Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal-organic frameworks with flexible ethoxy substituent
- A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H-2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.
Author details: | Suvendu Sekhar MondalORCiDGND, Subarna Dey, Igor A. Baburin, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen HoldtORCiD |
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DOI: | https://doi.org/10.1039/c3ce41632a |
ISSN: | 1466-8033 |
Title of parent work (English): | CrystEngComm |
Publisher: | Royal Society of Chemistry |
Place of publishing: | Cambridge |
Publication type: | Article |
Language: | English |
Year of first publication: | 2013 |
Publication year: | 2013 |
Release date: | 2017/03/26 |
Volume: | 15 |
Issue: | 45 |
Number of pages: | 6 |
First page: | 9394 |
Last Page: | 9399 |
Funding institution: | German Research Foundation on "Metal-Organic Frameworks" [1362] |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |