp deposits from Minerve, Campo and Serraduy revealed the end-member of a tropical carbonate factory with carbonate production dominated by the end-members of biotically (photo-autotrophic skeletal) controlled and biotically induced carbonate precipitation. Inner platform environments are dominated by alveolinids and in part by orbitolitids, middle platform environments are dominated by nummulitids. Corals are present, but they do not form reefs, which is a typical feature for the Eocene. Nummulite shoal complexes, which are well-known from the Middle Eocene are also absent during the studied Early Ilerdian interval, which may reflect the early evolutionary stage of this group
We report on a receiver function study of the crust and upper mantle within DESERT, a multidisciplinary geophysical project to study the lithosphere across the Dead Sea Transform (DST). A temporary seismic network was operated on both sides of the DST between 2000 April and 2001 June. The depth of the Moho increases smoothly from about 30 to 34-38 km towards the east across the DST, with significant north-south variations east of the DST. These Moho depth estimates from receiver functions are consistent with results from steep-and wide-angle controlled-source techniques. Steep-angle reflections and receiver functions reveal an additional discontinuity in the lower crust, but only east of the DST. This leads to the conclusion that the internal crustal structure east and west of the DST is different. The P to S converted phases from both discontinuities at 410 and 660 km are delayed by 2 s with respect to the IASP91 global reference model. This would indicate that the transition zone is consistent with the global average, but the upper mantle above 410 km is 3-4 per cent slower than the standard earth model
The interplay between topography and Indian summer monsoon circulation profoundly controls precipitation distribution, sediment transport, and river discharge along the Southern Himalayan Mountain Front (SHF). The Higher Himalayas form a major orographic barrier that separates humid sectors to the south and and regions to the north. During the Indian summer monsoon, vortices transport moisture from the Bay of Bengal, swirl along the SHF to the northwest, and cause heavy rainfall when colliding with the mountain front. In the eastern and central parts of the Himalaya, precipitation measurements derived from passive microwave analysis (SSM/I) show a strong gradient, with high values at medium elevations and extensive penetration of moisture along major river valleys into the orogen. The end of the monsoonal conveyer belt is near the Sutlej Valley in the NW Himalaya, where precipitation is lower and rainfall maxima move to lower elevations. This region thus comprises a climatic transition zone that is very sensitive to changes in Indian summer monsoon strength. To constrain magnitude, temporal, and spatial distribution of precipitation, we analyzed high-resolution passive microwave data from the last decade and identified an abnormal monsoon year (AMY) in 2002. During the 2002 AMY, violent rainstorms conquered orographic barriers and penetrated far into otherwise and regions in the northwest Himalaya at elevations in excess of 3 km asl. While precipitation in these regions was significantly increased and triggered extensive erosional processes (i.e., debris flows) on sparsely vegetated, steep hillslopes, mean rainfall along the low to medium elevations was not significantly greater in magnitude. This shift may thus play an important role in the overall sediment flux toward the Himalayan foreland. Using extended precipitation and sediment flux records for the last century, we show that these events have a decadal recurrence interval during the present-day monsoon circulation. Hence, episodically occurring AMYs control geomorphic processes primarily in the high-elevation and sectors of the orogen, while annual recurring monsoonal rainfall distribution dominates erosion in the low- to medium- elevation parts along the SHF. (C) 2004 Elsevier B.V. All rights reserved
Carpholite+chloritoid+pyrophyllite association occurs widely in the Triassic metaclastic rocks of the Afyon Zone in west-central Turkey. Fe-Mg-carpholite is associated with rare aragonite pseudomorphs and glaucophane in marbles and metabasites, respectively. The Afyon Zone consists stratigraphically of a Pan-African basement and an overlying Mesozoic cover sequence. The Pan-African basement, which shows Barrovian-type amphibolite-facies metamorphism, comprises garnet-mica schists, intruded by sodic amphibole-bearing metagabbros and leucocratic metagranites. It is unconformably overlain by a continuous metasedimentary sequence extending from Triassic to early Palaeocene. This cover sequence begins with metaconglomerates, which pass upwards into phyllites. Fe-Mg-carpholite occurs within this metaclastic sequence as rosette-like