Synthesis of Phenylpropanoids via Matsuda-Heck Coupling of Arene Diazonium Salts
- The Pd-catalyzed Heck-type coupling (Matsuda Heck reaction) of electron rich arene diazonium salts with electron deficient olefins has been exploited for the synthesis of phenylpropanoid natural products. Examples described herein are the naturally occurring benzofurans methyl wutaifuranate, wutaifuranol, wutaifuranal, their 7-methoxy derivatives, and the O-prenylated natural products boropinols A and C.
| Author details: | Bernd SchmidtORCiDGND, Felix Wolf |
|---|---|
| DOI: | https://doi.org/10.1021/acs.joc.7b00447 |
| ISSN: | 0022-3263 |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/28394127 |
| Title of parent work (English): | The journal of organic chemistry |
| Publisher: | American Chemical Society |
| Place of publishing: | Washington |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2017 |
| Publication year: | 2017 |
| Release date: | 2020/04/20 |
| Volume: | 82 |
| Number of pages: | 10 |
| First page: | 4386 |
| Last Page: | 4395 |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
