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Content: 1. Introduction 2. Early Examples of the AFP in Hiberno-English 3. Assessments of the Evidence 4. Attempts to Explain the Early HE Construction 5. Distribution and Function of the AFP in EMI and HE 5.1. The AFP with the Future Tense in Irish 5.2. The AFP with the Secondary Future or Conditional 5.3. The AFP with the Subjunctive 5.5. Functions of the AFP in Early Modern Irish and HE 6. The Restriction of the AFP to the Recent Perfect 7. Conclusions
Content: 1. Preverbal Composition in Old Irish and Old English 2. The Shape of the Modern Irish Verbal Lexeme 3. Particle Verbs in Irish and English 3.1. Definitions: Phrasal Verb or Prepositional Verb? 3.2. Examples 3.3. Obvious Similarities 3.4. Irish English Peculiarities 4. The Abolition of Verbal Composition in Irish and English – Parallels and Differences in Historical Syntax 5. Conclusions
Content: 1. Introduction 2. Getting to the Seen from the Unseen 2.1. The Theory of the Zones 2.2. Brief Comments on Mechanism 3. The Areal Evidence: Shared Features and Their Dialectal Provenance 4. Explaining the Evidence Seen 4.1. Why It Is Not Due to Mere Misleading Coincidence 4.2. Why It Is Not Due to French Influence 4.3. Why It Is Not Due to Norse Influence 4.4. Why It Is Not Due to English Influence over Brittonic 4.5. Why It Is Due to Brittonic Influence 5. Conclusion 5.1. The Areal Pattern and Its Explanation 5.2. Substrate versus Superstrate 5.3. Some Final Arguments, and Good Questions 6. Addenda
The layer-by-layer assembly (LBL) of polyelectrolytes has been extensively studied for the preparation of ultrathin films due to the versatility of the build-up process. The control of the permeability of these layers is particularly important as there are potential drug delivery applications. Multilayered polyelectrolyte microcapsules are also of great interest due to their possible use as microcontainers. This work will present two methods that can be used as employable drug delivery systems, both of which can encapsulate an active molecule and tune the release properties of the active species. Poly-(N-isopropyl acrylamide), (PNIPAM) is known to be a thermo-sensitive polymer that has a Lower Critical Solution Temperature (LCST) around 32oC; above this temperature PNIPAM is insoluble in water and collapses. It is also known that with the addition of salt, the LCST decreases. This work shows Differential Scanning Calorimetry (DSC) and Confocal Laser Scanning Microscopy (CLSM) evidence that the LCST of the PNIPAM can be tuned with salt type and concentration. Microcapsules were used to encapsulate this thermo-sensitive polymer, resulting in a reversible and tunable stimuli- responsive system. The encapsulation of the PNIPAM inside of the capsule was proven with Raman spectroscopy, DSC (bulk LCST measurements), AFM (thickness change), SEM (morphology change) and CLSM (in situ LCST measurement inside of the capsules). The exploitation of the capsules as a microcontainer is advantageous not only because of the protection the capsules give to the active molecules, but also because it facilitates easier transport. The second system investigated demonstrates the ability to reduce the permeability of polyelectrolyte multilayer films by the addition of charged wax particles. The incorporation of this hydrophobic coating leads to a reduced water sensitivity particularly after heating, which melts the wax, forming a barrier layer. This conclusion was proven with Neutron Reflectivity by showing the decreased presence of D2O in planar polyelectrolyte films after annealing creating a barrier layer. The permeability of capsules could also be decreased by the addition of a wax layer. This was proved by the increase in recovery time measured by Florescence Recovery After Photobleaching, (FRAP) measurements. In general two advanced methods, potentially suitable for drug delivery systems, have been proposed. In both cases, if biocompatible elements are used to fabricate the capsule wall, these systems provide a stable method of encapsulating active molecules. Stable encapsulation coupled with the ability to tune the wall thickness gives the ability to control the release profile of the molecule of interest.
We analyze the notions of monotonicity and complete monotonicity for Markov Chains in continuous-time, taking values in a finite partially ordered set. Similarly to what happens in discrete-time, the two notions are not equivalent. However, we show that there are partially ordered sets for which monotonicity and complete monotonicity coincide in continuous time but not in discrete-time.
Deutschland und Polen bedürfen eines erneuerten strategischen Kontextes für ihre partnerschaftlichen Beziehungen. Die unterschiedlichen Haltungen zu Militäreinsätzen sind durch historische Erfahrungen bestimmt. Falls die schwarz-rote Koalition für Deutschland wieder die Rolle des euro-atlantischen Vermittlers übernimmt, wird sich das positiv auf die deutsch-polnischen Beziehungen auswirken.