In situ synthesis of an imidazolate-4-amide-5-imidate ligand and formation of a microporous zinc-organic framework with H2-and CO2-storage ability
- Narrow channels with polar walls are the structural and functional features responsible for the high capacity of a zinc-organic framework based on an imidazolate-amide-imidate ligand for the uptake of H2 and CO2 (see structure: orange Zn, blue N, red O, dark gray C, light gray H). The rigid and stable chelating ligand was synthesized in situ by partial hydrolysis of a dicyanoimidazole compound.
Author details: | Franziska Debatin, Arne Thomas, Alexandra Kelling, Niklas Hedin, Zoltan Bacsik, Irena Senkovska, Stefan Kaskel, Matthias Junginger, Holger Müller, Uwe SchildeORCiDGND, Christian Jäger, Alwin Friedrich, Hans-Jürgen HoldtORCiD |
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URL: | http://www3.interscience.wiley.com/cgi-bin/jhome/26737/ |
DOI: | https://doi.org/10.1002/anie.200906188 |
ISSN: | 1433-7851 |
Publication type: | Article |
Language: | English |
Year of first publication: | 2010 |
Publication year: | 2010 |
Release date: | 2017/03/25 |
Source: | Angewandte Chemie. - ISSN 1433-7851. - 49 (2010), 7, S. 1258 - 1262 |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |