Refine
Year of publication
- 2001 (160) (remove)
Document Type
- Article (119)
- Doctoral Thesis (26)
- Monograph/Edited Volume (13)
- Habilitation Thesis (2)
Is part of the Bibliography
- yes (160)
Keywords
- chaos (2)
- synchronization (2)
- Absorptionsspektroskopie (1)
- Akkretionsscheiben (1)
- Autokorrelation (1)
- Chaos (1)
- Chaostheorie (1)
- Chaotische Sattel (1)
- Dynamische Systeme (1)
- Effekt (1)
- Elektrolyte (1)
- Feld (1)
- Hochdruck (1)
- Hydrodynamik (1)
- Integral field spectroscopy (1)
- Interaktion (1)
- Ladungsträger (1)
- Leistungsspektrum (1)
- Multistability (1)
- Multistabilität (1)
- Nichtlineare Dynamik (1)
- Nichtlineare Systeme (1)
- Nichtlineares dynamisches System / Harmonische Analyse / Fraktal (1)
- Ortsauflösende Spektrofotometrie (1)
- P (1)
- P hasensynchronisierung (1)
- Phase (1)
- Polypyrrol (1)
- Rauschen (1)
- Schwingungsspektroskopie (1)
- Simulation (1)
- Sternwinde (1)
- Stochastische Prozesse (1)
- Strahlungstransport (1)
- Synchronisation (1)
- Synchronisierung (1)
- System (1)
- Theorie (1)
- Transmissionselektronenmikroskopie (1)
- accretion disks (1)
- autocorrelation (1)
- chaotic (1)
- chaotic saddle (1)
- chaotisch (1)
- charged systems (1)
- complex (1)
- complex systems (1)
- coupled (1)
- dynamical systems (1)
- electric double layer (1)
- electrolytes (1)
- elektrische Doppelschicht (1)
- extragalactic stellar astronomy (1)
- extragalaktische Stellarastronomie (1)
- field (1)
- gekoppelt (1)
- geladene Systeme (1)
- hydrodynamics (1)
- interaction (1)
- komplex (1)
- komplexe Systeme (1)
- leitfähige Polymere (1)
- meanfield (1)
- noise (1)
- nonlinear dynamics (1)
- nonlinear systems (1)
- o (1)
- phase (1)
- phase synchronization (1)
- power spectrum (1)
- radiative transfer (1)
- simulation (1)
- stellar winds (1)
- stochastic processes (1)
- system (1)
- theory (1)
- transition (1)
- Übergang (1)
Institute
- Institut für Physik und Astronomie (160) (remove)
The Problem of front propagation in flowing media is addressed for laminar velocity fields in two dimensions. Three representative cases are discussed: stationary cellular flow, stationary shear flow, and percolating flow. Production terms of Fisher-Kolmogorov-Petrovskii-Piskunov type and of Arrhenius type are considered under the assumption of no feedback of the concentration on the velocity. Numerical simulations of advection-reaction-diffusion equations have been performed by an algorithm based on discrete-time maps. The results show a generic enhancement of the speed of front propagation by the underlying flow. For small molecular diffusivity, the front speed <i>V<sub><i>f</sub> depends on the typical flow velocity <i>U as<sup> </sup>a power law with an exponent depending on the topological properties of the flow, and on the ratio of reactive and advective time scales. For open-streamline flows we find always<sup> </sup><i>V<sub><i>f</sub>~<i>U, whereas for cellular flows we observe <i>V<sub><i>f</ sub>~<i>U<sup>1/4</sup> for fast advection and <i>V<sub><i>f</sub>~<i>U<sup>3/4</sup> for slow advection.
Subject of this work is the investigation of universal scaling laws which are observed in coupled chaotic systems. Progress is made by replacing the chaotic fluctuations in the perturbation dynamics by stochastic processes. First, a continuous-time stochastic model for weakly coupled chaotic systems is introduced to study the scaling of the Lyapunov exponents with the coupling strength (coupling sensitivity of chaos). By means of the the Fokker-Planck equation scaling relations are derived, which are confirmed by results of numerical simulations. Next, the new effect of avoided crossing of Lyapunov exponents of weakly coupled disordered chaotic systems is described, which is qualitatively similar to the energy level repulsion in quantum systems. Using the scaling relations obtained for the coupling sensitivity of chaos, an asymptotic expression for the distribution function of small spacings between Lyapunov exponents is derived and compared with results of numerical simulations. Finally, the synchronization transition in strongly coupled spatially extended chaotic systems is shown to resemble a continuous phase transition, with the coupling strength and the synchronization error as control and order parameter, respectively. Using results of numerical simulations and theoretical considerations in terms of a multiplicative noise partial differential equation, the universality classes of the observed two types of transition are determined (Kardar-Parisi-Zhang equation with saturating term, directed percolation).
