Stereocontrolled synthesis of new tetrahydrofuro[2,3-d]thiazole derivatives via activated vinylogous iminium ions
- Heterocyclization of (Z)-5-(2-hydroxyethyl)-3-methyl-4-oxothiazolidines, bearing electron-withdrawing groups conjugated to an exocyclic double bond at C(2)-position, afforded under reductive conditions, cis-tetrahydroftiro[2,3- d]thiazole derivatives. The reactions of these functionalized push-pull beta-enamines occur in a stereocontrolled fashion via activated vinylogous N-methyliminium ions, which are trapped by an internal hydroxyethyl group
Author details: | Rade Markovic, Marija Baranac-StojanovicORCiD, Peter J. Steel, Erich KleinpeterORCiDGND |
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ISSN: | 0385-5414 |
Publication type: | Article |
Language: | English |
Year of first publication: | 2005 |
Publication year: | 2005 |
Release date: | 2017/03/24 |
Source: | Heterocycles. - ISSN 0385-5414. - 65 (2005), 11, S. 2635 - 2647 |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |