Giant Zn-14 molecular building block in hydrogen-bonded network with permanent porosity for gas uptake
- In situ imidazolate-4,5-diamide-2-olate linker generation leads to the formation of a [Zn-14(L2)(12)(O)-(OH)(2)(H2O)(4)] molecular building block (MBB) with a Zn-6 octahedron inscribed in a Zn-8 cube. The MBBs connect by amide-amide hydrogen bonds to a 3D robust supramolecular network which can be activated for N-2, CO2, CH4, and H-2 gas sorption.
Author details: | Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD |
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DOI: | https://doi.org/10.1021/ja410595q |
ISSN: | 0002-7863 |
Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/24313724 |
Title of parent work (English): | Journal of the American Chemical Society |
Publisher: | American Chemical Society |
Place of publishing: | Washington |
Publication type: | Article |
Language: | English |
Year of first publication: | 2014 |
Publication year: | 2014 |
Release date: | 2017/03/27 |
Volume: | 136 |
Issue: | 1 |
Number of pages: | 4 |
First page: | 44 |
Last Page: | 47 |
Funding institution: | German Research Foundation on "Metal-Organic Frameworks" [1362] |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |