Photochemical synthesis and properties of 1,6- and 1,8-Naphthalenophanes
- Various 1,6- and 1,8-naphthalenophanes were synthesized by using the Photo-Dehydro-Diels-Alder (PDDA) reaction of bis-ynones. These compounds are easily accessible from omega-(3-iodophenyl)carboxylic acids in three steps. The obtained naphthalenophanes are axially chiral and the activation barrier for the atropisomerization could be determined in some cases by means of dynamic NMR (DNMR) and/or dynamic HPLC (DHPLC) experiments.
Author details: | Pablo WessigORCiDGND, Annika Matthes |
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URN: | urn:nbn:de:kobv:517-opus4-476675 |
DOI: | https://doi.org/10.25932/publishup-47667 |
ISSN: | 1866-8372 |
Title of parent work (German): | Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe |
Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (1042) |
Publication type: | Postprint |
Language: | English |
Date of first publication: | 2020/12/17 |
Publication year: | 2013 |
Publishing institution: | Universität Potsdam |
Release date: | 2020/12/17 |
Tag: | atropisomerism; dynamic HPLC; dynamic NMR; naphthalenophanes; photo-dehydro-Diels-Alder reaction |
Issue: | 1042 |
Number of pages: | 13 |
Source: | Molecules 18(2013) 1, 1314-1324; DOI: 10.3390/molecules18011314 |
Funding institution: | Deutsche Forschungsgemeinschaft (DFG) |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access / Green Open-Access |
License (German): | CC-BY - Namensnennung 4.0 International |
External remark: | Bibliographieeintrag der Originalveröffentlichung/Quelle |