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Synthesis and characterization of quantum dot nanoparticles bound to the plant volatile precursor of Hydroxy-apo-10'-carotenal

  • This study is focused on the synthesis and characterization of hydroxy-apo-10'-carotenal/quantum dot (QD) conjugates aiming at the in vivo visualization of beta-ionone, a carotenoid-derived volatile compound known for its important contribution to the flavor and aroma of many fruits, vegetables, and plants. The synthesis of nanoparticles bound to plant volatile precursors was achieved via coupling reaction of the QD to C-27-aldehyde which was prepared from alpha-ionone via 12 steps in 2.4% overall yield. The formation of the QD-conjugate was confirmed by measuring its fluorescence spectrum to observe the occurrence of fluorescence resonance energy transfer.

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Author details:Vo Anh Tu, Atsushi Kaga, Karl-Heinz Gericke, Naoharu Watanabe, Tetsuo Narumi, Mitsuo Toda, Bernhard Brueckner, Susanne BaldermannORCiDGND, Nobuyuki Mase
DOI:https://doi.org/10.1021/jo500605c
ISSN:0022-3263
Pubmed ID:https://pubmed.ncbi.nlm.nih.gov/25026389
Title of parent work (English):The journal of organic chemistry
Publisher:American Chemical Society
Place of publishing:Washington
Publication type:Article
Language:English
Year of first publication:2014
Publication year:2014
Release date:2017/03/27
Volume:79
Issue:15
Number of pages:8
First page:6808
Last Page:6815
Funding institution:Nanobio Project from Shizuoka University
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Ernährungswissenschaft
Peer review:Referiert
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