crystals in metapelites and fibres in quartz segregations. The metaclastic rocks are succeeded by metamorphosed platform carbonates, grading into Latest Mesozoic metamorphosed pelagic limestones, which in turn progress up to a Late Mesozoic-Early Tertiary olistostrome. This sequence is tectonically overlain by the blueschists of the Tavsanh Zone. Fe-Mg-carpholite-bearing assemblages imply temperatures of about 350 degrees C and minimum pressures of 6-9 kbar, corresponding to burial depths of about 30 km for the Mesozoic passive continental margin sediments and the underlying Pan-African supracrustal metasediments and metaintrusives. The metamorphic rocks of the Afyon Zone are unconformably overlain by Upper Palaeocene-Lower Eocene sedimentary rocks, indicating a Paleocene age for the regional HP/LT metamorphism. This implies continuous younging of HP/LT metamorphism in the Anatolides related to northward subduction of the Anatolide-Tauride platform beneath the Sakarya Zone. From north to south this involved the Tavsanh Zone (Campanian, 80 +/- 5 Ma), the Afyon Zone (Palaeocene?), the Menderes Massif (Middle Eocene) and the Lycian Nappes (Late Cretaceous-Eocene?), all of which were probably derived from the frontal part of the Anatolide-Tauride platform. (c) 2005 Elsevier B.V. All rights reserved
Alpine thermal and structural evolution of the highest external crystalline massif : the Mont Blanc
(2005)
The alpine structural evolution of the Mont Blanc, highest point of the Alps (4810 m), and of the surrounding area has been reexamined. The Mont Blanc and the Aiguilles Rouges external crystalline massifs are windows of Variscan basement within the Penninic and Helvetic nappes. New structural, Ar-40/Ar-39, and fission track data combined with a compilation of earlier P-T estimates and geochronological data give constraints on the amount and timing of the Mont Blanc and Aiguilles Rouges massifs exhumation. Alpine exhumation of the Aiguilles Rouges was limited to the thickness of the overlying nappes (similar to 10 km), while rocks now outcropping in the Mont Blanc have been exhumed from 15 to 20 km depth. Uplift of the two massifs started similar to 22 Myr ago, probably above an incipient thrust: the Alpine sole thrust. At similar to 12 Ma, the NE-SW trending Mont Blanc shear zone (MBsz) initiated. It is a major steep reverse fault with a dextral component, whose existence has been overlooked by most authors, that brings the Mont Blanc above the Aiguilles Rouges. Total vertical throw on the MBsz is estimated to be between 4 and 8 km. Fission track data suggest that relative motion between the Aiguilles Rouges and the Mont Blanc stopped similar to 4 Myr ago. Since that time, uplift of the Mont Blanc has mostly taken place along the Mont Blanc back thrust, a steep north dipping fault bounding the southern flank of the range. The "European roof'' is located where the back thrust intersects the MBsz. Uplift of the Mont Blanc and Aiguilles Rouges occurred toward the end of motion on the Helvetic basal decollement (HBD) at the base of the Helvetic nappes but is coeval with the Jura thin-skinned belt. Northwestward thrusting and uplift of the external crystalline massifs above the Alpine sole thrust deformed the overlying Helvetic nappes and formed a backstop, inducing the formation of the Jura arc. In that part of the external Alps, similar to NW-SE shortening with minor dextral NE-SW motions appears to have been continuous from similar to 22 Ma until at least similar to 4 Ma but may be still active today. A sequential history of the alpine structural evolution of the units now outcropping NW of the Pennine thrust is proposed
In a series of timed experiments, monazite inclusions are induced to form in the Durango fluorapatite using 1 and 2 N HCl and H2SO4 solutions at temperatures of 300, 600, and 900 degrees C and pressures of 500 and 1,000 MPa. The monazite inclusions form only in reacted areas, i.e. depleted in (Y+REE)+Si+Na+S+Cl. In the HCl experiments, the reaction front between the reacted and unreacted regions is sharp, whereas in the H2SO4 experiments it ranges from sharp to diffuse. In the 1 N HCl experiments, Ostwald ripening of the monazite inclusions took place both as a function of increased reaction time as well as increased temperature and pressure. Monazite growth was more sluggish in the H2SO4 experiments. Transmission electron microscopic (TEM) investigation of foils cut across the reaction boundary in a fluorapatite from the 1 N HCl experiment (600 degrees C and 500 MPa) indicate that the reacted region along the reaction front is characterized by numerous, sub-parallel, 10-20 nm diameter nano-channels. TEM investigation of foils cut from a reacted region in a fluorapatite from the 1 N H2SO4 experiment at 900 degrees C and 1,000 MPa indicates a pervasive nano- porosity, with the monazite inclusions being in direct contact with the surrounding fluorapatite. For either set of experiments, reacted areas in the fluorapatite are interpreted as replacement reactions, which proceed via a moving interface or reaction front associated with what is essentially a simultaneous dissolution-reprecipitation process. The formation of a micro- and nano-porosity in the metasomatised regions of the fluorapatite allows fluids to permeate the reacted areas. This permits rapid mass transfer in the form of fluid-aided diffusion of cations to and from the growing monazite inclusions. Nano-channels and nano-pores also serve as sites for nucleation and the subsequent growth of the monazite inclusions
About 24 % of the land surface in the northern hemisphere are underlayed by permafrost in various states. Permafrost aggradation occurs under special environmental conditions with overall low annual precipitation rates and very low mean annual temperatures. Because the general permafrost occurrence is mainly driven by large-scale climatic conditions, the distribution of permafrost deposits can be considered as an important climate indicator. The region with the most extensive continuous permafrost is Siberia. In northeast Siberia, the ice- and organic-rich permafrost deposits of the Ice Complex are widely distributed. These deposits consist mostly of silty to fine-grained sandy sediments that were accumulated during the Late Pleistocene in an extensive plain on the then subaerial Laptev Sea shelf. One important precondition for the Ice Complex sedimentation was, that the Laptev Sea shelf was not glaciated during the Late Pleistocene, resulting in a mostly continuous accumulation of permafrost sediments for at least this period. This shelf landscape became inundated and eroded in large parts by the Holocene marine transgression after the Last Glacial Maximum. Remnants of this landscape are preserved only in the present day coastal areas. Because the Ice Complex deposits contain a wide variety of palaeo-environmental proxies, it is an excellent palaeo-climate archive for the Late Quaternary in the region. Furthermore, the ice-rich Ice Complex deposits are sensible to climatic change, i.e. climate warming. Because of the large-scale climatic changes at the transition from the Pleistocene to the Holocene, the Ice Complex was subject to extensive thermokarst processes since the Early Holocene. Permafrost deposits are not only an environmental indicator, but also an important climate factor. Tundra wetlands, which have developed in environments with aggrading permafrost, are considered a net sink for carbon, as organic matter is stored in peat or is syn-sedimentary frozen with permafrost aggradation. Contrary, the Holocene thermokarst development resulted in permafrost degradation and thus the release of formerly stored organic carbon. Modern tundra wetlands are also considered an important source for the climate-driving gas methane, originating mainly from microbial activity in the seasonal active layer. Most scenarios for future global climate development predict a strong warming trend especially in the Arctic. Consequently, for the understanding of how permafrost deposits will react and contribute to such scenarios, it is necessary to investigate and evaluate ice-rich permafrost deposits like the widespread Ice Complex as climate indicator and climate factor during the Late Quaternary. Such investigations are a pre-condition for the precise modelling of future developments in permafrost distribution and the influence of permafrost degradation on global climate. The focus of this work, which was conducted within the frame of the multi-disciplinary joint German-Russian research projects "Laptev Sea 2000" (1998-2002) and "Dynamics of Permafrost" (2003-2005), was twofold. First, the possibilities of using remote sensing and terrain modelling techniques for the observation of periglacial landscapes in Northeast Siberia in their present state was evaluated and applied to key sites in the Laptev Sea coastal lowlands. The key sites were situated in the eastern Laptev Sea (Bykovsky Peninsula and Khorogor Valley) and the western Laptev Sea (Cape Mamontovy Klyk region). For this task, techniques using CORONA satellite imagery, Landsat-7 satellite imagery, and digital elevation models were developed for the mapping of periglacial structures, which are especially indicative of permafrost degradation. The major goals were to quantify the extent of permafrost degradation structures and their distribution in the investigated key areas, and to establish techniques, which can be used also for the investigation of other regions with thermokarst occurrence. Geographical information systems were employed for the mapping, the spatial analysis, and the enhancement of classification results by rule-based stratification. The results from the key sites show, that thermokarst, and related processes and structures, completely re-shaped the former accumulation plain to a strongly degraded landscape, which is characterised by extensive deep depressions and erosional remnants of the Late Pleistocene surface. As a results of this rapid process, which in large parts happened within a short period during the Early Holocene, the hydrological and sedimentological regime was completely changed on a large scale. These events resulted also in a release of large amounts of organic carbon. Thermokarst is now the major component in the modern periglacial landscapes in terms of spatial extent, but also in its influence on hydrology, sedimentation and the development of vegetation assemblages. Second, the possibilities of using remote sensing and terrain modelling as a supplementary tool for palaeo-environmental reconstructions in the investigated regions were explored. For this task additionally a comprehensive cryolithological field database was developed for the Bykovsky Peninsula and the Khorogor Valley, which contains previously published data from boreholes, outcrops sections, subsurface samples, and subsurface samples, as well as additional own field data. The period covered by this database is mainly the Late Pleistocene and the Holocene, but also the basal deposits of the sedimentary sequence, interpreted as Pliocene to Early Pleistocene, are contained. Remote sensing was applied for the observation of periglacial strucures, which then were successfully related to distinct landscape development stages or time intervals in the investigation area. Terrain modelling was used for providing a general context of the landscape development. Finally, a scheme was developed describing mainly the Late Quaternary landscape evolution in this area. A major finding was the possibility of connecting periglacial surface structures to distinct landscape development stages, and thus use them as additional palaeo-environmental indicator together with other proxies for area-related palaeo-environmental reconstructions. In the landscape evolution scheme, i.e. of the genesis of the Late Pleistocene Ice Complex and the Holocene thermokarst development, some new aspects are presented in terms of sediment source and general sedimentation conditions. This findings apply also for other sites in the Laptev Sea region.
Seismic tomography, imaging of seismic scatterers, and magnetotelluric soundings reveal a sharp lithologic contrast along a similar to 10 km long segment of the Arava Fault (AF), a prominent fault of the southern Dead Sea Transform (DST) in the Middle East. Low seismic velocities and resistivities occur on its western side and higher values east of it, and the boundary between the two units coincides partly with a seismic scattering image. At 1 - 4 km depth the boundary is offset to the east of the AF surface trace, suggesting that at least two fault strands exist, and that slip occurred on multiple strands throughout the margin's history. A westward fault jump, possibly associated with straightening of a fault bend, explains both our observations and the narrow fault zone observed by others
The rise and fall of the Classic Maya provides a textbook example of human social evolution. It is therefore significant to discover that the history of theMaya was so closely tied to environmental constraints. If Maya civilization could collapse under the weight of natural climate events, it is of more than academic interest to ponder how modem society will fare in the face of an uncertain climate in the years ahead. An understanding of how ancient cultures responded to climatic changes in the past may thus provide important lessons for humanity in the future
The up to similar to4 km high southern Patagonian Andes form a pronounced topographic barrier to atmospheric circulation in the southern hemisphere westerlies, and cause one of the most drastic orographic rain shadows on earth. Geologic data imply that this climatic pattern has been established or significantly enhanced during Miocene surface uplift of this Andean segment. We report evidence for important climatic and ecologic changes in the eastern foreland of the Patagonian Andes that appear to be the result of this uplift. To provide constraints on Miocene plant ecosystems and precipitation in the eastern (leeward) foreland of the Patagonian Andes, we determined carbon and oxygen isotope values of pedogenic carbonate nodules from a similar to500 m thick section of the continental Santa Cruz Formation. The age of these deposits was constrained by Ar/Ar dating of intercalated tuffs, which range from similar to22 to 14 Ma. At similar to16.5 Ma, the delta(13)C values increase by similar to3parts per thousand, the delta(18)O values decrease by >2parts per thousand, and the scatter in the oxygen isotope data increases significantly. We interpret these changes as the consequence of >1 km surface uplift in this Andean segment (from the delta(18)O values), and increased aridity to its east (from the delta(13)C values and the increased scatter in the delta(18)O values). Sediments overlying the Santa Cruz Formation are very limited in extent and volume, and dominated by coarse conglomerates related to Pleistocene and older glaciations. It thus seems that, by similar to14 Ma, deposition in the eastern foreland of the Southern Patagonian Andes had essentially ceased as the result of rain shadow formation. (C) 2004 Elsevier B.V. All rights reserved
We investigate the controls on the architecture of coarse-grained delta progradational units (PUs) in the Pliocene Loreto basin (Baja California Sur, Mexico), a half-graben located on the western margin of the Gulf of California. Dorsey et al. (1997b) argued that delta progradation and transgression cycles in the basin were driven by episodic fault-controlled subsidence along the basin-bounding Loreto fault. Here we test this hypothesis by a detailed analysis of the sedimentary architecture of 11 exceptionally well-exposed, vertically arranged fluvio-deltaic PUs, each of which shows lateral facies transition from proximal alluvial facies palaeo-seaward into distal pro-delta facies. Of these 11 PUs, seven exhibit a lateral transition from a shoal water to Gilbert-delta facies associations as they are traced palaeo-seaward. This transition is characterised by down-transport development of foresets, which grow in height up to 35 m. Foreset units thicken in a basinward direction, with initially an oblique topset-foreset geometry that becomes increasingly sigmoidal. Each delta is capped by a shell bed that records drowning of the delta top. This systematic transition in delta architecture records increasing water depth through time during individual episodes of progradation. A mechanism that explains this transition is an accelerating rate of fault-controlled subsidence during each PU. During episodes of low slip rate, shoal-water deltas prograde across the submerged topography of the underlying delta unit. As displacement rate accelerates, increasing bathymetry at the delta front leads to steepening of foresets and initiation of Gilbert deltas. Subsequent delta drowning results from sediment starvation at the shoreline at high slip rates because of sediment trapping upstream. The observed delta architecture suggests that the long-term (> 100 kyr) history of slip on the Loreto fault was characterised by repetitive episodes of accelerating displacement accumulation. Such episodic fault behaviour is most likely to be because of variations in temporal and spatial strain partitioning between the Loreto fault and other faults in the Gulf of California. A physical explanation for the acceleration phenomenon involves evolving frictional properties on the episodically active Loreto fault
Composite ground-motion models and logic trees: Methodology, sensitivities, and uncertainties
(2005)
Logic trees have become a popular tool in seismic hazard studies. Commonly, the models corresponding to the end branches of the complete logic tree in a probabalistic seismic hazard analysis (PSHA) are treated separately until the final calculation of the set of hazard curves. This comes at the price that information regarding sensitivities and uncertainties in the ground-motion sections of the logic tree are only obtainable after disaggregation. Furthermore, from this end-branch model perspective even the designers of the logic tree cannot directly tell what ground-motion scenarios most likely would result from their logic trees for a given earthquake at a particular distance, nor how uncertain these scenarios might be or how they would be affected by the choices of the hazard analyst. On the other hand, all this information is already implicitly present in the logic tree. Therefore, with the ground-motion perspective that we propose in the present article, we treat the ground-motion sections of a complete logic tree for seismic hazard as a single composite model representing the complete state-of-knowledge-and-belief of a particular analyst on ground motion in a particular target region. We implement this view by resampling the ground-motion models represented in the ground-motion sections of the logic tree by Monte Carlo simulation (separately for the median values and the sigma values) and then recombining the sets of simulated values in proportion to their logic-tree branch weights. The quantiles of this resampled composite model provide the hazard analyst and the decision maker with a simple, clear, and quantitative representation of the overall physical meaning of the ground-motion section of a logic tree and the accompanying epistemic uncertainty. Quantiles of the composite model also provide an easy way to analyze the sensitivities and uncertainties related to a given logic-tree model. We illustrate this for a composite ground- motion model for central Europe. Further potential fields of applications are seen wherever individual best estimates of ground motion have to be derived from a set of candidate models, for example, for hazard rnaps, sensitivity studies, or for modeling scenario earthquakes
"Green water"-the water stored in the soil and productively used for plant transpiration-is an important quantity particularly in rainfed agriculture (in contrast to "blue water" available in streams and lakes, on which irrigation relies). This study provides preliminary estimates of contemporary (1961-1990) global green water flows (i.e. plant transpiration), using a well-established, process-based dynamic global vegetation and water balance model, LPJ. Transpiration is analysed with respect to differences between a simulation that accounts for human land cover changes and a simulation under conditions of potential natural vegetation. We found that historic land cover change usually reduced the green water flow to the atmosphere, resulting in a global decrease of similar to 7% in total. To further explore how the biophysical setting influences the green water flow, we analyse the ratio between soil moisture-limited canopy conductance of carbon and water and energy-controlled potential conductance. This plant physiology-based ratio measures the degree to which actual green water flow falls below the potential flow that would occur when the soil is saturated, thus it represents a measure of the water limitation of terrestrial vegetation. We found that plant water limitation is lowest in the wet tropics and at high latitudes, where soil moisture is high enough to meet the atmospheric demand for transpiration. The present results are preliminary, since irrigation is not yet accounted for, and because the model simulations are compromised primarily by the quality of the input data. A more comprehensive and consistent assessment of global green and blue water flows and limitations using an enhanced LPJ model is identified as a prime task for future studies. (c) 2005 Elsevier Ltd. All rights reserved
An analysis of the shear (S) waves recorded during the wide-angle reflection/refraction (WRR) experiment as part of the DESERT project crossing the Dead Sea Transform (DST) reveals average crustal S-wave velocities of 3.3-3.5 km s(-1) beneath the WRR profile. Together with average crustal P-wave velocities of 5.8-6.1 km s(-1) from an already published study this provides average crustal Poisson's ratios of 0.26-0.27 (V-p/V-s = 1.76-1.78) below the profile. The top two layers consisting predominantly of sedimentary rocks have S- wave velocities of 1.8-2.7kms(-1) and Poisson's ratios of 0.25-0.31 (V-p/V-s = 1.73-1.91). Beneath these two layers the seismic basement has average S- wave velocities of around 3.6 km s(-1) east of the DST and about 3.7 km s(-1) west of the DST and Poisson's ratios of 0.24-0.25 (V-p/V-s = 1.71-1.73). The lower crust has an average S-wave velocity of about 3.75 km s(-1) and an average Poisson's ratio of around 0.27 (V-p/V-s = 1.78). No Sn phase refracted through the uppermost mantle was observed. The results provide for the first time information from controlled source data on the crustal S-wave velocity structure for the region west of the DST in Israel and Palestine and agree with earlier results for the region east of the DST in the Jordanian highlands. A shear wave splitting study using SKS waves has found evidence for crustal anisotropy beneath the WRR profile while a receiver function study has found evidence for a lower crustal, high S-wave velocity layer east of the DST below the profile. Although no evidence was found in the S-wave data for either feature, the S-wave data are not incompatible with crustal anisotropy being present as the WRR profile only lies 30 degrees off the proposed symmetry axis of the anisotropy where the difference in the two S-wave velocities is still very small. In the case of the lower crustal, high S-wave velocity layer, if the velocity change at the top of this layer comprises a small first-order discontinuity underlain by a 2 km thick transition zone, instead of just a large first-order discontinuity, then both the receiver function data and the WRR data presented here can be satisfied. Finally, the S-wave velocities and Poisson's ratios which have been derived in this study are typical of continental crust and do not require extensional processes to explain them
Annite and Fe-rich siderophyllite constitute the rock-forming micas in the late-Variscan composite granite pluton of Konigshain, Lausitz, Germany. This multiphase pluton is composed of three fractionated, but not chemically specialized monzogranite types, which contain lithophile elements such as Li, Rb, Cs, Sn, and F in average quantities. Abundant miarolitic pegmatites of the NYF family with a broad diversity of rare minerals occur in the apical part of the pluton. These pegmatitic cavities locally contain di- and trioctabedral micas as well as cation-deficient micas. Trioctahedral micas comprise F-rich manganoan lithian siderophyllite to manganoan zinnwaldite, zinnwaldite, and minor lepidolite. The formula [calculated on the basis of 22 anion valencies and 2 (F + OH + Cl)] of the most Mn-rich siderophyllite is (K0.85Rb0.08Na0.04)(0.97)(Al0.99Li0.91Fe0.51Mn0.42Ti0.01Zn0.01)(2.85) (Si3.21Al0.79)(4)O- 10(F1.80OH0.19Cl0.01)(2). This mica constitutes one of the most Mn-rich siderophyllite compositions reported to date. The lithium micas poorer in Mn are distinguished by elevated concentrations of Rb (up to 2.5 wt % Rb2O), CS (UP to 1.2 wt % Cs2O), and F (up to 9.6 wt %). This fluorine content is probably consistent with the maximum possible F occupation of 2 of the (F,OH,Cl)-site. The structural formula of the most Li-rich lepidolite is (K0.83Rb0.07Cs0.03)(0.93) (Li1.62Al1.00Fe0.38)(3.00)(Si3.62Al0.38)(4) O-10(F1.91OH0.09)(2). During hydrothermal alteration, lepidolite and zinnwaldite became partially depleted in K, Li, Rb, Cs, and F and gradually transformed into cation-deficient micas (lithian phengite to illite of phengitic affinity)
Fe K-edge X-ray absorption near edge structure (XANES) and Mossbauer spectra were collected on synthetic glasses of basaltic composition and of glasses on the sodium oxide-silica binary to establish a relation between the pre- edge of the XANES at the K-edge and the Fe oxidation state of depolymerised glasses. Charges of sample material were equilibrated at ambient pressure, superliquidus temperatures and oxygen fugacities that were varied over a range of about 15 orders of magnitude. Most experiments were carried out in gas-flow furnaces, either with pure oxygen, air, or different CO/CO2 mixtures. For the most reduced conditions, the samples charges were enclosed together with a pellet of the IQF oxygen buffer in an evacuated silica glass ampoule. Fe3+/Sigma Fe x 100 of the samples determined by Mossbauer spectroscopy range between 0% and 100%. Position and intensity of the pre-edge centroid position vary strongly depending on the Fe oxidation state. The pre-edge centroid position and the Fe oxidation state determined by Mossbauer spectroscopy are nonlinearly related and have been fitted by a quadratic polynomial. Alternatively, the ratio of intensities measured at positions sensitive to Fe2+ and Fe3+, respectively, provides an even more sensitive method. Pre- edge intensities of the sample suite indicate average Fe co-ordination between 4 and 6 for all samples regardless of oxidation state. A potential application of the calibration given here opens the possibility of determining Fe oxidation state in glasses of similar compositions with high spatial resolution by use of a Micro-XANES setup (e.g., glass inclusions in natural minerals). (c) 2004 Elsevier B.V. All rights reserved
Ambient vibration techniques are promising methods for assessing the subsurface structure, in particular the shear-wave velocity profile (V-s). They are based on the dispersion property of surface waves in layered media. Therefore, the penetration depth is intrinsically linked to the energy content of the sources. For ambient vibrations, the spectral content extends in general to lower frequency when compared to classical artificial sources. Among available methods for processing recorded signals, we focus here on the spatial autocorrelation method. For stationary wavefields, the spatial autocorrelation is mathematically related to the frequency-dependent wave velocity c(omega). This allows the determination of the dispersion curve of traveling surface waves, which, in turn, is linked to the V-s profile. Here, we propose a direct inversion scheme for the observed autocorrelation curves to retrieve, in a single step, the V-s profile. The powerful neighborhood algorithm is used to efficiently search for all solutions in an n- dimensional parameter space. This approach has the advantage of taking into account the existing uncertainty over the measured curves, thus generating all V-s profiles that fit the data within their experimental errors. A preprocessing tool is also developed to estimate the validity of the autocorrelation curves and to reject parts of them if necessary before starting the inversion itself. We present two synthetic cases to test the potential of the method: one with ideal autocorrelation curves and another with autocorrelation curves computed from simulated ambient vibrations. The latter case is more realistic and makes it possible to figure out the problems that may be encountered in real experiments. The V-s profiles are correctly retrieved up to the depth of the first major velocity contrast unless low-velocity zones are accepted. We demonstrate that accepting low-velocity zones in the parameterization has a dramatic influence on the result of the inversion, with a considerable increase in the nonuniqueness of the problem. Finally, a real data set is processed with the same method