NMR spectroscopic and molecular modelling study of the solution structure and the complexational behavior of maleonitrile tetrathia crown ethers with silver(I)
- The flexibility and complex formation of two maleonitrile tetrathia crown ethers were studied in solution using H-1 and C-13 NMR spectroscopy and molecular modelling. Both the stoichiometry and the stability of the complexes that these crown ethers form with Ag(I) were determined by NMR titration measurements. Spin-lattice relaxation time measurements provided information concerning the donor atoms involved in complex formation and also the intramolecular mobility of the free and complexed ligands. Molecular modelling was also used to gain further insight into the conformational space of the free ligands and their silver(I) complexes. Copyright (C) 2004 John Wiley Sons, Ltd
Author details: | Anja Holzberger, H. N. Holdt, Erich KleinpeterORCiDGND |
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Publication type: | Article |
Language: | English |
Year of first publication: | 2004 |
Publication year: | 2004 |
Release date: | 2017/03/24 |
Source: | Journal of Physical Organic Chemistry. - 17 (2004), 3, S. 257 - 265 |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |