Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties
- A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N-2, CO2, CH4 and H-2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.
Author details: | Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Serhiy Demeshko, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD |
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DOI: | https://doi.org/10.1039/c3ce42040j |
ISSN: | 1466-8033 |
Title of parent work (English): | CrystEngComm |
Publisher: | Royal Society of Chemistry |
Place of publishing: | Cambridge |
Publication type: | Article |
Language: | English |
Year of first publication: | 2014 |
Publication year: | 2014 |
Release date: | 2017/03/27 |
Volume: | 16 |
Issue: | 1 |
Number of pages: | 4 |
First page: | 39 |
Last Page: | 42 |
Funding institution: | German Research Foundation on "Metal-Organic Frameworks" [1362] |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |