Mn(ii) sub-nanometric site stabilization in noble, N-doped carbonaceous materials for electrochemical CO2 reduction
- The preparation of stable and efficient electrocatalysts comprising abundant and non-critical row-materials is of paramount importance for their industrial implementation. Herein, we present a simple synthetic route to prepare Mn(ii) sub-nanometric active sites over a highly N-doped noble carbonaceous support. This support not only promotes a strong stabilization of the Mn(ii) sites, improving its stability against oxidation, but also provides a convenient coordination environment in the Mn(ii) sites able to produce CO, HCOOH and CH3COOH from electrochemical CO2 reduction.
Author details: | Janina KossmannORCiDGND, Maria Luz Ortiz Sanchez-Manjavacas, Jessica Brandt, Tobias HeilORCiDGND, Nieves López-SalasORCiD, Josep AlberoORCiD |
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DOI: | https://doi.org/10.1039/d2cc00585a |
ISSN: | 1359-7345 |
ISSN: | 1364-548X |
Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/35348156 |
Title of parent work (English): | Chemical communications : ChemComm / The Royal Society of Chemistry |
Publisher: | Royal Society of Chemistry |
Place of publishing: | Cambridge |
Publication type: | Article |
Language: | English |
Date of first publication: | 2022/03/21 |
Publication year: | 2022 |
Release date: | 2023/04/25 |
Volume: | 58 |
Issue: | 31 |
Number of pages: | 5 |
First page: | 4841 |
Last Page: | 4844 |
Funding institution: | Max Planck Society |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access / Hybrid Open-Access |
License (English): | Creative Commons - Namensnennung 3.0 Unported |