Understanding fracturing processes and the hydromechanical relation to induced seismicity is a key question for enhanced geothermal systems (EGS). Commonly massive fluid injection, predominately causing hydroshearing, are used in large-scale EGS but also hydraulic fracturing approaches were discussed. To evaluate the applicability of hydraulic fracturing techniques in EGS, six in situ, multistage hydraulic fracturing experiments with three different injection schemes were performed under controlled conditions in crystalline rock at the Aspo Hard Rock Laboratory (Sweden). During the experiments the near-field ground motion was continuously recorded by 11 piezoelectric borehole sensors with a sampling rate of 1 MHz. The sensor network covered a volume of 30x30x30 m around a horizontal, 28-m-long injection borehole at a depth of 410 m. To extract and characterize massive, induced, high-frequency acoustic emission (AE) activity from continuous recordings, a semi-automated workflow was developed relying on full waveform based detection, classification and location procedures. The approach extended the AE catalogue from 196 triggered events in previous studies to more than 19600 located AEs. The enhanced catalogue, for the first time, allows a detailed analysis of induced seismicity during single hydraulic fracturing experiments, including the individual fracturing stages and the comparison between injection schemes. Beside the detailed study of the spatio-temporal patterns, event clusters and the growth of seismic clouds, we estimate relative magnitudes and b-values of AEs for conventional, cyclic progressive and dynamic pulse injection schemes, the latter two being fatigue hydraulic fracturing techniques. While the conventional fracturing leads to AE patterns clustered in planar regions, indicating the generation of a single main fracture plane, the cyclic progressive injection scheme results in a more diffuse, cloud-like AE distribution, indicating the activation of a more complex fracture network. For a given amount of hydraulic energy (pressure multiplied by injected volume) pumped into the system, the cyclic progressive scheme is characterized by a lower rate of seismicity, lower maximum magnitudes and significantly larger b-values, implying an increased number of small events relative to the large ones. To our knowledge, this is the first direct comparison of high resolution seismicity in a mine-scale experiment induced by different hydraulic fracturing schemes.

In snow-dominated river basins, floods often occur during early summer, when snowmelt-induced runoff superimposes with rainfall-induced runoff. An earlier onset of seasonal snowmelt as a consequence of a warming climate is often expected to shift snowmelt contribution to river runoff and potential flooding to an earlier date. Against this background, we assess the impact of rising temperatures on seasonal snowpacks and quantify changes in timing, magnitude and elevation of snowmelt. We analyse in situ snow measurements, conduct snow simulations and examine changes in river runoff at key gauging stations. With regard to snowmelt, we detect a threefold effect of rising temperatures: snowmelt becomes weaker, occurs earlier and forms at higher elevations. Due to the wide range of elevations in the catchment, snowmelt does not occur simultaneously at all elevations. Results indicate that elevation bands melt together in blocks. We hypothesise that in a warmer world with similar sequences of weather conditions, snowmelt is moved upward to higher elevation. The movement upward the elevation range makes snowmelt in individual elevation bands occur earlier, although the timing of the snowmelt-induced runoff stays the same. Meltwater from higher elevations, at least partly, replaces meltwater from elevations below.

Nutrient storage, transform and transport are important processes for achieving environmental and ecological health, as well as conducting water management plans. Nitrogen is one of the most noticeable elements due to its impacts on tremendous consequences of eutrophication in aquatic systems. Among all nitrogen components, researches on nitrate are blooming because of widespread deployments of in-situ high-frequency sensors. Monitoring and studying nitrate can become a paradigm for any other reactive substances that may damage environmental conditions and cause economic losses. Identifying nitrate storage and its transport within a catchment are inspiring to the management of agricultural activities and municipal planning. Storm events are periods when hydrological dynamics activate the exchange between nitrate storage and flow pathways. In this dissertation, long-term high-frequency monitoring data at three gauging stations in the Selke river were used to quantify event-scale nitrate concentration-discharge (C-Q) hysteretic relationships. The Selke catchment is characterized into three nested subcatchments by heterogeneous physiographic conditions and land use. With quantified hysteresis indices, impacts of seasonality and landscape gradients on C-Q relationships are explored. For example, arable area has deep nitrate legacy and can be activated with high intensity precipitation during wetting/wet periods (i.e., the strong hydrological connectivity). Hence, specific shapes of C-Q relationships in river networks can identify targeted locations and periods for agricultural management actions within the catchment to decrease nitrate output into downstream aquatic systems like the ocean. The capacity of streams for removing nitrate is of both scientific and social interest, which makes the quantification motivated. Although measurements of nitrate dynamics are advanced compared to other substances, the methodology to directly quantify nitrate uptake pathways is still limited spatiotemporally. The major problem is the complex convolution of hydrological and biogeochemical processes, which limits in-situ measurements (e.g., isotope addition) usually to small streams with steady flow conditions. This makes the extrapolation of nitrate dynamics to large streams highly uncertain. Hence, understanding of in-stream nitrate dynamic in large rivers is still necessary. High-frequency monitoring of nitrate mass balance between upstream and downstream measurement sites can quantitatively disentangle multi-path nitrate uptake dynamics at the reach scale (3-8 km). In this dissertation, we conducted this approach in large stream reaches with varying hydro-morphological and environmental conditions for several periods, confirming its success in disentangling nitrate uptake pathways and their temporal dynamics. Net nitrate uptake, autotrophic assimilation and heterotrophic uptake were disentangled, as well as their various diel and seasonal patterns. Natural streams generally can remove more nitrate under similar environmental conditions and heterotrophic uptake becomes dominant during post-wet seasons. Such two-station monitoring provided novel insights into reach-scale nitrate uptake processes in large streams. Long-term in-stream nitrate dynamics can also be evaluated with the application of water quality model. This is among the first time to use a data-model fusion approach to upscale the two-station methodology in large-streams with complex flow dynamics under long-term high-frequency monitoring, assessing the in-stream nitrate retention and its responses to drought disturbances from seasonal to sub-daily scale. Nitrate retention (both net uptake and net release) exhibited substantial seasonality, which also differed in the investigated normal and drought years. In the normal years, winter and early spring seasons exhibited extensive net releases, then general net uptake occurred after the annual high-flow season at later spring and early summer with autotrophic processes dominating and during later summer-autumn low-flow periods with heterotrophy-characteristics predominating. Net nitrate release occurred since late autumn until the next early spring. In the drought years, the late-autumn net releases were not so consistently persisted as in the normal years and the predominance of autotrophic processes occurred across seasons. Aforementioned comprehensive results of nitrate dynamics on stream scale facilitate the understanding of instream processes, as well as raise the importance of scientific monitoring schemes for hydrology and water quality parameters.

Drainage divides are organized into tree-like networks that may record information about drainage divide mobility. However, views diverge about how to best assess divide mobility. Here, we apply a new approach of automatically extracting and ordering drainage divide networks from digital elevation models to results from landscape evolution model experiments. We compared landscapes perturbed by strike-slip faulting and spatiotemporal variations in erodibility to a reference model to assess which topographic metrics (hillslope relief, flow distance, and chi) are diagnostic of divide mobility. Results show that divide segments that are a minimum distance of similar to 5 km from river confluences strive to attain constant values of hillslope relief and flow distance to the nearest stream. Disruptions of such patterns can be related to mobile divides that are lower than stable divides, closer to streams, and often asymmetric in shape. In general, we observe that drainage divides high up in the network, i.e., at great distances from river confluences, are more susceptible to disruptions than divides closer to these confluences and are thus more likely to record disturbance for a longer time period. We found that across-divide differences in hillslope relief proved more useful for assessing divide migration than other tested metrics. However, even stable drainage divide networks exhibit across-divide differences in any of the studied topographic metrics. Finally, we propose a new metric to quantify the connectivity of divide junctions.

Extreme weather and climate events are one of the greatest dangers for present-day society. Therefore, it is important to provide reliable statements on what changes in extreme events can be expected along with future global climate change. However, the projected overall response to future climate change is generally a result of a complex interplay between individual physical mechanisms originated within the different climate subsystems. Hence, a profound understanding of these individual contributions is required in order to provide meaningful assessments of future changes in extreme events. One aspect of climate change is the recently observed phenomenon of Arctic Amplification and the related dramatic Arctic sea ice decline, which is expected to continue over the next decades. The question to what extent Arctic sea ice loss is able to affect atmospheric dynamics and extreme events over mid-latitudes has received a lot of attention over recent years and still remains a highly debated topic. In this respect, the objective of this thesis is to contribute to a better understanding on the impact of future Arctic sea ice retreat on European temperature extremes and large-scale atmospheric dynamics. The outcomes are based on model data from the atmospheric general circulation model ECHAM6. Two different sea ice sensitivity simulations from the Polar Amplification Intercomparison Project are employed and contrasted to a present day reference experiment: one experiment with prescribed future sea ice loss over the entire Arctic, as well as another one with sea ice reductions only locally prescribed over the Barents-Kara Sea.% prescribed over the entire Arctic, as well as only locally over the Barent/Karasea with a present day reference experiment. The first part of the thesis focuses on how future Arctic sea ice reductions affect large-scale atmospheric dynamics over the Northern Hemisphere in terms of occurrence frequency changes of five preferred Euro-Atlantic circulation regimes. When compared to circulation regimes computed from ERA5 it shows that ECHAM6 is able to realistically simulate the regime structures. Both ECHAM6 sea ice sensitivity experiments exhibit similar regime frequency changes. Consistent with tendencies found in ERA5, a more frequent occurrence of a Scandinavian blocking pattern in midwinter is for instance detected under future sea ice conditions in the sensitivity experiments. Changes in occurrence frequencies of circulation regimes in summer season are however barely detected. After identifying suitable regime storylines for the occurrence of European temperature extremes in winter, the previously detected regime frequency changes are used to quantify dynamically and thermodynamically driven contributions to sea ice-induced changes in European winter temperature extremes. It is for instance shown how the preferred occurrence of a Scandinavian blocking regime under low sea ice conditions dynamically contributes to more frequent midwinter cold extreme occurrences over Central Europe. In addition, a reduced occurrence frequency of a Atlantic trough regime is linked to reduced winter warm extremes over Mid-Europe. Furthermore, it is demonstrated how the overall thermodynamical warming effect due to sea ice loss can result in less (more) frequent winter cold (warm) extremes, and consequently counteracts the dynamically induced changes. Compared to winter season, circulation regimes in summer are less suitable as storylines for the occurrence of summer heat extremes. Therefore, an approach based on circulation analogues is employed in order to quantify thermodyamically and dynamically driven contributions to sea ice-induced changes of summer heat extremes over three different European sectors. Reduced occurrences of blockings over Western Russia are detected in the ECHAM6 sea ice sensitivity experiments; however, arguing for dynamically and thermodynamically induced contributions to changes in summer heat extremes remains rather challenging.