The behavior of the Lyapunov exponents (LEs) of a disordered system consisting of mutually coupled chaotic maps with different parameters is studied. The LEs are demonstrated to exhibit avoided crossing and level repulsion, qualitatively similar to the behavior of energy levels in quantum chaos. Recent results for the coupling dependence of the LEs of two coupled chaotic systems are used to explain the phenomenon and to derive an approximate expression for the distribution functions of LE spacings. The depletion of the level spacing distribution is shown to be exponentially strong at small values. The results are interpreted in terms of the random matrix theory.
We present an analytical formula for the asymptotic relative entropy of entanglement for Werner states of arbitrary dimensionality. We then demonstrate its validity using methods from convex optimization. This is the first case in which the value of a subadditive entanglement measure has been obtained in the asymptotic limit. This formula also gives the sharpest known upper bound on the distillable entanglement of these states.
Energie
(2001)
We describe automatic procedures for the selection of DA white dwarfs in the Hamburg/ESO objective-prism survey (HES). For this purpose, and the selection of other stellar objects (e.g., metal-poor stars and carbon stars), a flexible, robust algorithm for detection of stellar absorption and emission lines in the digital spectra of the HES was developed. Broad band (U-B, B-V) and intermediate band (Strömgren c_1) colours can be derived directly from HES spectra, with precisions of sigma U-B=0.092 mag; sigma B-V=0.095 mag; sigma c_1=0.15 mag. We describe simulation techniques that allow one to convert model or slit spectra to HES spectra. These simulated objective-prism spectra are used to determine quantitative selection criteria, and for the study of selection functions. We present an atlas of simulated HES spectra of DA and DB white dwarfs. Our current selection algorithm is tuned to yield maximum efficiency of the candidate sample (minimum contamination with non-DAs). DA candidates are selected in the B-V versus U-B and c_1 versus W_lambda (Hbeta +Hgamma +Hdelta ) parameter spaces. The contamination of the resulting sample with hot subdwarfs is expected to be as low as ~ 8%, while there is essentially no contamination with main sequence or horizontal branch stars. We estimate that with the present set of criteria, ~ 80% of DAs present in the HES database are recovered. A yet higher degree of internal completeness could be reached at the expense of higher contamination. However, the external completeness is limited by additional losses caused by proper motion effects and the epoch differences between direct and spectral plates used in the HES. Based on observations collected at the European Southern Observatory, La Silla and Paranal, Chile.
We study the dynamo properties of asymmetric square patterns in Boussinesq Rayleigh-B'enard convection in a plane horizontal layer. Cases without rotation and with weak rotation about a vertical axis are considered. There exist different types of solutions distinguished by their symmetry, among them such with flows possessing a net helicity and being capable of kinematic dynamo action in the presence as well as in the absence of rotation. In the nonrotating case these flows are, however, always only kinematic, not nonlinear dynamos. Nonlinearly the back-reaction of the magnetic field then forces the solution into the basin of attraction of a roll pattern incapable of dynamo action. But with rotation added parameter regions are found where the Coriolis force counteracts the Lorentz force in such a way that the asymmetric squares are also nonlinear dynamos.
We numerically investigate nonlinear asymmetric square patterns in a horizontal convection layer with up-down reflection symmetry. As a novel feature we find the patterns to appear via the skewed varicose instability of rolls. The time-independent nonlinear state is generated by two unstable checkerboard (symmetric square) patterns and their nonlinear interaction. As the bouyancy forces increase the interacting modes give rise to bifurcations leading to a periodic alternation between a nonequilateral hexagonal pattern and the square pattern or to different kinds of standing oscillations.
Metal ion mediated mesomorphism and thin film behaviour of amphitropic tetraazaporphyrin complexes
(2001)
We present a measure of quantum entanglement which is capable of quantifying the degree of entanglement of a multi-partite quantum system. This measure, which is based on a generalization of the Schmidt rank of a pure state, is defined on the full state space and is shown to be an entanglement monotone, that is, it cannot increase under local quantum operations with classical communication and under mixing. For a large class of mixed states this measure of entanglement can be calculated exactly, and it provides a detailed classification of mixed states.
Coating of porous polytetrafluoroethylene films with other polymers for electret applications
(2001)
Line driven winds are accelerated by the momentum transfer from photons to a plasma, by absorption and scattering in numerous spectral lines. Line driving is most efficient for ultraviolet radiation, and at plasma temperatures from 10^4 K to 10^5 K. Astronomical objects which show line driven winds include stars of spectral type O, B, and A, Wolf-Rayet stars, and accretion disks over a wide range of scales, from disks in young stellar objects and cataclysmic variables to quasar disks. It is not yet possible to solve the full wind problem numerically, and treat the combined hydrodynamics, radiative transfer, and statistical equilibrium of these flows. The emphasis in the present writing is on wind hydrodynamics, with severe simplifications in the other two areas. I consider three topics in some detail, for reasons of personal involvement. 1. Wind instability, as caused by Doppler de-shadowing of gas parcels. The instability causes the wind gas to be compressed into dense shells enclosed by strong shocks. Fast clouds occur in the space between shells, and collide with the latter. This leads to X-ray flashes which may explain the observed X-ray emission from hot stars. 2. Wind runaway, as caused by a new type of radiative waves. The runaway may explain why observed line driven winds adopt fast, critical solutions instead of shallow (or breeze) solutions. Under certain conditions the wind settles on overloaded solutions, which show a broad deceleration region and kinks in their velocity law. 3. Magnetized winds, as launched from accretion disks around stars or in active galactic nuclei. Line driving is assisted by centrifugal forces along co-rotating poloidal magnetic field lines, and by Lorentz forces due to toroidal field gradients. A vortex sheet starting at the inner disk rim can lead to highly enhanced mass loss rates.
Electrically conducting fluids in motion can act as self-excited dynamos. The magnetic fields of celestial bodies like the Earth and the Sun are generated by such dynamos. Their theory aims at modeling and understanding both the kinematic and dynamic aspects of the underlying processes. Kinematic dynamo models, in which for a prescribed flow the linear induction equation is solved and growth rates of the magnetic field are calculated, have been studied for many decades. But in order to get consistent models and to take into account the back-reaction of the magnetic field on the fluid motion, the full nonlinear system of the magnetohydrodynamic (MHD) equations has to be studied. It is generally accepted that these equations, i.e. the Navier-Stokes equation (NSE) and the induction equation, provide a theoretical basis for the explanation of the dynamo effect. The general idea is that mechanical energy pumped into the fluid by heating or other mechanisms is transferred to the magnetic field by nonlinear interactions. For two special helical flows which are known to be effective kinematic dynamos and which can be produced by appropriate external mechanical forcing, we review the nonlinear dynamo properties found in the framework of the full MHD equations. Specifically, we deal with the ABC flow (named after Arnold, Beltrami and Childress) and the Roberts flow (after G.~O. Roberts). The appearance of generic dynamo effects is demonstrated. Applying special numerical bifurcation-analysis techniques to high-dimensional approximations in Fourier space and varying the Reynolds number (or the strength of the forcing) as the relevant control parameter, qualitative changes in the dynamics are investigated. We follow the bifurcation sequences until chaotic states are reached. The transitions from the primary flows with vanishing magnetic field to dynamo-active states are described in particular detail. In these processes the stagnation points of the flows and their heteroclinic connections play a promoting role for the magnetic field generation. By the example of the Roberts flow we demonstrate how the break up of the heteroclinic lines after the primary bifurcation leads to a complicated intersection of stable and unstable manifolds forming a chaotic web which is in turn correlated with the spatial appearance of the dynamo.
Complete relaxation map of polyethylene : filler-induced chemical modifications as dielectric probes
(2001)
From optical R-band data of the double quasar QSO 0957+561A,B, we made two new difference light curves (with an overlap of about 330d between the time-shifted light curve for the A image and the magnitude-shifted light curve for the B image). We observed noisy behaviours around the zero line and no short time-scale events (with a duration of months), where the term `event' refers to a prominent feature that may be a result of microlensing or another source of variability. Only one event lasting two weeks and rising -33mmag was found. Measured constraints on the possible microlensing variability can be used to obtain information on the granularity of the dark matter in the main lensing galaxy and the size of the source. In addition, one can also test the ability of the observational noise to cause the rms averages and the local features of the difference signals. We focused on this last issue. The combined photometries were related to a process consisting of an intrinsic signal plus a Gaussian observational noise. The intrinsic signal has been assumed to be either a smooth function (polynomial), a smooth function plus a stationary noise process, or a correlated stationary process. Using these three pictures without microlensing, we derived some models totally consistent with the observations. We finally discussed the sensitivity of our telescope (at Teide Observatory) to several classes of microlensing variability.
Coherence properties of thermal near fields : implications for nanometer-scale radiative transfer
(2001)
With the recent development of local (optical and thermal) probe microscopy and the advent of nanotechnology, it seems necessary to revisit the old subject of coherence properies of thermal sources of light. Concerning temporal coherence, we show that thermal sources may produce quasi-monochromatic near fields. In light of this result, the possibility of perfoming near-field solid-state spectroscopy and of designing near-field infrared sources is discussed. The problem of radiative transfer between two thermal sources held at subwavelength distance is studied. The radiative flux may be enhanced by several orders of magnitude due to the excitation of resonant surface waves, and this may occur at particular frequencies. Finally, we study the spatial coherence of thermal sources and the substantial influence of the near field. Surface waves may induce long-range spatial correlation, on a scale much larger than the wavelength. Conversely, quasi-static contributions, as well as skin-layer currents, induce arbitary small correlations. With the recent development of local (optical and thermal) probe microscopy and the advent of nanotechnology, it seems necessary to revisit the old subject of coherence of thermal fields.
A series of new poly-1,3,4-oxadiazoles has been synthesized by polycondensation reaction of hydrazine sulfate with a mixture of a dicarboxylic acid containing unsaturated bonds and a dicarboxylic acid containing silicon, by using methanesulfonic acid/phosphorus pentoxide as a reaction medium. These polymers were highly thermostable but they were only soluble in strong inorganic acids such as sulfuric or methanesulfonic ones. An alternative way was followed by using the corresponding dihydrazides containing unsaturated bonds and the corresponding diacid chloride containing silicon that reacted in N-methylpyrrolidinone (NMP) to give soluble silicon-containing unsaturated polyhydrazides, which were cyclodehydrated either by thermal or chemical treatment to give the corresponding polyoxadiazoles. Very thin coatings of polyhydrazides and polyoxadiazoles were deposited onto silicon wafers and they showed a very smooth surface, free of pinholes, when studied by atomic force microscopy (AFM). Some polyoxadiazole films showed strong blue photoluminescence.
Spectral lines formed in stellar winds from OB stars are observed to exhibit profile variations. Discrete Absorption Components (DACs) show a remarkably slow wavelength drift with time. In a straightforward interpretation, this is in sharp contradiction to the steep velocity law predicted by the radiation-driven wind theory, and by semi- empirical profile fitting. In the present paper we re-discuss the interpretation of the drift rate. We show that the Co- rotating Interaction Region (CIR) model for the formation of DACs does not explain their slow drift rate as a consequence of rotation. On the contrary, the apparent acceleration of a spectral CIR feature is even higher than for the corresponding kinematical model without rotation. However, the observations can be understood by distinguishing between the velocity field of the matter flow, and the velocity law for the motion of the patterns in which the DAC features are formed. If the latter propagate upstream against the matter flow, the resulting wavelength drift mimics a much slower acceleration although the matter is moving fast. Additional to the DACs, a second type of recurrent structures is present in observed OB star spectra, the so-called modulations. In contrast to the DACs, these structures show a steep acceleration compatible with the theoretically predicted velocity law. We see only two possible consistent scenarios. Either, the wind is accelerated fast, and the modulations are formed in advected structures, while the DACs come from structures which are propagating upstream. Or, alternatively, steep and shallow velocity laws may co-exist at the same time in different spatial regions or directions of the wind.
Competitive random sequential adsorption of point and fixed-sized particles: analytical results
(2001)
Coherent transport
(2001)
We discuss the transport of matter waves in low-dimensional waveguides. Due to scattering from uncontrollable noise fields, the spatial coherence gets reduced and eventually lost. We develop a description of this decoherence process in terms of transport equations for the atomic Wigner function. We outline its derivation and discuss the special case of white noise where an analytical solution can be found.
A transport theory for atomic matter waves in low-dimensional waveguides is outlined. The thermal fluctuation spectrum of magnetic near fields leaking out of metallic microstructures is estimated. The corresponding scattering rate for paramagnetic atoms turns out to be quite large in micrometer-sized waveguides (approx. 100/s). Analytical estimate for the heating and decoherence of a cold atom cloud are given. We finally discuss numerical and analytical results for the scattering from static potential imperfections and the ensuing spatial diffusion process.
Atomic force microscopy inspection of the early state of formation of polymer surface relief grating
(2001)
Recent advances in constructing stellar evolution models of hydrogen-deficient post-asymptotic giant branch (AGB) stars are presented. Hydrogen-deficiency can originate from mixing and subsequent convective burning of protons in the deeper layers during a thermal pulse on the post-AGB (VLTP). Dredge-up alone may also be responsible for hydrogen- deficiency of post-AGB stars. Models of the last thermal pulse on the AGB with very small envelope masses have shown efficient third dredge-up. The hydrogen content of the envelope is diluted sufficiently to produce H-deficient post-AGB stars (AFTP). Moreover, dredge-up alone may also cause H-deficiency during the Born-again phase (LTP). During the second AGB phase a convective envelope develops. A previously unknown lithium enrichment at the surface of Born-again stellar models may be used to distinguish between objects with different post-AGB evolution. The observed abundance ratios of C, O and He can be reproduced by all scenarios if an AGB starting model with inclusion of overshoot is used for the post- AGB model sequence. An appendix is devoted to the numerical methods for models of proton capture nucleosynthesis in the He-flash convection zone during a thermal pulse.
So far, the evolution of post-AGB stars is not fully understood. In particular the formation of hydrogen- deficient and hydrogen-free Central Stars of Planetary Nebulae (CSPN) is unsettled. New evolution models, which allow for the consistent treatment of the physics of late thermal pulses, promise new insights to the formation of these stars. In this paper we summarize the results of non-LTE analyses of CSPN with wind. By comparing these results with the predictions of the new evolution models, open questions concerning the evolution of the stars might be answered. In addition we discuss the driving mechanism of the winds of Wolf-Rayet CSPN. New models, which account for millions of iron lines, support the assumptions that these winds are driven by radiation.
We have obtained time-resolved observations of line-profile variations of the two Wolf-Rayet stars WR 135 and WR 111. The spectra, taken during two consecutive nights, cover a broad range from 4470 to 6590 Ang. The profile variability of the C iii emission line at 5696 Ang in WR 135 is shown in detail. The principal difficulties to constrain the velocity law from the frequency drift of discrete spectral features is discussed, emphasizing the crucial dependence on the adopted location of the line-emission region, and the possible necessity to distinguish between the motion of structures and the flow of the matter. - Full access to the observational data is provided via anonymous file transfer.
First, we review the current status of the detection of strong `external' variability in the CLASS gravitational B1600+434, focusing on the 1998 VLA 8.5-GHz and 1998/9 WSRT multi-frequency observations. We show that this data can best be explained in terms of radio-microlensing. We then proceed to show some preliminary results from our new multi-frequency VLA monitoring program, in particular the detection of a strong feature (~30%) in the light curve of the lensed image which passes predominantly through the dark-matter halo of the lens galaxy. We tentatively interpret this event, which lasted for several weeks, as a radio-microlensing caustic crossing, i.e. the superluminal motion of a micro-arcsec-scale jet-component in the lensed source over a single caustic in the magnification pattern, that has been created by massive compact objects along the line-of-sight to the lensed image.
The declining light curve of the optical afterglow of gamma-ray burst (GRB) GRB000301C showed rapid variability with one particularly bright feature at about t-t0=3.8d. This event was interpreted as gravitational microlensing by Garnavich, Loeb & Stanek and subsequently used to derive constraints on the structure of the GRB optical afterglow. In this paper, we use these structural parameters to calculate the probability of such a microlensing event in a realistic scenario, where all compact objects in the universe are associated with observable galaxies. For GRB000301C at a redshift of z=2.04, the a posteriori probability for a microlensing event with an amplitude of m>=0.95mag (as observed) is 0.7 per cent (2.7 per cent) for the most plausible scenario of a flat -dominated Friedmann- Robertson-Walker (FRW) universe with m=0.3 and a fraction f*=0.2 (1.0) of dark matter in the form of compact objects. If we lower the magnification threshold to m>=0.10mag, the probabilities for microlensing events of GRB afterglows increase to 17 per cent (57 per cent). We emphasize that this low probability for a microlensing signature of almost 1mag does not exclude that the observed event in the afterglow light curve of GRB000301C was caused by microlensing, especially in light of the fact that a galaxy was found within 2arcsec from the GRB. In that case, however, a more robust upper limit on the a posteriori probability of ~5 per cent is found. It does show, however, that it will not be easy to create a large sample of strong GRB afterglow microlensing events for statistical studies of their physical conditions on microarcsec scales.
Nonlinear multistable systems under the influence of noise exhibit a plethora of interesting dynamical properties. A medium noise level causes hopping between the metastable states. This attractorhopping process is characterized through laminar motion in the vicinity of the attractors and erratic motion taking place on chaotic saddles, which are embedded in the fractal basin boundary. This leads to noise-induced chaos. The investigation of the dissipative standard map showed the phenomenon of preference of attractors through the noise. It means, that some attractors get a larger probability of occurrence than in the noisefree system. For a certain noise level this prefernce achieves a maximum. Other attractors are occur less often. For sufficiently high noise they are completely extinguished. The complexity of the hopping process is examined for a model of two coupled logistic maps employing symbolic dynamics. With the variation of a parameter the topological entropy, which is used together with the Shannon entropy as a measure of complexity, rises sharply at a certain value. This increase is explained by a novel saddle merging bifurcation, which is mediated by a snapback repellor. Scaling laws of the average time spend on one of the formerly disconnected parts and of the fractal dimension of the connected saddle describe this bifurcation in more detail. If a chaotic saddle is embedded in the open neighborhood of the basin of attraction of a metastable state, the required escape energy is lowered. This enhancement of noise-induced escape is demonstrated for the Ikeda map, which models a laser system with time-delayed feedback. The result is gained using the theory of quasipotentials. This effect, as well as the two scaling laws for the saddle merging bifurcation, are of experimental relevance.
Aspects of open ocean deep convection variability are explored with a two-box model. In order to place the model in a region of parameter space relevant to the real ocean, it is fitted to observational data from the Labrador Sea. A systematic fit to OWS Bravo data allows us to determine the model parameters and to locate the position of the Labrador Sea on a stability diagram. The model suggests that the Labrador Sea is in a bistable regime where winter convection can be either ?on? or ?off?, with both these possibilities being stable climate states. When shifting the surface buoyancy forcing slightly to warmer or fresher conditions, the only steady solution is one without winter convection. We then introduce short-term variability by adding a noise term to the surface temperature forcing, turning the box model into a stochastic climate model. The surface forcing anomalies generated in this way induce jumps between the two model states. These state transitions occur on the interannual to decadal timescale. Changing the average surface forcing towards more buoyant conditions lowers the frequency of convection. However, convection becomes more frequent with stronger variability in the surface forcing. As part of the natural variability, there is a non-negligible probability for decadal interruptions of convection. The results highlight the role of surface forcing variability for the persistence of convection in the ocean.
Physik plus : mit fächerübergreifenden Themen und Projektangeboten ; Kl. 6, Mecklenburg-Vorpommern
(2001)
We use the extension of the method of recurrence plots to cross recurrence plots (CRP) which enables a nonlinear analysis of bivariate data. To quantify CRPs, we develop further three measures of complexity mainly basing on diagonal structures in CRPs. The CRP analysis of prototypical model systems with nonlinear interactions demonstrates that this technique enables to find these nonlinear interrelations from bivariate time series, whereas linear correlation tests do not. Applying the CRP analysis to climatological data, we find a complex relationship between rainfall and El Nino data.
The rescaling of geological data series to a geological reference time series is of major interest in many investigations. For example, geophysical borehole data should be correlated to a given data series whose time scale is known in order to achieve an age-depth function or the sedimentation rate for the borehole data. Usually this synchronization is performed visually and by hand. Instead of using this wiggle matching by eye, we present the application of cross recurrence plots for such tasks. Using this method, the synchronization and rescaling of geological data to a given time scale is much easier and faster than by hand.
Chemisch dotiertes Polypyrrol gilt als Modellsubstanz für leitfähige Polymere mit nichtdegeneriertem Grundzustand. Das elektrische Transportverhalten in dotiertem Polypyrrol wird durch lokalisierte Ladungsträger, Bipolaronen und Polaronen, bestimmt. Es besteht dabei eine enge gegenseitige Wechselwirkung zwischen der Struktur der Polymerkette und den Eigenschaften der Ladungsträger. Die in dieser Arbeit vorgestellte Kombination von Hochdruckmethodik und optischer Spektroskopie vertieft das Verständnis der Beziehung zwischen der molekularen und supramolekularen Struktur und den elektronischen und optischen Eigenschaften. Durch spezifische Synthesemethoden lassen sich unterschiedliche Strukturen in der polymeren Probe induzieren, die sich durch den Anteil an hochgeordneten Polymerketten unterscheiden. Die gezielte Veränderung dieser Strukturen durch Druckexperimente ermöglicht das Studium des Einflusses der Synthesemethoden auf die Ladungsträgereigenschaften. Für diese Studien wurden herkömmlich synthetisierte Polypyrrol-Filme und Filme, die sich aus Polypyrrol-Nanoröhren zusammensetzen (Synthese in Kernspur-membranen, "Template-Synthese") bei ansonsten gleichen Syntheseparametern untersucht. Raman- und Infrarotspektroskopie sowie UV-Vis-NIR-Absorptionsspektroskopie, die jeweils für die Hochdruckmethodik adaptiert wurden, dienten der Charakterisierung der Proben. Zusätzlich wurden temperatur- und druckabhängige Messungen des elektrischen Widerstands an den Template-Proben durchgeführt. Die Morphologie template-synthetisierter Polypyrrol-Nanoröhren und die filmbildenden Eigenschaften sowie der mögliche Aufbau von Schichtarchitekturen wurden mit transmissions- und rasterelektronenmikroskopischen Techniken untersucht. Die aus den Hochdruckexperimenten gewonnenen Daten werden in der Arbeit im Hinblick auf die Stabilität der Ladungsträger interpretiert. Im Ergebnis bewirkt die Druckerhöhung eine Dissoziation der Bipolaronen in den untersuchten Proben. Das Ladungsträger-gleichgewicht verschiebt sich dadurch mit steigendem Druck zu Zuständen mit höherem Anteil an polaronischen Ladungsträgern. Die Template-Synthese bewirkt gegenüber herkömmlich synthetisierten Proben einen höheren Anteil an Polaronen bereits bei Normaldruck, und eine Lage des Systems näher bei einem Isolator-Metall-Übergang. Die Dissoziationsrate der Bipolaronen ist für Template- und herkömmlich synthetisierte Proben vergleichbar groß und unabhängig vom Initialzustand nach der Synthese. Dieses Verhalten der Ladungsträger wird weitergehend im Rahmen eines Modells untersucht, bei dem der Einfluß benachbarter Polymerketten und der Dotandionen berücksichtigt wird. Dementsprechend können sich die Wellenfunktionen der Ladungsträger unter bestimmten Bedingungen auch auf benachbarte Ketten erstrecken (transversale Polaronen bzw. Bipolaronen). Eine solche Ausdehnung der Wellenfunktionen unter Mitwirkung der Dotandionen wurde in den untersuchten Proben nicht festgestellt. Die Wellenfunktionen der Ladungsträger besitzen demnach hauptsächlich Komponenten entlang der Polymerkette (longitudinale Polaronen bzw. Bipolaronen). Aus der Änderungsrate druckabhängiger spektraler Charakteristiken lassen sich Aussagen über den Ordnungszustand der Probe ableiten. Diese auf experimentellem Wege gefundenen Ergebnisse liefern somit Hinweise für die bisher kontrovers diskutierte Koexistenz der beiden Ladungsträgerarten Polaronen und Bipolaronen und die Größe ihrer jeweiligen Bindungsenergien. Druckerhöhung und Template-Synthese bewirken analoge Änderungen der Polymerstruktur. Sowohl höherer Druck wie auch die Template-Synthese lassen sich mit einem höheren Ordnungsgrad in den Template-Proben korrelieren. Der Ladungstransport in den Proben kann durch ein Mott Variable Range Hopping-Modell mit druckabhängiger charakteristischer Dimension beschrieben werden. Die Erhöhung des Drucks bewirkt einen Anstieg der Dimension, eine bessere Überlappung der Wellenfunktionen der Ladungsträger und eine Vergrößerung der Lokalisierungslänge der Ladungsträger. Die druckinduzierte Dissoziation der Bipolaronen beeinflußt den Ladungstransport zusätzlich durch Erhöhung der Anzahl unabhängiger Ladungsträger und verbessert diesen aufgrund stärkerer Überlappung der Wellenfunktionen. Template-Proben niedriger Synthesetemperatur zeigen bei Normaldruck eine höhere Dimension des Mott Variable Range Hoppings und eine größere Lokalisierungslänge gegenüber bei Raumtemperatur synthetisierten Proben. Kürzere Synthesezeiten bewirken einen Anstieg der Dimension bei Normaldruck und eine Verschiebung des Dimensionscrossovers zu niedrigeren Temperaturen. Template-Proben kurzer Synthesezeit zeigen geringere druckinduzierte Änderungen als solche mit langer Synthesezeit. Es wurde ein kontinuierliches Ordnungsmodell der Polypyrrol-Nanoröhren entwickelt, das dieses Verhalten beschreibt. Die Morphologie und die mechanischen Eigenschaften der Nanoröhren werden durch spezifische Syntheseparameter, wie Temperatur und Dauer, beeinflußt und können mit Transmissions- und Rasterelektronenmikroskopie beobachtet werden. Die filmbildenden Eigenschaften der Röhren hängen stark von diesen mechanischen Eigenschaften ab. Die Struktur der Filme kann dabei von einer unregelmäßigen Anordnung der Röhren bis zu nahezu parallel ausgerichteten Röhren variieren. Es wurden Möglichkeiten untersucht, die Röhren in den Filmen zu orientieren und aus diesen Filmen durch Schichtung makroskopische Architekturen mit einem hohen Grad an orientierten Röhren aufzubauen. Solche Architekturen können für verschiedene Anwendungen, z.B. in elektronischen Bauteilen oder mikroskopischen Bioreaktoren, von Interesse sein.
