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Diversified applications of chemically modified 1,2-Polybutadiene
- Commercially available 1,2-PB was transformed into a well-defined reactive intermediate by quantitative bromination. The brominated polymer was used as a polyfunctional macroinitiator for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline to yield a water-soluble brush polymer. Nucleophilic substitution of bromide by 1-methyl imidazole resulted in the formation of polyelectrolyte copolymers consisting of mixed units of imidazolium, bromo, and double bond. These copolymers, which were soluble in water without forming aggregates, were used as stabilizers in the heterophase polymerization of styrene and were also studied for their ionic conducting properties.
| Verfasserangaben: | Jiayin YuanORCiDGND, Niels ten Brummelhuis, Mathias Junginger, Zailai Xie, Yan LuORCiDGND, Andreas TaubertORCiDGND, Helmut SchlaadORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1002/marc.201100254 |
| ISSN: | 1022-1336 |
| Titel des übergeordneten Werks (Englisch): | Macromolecular rapid communications |
| Verlag: | Wiley-Blackwell |
| Verlagsort: | Malden |
| Publikationstyp: | Wissenschaftlicher Artikel |
| Sprache: | Englisch |
| Jahr der Erstveröffentlichung: | 2011 |
| Erscheinungsjahr: | 2011 |
| Datum der Freischaltung: | 26.03.2017 |
| Freies Schlagwort / Tag: | emulsion polymerization; polybutadiene; polyelectrolytes; polymer modification; ring-opening polymerization |
| Band: | 32 |
| Ausgabe: | 15 |
| Seitenanzahl: | 6 |
| Erste Seite: | 1157 |
| Letzte Seite: | 1162 |
| Fördernde Institution: | Max Planck Society; MPI Colloids Interfaces |
| Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer Review: | Referiert |
