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Pargasite in fluid inclusions of mantle xenoliths from northeast Australia (Mt. Quincan)

  • Three spinel lherzolite xenoliths from Mt. Quincan (Queensland, northeastern Australia) were studied with special attention to their enclosed fluid inclusions. The xenoliths are deformed, have porphyroclastic textures and overall show very similar petrographic features. The only significant difference is manifested in the abundance of fluid inclusions in the samples, mostly in orthopyroxene porphyroclasts. Xenolith JMTQ11 is fluid inclusion-free, whereas xenolith JMTQ20 shows a high abundance of fluid inclusions (fluid inclusion-rich). Xenolith JMTQ45 represents a transitional state between the previous two, as it contains only a small amount of fluid inclusions (fluid inclusion-bearing). Previous studies revealed that these xenoliths and the entrapped fluid inclusions represent a former addition of a MORB-type fluid to the pre-existing lithosphere, resulting from asthenosphere upwelling. There is a progressive enrichment in LREE, Nb, Sr and Ti from the fluid inclusion-free xenolith through the fluid inclusion-bearing one to the fluidThree spinel lherzolite xenoliths from Mt. Quincan (Queensland, northeastern Australia) were studied with special attention to their enclosed fluid inclusions. The xenoliths are deformed, have porphyroclastic textures and overall show very similar petrographic features. The only significant difference is manifested in the abundance of fluid inclusions in the samples, mostly in orthopyroxene porphyroclasts. Xenolith JMTQ11 is fluid inclusion-free, whereas xenolith JMTQ20 shows a high abundance of fluid inclusions (fluid inclusion-rich). Xenolith JMTQ45 represents a transitional state between the previous two, as it contains only a small amount of fluid inclusions (fluid inclusion-bearing). Previous studies revealed that these xenoliths and the entrapped fluid inclusions represent a former addition of a MORB-type fluid to the pre-existing lithosphere, resulting from asthenosphere upwelling. There is a progressive enrichment in LREE, Nb, Sr and Ti from the fluid inclusion-free xenolith through the fluid inclusion-bearing one to the fluid inclusion-rich lherzolite. This suggests an increase in the extent of the interaction between the fluid-rich melt and the lherzolite wallrock. In addition, the same interaction is considered to be responsible for the formation of pargasitic amphibole as well. The presence of fluid inclusions indicates fluid migration at mantle depth, and their association with exsolution lamellae in orthopyroxene suggests fluid entrapment following the continental rifting (thermal relaxation) during cooling. A series of analyses, including microthermometry coupled with Raman spectroscopy, FTIR hyperspectral imaging, and Focused Ion Beam-Scanning Electron Microscopy (FIB-SEM) was carried out on the fluid inclusions. Based on the results, the entrapped high-density fluid is composed of 7589 mol% CO2, 918 mol% H2O, 0.11.7 mol% N-2 and <= 0.5 mol% H2S with dissolved trace elements (melt component). Our findings suggest that the metasomatic fluid phase could have been either a fluid/fluid-rich silicate melt released from the deeper asthenosphere, or a coexisting incipient fluid-rich silicate melt. Further cooling, possibly due to thermal relaxation and the upward migration of the fluid phase, caused the investigated lherzolites to reach pargasite stability conditions. We conclude that pargasite, even if only present in very limited modal proportions, can be a common phase at spinel lherzolite stability in the lithospheric upper mantle in continental rift back-arc settings. Studies of fluid inclusions indicate that significant CO2 release from the asthenosphere in a continental rifting environment is resulting from asthenosphere upwelling and its addition to the lithospheric mantle together with fluid-rich melt lherzolite interaction that leaves a CO2-rich fluid behind.show moreshow less

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Author details:Marta Berkesi, Gyorgy Czuppon, Csaba Szabo, Istvan KovacsORCiD, Silvio FerreroORCiDGND, Marie-Christine Boiron, Chantal Peiffert
DOI:https://doi.org/10.1016/j.chemgeo.2018.06.022
ISSN:0009-2541
ISSN:1872-6836
Title of parent work (English):Chemical geology : official journal of the European Association for Geochemistry
Subtitle (English):evidence of interaction with asthenospheric fluid
Publisher:Elsevier
Place of publishing:Amsterdam
Publication type:Article
Language:English
Date of first publication:2018/06/30
Publication year:2018
Release date:2021/03/15
Tag:Asthenospheric fluid; Australia; Fluid inclusions; Metasomatism; Mt. Quincan; Pargasite
Volume:508
Number of pages:15
First page:182
Last Page:196
Funding institution:Hungarian Scientific Research Fund (OTKA)Orszagos Tudomanyos Kutatasi Alapprogramok (OTKA) [105410]; Bolyai Postdoctoral Fellowship Program grant; Ministry of Education, Science, Sports and CultureMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT) [17684029, 16GS021499]; 21st Century Center of Excellence ProgramMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT) [G17]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Geowissenschaften
DDC classification:5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften
Peer review:Referiert
Institution name at the time of the publication:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Erd- und Umweltwissenschaften
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