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Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether

  • This study aims to explore the photoinitiated cationic ring-opening polymerization of levoglucosenyl methyl ether (LGME), a chemical obtained from the most abundant biomass - cellulose. Direct and sensitized photopolymerizations of LGME using photoinitiators acting at the near UV or visible range in conjunction with diphenyliodonium hexafluoroantimonate (DPI) yielded unsaturated polyacetals with varying molar masses and distributions.

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Metadaten
Author details:Kerem Kaya, Tapas DebsharmaORCiDGND, Helmut SchlaadORCiDGND, Yusuf YagciORCiD
DOI:https://doi.org/10.1039/d0py01307b
ISSN:1759-9954
ISSN:1759-9962
Title of parent work (English):Polymer Chemistry
Publisher:Royal Society of Chemistry
Place of publishing:Cambridge
Publication type:Article
Language:English
Date of first publication:2020/10/19
Publication year:2020
Release date:2024/01/12
Volume:11
Issue:43
Number of pages:6
First page:6884
Last Page:6889
Funding institution:Alexander von Humboldt Foundation through a Humboldt Research; AwardAlexander von Humboldt Foundation
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
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