One of the rules-of-thumb of colloid and surface physics is that most surfaces are charged when in contact with a solvent, usually water. This is the case, for instance, in charge-stabilized colloidal suspensions, where the surface of the colloidal particles are charged (usually with a charge of hundreds to thousands of e, the elementary charge), monolayers of ionic surfactants sitting at an air-water interface (where the water-loving head groups become charged by releasing counterions), or bilayers containing charged phospholipids (as cell membranes). In this work, we look at some model-systems that, although being a simplified version of reality, are expected to capture some of the physical properties of real charged systems (colloids and electrolytes). We initially study the simple double layer, composed by a charged wall in the presence of its counterions. The charges at the wall are smeared out and the dielectric constant is the same everywhere. The Poisson-Boltzmann (PB) approach gives asymptotically exact counterion density profiles around charged objects in the weak-coupling limit of systems with low-valent counterions, surfaces with low charge density and high temperature (or small Bjerrum length). Using Monte Carlo simulations, we obtain the profiles around the charged wall and compare it with both Poisson-Boltzmann (in the low coupling limit) and the novel strong coupling (SC) theory in the opposite limit of high couplings. In the latter limit, the simulations show that the SC leads in fact to asymptotically correct density profiles. We also compare the Monte Carlo data with previously calculated corrections to the Poisson-Boltzmann theory. We also discuss in detail the methods used to perform the computer simulations. After studying the simple double layer in detail, we introduce a dielectric jump at the charged wall and investigate its effect on the counterion density distribution. As we will show, the Poisson-Boltzmann description of the double layer remains a good approximation at low coupling values, while the strong coupling theory is shown to lead to the correct density profiles close to the wall (and at all couplings). For very large couplings, only systems where the difference between the dielectric constants of the wall and of the solvent is small are shown to be well described by SC. Another experimentally relevant modification to the simple double layer is to make the charges at the plane discrete. The counterions are still assumed to be point-like, but we constraint the distance of approach between ions in the plane and counterions to a minimum distance D. The ratio between D and the distance between neighboring ions in the plane is, as we will see, one of the important quantities in determining the influence of the discrete nature of the charges at the wall over the density profiles. Another parameter that plays an important role, as in the previous case, is the coupling as we will demonstrate, systems with higher coupling are more subject to discretization effects than systems with low coupling parameter. After studying the isolated double layer, we look at the interaction between two double layers. The system is composed by two equally charged walls at distance d, with the counterions confined between them. The charge at the walls is smeared out and the dielectric constant is the same everywhere. Using Monte-Carlo simulations we obtain the inter-plate pressure in the global parameter space, and the pressure is shown to be negative (attraction) at certain conditions. The simulations also show that the equilibrium plate separation (where the pressure changes from attractive to repulsive) exhibits a novel unbinding transition. We compare the Monte Carlo results with the strong-coupling theory, which is shown to describe well the bound states of systems with moderate and high couplings. The regime where the two walls are very close to each other is also shown to be well described by the SC theory. Finally, Using a field-theoretic approach, we derive the exact low-density ("virial") expansion of a binary mixture of positively and negatively charged hard spheres (two-component hard-core plasma, TCPHC). The free energy obtained is valid for systems where the diameters d_+ and d_- and the charge valences q_+ and q_- of positive and negative ions are unconstrained, i.e., the same expression can be used to treat dilute salt solutions (where typically d_+ ~ d_- and q_+ ~ q_-) as well as colloidal suspensions (where the difference in size and valence between macroions and counterions can be very large). We also discuss some applications of our results.
Strain induced compositional modulations in AlGaAs overlayers induced by lateral surface gratings
(2001)
Comment on "Simple approach to the creation of a strange nonchaotic attractor in any chaotic system"
(2001)
We address the problem of existence of strange nonchaotic attractors (SNAs) in quasiperiodically forced dynamical systems. Recently, Shuai and Wong [Phys. Rev. E 59, 5338 (1999)] suggested a universal method for constructing a SNA in an arbitrary system possessing chaos. We demonstrate here that, in general, this method fails. For arbitrary systems, it gives a SNA only in a vicinity of transition to chaos. We discuss also a special example, where the method by Shuai and Wong indeed produces a SNA.
Clustering in ensembles of globally coupled identical chaotic oscillators is reconsidered using a twofold approach. Stability of clusters towards "emanation" of the elements is described with the evaporation Lyapunov exponents. It appears that direct numerical simulations of ensembles often lead to spurious clusters that have positive evaporation exponents, due to a numerical trap. We propose a numerical method that surmounts the spurious clustering. We also demonstrate that clustering can be very sensitive to the number of elements in the ensemble.
Lai et al. [Phys. Rev. E 62, R29 (2000)] claim that the angular velocity of the phase point moving along the chaotic trajectory in a properly chosen projection (the instantaneous frequency) is intermittent. Using the same examples, namely the Rössler and the Lorenz systems, we show the absence of intermittency in the dynamics of the instantaneous frequency.This is confirmed by demonstrating that the phase dynamics exhibits normal diffusion. We argue that the nonintermittent behavior is generic.
We propose a method for experimental detection of directionality of weak coupling between two self-sustained oscillators from bivariate data. The technique is applicable to both noisy and chaotic systems that can be nonidentical or even structurally different. We introduce an index that quantifies the asymmetry in coupling.